File name: Pandora254s1_TubaCityAZ_20240818_L2Fit_fout2c2d20221208p1-8.txt File generation date: 20240906T210155.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Vaughn Salabye Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 254 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora254_OF_v2d20221208.txt Instrument calibration file used: Pandora254s1_CF_v2d20221208.txt Level 1 file used: Pandora254s1_TubaCityAZ_20240818_L1_smca1c2d20221208p1-8.txt Full location name: Greyhills Academy High School, Tuba City, AZ Short location name: TubaCityAZ Country of location: United States Location latitude [deg]: 36.1270 Location longitude [deg]: -111.2212 Location altitude [m]: 1470 Local noon date: 20240818 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 192 334 Nominal wavelengths inside fitting window [nm]: 305.0315 305.1725 305.3134 305.4543 305.5952 305.7361 305.8770 306.0179 306.1587 306.2996 306.4404 306.5812 306.7220 306.8629 307.0036 307.1444 307.2852 307.4260 307.5667 307.7074 307.8482 307.9889 308.1296 308.2703 308.4110 308.5516 308.6923 308.8330 308.9736 309.1142 309.2548 309.3954 309.5360 309.6766 309.8172 309.9577 310.0983 310.2388 310.3793 310.5199 310.6604 310.8009 310.9413 311.0818 311.2223 311.3627 311.5031 311.6436 311.7840 311.9244 312.0648 312.2052 312.3455 312.4859 312.6262 312.7666 312.9069 313.0472 313.1875 313.3278 313.4681 313.6083 313.7486 313.8888 314.0291 314.1693 314.3095 314.4497 314.5899 314.7301 314.8702 315.0104 315.1505 315.2906 315.4308 315.5709 315.7110 315.8511 315.9911 316.1312 316.2712 316.4113 316.5513 316.6913 316.8313 316.9713 317.1113 317.2513 317.3912 317.5312 317.6711 317.8111 317.9510 318.0909 318.2308 318.3706 318.5105 318.6504 318.7902 318.9301 319.0699 319.2097 319.3495 319.4893 319.6291 319.7688 319.9086 320.0483 320.1881 320.3278 320.4675 320.6072 320.7469 320.8865 321.0262 321.1659 321.3055 321.4451 321.5847 321.7243 321.8639 322.0035 322.1431 322.2827 322.4222 322.5617 322.7013 322.8408 322.9803 323.1198 323.2593 323.3987 323.5382 323.6776 323.8171 323.9565 324.0959 324.2353 324.3747 324.5141 324.6534 324.7928 324.9321 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 77: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 79: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 80: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 82: Atmospheric variability [%], 999=no atmospheric variability was determined Column 83: Wavelength effective temperature [°C], 999=no effective temperature given Column 84: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 85: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 86: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 87: Number of bright count cycles Column 88: Number of dark count cycles Column 89: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 90: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 91: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 92: Integration time [ms] Column 93: Temperature at electronics board [°C], 999=no temperature signal Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Humidity in head sensor [%], -9=no humidity signal