File name: Pandora176s1_Tsukuba-NIES_20250520_L2Fit_fout2c4d20240516p1-8.txt File generation date: 20250520T145052.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Tamaki Fujinawa Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 176 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora176_OF_v3d20200605.txt Instrument calibration file used: Pandora176s1_CF_v4d20240516.txt Level 1 file used: Pandora176s1_Tsukuba-NIES_20250520_L1_smca1c4d20240516p1-8.txt Full location name: National Institute for Environmental Studies (NIES) Short location name: Tsukuba-NIES Country of location: Japan Location latitude [deg]: 36.0513 Location longitude [deg]: 140.1210 Location altitude [m]: 45 Local noon date: 20250520 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 256 398 Nominal wavelengths inside fitting window [nm]: 305.0215 305.1624 305.3032 305.4440 305.5848 305.7256 305.8664 306.0072 306.1480 306.2888 306.4295 306.5702 306.7110 306.8517 306.9924 307.1331 307.2737 307.4144 307.5551 307.6957 307.8363 307.9770 308.1176 308.2582 308.3987 308.5393 308.6799 308.8204 308.9610 309.1015 309.2420 309.3825 309.5230 309.6635 309.8039 309.9444 310.0848 310.2253 310.3657 310.5061 310.6465 310.7869 310.9272 311.0676 311.2079 311.3483 311.4886 311.6289 311.7692 311.9095 312.0498 312.1901 312.3303 312.4706 312.6108 312.7510 312.8912 313.0314 313.1716 313.3118 313.4519 313.5921 313.7322 313.8723 314.0124 314.1526 314.2926 314.4327 314.5728 314.7128 314.8529 314.9929 315.1329 315.2729 315.4129 315.5529 315.6929 315.8329 315.9728 316.1127 316.2527 316.3926 316.5325 316.6724 316.8122 316.9521 317.0920 317.2318 317.3716 317.5115 317.6513 317.7911 317.9308 318.0706 318.2104 318.3501 318.4899 318.6296 318.7693 318.9090 319.0487 319.1884 319.3280 319.4677 319.6073 319.7469 319.8866 320.0262 320.1658 320.3053 320.4449 320.5845 320.7240 320.8635 321.0031 321.1426 321.2821 321.4216 321.5610 321.7005 321.8400 321.9794 322.1188 322.2582 322.3976 322.5370 322.6764 322.8158 322.9551 323.0945 323.2338 323.3731 323.5124 323.6517 323.7910 323.9303 324.0696 324.2088 324.3481 324.4873 324.6265 324.7657 324.9049 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250519T202412.1Z 9270.850140 189 1 48.91 2 80.71 72.02 54.02 179.45 0.00 1 0.00 1 0 17 4.533e-01 2.646e-02 3.646e-01 1.951e-02 7.541654e-01 1.147724e-02 8.333384e-03 -6.000000e+00 2.696426e-01 231.51 -2.00 3.41 -2.00 321.80 0.00e+00 1.081410e-02 5.996341e-03 1.225269e-03 -6.000000e+00 1.255167e-02 286.77 -2.00 20.00 -2.00 321.26 0.00e+00 5.883 0.003 302.00 328.00 3 3.4277e+00 4.2645e-02 7.3058e-02 -6.0000e+00 6.7702e-01 7.2186e-01 5.6135e-02 4.9568e-02 -6.0000e+00 7.3418e-01 -9.1323e-01 4.7067e-02 2.1056e-02 -6.0000e+00 4.3535e-01 3.6805e-01 2.2096e-02 1.4538e-02 -6.0000e+00 