File name: Pandora254s1_TubaCityAZ_20250409_L2Fit_fout2c2d20221208p1-8.txt File generation date: 20250410T073430.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Vaughn Salabye Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 254 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora254_OF_v2d20221208.txt Instrument calibration file used: Pandora254s1_CF_v2d20221208.txt Level 1 file used: Pandora254s1_TubaCityAZ_20250409_L1_smca1c2d20221208p1-8.txt Full location name: Greyhills Academy High School, Tuba City, AZ Short location name: TubaCityAZ Country of location: United States Location latitude [deg]: 36.1270 Location longitude [deg]: -111.2212 Location altitude [m]: 1470 Local noon date: 20250409 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 192 334 Nominal wavelengths inside fitting window [nm]: 305.0315 305.1725 305.3134 305.4543 305.5952 305.7361 305.8770 306.0179 306.1587 306.2996 306.4404 306.5812 306.7220 306.8629 307.0036 307.1444 307.2852 307.4260 307.5667 307.7074 307.8482 307.9889 308.1296 308.2703 308.4110 308.5516 308.6923 308.8330 308.9736 309.1142 309.2548 309.3954 309.5360 309.6766 309.8172 309.9577 310.0983 310.2388 310.3793 310.5199 310.6604 310.8009 310.9413 311.0818 311.2223 311.3627 311.5031 311.6436 311.7840 311.9244 312.0648 312.2052 312.3455 312.4859 312.6262 312.7666 312.9069 313.0472 313.1875 313.3278 313.4681 313.6083 313.7486 313.8888 314.0291 314.1693 314.3095 314.4497 314.5899 314.7301 314.8702 315.0104 315.1505 315.2906 315.4308 315.5709 315.7110 315.8511 315.9911 316.1312 316.2712 316.4113 316.5513 316.6913 316.8313 316.9713 317.1113 317.2513 317.3912 317.5312 317.6711 317.8111 317.9510 318.0909 318.2308 318.3706 318.5105 318.6504 318.7902 318.9301 319.0699 319.2097 319.3495 319.4893 319.6291 319.7688 319.9086 320.0483 320.1881 320.3278 320.4675 320.6072 320.7469 320.8865 321.0262 321.1659 321.3055 321.4451 321.5847 321.7243 321.8639 322.0035 322.1431 322.2827 322.4222 322.5617 322.7013 322.8408 322.9803 323.1198 323.2593 323.3987 323.5382 323.6776 323.8171 323.9565 324.0959 324.2353 324.3747 324.5141 324.6534 324.7928 324.9321 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 77: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 79: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 80: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 82: Atmospheric variability [%], 999=no atmospheric variability was determined Column 83: Wavelength effective temperature [°C], 999=no effective temperature given Column 84: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 85: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 86: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 87: Number of bright count cycles Column 88: Number of dark count cycles Column 89: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 90: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 91: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 92: Integration time [ms] Column 93: Temperature at electronics board [°C], 999=no temperature signal Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Humidity in head sensor [%], -9=no humidity signal Column 98: Pressure in head sensor [hPa], -9=no pressure signal Columns 99-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250409T133024.9Z 