File name: Pandora254s1_TubaCityAZ_20240606_L2Fit_fout2c2d20221208p1-8.txt File generation date: 20240715T141416.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Vaughn Salabye Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 254 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora254_OF_v2d20221208.txt Instrument calibration file used: Pandora254s1_CF_v2d20221208.txt Level 1 file used: Pandora254s1_TubaCityAZ_20240606_L1_smca1c2d20221208p1-8.txt Full location name: Greyhills Academy High School, Tuba City, AZ Short location name: TubaCityAZ Country of location: United States Location latitude [deg]: 36.1270 Location longitude [deg]: -111.2212 Location altitude [m]: 1470 Local noon date: 20240606 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 192 334 Nominal wavelengths inside fitting window [nm]: 305.0315 305.1725 305.3134 305.4543 305.5952 305.7361 305.8770 306.0179 306.1587 306.2996 306.4404 306.5812 306.7220 306.8629 307.0036 307.1444 307.2852 307.4260 307.5667 307.7074 307.8482 307.9889 308.1296 308.2703 308.4110 308.5516 308.6923 308.8330 308.9736 309.1142 309.2548 309.3954 309.5360 309.6766 309.8172 309.9577 310.0983 310.2388 310.3793 310.5199 310.6604 310.8009 310.9413 311.0818 311.2223 311.3627 311.5031 311.6436 311.7840 311.9244 312.0648 312.2052 312.3455 312.4859 312.6262 312.7666 312.9069 313.0472 313.1875 313.3278 313.4681 313.6083 313.7486 313.8888 314.0291 314.1693 314.3095 314.4497 314.5899 314.7301 314.8702 315.0104 315.1505 315.2906 315.4308 315.5709 315.7110 315.8511 315.9911 316.1312 316.2712 316.4113 316.5513 316.6913 316.8313 316.9713 317.1113 317.2513 317.3912 317.5312 317.6711 317.8111 317.9510 318.0909 318.2308 318.3706 318.5105 318.6504 318.7902 318.9301 319.0699 319.2097 319.3495 319.4893 319.6291 319.7688 319.9086 320.0483 320.1881 320.3278 320.4675 320.6072 320.7469 320.8865 321.0262 321.1659 321.3055 321.4451 321.5847 321.7243 321.8639 322.0035 322.1431 322.2827 322.4222 322.5617 322.7013 322.8408 322.9803 323.1198 323.2593 323.3987 323.5382 323.6776 323.8171 323.9565 324.0959 324.2353 324.3747 324.5141 324.6534 324.7928 324.9321 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 77: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 79: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 80: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 82: Atmospheric variability [%], 999=no atmospheric variability was determined Column 83: Wavelength effective temperature [°C], 999=no effective temperature given Column 84: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 85: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 86: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 87: Number of bright count cycles Column 88: Number of dark count cycles Column 89: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 90: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 91: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 92: Integration time [ms] Column 93: Temperature at electronics board [°C], 999=no temperature signal Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Humidity in head sensor [%], -9=no humidity signal