File name: Pandora176s1_Tsukuba-NIES_20250609_L2Fit_fout2c4d20240516p1-8.txt File generation date: 20250609T145225.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Tamaki Fujinawa Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 176 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora176_OF_v3d20200605.txt Instrument calibration file used: Pandora176s1_CF_v4d20240516.txt Level 1 file used: Pandora176s1_Tsukuba-NIES_20250609_L1_smca1c4d20240516p1-8.txt Full location name: National Institute for Environmental Studies (NIES) Short location name: Tsukuba-NIES Country of location: Japan Location latitude [deg]: 36.0513 Location longitude [deg]: 140.1210 Location altitude [m]: 45 Local noon date: 20250609 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 256 398 Nominal wavelengths inside fitting window [nm]: 305.0215 305.1624 305.3032 305.4440 305.5848 305.7256 305.8664 306.0072 306.1480 306.2888 306.4295 306.5702 306.7110 306.8517 306.9924 307.1331 307.2737 307.4144 307.5551 307.6957 307.8363 307.9770 308.1176 308.2582 308.3987 308.5393 308.6799 308.8204 308.9610 309.1015 309.2420 309.3825 309.5230 309.6635 309.8039 309.9444 310.0848 310.2253 310.3657 310.5061 310.6465 310.7869 310.9272 311.0676 311.2079 311.3483 311.4886 311.6289 311.7692 311.9095 312.0498 312.1901 312.3303 312.4706 312.6108 312.7510 312.8912 313.0314 313.1716 313.3118 313.4519 313.5921 313.7322 313.8723 314.0124 314.1526 314.2926 314.4327 314.5728 314.7128 314.8529 314.9929 315.1329 315.2729 315.4129 315.5529 315.6929 315.8329 315.9728 316.1127 316.2527 316.3926 316.5325 316.6724 316.8122 316.9521 317.0920 317.2318 317.3716 317.5115 317.6513 317.7911 317.9308 318.0706 318.2104 318.3501 318.4899 318.6296 318.7693 318.9090 319.0487 319.1884 319.3280 319.4677 319.6073 319.7469 319.8866 320.0262 320.1658 320.3053 320.4449 320.5845 320.7240 320.8635 321.0031 321.1426 321.2821 321.4216 321.5610 321.7005 321.8400 321.9794 322.1188 322.2582 322.3976 322.5370 322.6764 322.8158 322.9551 323.0945 323.2338 323.3731 323.5124 323.6517 323.7910 323.9303 324.0696 324.2088 324.3481 324.4873 324.6265 324.7657 324.9049 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250608T204624.3Z 9290.865559 179 1 9.81 2 75.28 72.13 128.79 268.91 0.00 1 0.00 1 0 17 4.297e-01 1.838e-02 3.266e-01 1.536e-02 4.938363e-01 8.198234e-03 5.559858e-03 -6.000000e+00 2.538556e-01 232.46 -2.00 3.41 -2.00 320.32 0.00e+00 4.342445e-03 2.908134e-03 7.345914e-04 -6.000000e+00 1.140380e-02 288.64 -2.00 20.00 -2.00 319.59 0.00e+00 3.855 0.001 302.00 328.00 3 4.8209e+00 2.5005e-02 4.6172e-02 -6.0000e+00 6.3645e-01 9.3292e-02 3.0670e-02 2.5687e-02 -6.0000e+00 6.8649e-01 -1.2269e-01 2.5702e-02 1.3618e-02 -6.0000e+00 4.0800e-01 4.3767e-02 1.3094e-02 5.7699e-03 -6.0000e+00 1.7365e-01 5.0933e-05 -6.2373e-04 4.5519e-04 6.2255e-05 -6.0000e+00 1.1813e-02 -4.5739e-03 0.0000e+00 12 9 9 12 1 1 999.00 19.86 0.44 -0.00457 -0.00926 2 4 1 5 0 3270.360 26.41 19.99 19.86 27.19 18.8 985.13 -6503 -59127 900000 -47684 192821 2159 900000 -130180 -25129 124361 113879 -61516 75053 275206 51518 103688 -23929 -26979 -60758 -745 -2566 22226 169007 5485 -20798 3091 124998 -44774 -25906 3741 21664 12752 39872 -7167 