File name: Pandora176s1_Tsukuba-NIES_20250110_L2Fit_fout2c2d20210908p1-8.txt File generation date: 20250111T001200.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Tamaki Fujinawa Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 176 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora176_OF_v3d20200605.txt Instrument calibration file used: Pandora176s1_CF_v2d20210908.txt Level 1 file used: Pandora176s1_Tsukuba-NIES_20250110_L1_smca1c2d20210908p1-8.txt Full location name: National Institute for Environmental Studies (NIES) Short location name: Tsukuba-NIES Country of location: Japan Location latitude [deg]: 36.0513 Location longitude [deg]: 140.1210 Location altitude [m]: 45 Local noon date: 20250110 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 256 398 Nominal wavelengths inside fitting window [nm]: 305.0235 305.1643 305.3051 305.4460 305.5867 305.7275 305.8683 306.0091 306.1498 306.2905 306.4313 306.5720 306.7127 306.8534 306.9941 307.1347 307.2754 307.4160 307.5567 307.6973 307.8379 307.9785 308.1191 308.2597 308.4002 308.5408 308.6813 308.8218 308.9624 309.1029 309.2434 309.3838 309.5243 309.6648 309.8052 309.9457 310.0861 310.2265 310.3669 310.5073 310.6477 310.7880 310.9284 311.0687 311.2091 311.3494 311.4897 311.6300 311.7703 311.9105 312.0508 312.1910 312.3313 312.4715 312.6117 312.7519 312.8921 313.0323 313.1725 313.3126 313.4528 313.5929 313.7330 313.8731 314.0132 314.1533 314.2934 314.4334 314.5735 314.7135 314.8535 314.9935 315.1335 315.2735 315.4135 315.5535 315.6934 315.8334 315.9733 316.1132 316.2531 316.3930 316.5329 316.6728 316.8126 316.9525 317.0923 317.2322 317.3720 317.5118 317.6516 317.7913 317.9311 318.0709 318.2106 318.3503 318.4900 318.6298 318.7694 318.9091 319.0488 319.1885 319.3281 319.4677 319.6074 319.7470 319.8866 320.0262 320.1657 320.3053 320.4449 320.5844 320.7239 320.8634 321.0030 321.1424 321.2819 321.4214 321.5609 321.7003 321.8397 321.9792 322.1186 322.2580 322.3974 322.5367 322.6761 322.8154 322.9548 323.0941 323.2334 323.3727 323.5120 323.6513 323.7906 323.9298 324.0691 324.2083 324.3475 324.4867 324.6259 324.7651 324.9043 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250109T222336.8Z 9140.933065 166 1 48.97 2 85.01 121.86 120.19 350.17 0.00 1 0.00 1 0 25 7.252e-01 5.480e-02 5.786e-01 5.248e-02 1.139938e+00 3.168637e-02 1.348936e-02 -6.000000e+00 4.141917e-01 224.12 -2.00 3.41 -2.00 322.50 0.00e+00 -3.316546e-02 1.407126e-02 2.872986e-03 -6.000000e+00 2.089821e-02 279.73 -2.00 20.00 -2.00 322.06 0.00e+00 9.847 0.015 302.00 328.00 3 -6.8964e-02 1.1797e-01 1.2283e-01 -6.0000e+00 1.0188e+00 2.0592e+00 1.3766e-01 9.6230e-02 -6.0000e+00 1.1088e+00 -2.4302e+00 8.6242e-02 2.9583e-02 -6.0000e+00 6.6173e-01 8.8650e-01 4.8744e-02 2.6706e-02 -6.0000e+00 2.8648e-01 1.0268e-05 5.9521e-05 1.3572e-03 4.0358e-04 -6.0000e+00 2.0347e-02 1.1707e-03 -5.0459e-05 12 8 8 10 0 0 30.76 19.01 1.05 0.00117 0.00162 45 11 1 5 0 1087.980 25.47 20.00 19.01 5.82 16.6 1001.91 900000 90786 63063 127321 -7086 -108813 -96841 155680 240167 -55359 142092 900000 900000 64588 -20069 47048 87253 263494 189289 2214 171895 24527 -48227 141582 900000 -50949 900000 111108 900000 -71463 -33136 4490 133576 -104003 -26777 -2228 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3766 2091 4314 1783 8930 -1020 3827 -3303 1768 1189 -1596 -360 -4539 1406 8830 975 -1876 9269 5946 -413 7885 3646 1102 -2788 -1610 -2447 -1873 -3163 -4550 -1132 -7857 8006 8448 1009 7785 -2142 -2120 -3066 -8722 -6673 -3076 1416 -8454 3098 2669 -900 2161 4551 -3022 -3933 8501 5996 -9968 -2244 2745 202 7072 -2883 -2380 -1032 3950 11079 6351 -940 -4972 -4099 -1394 -615 1639 -3183 662 1536 2930 -3851 -456 2533 SS 20250109T223415.0Z 9140.940452 169 1 48.48 2 83.20 123.54 120.46 352.84 0.00 1 0.00 1 0 25 5.502e-01 2.350e-02 3.337e-01 1.105e-02 1.021726e+00 6.679337e-03 1.115989e-02 -6.000000e+00 3.189007e-01 224.12 -2.00 3.41 -2.00 322.49 0.00e+00 1.362974e-02 4.014455e-03 1.622076e-02 -6.000000e+00 1.465078e-02 279.73 -2.00 20.00 -2.00 322.09 0.00e+00 7.720 0.007 302.00 328.00 3 -1.0476e-01 2.7003e-02 1.4107e-01 -6.0000e+00 7.8981e-01 1.4554e+00 3.4224e-02 1.4846e-01 -6.0000e+00 8.6167e-01 -1.8892e+00 2.8867e-02 4.1746e-02 -6.0000e+00 5.0954e-01 7.5655e-01 1.4021e-02 1.7976e-02 -6.0000e+00 2.1706e-01 8.5911e-05 -3.1662e-03 3.0135e-04 1.6784e-04 -6.0000e+00 1.5449e-02 1.8626e-03 -1.2318e-04 12 8 8 10 0 0 -5.91 19.01 0.38 0.00186 -0.02193 154 37 1 5 0 314.750 25.47 20.01 19.01 6.71 16.6 1008.39 196010 -39431 900000 -33330 900000 -114144 900000 -130077 900000 -109422 -75392 -27833 104274 45515 -35992 39043 -13518 900000 -12098 900000 -51070 200136 -43712 96357 -19764 48351 4377 29075 53658 -57502 900000 -31108 159893 -18294 259157 -47326 126270 -7126 55578 43890 73567 90388 97115 53992 15901 105124 -21473 100907 6363 59002 10237 113407 32762 59626 62181 54673 59265 32319 56203 9671 78572 -6871 62878 6264 48658 5604 42784 14456 35585 18608 24865 31394 21069 14753 -4001 14711 -11463 13015 -16741 18378 -277 10740 806 5154 7743 355 8060 -603 5979 -5214 3713 -6096 2438 -8479 583 -6289 -1576 -2544 -925 -45 -167 1586 -3781 1324 -8073 -2281 -6417 -1696 -3973 -1085 -2825 -1857 -1046 -253 -123 -904 664 -2130 772 -1253 1663 301 3633 1160 2864 2188 4221 2703 867 1511 -143 1140 -255 790 -527 439 -307 763 -683 428 -465 -1193 -1314 2109 -1273 900000 -926 900000 -4810 900000 -5364 900000 -3639 -1696 -408 1122 534 -1232 764 -502 900000 -485 900000 -2747 2153 -1796 1037 -599 709 94 455 693 -2193 900000 -1399 1720 -912 2788 -2685 1358 -286 1495 1374 2058 2237 2299 1975 762 2262 -1512 2388 373 2412 681 3294 2115 3149 3345 3208 3304 2276 3205 747 3297 -659 3788 704 3997 729 3850 1796 3898 2748 3818 4698 3421 2352 -681 1813 -1682 1527 -3029 2876 -64 2605 244 1608 2476 128 2814 -236 2187 -2065 1264 -2152 772 -3151 228 -3186 -922 -1789 -733 -37 -134 1118 -2456 761 -5290 -1504 -4663 -1274 -3431 -1067 -3313 -2436 -1448 -352 -167 -1205 871 -2995 1114 -1914 2428 421 4619 1464 3456 2590 4768 3207 1212 2509 -279 2452 -601 1991 -1450 1270 -919 2272 -2056 1225 -1240 -2917 -2984 SS 20250109T224436.4Z 9140.947644 172 1 48.45 2 81.48 125.22 120.64 355.45 0.00 1 0.00 1 0 25 6.436e-01 1.317e-02 1.797e-01 4.208e-03 9.017230e-01 2.410512e-03 9.774041e-03 -6.000000e+00 3.655450e-01 224.12 -2.00 3.41 -2.00 322.17 0.00e+00 7.199141e-03 1.422213e-03 5.812432e-03 -6.000000e+00 1.612996e-02 279.73 -2.00 20.00 -2.00 321.73 0.00e+00 6.357 0.004 302.00 328.00 3 1.9052e-02 9.4762e-03 8.8134e-02 -6.0000e+00 9.0167e-01 5.7744e-01 1.4224e-02 7.3287e-02 -6.0000e+00 9.8029e-01 -7.6992e-01 1.4980e-02 3.0659e-02 -6.0000e+00 5.8468e-01 3.1202e-01 6.7923e-03 1.0875e-02 -6.0000e+00 2.5069e-01 3.6073e-04 -2.4185e-03 1.1506e-04 1.2580e-04 -6.0000e+00 1.7559e-02 1.4645e-03 -1.3202e-04 12 9 8 11 8 0 4.65 19.01 0.26 0.00146 -0.01671 344 82 1 5 0 140.820 25.47 20.00 19.01 7.37 16.5 1012.09 -160724 -210355 -162575 -231323 -183313 -239194 -110191 -224922 -160520 -200331 -186910 -175775 -179153 -101425 -104006 -75207 -115210 -41344 -45523 -18674 -85723 -47429 -85612 -20495 -62164 -44384 -20700 -55947 -63976 -66098 -18727 -42844 7176 -13626 20687 -37721 4381 -18100 25350 20002 33278 13841 11127 28757 -8934 16081 12904 25566 1892 28359 22467 27052 24362 26286 32741 24847 21016 11461 15862 3471 9959 5315 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