File name: Pandora176s1_Tsukuba-NIES_20241101_L2Fit_fwvt1c4d20240516p1-8.txt File generation date: 20250128T000319.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c4p1-8 Local principal investigator: Tamaki Fujinawa Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 176 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora176_OF_v3d20200605.txt Instrument calibration file used: Pandora176s1_CF_v4d20240516.txt Level 1 file used: Pandora176s1_Tsukuba-NIES_20241101_L1_smca1c4d20240516p1-8.txt Full location name: National Institute for Environmental Studies (NIES) Short location name: Tsukuba-NIES Country of location: Japan Location latitude [deg]: 36.0513 Location longitude [deg]: 140.1210 Location altitude [m]: 45 Local noon date: 20241101 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 3, but MLE correction for HCHO. First and last pixel inside fitting window: 1679 1828 Nominal wavelengths inside fitting window [nm]: 492.1082 492.2290 492.3498 492.4706 492.5914 492.7121 492.8328 492.9535 493.0742 493.1949 493.3156 493.4362 493.5569 493.6775 493.7981 493.9187 494.0392 494.1598 494.2803 494.4008 494.5213 494.6418 494.7623 494.8827 495.0032 495.1236 495.2440 495.3644 495.4847 495.6051 495.7254 495.8457 495.9660 496.0863 496.2065 496.3268 496.4470 496.5672 496.6874 496.8076 496.9278 497.0479 497.1680 497.2882 497.4082 497.5283 497.6484 497.7684 497.8885 498.0085 498.1285 498.2484 498.3684 498.4883 498.6083 498.7282 498.8481 498.9679 499.0878 499.2076 499.3275 499.4473 499.5671 499.6868 499.8066 499.9263 500.0460 500.1658 500.2854 500.4051 500.5248 500.6444 500.7640 500.8836 501.0032 501.1228 501.2423 501.3619 501.4814 501.6009 501.7204 501.8398 501.9593 502.0787 502.1981 502.3175 502.4369 502.5563 502.6756 502.7950 502.9143 503.0336 503.1529 503.2721 503.3914 503.5106 503.6298 503.7490 503.8682 503.9873 504.1065 504.2256 504.3447 504.4638 504.5829 504.7019 504.8210 504.9400 505.0590 505.1780 505.2970 505.4159 505.5349 505.6538 505.7727 505.8916 506.0104 506.1293 506.2481 506.3669 506.4857 506.6045 506.7233 506.8420 506.9608 507.0795 507.1982 507.3169 507.4355 507.5542 507.6728 507.7914 507.9100 508.0286 508.1471 508.2657 508.3842 508.5027 508.6212 508.7397 508.8581 508.9766 509.0950 509.2134 509.3318 509.4501 509.5685 509.6868 509.8051 509.9234 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20241031T213253.4Z 9070.897841 57 1 48.67 2 84.99 111.99 80.20 116.61 0.00 1 0.00 1 0 22 3.462e-03 3.436e-03 9.362e-04 9.336e-04 1.089266e+04 6.337270e+01 7.327301e+02 -6.000000e+00 1.906528e+02 285.59 -2.00 20.00 -2.00 505.40 0.00e+00 2.710667e-03 2.587296e-05 1.570621e-04 -6.000000e+00 9.709422e-05 285.59 -2.00 20.00 -2.00 500.76 0.00e+00 8.496188e-01 1.809744e-02 7.492953e-02 -6.000000e+00 6.784803e-02 225.31 -2.00 3.41 -2.00 502.34 0.00e+00 9.791 0.015 489.00 513.00 1 6.6880e+00 1.3834e-03 1.5934e-02 -6.0000e+00 5.1987e-03 -1.5149e-02 3.5366e-04 1.9353e-03 -6.0000e+00 1.3620e-03 5.3898e-04 -1.2060e-04 8.3197e-05 9.3203e-05 -6.0000e+00 3.2920e-04 1.5455e-02 -1.4789e-04 10 0 0 10 0 0 98.36 19.66 0.81 0.01546 0.01462 29 7 1 4 0 1678.090 26.21 20.00 19.66 16.92 17.1 988.17 -898 -331 78 -11 160 770 675 347 188 266 296 -458 -148 -393 -268 -230 -93 518 -57 205 330 148 247 294 332 353 264 253 -319 -131 -562 -432 -524 351 87 -73 57 -128 -348 -114 -135 -241 107 124 400 232 498 50 109 -231 -662 -549 -731 -410 -307 341 24 225 239 185 202 394 255 652 -3 43 113 -155 -244 -530 -279 -372 -482 34 -4 -207 -194 -438 -344 -348 -354 -444 -450 -66 -336 7 -487 -17 -212 392 -335 433 468 318 568 416 -210 -66 -288 -539 -668 -666 -575 -111 149 -278 -85 -179 -156 -294 -115 47 261 423 312 736 504 685 293 349 -44 12 118 134 2 154 479 -8 210 283 -40 -316 -38 -582 -273 77 85 45 38 113 110 219 169 255 277 298 -52 -174 -600 -470 -794 -299 73 -11 158 773 690 358 193 269 296 -454 -144 -380 -258 -223 -91 523 -59 214 345 156 259 311 329 350 261 264 -326 -130 -551 -427 -533 367 88 -74 57 -127 -342 -111 -133 -240 107 126 410 239 508 50 108 -224 -671 -544 -721 -410 -295 336 24 228 243 188 206 404 263 667 -4 43 112 -151 -236 -508 -265 -356 -467 33 -4 -203 -186 -414 -322 -324 -331 -419 -428 -63 -327 6 -478 -16 -205 379 -329 428 468 317 551 393 -193 -64 -270 -500 -621 -634 -532 -107 148 -280 -84 -177 -153 -293 -116 48 269 438 325 770 535 732 313 368 -46 13 119 136 2 158 492 -8 216 291 -41 -319 -38 -577 -272 77 87 47 41 122 113 225 176 265 288 307 -53 -185 -629 -493 SQ 20241031T214324.7Z 9070.905147 60 1 48.67 2 83.03 113.63 78.38 118.33 0.00 1 0.00 1 0 22 2.652e-03 2.643e-03 4.456e-04 4.448e-04 8.618596e+03 2.927347e+01 5.834903e+02 -6.000000e+00 1.460533e+02 285.59 -2.00 20.00 -2.00 505.37 0.00e+00 2.102531e-03 1.230568e-05 1.233430e-04 -6.000000e+00 7.437911e-05 285.59 -2.00 20.00 -2.00 500.76 0.00e+00 6.309755e-01 8.604426e-03 6.056463e-02 -6.000000e+00 5.196487e-02 225.31 -2.00 3.41 -2.00 502.32 0.00e+00 7.549 0.007 489.00 513.00 1 5.7676e+00 6.5789e-04 1.2320e-02 -6.0000e+00 3.9819e-03 -2.1665e-02 1.6904e-04 1.5382e-03 -6.0000e+00 1.0429e-03 1.9155e-03 1.9425e-04 4.0173e-05 7.6908e-05 -6.0000e+00 2.5217e-04 1.4489e-02 -1.2590e-04 10 0 0 10 0 0 75.99 19.67 0.73 0.01449 0.01584 65 15 1 4 0 748.720 26.21 20.00 19.67 17.01 17.1 989.11 -554 -311 89 69 226 524 555 347 416 235 75 -146 -228 -249 -270 -181 -71 301 84 99 133 168 190 305 275 309 269 22 -193 -255 -329 -531 -118 117 41 -9 20 -114 -276 -181 -187 -65 53 181 285 345 257 176 -25 -240 -325 -461 -535 -330 -234 4 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245 188 268 98 -79 -274 -371 -476 SQ 20241031T215332.5Z 9070.912181 63 1 42.54 2 81.16 115.24 76.66 120.04 0.00 1 0.00 1 0 15 2.688e-03 2.667e-03 6.646e-04 6.638e-04 7.390289e+03 4.316099e+01 5.031846e+02 -6.000000e+00 1.480419e+02 285.59 -2.00 20.00 -2.00 505.33 0.00e+00 1.852839e-03 1.831803e-05 1.075679e-04 -6.000000e+00 7.539269e-05 285.59 -2.00 20.00 -2.00 500.67 0.00e+00 5.010521e-01 1.287390e-02 5.162391e-02 -6.000000e+00 5.267707e-02 225.31 -2.00 3.41 -2.00 502.23 0.00e+00 6.155 0.004 489.00 513.00 1 6.6184e+00 9.8533e-04 1.0151e-02 -6.0000e+00 4.0364e-03 -1.1757e-02 2.5374e-04 1.2996e-03 -6.0000e+00 1.0573e-03 1.0124e-03 3.9662e-04 6.0323e-05 6.8330e-05 -6.0000e+00 2.5561e-04 1.3161e-02 -1.2384e-04 12 1 1 12 1 1 99.90 19.67 0.72 0.01316 0.01591 28 8 1 4 0 1466.590 26.21 20.00 19.67 17.23 17.1 989.76 -505 -413 91 59 249 538 505 356 397 267 121 -152 -253 -90 -335 -171 -114 445 -3 140 124 210 27 383 382 325 288 -77 -126 -337 -185 -558 -158 221 66 -34 31 -162 -266 -133 -222 -165 12 186 112 312 209 107 44 -288 -435 -496 -389 -289 -258 -12 147 24 181 146 189 136 237 443 157 73 114 -87 -217 -229 -164 -211 -392 147 -48 -116 -240 -358 -384 -418 -209 -473 -362 -149 -227 -294 -274 -272 -70 8 -110 278 265 246 313 313 -144 -142 -304 -370 -658 -447 -366 -75 -80 -47 -93 -193 -93 23 -125 125 262 393 469 513 577 405 299 211 181 50 177 82 38 116 347 158 291 216 -96 -141 -149 -318 -292 7 -3 -44 87 225 120 38 239 151 229 197 1 -216 -458 -440 -469 -389 88 58 248 541 513 364 403 269 121 -151 -249 -88 -327 -168 -113 447 -3 143 127 215 28 394 393 335 295 -78 -126 -331 -180 -549 -158 225 68 -35 32 -166 -270 -135 -225 -168 13 192 116 324 216 110 44 -288 -426 -480 -375 -281 -256 -12 150 25 186 149 193 140 244 455 160 74 114 -86 -214 -225 -160 -206 -388 146 -48 -115 -235 -347 -371 -403 -202 -459 -352 -145 -224 -292 -272 -269 -69 7 -110 278 267 247 311 305 -139 -134 -284 -342 -609 -420 -352 -74 -80 -47 -93 -191 -92 23 -126 126 266 400 478 525 594 419 308 215 183 50 176 81 38 117 348 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