File name: Pandora254s1_TubaCityAZ_20240616_L2Fit_fout2c2d20221208p1-8.txt File generation date: 20240715T141417.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Vaughn Salabye Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 254 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora254_OF_v2d20221208.txt Instrument calibration file used: Pandora254s1_CF_v2d20221208.txt Level 1 file used: Pandora254s1_TubaCityAZ_20240616_L1_smca1c2d20221208p1-8.txt Full location name: Greyhills Academy High School, Tuba City, AZ Short location name: TubaCityAZ Country of location: United States Location latitude [deg]: 36.1270 Location longitude [deg]: -111.2212 Location altitude [m]: 1470 Local noon date: 20240616 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 192 334 Nominal wavelengths inside fitting window [nm]: 305.0315 305.1725 305.3134 305.4543 305.5952 305.7361 305.8770 306.0179 306.1587 306.2996 306.4404 306.5812 306.7220 306.8629 307.0036 307.1444 307.2852 307.4260 307.5667 307.7074 307.8482 307.9889 308.1296 308.2703 308.4110 308.5516 308.6923 308.8330 308.9736 309.1142 309.2548 309.3954 309.5360 309.6766 309.8172 309.9577 310.0983 310.2388 310.3793 310.5199 310.6604 310.8009 310.9413 311.0818 311.2223 311.3627 311.5031 311.6436 311.7840 311.9244 312.0648 312.2052 312.3455 312.4859 312.6262 312.7666 312.9069 313.0472 313.1875 313.3278 313.4681 313.6083 313.7486 313.8888 314.0291 314.1693 314.3095 314.4497 314.5899 314.7301 314.8702 315.0104 315.1505 315.2906 315.4308 315.5709 315.7110 315.8511 315.9911 316.1312 316.2712 316.4113 316.5513 316.6913 316.8313 316.9713 317.1113 317.2513 317.3912 317.5312 317.6711 317.8111 317.9510 318.0909 318.2308 318.3706 318.5105 318.6504 318.7902 318.9301 319.0699 319.2097 319.3495 319.4893 319.6291 319.7688 319.9086 320.0483 320.1881 320.3278 320.4675 320.6072 320.7469 320.8865 321.0262 321.1659 321.3055 321.4451 321.5847 321.7243 321.8639 322.0035 322.1431 322.2827 322.4222 322.5617 322.7013 322.8408 322.9803 323.1198 323.2593 323.3987 323.5382 323.6776 323.8171 323.9565 324.0959 324.2353 324.3747 324.5141 324.6534 324.7928 324.9321 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 77: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 79: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 80: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 82: Atmospheric variability [%], 999=no atmospheric variability was determined Column 83: Wavelength effective temperature [°C], 999=no effective temperature given Column 84: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 85: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 86: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 87: Number of bright count cycles Column 88: Number of dark count cycles Column 89: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 90: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 91: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 92: Integration time [ms] Column 93: Temperature at electronics board [°C], 999=no temperature signal Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Humidity in head sensor [%], -9=no humidity signal