File name: Pandora176s1_Tsukuba-NIES_20250102_L2Fit_fout2c4d20240516p1-8.txt File generation date: 20250128T002714.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Tamaki Fujinawa Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 176 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora176_OF_v3d20200605.txt Instrument calibration file used: Pandora176s1_CF_v4d20240516.txt Level 1 file used: Pandora176s1_Tsukuba-NIES_20250102_L1_smca1c4d20240516p1-8.txt Full location name: National Institute for Environmental Studies (NIES) Short location name: Tsukuba-NIES Country of location: Japan Location latitude [deg]: 36.0513 Location longitude [deg]: 140.1210 Location altitude [m]: 45 Local noon date: 20250102 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 3, but MLE correction for HCHO. First and last pixel inside fitting window: 256 398 Nominal wavelengths inside fitting window [nm]: 305.0215 305.1624 305.3032 305.4440 305.5848 305.7256 305.8664 306.0072 306.1480 306.2888 306.4295 306.5702 306.7110 306.8517 306.9924 307.1331 307.2737 307.4144 307.5551 307.6957 307.8363 307.9770 308.1176 308.2582 308.3987 308.5393 308.6799 308.8204 308.9610 309.1015 309.2420 309.3825 309.5230 309.6635 309.8039 309.9444 310.0848 310.2253 310.3657 310.5061 310.6465 310.7869 310.9272 311.0676 311.2079 311.3483 311.4886 311.6289 311.7692 311.9095 312.0498 312.1901 312.3303 312.4706 312.6108 312.7510 312.8912 313.0314 313.1716 313.3118 313.4519 313.5921 313.7322 313.8723 314.0124 314.1526 314.2926 314.4327 314.5728 314.7128 314.8529 314.9929 315.1329 315.2729 315.4129 315.5529 315.6929 315.8329 315.9728 316.1127 316.2527 316.3926 316.5325 316.6724 316.8122 316.9521 317.0920 317.2318 317.3716 317.5115 317.6513 317.7911 317.9308 318.0706 318.2104 318.3501 318.4899 318.6296 318.7693 318.9090 319.0487 319.1884 319.3280 319.4677 319.6073 319.7469 319.8866 320.0262 320.1658 320.3053 320.4449 320.5845 320.7240 320.8635 321.0031 321.1426 321.2821 321.4216 321.5610 321.7005 321.8400 321.9794 322.1188 322.2582 322.3976 322.5370 322.6764 322.8158 322.9551 323.0945 323.2338 323.3731 323.5124 323.6517 323.7910 323.9303 324.0696 324.2088 324.3481 324.4873 324.6265 324.7657 324.9049 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250101T222349.8Z 9132.933215 55 1 48.90 2 85.03 123.15 105.64 107.44 0.00 1 0.00 1 0 17 5.250e-01 5.013e-02 5.439e-01 5.624e-02 9.142098e-01 3.262416e-02 9.848630e-03 -6.000000e+00 3.004612e-01 223.98 -2.00 3.41 -2.00 322.20 0.00e+00 -1.314272e-02 1.373759e-02 4.079615e-03 -6.000000e+00 1.444456e-02 280.14 -2.00 20.00 -2.00 321.69 0.00e+00 9.864 0.015 302.00 328.00 3 4.9774e-01 1.1588e-01 1.1335e-01 -6.0000e+00 7.3888e-01 1.7909e+00 1.3552e-01 6.5931e-02 -6.0000e+00 8.0371e-01 -1.9959e+00 8.4046e-02 2.3884e-02 -6.0000e+00 4.7907e-01 7.0332e-01 4.6303e-02 1.2391e-02 -6.0000e+00 2.0855e-01 7.0906e-06 1.0105e-03 1.5817e-03 1.2990e-04 -6.0000e+00 1.4976e-02 -9.5590e-04 0.0000e+00 12 8 8 10 0 0 32.34 19.02 1.26 -0.00096 0.00664 35 8 1 5 0 1396.950 25.47 19.99 19.02 5.61 16.4 998.66 900000 -610 -13061 75662 -35294 900000 -6166 2107 -21543 141956 -54170 900000 11659 201783 -1858 32529 -2821 14057 179172 63911 5193 128489 -29136 -64040 900000 5133 137735 124001 900000 -13472 -4962 -49249 204447 46097 4136 -29960 4040 900000 -58790 58706 68790 100834 24259 133781 -50295 -10086 -48559 63496 65470 900000 25788 -17793 107057 -27419 68401 59780 114881 -38248 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-5313 -2052 -4834 -6828 2388 3184 -3005 -6023 -172 -283 3417 -2436 -3351 -8239 2208 2471 -266 1208 -703 1156 2848 3462 -4551 1894 2361 3985 -4741 3631 -2520 7317 -4835 89 1941 224 1039 -3672 -2155 1088 4365 -47 2601 -8082 4609 -402 -859 SS 20250101T223426.5Z 9132.940585 58 1 48.61 2 