Column 98: Pressure in head sensor [hPa], -9=no pressure signal Columns 99-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240606T124059.4Z 8923.528465 52 1 54.37 2 84.85 65.51 82.80 62.15 0.00 1 0.00 1 0 25 6.719e-01 2.114e-02 5.005e-01 1.641e-02 1.021724e+00 9.965808e-03 1.004296e-02 -6.000000e+00 3.929756e-01 231.26 -2.00 3.37 -2.00 322.57 0.00e+00 -1.141243e-02 6.350455e-03 4.152053e-03 -6.000000e+00 1.850290e-02 281.09 -2.00 20.00 -2.00 322.15 0.00e+00 9.643 0.014 302.00 328.00 3 4.1852e-01 4.3148e-02 1.0226e-01 -6.0000e+00 9.8993e-01 1.0270e+00 6.4972e-02 6.8731e-02 -6.0000e+00 1.0789e+00 -1.3021e+00 6.4157e-02 3.4390e-02 -6.0000e+00 6.3241e-01 4.9873e-01 2.8326e-02 1.0222e-02 -6.0000e+00 2.6668e-01 3.9542e-05 5.6684e-04 4.4797e-04 1.2302e-04 -6.0000e+00 1.9089e-02 2.9280e-02 12 8 8 10 0 0 17.22 25.43 0.83 0.02928 0.03354 71 7 1 5 0 765.670 34.00 20.00 25.43 22.94 4.1 952.98 900000 -82957 -152682 -150783 900000 -44043 900000 900000 -185744 -212409 900000 -107529 900000 56966 900000 900000 -109407 -74002 900000 -1726 -65540 170620 108226 900000 -17443 137514 -136189 -70568 -9487 900000 -101773 900000 -4408 8907 -47887 -32647 39621 46169 900000 67919 24978 -5110 105529 212016 207754 154911 -27169 -9177 -19267 337054 -4849 92646 44103 54176 38787 26027 57413 13318 -7991 25319 105529 17889 -8187 44353 12792 35652 31298 30156 16662 11924 10081 19974 21623 10494 -5155 -2425 26810 -8383 -10004 -9480 11650 4237 8501 6063 5043 -35 3367 5768 4747 605 -1051 634 2926 113 -1738 -2345 -819 483 -257 -5346 -1688 -3019 -1933 -3043 -2014 -2934 123 -3256 -1483 613 -2175 -1350 556 335 -2913 -830 -1119 -1837 1159 1390 3351 3766 1333 1333 -62 -459 374 767 421 2043 -498 -2 -673 -205 223 -323 370 1511 304 -88 217 -2243 -1126 900000 -1324 -2437 -2407 900000 -703 900000 900000 -2965 -5240 900000 -1717 900000 909 900000 900000 -2540 -1289 900000 -28 -1046 2724 1728 900000 -278 2195 -5929 -1434 -151 900000 -3397 900000 -77 142 -1251 -711 632 737 900000 1084 689 -200 1685 3385 3316 2473 -1222 -360 -895 5381 -246 2017 1728 2123 1914 1549 2583 908 -626 1323 2450 1090 -749 2768 1170 2846 2698 2840 2048 1789 1690 3125 3210 1591 -806 -325 2568 -1218 -1741 -2013 2399 1102 2361 1839 1650 -13 1231 2090 1713 216 -356 202 925 41 -749 -1220 -498 340 -201 -4387 -1242 -1986 -1123 -1797 -1270 -1967 85 -2563 -1309 623 -2632 -1773 741 445 -3869 -1054 -1457 -2537 1637 1990 4504 4732 1649 1602 -73 -532 422 948 624 3493 -989 -5 -1582 -520 611 -932 1073 4377 878 -237 538 -5228 -2505 SS 20240606T125220.1Z 8923.536343 55 1 54.53 2 82.75 67.08 80.83 63.58 0.00 1 0.00 1 0 17 7.398e-01 8.523e-03 2.567e-01 3.132e-03 8.404041e-01 1.744752e-03 8.949867e-03 -6.000000e+00 4.222719e-01 231.26 -2.00 3.37 -2.00 321.97 0.00e+00 4.374808e-03 1.007680e-03 4.246097e-03 -6.000000e+00 1.835194e-02 281.09 -2.00 20.00 -2.00 321.49 0.00e+00 7.329 0.006 302.00 328.00 3 3.8861e-01 6.6163e-03 7.7550e-02 -6.0000e+00 1.0588e+00 2.2566e-01 1.0788e-02 4.9812e-02 -6.0000e+00 1.1484e+00 -2.6775e-01 1.2183e-02 3.0327e-02 -6.0000e+00 6.8136e-01 9.7246e-02 5.4413e-03 1.1542e-02 -6.0000e+00 2.8671e-01 3.2852e-04 4.7026e-04 8.2876e-05 1.5555e-04 -6.0000e+00 1.9403e-02 2.9827e-02 11 8 0 10 0 0 6.37 25.43 0.34 0.02983 0.03336 233 24 1 5 0 234.020 34.25 20.00 25.43 23.26 4.1 956.22 -238535 -226800 -202710 -219017 -95132 -151040 -251626 -164356 -258001 -237808 -251391 -175632 -126953 -196657 -158441 -124759 -146696 -95955 -117204 -67086 -83424 -83427 -127626 -87274 -32550 -52282 -79214 -39566 -71063 -47292 -27615 -448 -36499 -12087 -7126 -26387 -31058 -36373 -8916 -7044 11621 -8066 5089 -2595 -491 7705 1201 -2726 14147 -1372 10411 885 6859 9116 6453 1118 2730 3663 300 4732 3410 1938 4498 7013 5202 4771 1944 909 3271 5006 3858 4838 948 1460 1041 -43 -1911 -187 -1807 -2746 -153 267 320 -332 245 243 2466 1046 841 1947 867 706 -1476 -1067 -1781 -916 -57 153 751 -827 -705 -1714 -1708 -79 -982 -1818 -1618 -1334 -319 209 228 -19 68 -479 -549 38 339 312 396 235 325 775 1255 792 701 -278 -501 1035 19 -92 223 2 -437 -63 -99 -289 147 645 90 -50 -87 -434 -445 -927 -945 -732 -912 -291 -461 -1467 -502 -2077 -1717 -2233 -878 -529 -2239 -1628 -1143 -1955 -879 -1464 -540 -811 -811 -2055 -1042 -244 -508 -1034 -341 -848 -512 -314 -5 -679 -210 -113 -508 -702 -1044 -242 -228 355 -325 191 -109 -21 308 54 -135 639 -80 620 66 538 774 603 116 288 379 31 458 348 226 596 1049 848 777 332 167 662 1163 1000 1290 257 366 236 -9 -381 -39 -444 -832 -54 108 143 -159 125 132 1370 604 484 1061 444 343 -724 -557 -1088 -659 -48 150 798 -887 -703 -1531 -1374 -64 -856 -1683 -1586 -1416 -376 255 316 -28 102 -706 -774 51 468 454 608 371 496 1117 1733 1166 997 -387 -680 1493 30 -163 441 4 -995 -153 -261 -796 408 1812 252 -132 -215 -996 -990 SS 20240606T130254.6Z 8923.543687 58 1 54.54 2 80.78 68.52 78.97 64.89 0.00 1 0.00 1 0 17 4.887e-01 6.173e-03 7.661e-02 1.268e-03 7.136525e-01 6.742481e-04 7.639410e-03 -6.000000e+00 2.789500e-01 231.26 -2.00 3.37 -2.00 321.31 0.00e+00 2.661573e-03 3.327376e-04 2.807868e-03 -6.000000e+00 1.212309e-02 281.09 -2.00 20.00 -2.00 320.77 0.00e+00 5.935 0.003 302.00 328.00 3 3.1384e-01 2.3032e-03 6.2993e-02 -6.0000e+00 6.9944e-01 8.8900e-02 3.3253e-03 3.9859e-02 -6.0000e+00 7.5861e-01 -8.9192e-02 3.5963e-03 2.2502e-02 -6.0000e+00 4.5010e-01 2.5158e-02 1.6901e-03 7.7960e-03 -6.0000e+00 1.8940e-01 1.2247e-03 4.6098e-04 3.3707e-05 1.0152e-04 -6.0000e+00 1.2818e-02 2.9759e-02 10 0 0 10 0 0 15.70 25.46 0.36 0.02976 0.03322 473 48 1 5 0 115.290 34.00 20.00 25.46 23.96 4.1 959.98 -163206 -140449 -136309 -156507 -203712 -166160 -151844 -177353 -131852 -129836 -130629 -137806 -99442 -89779 -43330 -50307 -57849 -26808 -48221 -25050 -19832 -42158 -38942 -29139 -20478 -27113 -29221 -35035 -35492 -28436 -22801 -16052 -13238 -12561 -18025 -17176 -13135 -12008 -5427 -3643 -2667 -2734 1642 643 -309 -28 -2052 1212 -1291 300 3045 1616 3058 5664 2765 3442 1397 1137 618 207 1458 2369 3805 3269 1948 1135 1133 -648 2013 1927 2230 2194 1190 857 -414 -482 -1092 -1941 -941 -1155 -563 -593 -1755 -1153 -789 -281 484 725 1019 727 419 -70 -1021 -660 -552 -438 396 972 429 -316 -600 -1020 -744 -172 -1231 -1444 -996 -598 -166 307 476 351 193 -239 -303 36 165 116 480 234 -93 487 743 349 489 -251 -46 783 136 -237 -235 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