1.8413e-01 1.9743e-05 -1.8032e-03 5.7176e-04 1.6965e-04 -6.0000e+00 1.2705e-02 -5.2087e-03 0.0000e+00 12 9 8 11 8 0 39.31 19.99 0.54 -0.00521 -0.01876 20 5 1 5 0 2445.120 26.51 20.00 19.99 21.83 17.9 976.55 13815 -112724 900000 -72348 900000 -180716 900000 -159050 -31735 -111831 -128305 21184 56458 900000 -85101 900000 7940 900000 -44587 900000 21907 900000 11170 900000 108320 151155 -61635 -47831 -82389 -39670 -12281 900000 31575 -35645 6697 25043 120954 9401 -18108 6023 175110 -9474 30070 90989 55181 31630 55971 55787 24661 3452 32074 82830 8318 4280 32247 56183 19733 5743 16929 7926 36524 15962 60363 14765 29900 17085 5441 -190 9211 1493 4689 4410 14564 19211 3352 19319 -1997 2539 -8535 3616 -8218 -303 381 1352 -6324 854 -4435 -34 -1552 -1046 -636 3625 5001 2542 -2059 -8078 1120 -4053 501 -2297 -159 -560 -801 -801 -2733 -185 -5136 -378 -2896 2206 -3506 -33 -2819 -1225 -1489 2317 50 -1562 2237 -959 2132 3100 1999 -102 2812 -208 3180 1619 2319 -224 -55 335 924 915 262 966 -90 403 -918 -142 -941 -1759 -474 262 -3405 900000 -1539 900000 -8501 900000 -5956 -603 -2819 -3758 402 1072 900000 -3446 900000 181 900000 -1934 900000 516 900000 270 900000 2057 2871 -3045 -2003 -4665 -1572 -436 900000 1042 -2417 297 877 2297 432 -1259 388 3325 -837 1910 3333 2866 2080 2986 3062 1892 341 2623 4640 1028 590 3590 5113 2569 846 2165 1071 3783 2161 6041 2588 4933 3218 1121 -42 1989 393 1334 1330 3983 4773 889 3948 -458 552 -2258 1004 -3039 -120 167 628 -3342 448 -2578 -20 -918 -603 -345 1768 2300 1209 -1128 -5454 811 -3576 476 -2337 -153 -493 -637 -609 -2228 -157 -4835 -363 -3113 2544 -4815 -48 -4345 -1840 -2157 3111 68 -2238 3270 -1518 3303 4610 2880 -145 3777 -279 3979 2081 3288 -373 -102 672 1952 2049 630 2447 -237 1074 -2489 -373 -2356 -4151 -1048 SS 20250519T203401.1Z 9270.856957 194 1 48.61 2 78.81 73.36 54.01 182.29 0.00 1 0.00 1 0 17 4.387e-01 1.550e-02 2.453e-01 7.285e-03 6.651449e-01 4.084823e-03 7.456319e-03 -6.000000e+00 2.596758e-01 231.51 -2.00 3.41 -2.00 321.47 0.00e+00 8.466844e-03 2.078153e-03 6.644332e-04 -6.000000e+00 1.167349e-02 286.77 -2.00 20.00 -2.00 320.89 0.00e+00 4.972 0.002 302.00 328.00 3 3.0286e+00 1.4688e-02 6.1032e-02 -6.0000e+00 6.5117e-01 2.7392e-01 1.9618e-02 3.7018e-02 -6.0000e+00 7.0367e-01 -3.5391e-01 1.8306e-02 1.9850e-02 -6.0000e+00 4.1587e-01 1.3885e-01 8.7048e-03 1.1400e-02 -6.0000e+00 1.7595e-01 8.3888e-05 -9.6799e-04 2.1383e-04 1.3031e-04 -6.0000e+00 1.2322e-02 -5.3335e-03 0.0000e+00 12 8 8 10 0 0 78.83 19.99 0.42 -0.00533 -0.01261 54 13 1 5 0 900.020 26.51 19.99 19.99 22.25 18.2 981.11 -118281 -187815 -6203 -181379 900000 -205703 900000 -142081 900000 -137852 -91181 -47100 -24127 -70925 -75265 -58836 -63039 -3278 -54740 60579 -57048 49820 -53636 158727 -21066 2573 -26545 -31775 24788 -21130 34836 -32175 1005 -26636 57054 -58397 30090 -5538 34018 4009 21724 19742 26 14865 1213 38031 -3443 16694 1770 41273 -730 34243 8821 17626 5931 18205 1697 1740 10003 -70 10788 2660 15906 1105 8218 -3073 12524 1347 6094 -213 6553 6462 3286 1937 -3169 1237 -5169 828 -7608 2505 -2709 2963 -1959 -1244 -3019 -100 -183 -664 471 -1551 782 -2201 1158 -3533 1496 -2825 123 -313 602 -1406 346 -77 -616 933 -2677 -1695 -1789 -287 -2125 863 -848 -353 -438 594 -282 1023 471 -30 282 -547 344 5 2084 -1170 1137 569 1852 1735 966 241 820 640 179 122 -124 -274 -662 566 -702 -169 -313 117 -448 -1145 -4271 -44 -4290 900000 -5268 900000 -2162 900000 -2334 -1020 -373 -189 -1132 -1597 -1303 -1670 -55 -1611 631 -1862 587 -1683 1127 -535 54 -750 -931 421 -585 660 -1386 37 -1398 1353 -3939 923 -271 1366 253 1310 1310 2 1136 108 2452 -338 1394 178 3017 -87 3247 1169 2324 929 2625 294 302 1570 -12 1679 484 2884 262 1963 -822 2815 340 1581 -67 2157 2258 1191 681 -1085 367 -1499 224 -2414 846 -1134 1348 -1037 -699 -1831 -63 -122 -462 327 -1077 502 -1358 658 -2104 926 -2099 103 -302 640 -1575 367 -75 -548 794 -2489 -1666 -1853 -311 -2541 1117 -1240 -552 -701 925 -422 1448 662 -44 436 -896 566 7 3162 -1778 1635 795 2464 2333 1438 407 1520 1274 376 270 -291 -683 -1704 1467 -1850 -435 -768 270 -996 SS 20250519T203946.0Z 9270.860949 197 1 48.74 2 77.69 74.14 54.05 183.94 0.00 1 0.00 1 0 25 3.707e-01 8.075e-03 2.281e-01 4.681e-03 6.186129e-01 2.582634e-03 6.879724e-03 -6.000000e+00 2.182206e-01 231.51 -2.00 3.41 -2.00 321.24 0.00e+00 4.259822e-03 1.241161e-03 7.633081e-04 -6.000000e+00 9.635074e-03 286.77 -2.00 20.00 -2.00 320.64 0.00e+00 4.555 0.001 302.00 328.00 3 2.8383e+00 8.9548e-03 5.5916e-02 -6.0000e+00 5.4621e-01 9.7263e-02 1.2117e-02 3.3120e-02 -6.0000e+00 5.8976e-01 -1.2730e-01 1.1668e-02 1.7967e-02 -6.0000e+00 3.5024e-01 4.5614e-02 5.5726e-03 7.4806e-03 -6.0000e+00 1.4855e-01 1.6491e-04 -7.1017e-04 1.3835e-04 8.4635e-05 -6.0000e+00 1.0186e-02 -4.8839e-03 0.0000e+00 11 9 0 11 8 0 98.72 20.00 0.26 -0.00488 -0.01022 87 21 1 5 0 560.150 26.51 20.00 20.00 22.68 18.2 984.20 -180109 627 -79286 -124124 -22062 -139467 900000 -133217 -59649 -118876 -7693 -121429 185032 -63220 57078 -53963 -45818 -41464 -10601 22541 -34928 39121 -68350 4491 -29046 11387 -31318 -5764 -27877 7885 -18423 -1758 3137 -10565 -13632 -23490 -7594 -8274 8733 -7784 13382 -4012 1268 2897 3999 6831 4222 1332 4140 3085 3261 8064 3374 9379 4457 5041 -573 3194 -2329 1998 461 4039 3223 3033 2124 1862 3462 -195 2473 687 2572 1464 1248 19 262 -730 -953 -1590 -1441 341 -1540 656 -2917 118 -1768 -61 -1528 71 -104 642 -364 498 784 -622 927 -1000 207 350 20 -1181 213 -1168 537 274 -830 -1633 -802 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