Column 98: Pressure in head sensor [hPa], -9=no pressure signal Columns 99-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240818T132648.9Z 8996.560289 184 1 55.28 2 82.85 79.33 115.28 259.58 0.00 1 0.00 1 0 25 4.361e-01 3.189e-02 4.513e-01 2.756e-02 8.107778e-01 1.589164e-02 8.756563e-03 -6.000000e+00 2.541039e-01 230.13 -2.00 3.37 -2.00 321.98 0.00e+00 2.094374e-03 8.297834e-03 2.643616e-03 -6.000000e+00 1.143847e-02 284.67 -2.00 20.00 -2.00 321.46 0.00e+00 7.407 0.006 302.00 328.00 3 2.9693e+00 5.9775e-02 7.6294e-02 -6.0000e+00 6.3835e-01 9.5035e-01 7.7393e-02 4.5394e-02 -6.0000e+00 6.9743e-01 -1.2908e+00 5.8986e-02 2.2594e-02 -6.0000e+00 4.1149e-01 5.2615e-01 2.7799e-02 6.3576e-03 -6.0000e+00 1.7372e-01 2.1059e-05 -1.8654e-03 7.8195e-04 9.6750e-05 -6.0000e+00 1.2001e-02 1.9325e-02 12 8 8 10 0 0 96.97 25.69 0.16 0.01933 0.00531 26 3 1 5 0 2126.050 34.25 20.00 25.69 25.13 3.6 963.57 900000 -67870 111542 72498 123106 -141369 -15098 45098 -144781 -58545 -76247 -14958 -102067 900000 -43387 57472 -10317 -39862 900000 900000 900000 900000 900000 30888 53891 -43687 40917 -59079 25046 -35629 35144 2335 900000 60800 900000 23120 137524 900000 80118 31057 71044 -2488 23776 95708 900000 42566 107353 -11350 11491 2803 15087 130135 85330 35372 19473 12031 73812 47124 58851 7778 97255 28349 43241 49194 17310 7851 -1528 35420 13489 13921 24788 16203 12953 21045 22949 1131 -2778 14317 -9820 9881 9230 -4816 6838 -836 2911 6676 -2143 2392 -3351 -6251 -5458 11763 -6565 -2852 -6452 561 -2697 -6604 -4671 -2202 -300 -1956 -5388 -8604 -611 -1893 -3011 -4786 -1498 -480 1188 882 2679 -283 -1415 -805 -663 -4997 1681 34 3598 2698 203 3815 4510 790 -706 4503 734 1079 -483 1549 -54 915 708 54 -536 345 -875 1129 -1265 -270 -2845 900000 -2731 2992 1945 3302 -7900 -405 1210 -9062 -1570 -2386 -401 -5724 900000 -2010 1542 -428 -2333 900000 900000 900000 900000 900000 829 1446 -2557 1098 -3602 672 -1651 943 102 900000 1779 900000 846 3689 900000 2344 1742 2945 -224 1681 3267 900000 2387 3141 -1107 925 260 1361 4125 4578 3364 2279 1555 5220 4252 4449 929 4743 2973 4429 5398 2786 1359 -287 4750 2467 2919 5652 4172 3370 4685 4494 243 -574 2535 -2502 2492 2773 -1925 2696 -377 1343 3152 -1156 1264 -1870 -3454 -2782 4733 -3081 -1346 -3600 345 -2011 -5970 -4599 -2138 -269 -1595 -4061 -6623 -469 -1559 -2650 -4634 -1559 -566 1567 1265 3859 -412 -1993 -1084 -900 -7439 2485 53 5328 3835 284 4994 5649 995 -873 5544 1085 1831 -931 3163 -120 2127 1776 143 -1459 943 -2411 2898 -3085 -604 -6227 SS 20240818T135724.3Z 8996.581531 201 1 54.54 2 76.75 83.68 121.06 263.57 0.00 1 0.00 1 0 17 3.437e-01 2.126e-02 3.526e-01 1.791e-02 5.291717e-01 9.387971e-03 6.408620e-03 -6.000000e+00 1.965122e-01 230.13 -2.00 3.37 -2.00 320.69 0.00e+00 2.970261e-03 3.737718e-03 3.936471e-03 -6.000000e+00 8.685156e-03 284.67 -2.00 20.00 -2.00 320.03 0.00e+00 4.255 0.001 302.00 328.00 3 5.0788e+00 2.9720e-02 4.8155e-02 -6.0000e+00 4.9156e-01 1.7082e-01 3.7503e-02 3.5349e-02 -6.0000e+00 5.3378e-01 -1.8057e-01 3.2533e-02 1.6630e-02 -6.0000e+00 3.1728e-01 6.5329e-02 1.6127e-02 4.1005e-03 -6.0000e+00 1.3388e-01 4.6762e-05 9.1262e-04 5.1721e-04 