File name: Pandora176s1_Tsukuba-NIES_20241212_L2Fit_fout2c2d20210908p1-8.txt File generation date: 20241213T000350.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Tamaki Fujinawa Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 176 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora176_OF_v3d20200605.txt Instrument calibration file used: Pandora176s1_CF_v2d20210908.txt Level 1 file used: Pandora176s1_Tsukuba-NIES_20241212_L1_smca1c2d20210908p1-8.txt Full location name: National Institute for Environmental Studies (NIES) Short location name: Tsukuba-NIES Country of location: Japan Location latitude [deg]: 36.0513 Location longitude [deg]: 140.1210 Location altitude [m]: 45 Local noon date: 20241212 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 256 398 Nominal wavelengths inside fitting window [nm]: 305.0235 305.1643 305.3051 305.4460 305.5867 305.7275 305.8683 306.0091 306.1498 306.2905 306.4313 306.5720 306.7127 306.8534 306.9941 307.1347 307.2754 307.4160 307.5567 307.6973 307.8379 307.9785 308.1191 308.2597 308.4002 308.5408 308.6813 308.8218 308.9624 309.1029 309.2434 309.3838 309.5243 309.6648 309.8052 309.9457 310.0861 310.2265 310.3669 310.5073 310.6477 310.7880 310.9284 311.0687 311.2091 311.3494 311.4897 311.6300 311.7703 311.9105 312.0508 312.1910 312.3313 312.4715 312.6117 312.7519 312.8921 313.0323 313.1725 313.3126 313.4528 313.5929 313.7330 313.8731 314.0132 314.1533 314.2934 314.4334 314.5735 314.7135 314.8535 314.9935 315.1335 315.2735 315.4135 315.5535 315.6934 315.8334 315.9733 316.1132 316.2531 316.3930 316.5329 316.6728 316.8126 316.9525 317.0923 317.2322 317.3720 317.5118 317.6516 317.7913 317.9311 318.0709 318.2106 318.3503 318.4900 318.6298 318.7694 318.9091 319.0488 319.1885 319.3281 319.4677 319.6074 319.7470 319.8866 320.0262 320.1657 320.3053 320.4449 320.5844 320.7239 320.8634 321.0030 321.1424 321.2819 321.4214 321.5609 321.7003 321.8397 321.9792 322.1186 322.2580 322.3974 322.5367 322.6761 322.8154 322.9548 323.0941 323.2334 323.3727 323.5120 323.6513 323.7906 323.9298 324.0691 324.2083 324.3475 324.4867 324.6259 324.7651 324.9043 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241211T221419.8Z 9111.926617 166 1 48.70 2 85.02 123.39 127.39 340.80 0.00 1 0.00 1 0 25 7.140e-01 7.187e-02 5.674e-01 6.866e-02 1.024974e+00 4.139390e-02 1.235133e-02 -6.000000e+00 4.170358e-01 223.75 -2.00 3.41 -2.00 322.14 0.00e+00 -2.755587e-02 1.384207e-02 5.153436e-04 -6.000000e+00 2.021181e-02 281.33 -2.00 20.00 -2.00 321.58 0.00e+00 9.853 0.015 302.00 328.00 3 2.5923e-01 1.3861e-01 1.1246e-01 -6.0000e+00 1.0253e+00 2.1104e+00 1.6177e-01 6.6663e-02 -6.0000e+00 1.1180e+00 -2.1956e+00 9.3018e-02 2.5153e-02 -6.0000e+00 6.6958e-01 7.4578e-01 5.3797e-02 2.1588e-02 -6.0000e+00 2.8921e-01 7.1818e-06 -1.3297e-03 1.8780e-03 3.3535e-04 -6.0000e+00 2.0498e-02 2.3269e-03 -3.4113e-05 12 8 8 10 0 0 -58.61 19.13 1.51 0.00233 -0.00767 27 6 1 5 0 1803.660 25.58 19.99 19.13 7.39 16.6 998.96 293837 52062 900000 -19435 -99605 -77661 -39518 246357 11581 -9341 131126 900000 -34913 1559 64515 219445 -15149 38624 173460 900000 -2580 11066 121277 2214 57477 -10751 900000 -71428 -61801 1197 -48959 61745 -29405 -31693 900000 140610 -31846 900000 36566 234998 33292 37123 -38458 900000 -39835 67428 280389 69698 900000 900000 16114 -5190 92867 49619 107863 39058 129392 26390 86843 30761 900000 126104 30921 31122 28348 263340 -23686 47301 2815 -6739 574 55537 49151 29373 9560 -26266 60882 -24798 21393 -30973 64818 21084 5883 -18937 54395 -32997 3837 18840 -1172 -4537 12395 -6418 -2416 -11769 -4263 16924 -2690 9116 -8922 -1364 3204 10616 10570 813 3310 -5005 -11667 -4995 7916 -5303 -3350 -8934 -1977 -4850 13641 -806 3390 1743 -619 -1030 -1586 8168 3234 442 -2502 7582 -5905 14049 -2384 2668 -1622 3682 -3165 1832 -3397 811 1152 1163 1111 -2440 -1087 -4099 5995 19638 3479 900000 -1840 -15362 -9083 -3301 16465 774 -832 8764 900000 -4278 139 4312 14666 -1772 2581 11593 900000 -216 740 8105 185 3841 -1257 900000 -12332 -7916 80 -5181 4127 -3112 -3851 900000 9397 -3289 900000 2666 15706 3439 3834 -8178 900000 -7019 4506 18739 4658 900000 900000 1566 -694 6207 4522 7209 4509 8648 3527 5804 3177 900000 8428 3194 3593 3617 17600 -5037 5173 530 -1597 140 8098 7466 4997 1742 -5905 5697 -4972 3288 -8656 9097 4868 1787 -7939 12724 -17642 1469 6296 -470 -1792 4225 -2262 -888 -4576 -1761 7352 -1520 5317 -6992 -1028 2200 6669 5863 473 1969 -3445 -9045 -3905 6084 -4930 -3562 -11291 -2475 -6335 15954 -1056 4237 2295 -878 -1515 -2300 10154 3999 546 -3111 8311 -7221 14648 -3394 4298 -3144 7529 -7530 4505 -9559 2336 3404 3473 3312 -7240 -2944 -10465 12981 SS 20241211T222451.8Z 9111.933933 169 1 48.49 2 83.26 125.06 127.96 343.78 0.00 1 0.00 1 0 25 4.290e-01 2.203e-02 3.896e-01 1.515e-02 9.529507e-01 8.844916e-03 1.027304e-02 -6.000000e+00 2.443646e-01 223.75 -2.00 3.41 -2.00 322.35 0.00e+00 6.152064e-03 5.180132e-03 6.724876e-03 -6.000000e+00 1.116682e-02 281.33 -2.00 20.00 -2.00 321.92 0.00e+00 7.772 0.007 302.00 328.00 3 4.0534e-01 3.5392e-02 1.0266e-01 -6.0000e+00 6.0132e-01 1.1756e+00 4.6577e-02 8.0975e-02 -6.0000e+00 6.5385e-01 -1.5017e+00 4.0024e-02 3.1073e-02 -6.0000e+00 3.8979e-01 5.9311e-01 1.8918e-02 1.1280e-02 -6.0000e+00 1.6740e-01 5.6496e-05 -2.2706e-03 4.1452e-04 1.3061e-04 -6.0000e+00 1.1720e-02 3.1661e-03 -9.0482e-05 12 8 8 10 0 0 0.22 19.13 0.47 0.00317 -0.01390 99 24 1 5 0 489.760 25.58 20.01 19.13 8.33 16.7 1007.16 -127336 -15002 -22479 -104496 -97153 900000 -105630 -46799 -157906 -3727 -143402 