Column 98: Pressure in head sensor [hPa], -9=no pressure signal Columns 99-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240616T124048.3Z 8933.528337 89 1 54.58 2 84.87 64.69 138.77 302.03 0.00 1 0.00 1 0 25 5.460e-01 2.383e-02 4.613e-01 1.716e-02 1.031450e+00 1.030232e-02 1.099532e-02 -6.000000e+00 3.161720e-01 231.59 -2.00 3.37 -2.00 322.62 0.00e+00 8.129558e-03 6.574216e-03 3.859483e-03 -6.000000e+00 1.459594e-02 282.08 -2.00 20.00 -2.00 322.20 0.00e+00 9.670 0.014 302.00 328.00 3 2.7937e-01 4.4480e-02 9.9436e-02 -6.0000e+00 7.9554e-01 1.5154e+00 5.9039e-02 5.7401e-02 -6.0000e+00 8.6502e-01 -1.9164e+00 4.8511e-02 3.0572e-02 -6.0000e+00 5.1210e-01 7.4380e-01 2.2482e-02 1.4353e-02 -6.0000e+00 2.1519e-01 3.7826e-05 3.0436e-04 4.5063e-04 2.6038e-04 -6.0000e+00 1.5076e-02 2.8701e-02 12 8 8 10 0 0 -9.05 25.76 0.78 0.02870 0.03099 70 7 1 5 0 779.610 34.25 20.00 25.76 26.40 3.9 973.97 -61626 59425 -48465 900000 5966 130540 -138854 -64154 900000 -89905 -79988 -35653 -110134 -77327 900000 900000 40164 -816 900000 -46790 102537 900000 198176 158187 127507 -7984 900000 -65689 -39493 145234 -26470 88812 -23524 41007 -57559 63081 -42580 900000 76342 -14478 125800 43950 101026 900000 -15973 11523 115748 110489 92217 74878 41996 33029 67569 170106 48432 68487 38368 63138 28369 49604 23428 -7189 40656 62730 69335 47371 68204 51318 12377 14583 31635 47393 17998 4604 -1120 32750 -9077 -9165 -4592 -197 -5865 15762 7252 5142 8146 -1446 6992 4204 -1243 6905 2117 -1028 182 -1198 -1091 -8105 2259 -2307 -5046 -839 -1482 -2910 1096 -3053 -3325 -7059 -2179 -2319 166 -114 3531 -2825 -2545 -1703 -36 -2543 -348 -415 144 472 -59 4533 3676 3001 1454 349 1640 -1559 356 1071 1204 -92 -1311 75 779 114 427 825 693 -157 -1068 -812 -2060 -1888 993 -1350 900000 100 2181 -5413 -1161 900000 -2185 -1701 -596 -4516 -2936 900000 900000 732 -24 900000 -2061 1713 900000 3311 2643 2130 -182 900000 -2295 -1020 2426 -844 1484 -1000 934 -3147 1054 -1940 900000 1391 -748 2102 1402 1841 900000 -898 490 1934 1846 1961 2047 1786 1706 2668 2842 2575 3017 2273 2781 1637 2185 1352 -622 2532 3621 4002 3382 4444 4201 1675 2217 4387 5701 2766 731 -165 3009 -1213 -1317 -752 -38 -1440 3634 2011 1538 2504 -515 2371 1489 -459 2238 669 -319 56 -412 -446 -4320 1302 -1646 -4098 -654 -1082 -1891 606 -1754 -2061 -4788 -1503 -1767 142 -116 3988 -3728 -3466 -2288 -46 -3275 -450 -568 208 690 -83 5703 4477 3575 1710 404 1849 -2000 538 1895 2415 -206 -3192 195 2173 336 1265 2458 2033 -434 -2730 -1897 -4677 SS 20240616T125200.3Z 8933.536114 92 1 54.37 2 82.82 66.23 140.62 304.99 0.00 1 0.00 1 0 17 6.851e-01 7.748e-03 2.810e-01 3.022e-03 8.634356e-01 1.710011e-03 9.366765e-03 -6.000000e+00 3.916625e-01 231.59 -2.00 3.37 -2.00 322.02 0.00e+00 6.592318e-03 1.010943e-03 4.766117e-03 -6.000000e+00 1.837317e-02 282.08 -2.00 20.00 -2.00 321.54 0.00e+00 7.380 0.006 302.00 328.00 3 2.6118e-01 6.6025e-03 7.8846e-02 -6.0000e+00 9.8270e-01 2.5694e-01 1.0887e-02 5.0935e-02 -6.0000e+00 1.0656e+00 -2.9282e-01 1.2367e-02 3.1685e-02 -6.0000e+00 6.3270e-01 1.0495e-01 5.4989e-03 1.2956e-02 -6.0000e+00 2.6887e-01 3.4293e-04 3.8936e-04 7.9334e-05 1.8175e-04 -6.0000e+00 