7.7605e-05 -6.0000e+00 9.0078e-03 1.8064e-02 12 8 8 10 0 0 99.74 25.75 0.23 0.01806 0.02492 14 1 1 5 0 3895.540 34.25 20.00 25.75 26.73 3.5 972.93 -96717 -96468 25640 -12536 170740 -89431 -173212 -104462 85790 -75191 -4336 -36449 -31856 5213 -59441 -71732 78957 35802 900000 13019 -27269 18376 50195 50884 16296 -30293 35079 5315 26371 41244 13234 -34441 -11785 33493 113112 13674 -10978 7125 10529 2801 15977 277 10112 10820 15968 -2690 10201 1130 12618 298 15982 13093 -6023 23138 9309 -6193 214 -10028 3638 1429 15125 7558 11188 6853 -338 -989 -6328 -3067 6584 5749 -2117 1838 5953 2525 -7061 -1853 1789 -3551 -7963 -3555 745 527 -3693 4272 -1276 2325 -4019 1269 -1142 -1573 -697 109 -2117 -4513 -1840 1032 -1424 522 1191 -124 -2595 969 -1992 -1766 707 -784 -2074 -1944 -960 2791 941 2501 4401 -148 615 -1050 -1849 -1500 455 -1743 634 -11 872 1747 118 -377 741 -82 3400 -692 -39 -421 -1808 -375 -127 -330 64 1710 349 -820 -81 -419 -292 -1971 -2246 448 -219 2982 -1692 -8066 -2736 1498 -1910 -76 -694 -708 99 -2642 -4214 1379 853 900000 434 -1385 583 1195 1293 621 -1924 1169 228 879 1244 609 -2953 -917 1755 2514 803 -906 577 1003 342 1902 41 1413 1529 2155 -444 1490 183 1863 52 2613 2432 -1463 4518 2187 -1750 58 -2993 918 363 3458 2040 3268 2317 -127 -355 -2310 -1096 2564 2600 -1139 988 3035 1261 -3551 -790 678 -1408 -3629 -1819 422 338 -2676 3006 -1016 1908 -3691 1137 -1047 -1390 -565 81 -1519 -3350 -1468 915 -1480 604 1476 -154 -3082 1002 -1952 -1764 749 -887 -2499 -2488 -1315 4066 1523 4145 7047 -235 907 -1496 -2674 -2267 719 -2952 1045 -18 1343 2563 168 -518 963 -112 4964 -1167 -71 -803 -3625 -781 -282 -771 152 4070 841 -1918 -177 -875 -590 SS 20240818T140731.4Z 8996.588558 204 1 41.83 2 74.71 85.12 122.98 264.92 0.00 1 0.00 1 0 17 7.705e-02 6.119e-03 3.651e-02 1.854e-03 4.645769e-01 9.513267e-04 5.174462e-03 -6.000000e+00 4.387452e-02 230.13 -2.00 3.37 -2.00 319.83 0.00e+00 1.291713e-03 2.925855e-04 7.843530e-04 -6.000000e+00 1.939841e-03 284.67 -2.00 20.00 -2.00 319.13 0.00e+00 3.723 0.001 302.00 328.00 3 3.0006e+00 2.7744e-03 3.9321e-02 -6.0000e+00 1.0958e-01 9.7610e-03 3.3324e-03 2.3663e-02 -6.0000e+00 1.1882e-01 -8.0669e-03 2.7640e-03 1.1932e-02 -6.0000e+00 7.0716e-02 -4.1359e-03 1.4337e-03 3.6226e-03 -6.0000e+00 2.9981e-02 6.4816e-04 2.1673e-04 5.2100e-05 3.9625e-05 -6.0000e+00 2.0195e-03 1.8087e-02 12 1 1 12 1 1 81.77 25.78 0.33 0.01809 0.01972 62 8 1 5 0 663.790 34.25 20.00 25.78 27.28 3.5 976.40 -8526 -14696 -21846 -23034 -16860 -20964 -41730 -34259 -379 -19513 -31578 -18947 -16314 -17325 -15686 -3959 -4343 -3414 -3619 -758 -6674 -9957 -1282 1759 -2748 -3586 -3529 -3424 -8636 -4141 -4361 -1926 -572 287 -8211 -5346 -3795 -3289 -2117 -2665 -1275 -860 -1375 312 -869 175 688 65 -1008 644 1500 623 631 2302 1553 1169 1437 1450 534 331 1494 2815 2840 3123 960 -288 -286 -772 999 686 681 1434 313 532 -241 -641 -1174 -1707 -944 -502 -946 -1627 -1677 -1884 -733 -431 53 172 784 950 927 218 -64 244 -22 -449 192 1078 290 -431 -533 -1094 -770 -150 -1023 -993 -1194 -832 -380 115 568 360 265 120 -248 141 328 118 271 147 -131 400 522 425 582 72 -187 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