1811 900000 89129 -85598 49438 -19075 -30429 13791 -46676 8383 -11177 65415 -42717 57722 -22386 -30523 -82323 101259 -88347 175267 22942 44602 20209 -31050 21872 27902 44303 66525 29704 11725 62277 45309 89723 43746 32940 34041 47573 68446 12699 70089 36268 65700 31001 52282 25801 48083 26296 32392 26182 11016 -4941 5947 33747 18998 27911 1241 15634 13338 15845 12191 24558 11594 14067 7217 9289 14360 -4298 -1319 3444 3352 -2532 2022 3347 4764 -4149 -966 -8 1412 2614 5584 -844 783 -333 -5905 313 -5019 -1830 -1805 -490 -3263 -156 -3388 -2966 -3532 -6594 -458 -4316 651 -5380 -275 -1938 -729 -652 945 438 148 -2282 461 535 509 2364 2233 3211 1645 3624 -346 2104 287 1057 -241 1578 224 780 498 -171 606 -310 -661 -640 -436 -1090 -265 -4615 -222 -332 -3226 -2348 900000 -2269 -691 -5935 -55 -4620 27 900000 1316 -3332 730 -512 -980 296 -1817 180 -270 966 -1376 852 -601 -860 -3647 1495 -4151 2588 576 1054 657 -1459 614 742 1112 1572 1184 623 2115 1873 2385 1809 1508 1558 1967 2426 844 2898 2356 3493 2518 3628 2400 3621 2407 2631 2126 1025 -576 711 3538 2553 3503 185 2309 2005 2659 2357 4385 2319 2549 1375 1523 2057 -755 -255 703 828 -778 670 1177 1746 -1754 -414 -4 606 1074 2091 -317 283 -127 -2735 163 -3302 -1376 -1541 -432 -2839 -118 -2333 -1923 -2409 -4948 -342 -3621 581 -5929 -335 -2679 -1051 -944 1311 592 201 -3293 683 824 773 3345 2995 4134 2091 4393 -424 2605 416 1801 -477 3393 526 1961 1352 -497 1792 -935 -1993 -1860 -1173 -2702 -609 SS 20241211T223514.9Z 9111.941144 172 1 48.53 2 81.56 126.75 128.43 346.76 0.00 1 0.00 1 0 25 6.542e-01 1.276e-02 1.905e-01 5.159e-03 8.196625e-01 2.901204e-03 8.971833e-03 -6.000000e+00 3.710254e-01 223.75 -2.00 3.41 -2.00 321.99 0.00e+00 5.618120e-03 1.680275e-03 3.654940e-03 -6.000000e+00 1.650365e-02 281.33 -2.00 20.00 -2.00 321.52 0.00e+00 6.413 0.004 302.00 328.00 3 4.4535e-01 1.1211e-02 8.0900e-02 -6.0000e+00 9.1392e-01 4.1460e-01 1.6624e-02 5.7309e-02 -6.0000e+00 9.9363e-01 -5.6087e-01 1.7231e-02 2.5745e-02 -6.0000e+00 5.9338e-01 2.2589e-01 7.8349e-03 9.5827e-03 -6.0000e+00 2.5496e-01 2.5375e-04 -2.1453e-03 1.4389e-04 1.0786e-04 -6.0000e+00 1.7848e-02 3.1809e-03 -1.1231e-04 12 8 8 10 0 0 -4.22 19.13 0.25 0.00318 -0.01294 232 55 1 5 0 209.140 25.58 20.01 19.13 9.03 16.5 1009.71 -222381 -214116 -185300 -194537 -225689 -219152 -205485 -178464 -215713 -151308 -210228 -146187 -126862 -142806 -115806 -48658 -58321 -100277 -45442 -25983 -32130 -41175 -33267 -58437 588 -57015 -60204 -73341 -59015 -44223 -50687 -32282 9904 -21790 -30964 -3365 -19361 -1558 12772 32997 -8131 11817 3100 10224 14475 21805 11874 17466 18224 9588 24457 23728 25225 13336 16869 8795 19523 11256 7807 10015 9821 16621 12838 18073 11238 13110 5696 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