83.25 124.83 103.66 108.76 0.00 1 0.00 1 0 25 5.620e-01 2.286e-02 3.328e-01 1.207e-02 8.477138e-01 7.025447e-03 9.153763e-03 -6.000000e+00 3.223825e-01 223.98 -2.00 3.41 -2.00 322.22 0.00e+00 9.790199e-03 4.034861e-03 2.368065e-03 -6.000000e+00 1.583566e-02 280.14 -2.00 20.00 -2.00 321.78 0.00e+00 7.761 0.007 302.00 328.00 3 5.5524e-01 2.7392e-02 9.1458e-02 -6.0000e+00 7.9472e-01 8.9891e-01 3.6850e-02 5.6135e-02 -6.0000e+00 8.6483e-01 -1.2046e+00 3.3482e-02 2.5005e-02 -6.0000e+00 5.1660e-01 4.9102e-01 1.5698e-02 1.1536e-02 -6.0000e+00 2.2316e-01 5.8648e-05 -2.1571e-03 3.5123e-04 1.4271e-04 -6.0000e+00 1.5548e-02 -1.6119e-03 0.0000e+00 12 8 8 10 0 0 49.90 19.02 0.37 -0.00161 -0.01782 126 30 1 5 0 385.740 25.47 20.01 19.02 5.86 16.6 1002.27 -152495 900000 -65261 57569 -109896 -104913 114221 -155889 -90598 -156441 900000 -134487 900000 -93765 85273 -68681 900000 -13049 39166 11329 25182 -2263 -87429 137250 -64057 900000 -101430 292706 -28608 900000 -44006 194060 -38212 86712 1455 -3096 90826 -13495 102981 13194 78524 6077 84871 17507 54237 -10072 93362 29436 45251 47209 26642 22809 42411 54730 16481 56586 21388 53248 19470 35491 1202 27344 15973 15109 20468 13075 29094 7553 18187 5838 23678 8471 22973 354 16866 -141 1859 4016 1937 8567 -3191 10368 -3780 8078 -4793 7554 -1089 4533 -2034 599 -1561 -2035 -2260 -3001 -3509 -5383 1350 -3783 -695 -4269 -860 -3696 -730 -1938 -4173 -3511 -3692 -1842 -1725 -935 -3493 384 -1452 997 -1376 1788 -205 1038 114 -336 642 2000 2049 471 2053 1482 3595 1186 1372 -226 1226 -133 1208 -26 325 -198 168 317 -859 -111 -962 449 -1519 -5230 900000 -1151 677 -2477 -1953 1343 -4583 -1421 -4753 900000 -3427 900000 -2573 1003 -2288 900000 -335 628 242 458 -51 -4027 1614 -2385 900000 -5367 3442 -734 900000 -1647 2282 -1961 1390 53 -109 1262 -592 1651 607 2099 357 2359 973 2087 -743 2495 1542 2129 2322 1766 1756 2947 3628 1691 3993 2172 3871 1894 2808 134 2514 1878 2067 2932 2055 3857 1169 2994 1138 4316 1893 4412 80 3191 -28 332 704 387 1932 -894 2967 -1404 2866 -2048 3028 -500 2039 -983 275 -690 -848 -910 -1253 -1657 -3070 858 -2973 -601 -4016 -753 -3014 -513 -1308 -3022 -2704 -3014 -1590 -1649 -1018 -4484 526 -2121 1421 -1943 2356 -274 1428 168 -519 982 2893 2820 639 2660 1875 4711 1628 1952 -383 2327 -282 2697 -64 841 -549 478 911 -2503 -311 -2544 1082 -3510 SS 20250101T224450.4Z 9132.947806 61 1 48.45 2 81.54 126.52 101.74 110.07 0.00 1 0.00 1 0 25 5.665e-01 1.147e-02 1.667e-01 4.207e-03 7.382823e-01 2.332330e-03 8.081103e-03 -6.000000e+00 3.219041e-01 223.98 -2.00 3.41 -2.00 321.81 0.00e+00 7.761462e-03 1.282698e-03 1.702581e-03 -6.000000e+00 1.423470e-02 280.14 -2.00 20.00 -2.00 321.33 0.00e+00 6.399 0.004 302.00 328.00 3 5.1907e-01 8.6281e-03 7.5893e-02 -6.0000e+00 7.9365e-01 3.1466e-01 1.2402e-02 4.6391e-02 -6.0000e+00 8.6258e-01 -4.2482e-01 1.2883e-02 2.1897e-02 -6.0000e+00 5.1469e-01 1.7322e-01 5.9613e-03 1.0989e-02 -6.0000e+00 2.2100e-01 2.6505e-04 -1.1728e-03 1.2108e-04 1.1855e-04 -6.0000e+00 1.5449e-02 -2.0927e-03 0.0000e+00 12 8 8 10 0 0 31.79 19.02 0.25 -0.00209 -0.01091 301 72 1 5 0 160.950 25.47 20.00 19.02 6.68 16.6 1009.70 -225469 51496 -189738 -142027 -218043 -205909 -176976 -153627 -169953 -175668 -156317 -167517 -96540 -75714 -73321 -78528 -41912 -51690 -40284 -81101 -35100 -36508 -61332 -42266 -62318 -8033 -62510 -35686 -67930 6764 -49068 -3745 -21883 26188 -13537 -7325 -22608 -6305 11534 3796 21643 10263 20040 6807 17755 11464 15422 2087 10478 7718 8469 14575 9730 18463 11571 16944 11004 10754 1048 10229 4830 12568 8506 10377 6127 8149 6158 2290 7464 5862 4859 2052 4143 369 1470 -1793 946 -4056 -654 508 276 361 -1644 -775 -1978 114 -1265 1087 -1322 -216 -713 790 -1044 -289 -715 -1149 -395 188 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