1.8166e-02 2.8961e-02 11 8 0 10 0 0 37.20 25.76 0.38 0.02896 0.03189 246 25 1 5 0 221.000 34.25 20.00 25.76 26.63 3.9 975.72 -235476 900000 -270769 -284655 -215677 -256819 -236917 -108787 -143929 -135244 900000 -200840 900000 -15999 -133441 -4171 -111583 -118138 -99867 -114224 -75875 -136861 -101877 -92408 -72104 -63509 30775 -39884 -75828 -60610 -80785 -70703 -34481 -52678 -21728 -57221 -32962 -24161 -5115 -16022 2472 8721 -8689 -4388 -5615 -14529 -951 -5940 12122 9428 6722 7641 10211 10017 7487 5810 5160 -2372 5002 2204 2855 2081 7686 4609 7032 4050 2125 738 2330 3450 5399 5391 2398 145 1024 122 -553 -3222 1618 -65 47 -486 -376 -1801 46 117 107 1600 1575 1498 -220 -1038 -1136 -787 -1262 -192 -443 1188 666 -401 -921 -1461 -908 -659 -1542 -1374 -1264 -1325 -682 312 257 -167 85 25 -393 -394 105 428 668 350 384 457 1260 796 146 -271 -126 663 170 146 304 -271 -546 -267 -120 -214 208 434 306 -129 -85 -399 -232 -757 900000 -1668 -1982 -693 -1238 -1015 -320 -424 -398 900000 -1076 900000 -47 -929 -12 -926 -1202 -936 -1315 -610 -2016 -1119 -1015 -695 -595 115 -299 -833 -665 -1406 -1401 -573 -1143 -365 -1365 -689 -555 -121 -510 74 267 -338 -169 -225 -663 -40 -280 518 458 386 497 722 785 644 532 491 -241 455 203 272 225 922 663 1061 628 343 129 452 772 1307 1355 606 35 219 23 -103 -650 366 -18 16 -191 -163 -840 22 61 58 880 862 786 -109 -492 -533 -394 -741 -133 -364 1119 692 -420 -901 -1271 -706 -515 -1310 -1227 -1196 -1366 -784 410 348 -244 126 37 -546 -530 143 612 1009 544 577 649 1707 1150 206 -370 -167 944 259 257 596 -577 -1240 -648 -313 -587 577 1216 849 -339 -208 -907 -510 SS 20240616T130233.1Z 8933.543439 95 1 54.45 2 80.86 67.67 142.29 307.98 0.00 1 0.00 1 0 17 5.573e-01 6.887e-03 6.530e-02 1.231e-03 7.329540e-01 6.583559e-04 7.916640e-03 -6.000000e+00 3.185195e-01 231.59 -2.00 3.37 -2.00 321.34 0.00e+00 3.276000e-03 3.290886e-04 3.123402e-03 -6.000000e+00 1.388068e-02 282.08 -2.00 20.00 -2.00 320.79 0.00e+00 5.980 0.003 302.00 328.00 3 1.7356e-01 2.2596e-03 6.4154e-02 -6.0000e+00 7.9904e-01 1.1948e-01 3.2803e-03 4.1335e-02 -6.0000e+00 8.6622e-01 -1.2042e-01 3.5293e-03 2.3479e-02 -6.0000e+00 5.1411e-01 3.7058e-02 1.6510e-03 8.2432e-03 -6.0000e+00 2.1642e-01 1.3130e-03 4.9343e-04 3.2466e-05 1.0708e-04 -6.0000e+00 1.4616e-02 2.8534e-02 11 8 0 10 0 0 11.47 25.77 0.30 0.02853 0.03224 515 52 1 5 0 105.720 34.25 20.00 25.77 27.06 3.9 978.36 -201630 -172639 -179488 -172695 -182671 -219419 -182965 -165823 -136088 -172969 -154959 -139190 -117090 -76250 -75354 -63655 -66169 -37321 -45420 -30646 -41197 -45757 -55208 -38468 -35096 -38627 -30171 -37840 -39918 -28013 -8967 -14298 -9120 -13638 -17982 -18441 -9224 -11762 -5512 -4820 -2147 -2325 -145 937 -1288 505 700 2048 -1019 453 2379 1529 4418 4942 4136 4027 2446 1830 1025 179 3121 3738 4370 3221 2564 1603 1427 672 2257 2423 1202 1749 1652 1307 -380 -637 -1557 -2322 -94 -736 -661 -1103 -1528 -1337 -473 -258 209 545 1082 1029 658 -228 -963 -677 -866 -360 207 1071 294 -539 -465 -1276 -833 -386 -1197 -1267 -1218 -669 -166 298 545 273 271 -204 -278 -36 181 67 409 146 9 566 894 397 351 -209 -13 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