40911 -30709 -10362 14489 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484 56 -1370 -396 -742 -675 -1823 331 -1216 1141 -1151 -1014 -4314 -454 -634 -617 -1503 551 2325 311 -1017 -704 1865 1993 3241 -2008 -79 -893 3443 -837 -125 -1822 1601 2304 3890 -1424 -436 -380 -1028 1464 249 -260 -3302 1348 1673 1626 819 -4447 -112 SS 20250608T205534.1Z 9290.871923 182 1 6.61 2 73.51 73.33 130.58 270.18 0.00 1 0.00 1 0 25 2.366e-01 1.071e-02 2.159e-01 8.711e-03 4.715038e-01 4.597131e-03 5.358691e-03 -6.000000e+00 1.394173e-01 232.46 -2.00 3.41 -2.00 319.89 0.00e+00 3.087576e-03 1.446738e-03 6.588027e-04 -6.000000e+00 6.259234e-03 288.65 -2.00 20.00 -2.00 319.13 0.00e+00 3.466 0.001 302.00 328.00 3 4.1306e+00 1.3513e-02 4.2390e-02 -6.0000e+00 3.4933e-01 5.5642e-02 1.6281e-02 2.4489e-02 -6.0000e+00 3.7668e-01 -6.2201e-02 1.3248e-02 1.2622e-02 -6.0000e+00 2.2408e-01 1.8549e-02 6.8538e-03 4.5998e-03 -6.0000e+00 9.5265e-02 1.5083e-04 -4.1711e-04 2.5450e-04 4.8508e-05 -6.0000e+00 6.4736e-03 -7.2081e-03 0.0000e+00 12 9 9 12 1 1 -158.11 19.86 0.23 -0.00721 -0.01034 4 9 1 5 0 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-573 -411 1014 -1208 816 -1521 1898 -559 1432 -868 -87 163 150 393 -58 -269 -1268 264 942 1351 -499 2177 273 2009 -531 773 331 906 1290 -68 1323 -1122 684 -1115 768 -1332 1085 -75 1314 -1350 -436 -2804 -252 -1289 -1598 1169 -704 2090 -438 1767 -939 1046 260 1366 -927 958 -62 -252 -1313 -865 -758 -1343 733 -747 -1894 -2012 -178 101 955 294 -431 -1223 485 1077 1644 2214 1885 1109 -2342 -1484 -301 1054 -521 1047 7 187 2067 400 787 -429 -464 -92 979 -700 277 -1073 881 -1513 386 -123 33 -381 SS 20250608T210112.1Z 9290.875834 186 1 19.11 2 72.42 74.06 131.68 270.97 0.00 1 0.00 1 0 17 8.690e-02 6.915e-03 4.916e-02 2.983e-03 4.422215e-01 1.565358e-03 5.009701e-03 -6.000000e+00 5.098980e-02 232.46 -2.00 3.41 -2.00 319.86 0.00e+00 8.082314e-04 4.812202e-04 2.973079e-04 -6.000000e+00 2.263456e-03 288.65 -2.00 20.00 -2.00 319.08 0.00e+00 3.264 0.001 302.00 328.00 3 3.3381e+00 4.5841e-03 3.9865e-02 -6.0000e+00 1.2789e-01 1.0785e-02 5.5033e-03 2.2986e-02 -6.0000e+00 1.3791e-01 -2.9080e-02 4.3895e-03 1.1316e-02 -6.0000e+00 8.2158e-02 7.1130e-03 2.2685e-03 3.2423e-03 -6.0000e+00 3.4957e-02 4.2889e-04 -5.7717e-04 8.7974e-05 3.5677e-05 -6.0000e+00 2.3751e-03 -4.1899e-03 0.0000e+00 12 9 1 12 1 1 86.11 19.86 0.28 -0.00419 -0.00853 36 22 1 5 0 516.240 26.41 19.99 19.86 27.90 18.8 989.21 -30548 -19378 -12466 -10200 -26043 -25015 1400 -32020 15280 -43438 10647 -46055 8290 -32586 3400 -9704 -3768 -2286 3410 3418 -3767 9615 -3025 9298 -10584 4197 -10431 7349 -5968 489 -4489 2243 2228 -1485 -1470 -2872 -1519 -2189 3327 -2794 1695 -4137 1302 -3155 2250 -575 91 -206 354 797 1514 3114 407 2976 -572 2587 -1153 1375 -903 1996 499 2725 1188 2275 1067 -836 1358 -1092 3213 -470 1510 -829 706 -926 288 -1084 270 -522 -5 -42 -949 -180 -2551 -828 -1452 -342 -752 198 -505 583 494 779 -1 1130 1254 -276 993 39 -227 -1035 -20 -1118 451 50 -210 -1291 -397 -459 -126 497 104 222 -392 460 296 1066 510 788 131 -187 -938 -112 -12 -294 611 69 337 854 848 -447 109 -558 335 -43 55 -530 27 426 -120 -238 -137 70 -81 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