9230.562788 187 1 54.03 2 84.61 84.27 113.03 299.35 0.00 1 0.00 1 0 17 6.284e-01 2.399e-02 5.046e-01 1.779e-02 9.988987e-01 1.056061e-02 1.012803e-02 -6.000000e+00 3.588939e-01 227.72 -2.00 3.37 -2.00 322.56 0.00e+00 1.400857e-02 6.182269e-03 5.285965e-03 -6.000000e+00 1.665883e-02 274.85 -2.00 20.00 -2.00 322.16 0.00e+00 9.324 0.013 302.00 328.00 3 7.1435e-01 4.1339e-02 1.0616e-01 -6.0000e+00 8.9358e-01 1.3414e+00 5.6909e-02 9.0381e-02 -6.0000e+00 9.7490e-01 -1.6972e+00 5.3792e-02 3.2167e-02 -6.0000e+00 5.7840e-01 6.6318e-01 2.5164e-02 1.6164e-02 -6.0000e+00 2.4517e-01 3.4559e-05 -9.8531e-04 4.7325e-04 1.7271e-04 -6.0000e+00 1.6721e-02 3.7829e-02 12 8 8 10 0 0 40.24 25.15 0.76 0.03783 0.03042 58 6 1 5 0 931.350 34.00 19.96 25.15 14.48 3.6 889.92 -12685 94992 900000 -91742 -48737 87335 -99154 -103230 -36775 68879 900000 -156411 -62681 900000 -101827 40992 900000 57742 -3187 -6033 188111 900000 -28483 -123069 -33757 164178 9104 -54840 221622 -35123 900000 -65371 46866 -1145 -6382 -82872 124057 -25675 131683 115763 900000 900000 227509 198863 900000 67306 63554 151527 34690 23704 107850 142495 85583 132956 50320 60372 66334 42152 88243 -7851 2702 22733 29205 42008 18142 17651 16601 22175 34724 21673 20491 16775 17203 15006 9131 1417 -19634 -2972 260 1798 5388 8547 7602 5368 -455 10176 9833 6673 3686 -6063 5011 2723 813 -2305 -8984 -1506 -2222 -1881 1330 -4604 -3223 -2057 -2923 723 -3490 -2753 -3913 403 -4243 -2067 831 -882 -817 886 -3736 -1851 1842 -2293 -613 1361 1513 2413 4778 1973 1407 -856 2235 631 -32 1154 -122 94 163 84 70 -35 1477 302 -232 -240 -83 -1424 -1603 -220 1645 900000 -2251 -844 1513 -1717 -1788 -637 1193 900000 -5171 -1086 900000 -4489 710 900000 1000 -75 -142 3258 900000 -673 -7363 -797 2843 158 -1381 3838 -829 900000 -3293 885 -36 -191 -4958 2148 -1011 2281 2005 900000 900000 3940 3444 900000 1590 1601 2624 1311 1082 2377 2468 2830 2931 2614 2851 2924 2256 2779 -618 196 1503 2115 3108 1828 1779 1898 2535 3909 3190 3300 2847 2771 2235 1265 186 -3060 -422 43 361 1250 2235 2212 1683 -160 3384 3406 2427 1366 -2363 1623 858 262 -838 -4154 -785 -1401 -1397 1060 -3899 -2501 -1382 -1752 416 -2248 -1854 -2846 309 -3902 -2190 990 -1169 -1116 1179 -5034 -2395 2358 -3233 -899 1990 2115 3134 5817 2399 1672 -1014 2528 797 -48 2046 -248 209 388 218 195 -103 4278 894 -680 -658 -209 -3320 -3596 SS 20250409T134139.4Z 9230.570595 190 1 54.53 2 82.34 85.90 114.95 301.41 0.00 1 0.00 1 0 17 7.266e-01 8.677e-03 2.204e-01 2.893e-03 8.308112e-01 1.586614e-03 8.655517e-03 -6.000000e+00 4.087394e-01 227.72 -2.00 3.37 -2.00 321.89 0.00e+00 5.109092e-03 8.439327e-04 2.623135e-03 -6.000000e+00 1.755387e-02 274.85 -2.00 20.00 -2.00 321.45 0.00e+00 6.996 0.005 302.00 328.00 3 6.0856e-01 5.5780e-03 7.2938e-02 -6.0000e+00 1.0183e+00 2.1101e-01 9.1191e-03 4.5016e-02 -6.0000e+00 1.1090e+00 -2.7285e-01 1.0743e-02 2.7901e-02 -6.0000e+00 6.5754e-01 1.0145e-01 4.8855e-03 1.2309e-02 -6.0000e+00 2.7685e-01 3.5503e-04 3.8677e-04 7.5831e-05 1.4982e-04 -6.0000e+00 1.9042e-02 3.8292e-02 11 8 0 10 0 0 33.71 25.17 0.35 0.03829 0.04120 235 24 1 5 0 231.990 34.25 20.04 25.17 14.97 3.6 893.98 -293985 -262696 -160204 -275947 -1161 -226237 -142728 -199645 -216349 -211913 -200750 -181644 -217902 -170786 -110767 -118602 -92610 -82497 -86260 -96255 -81089 -57242 -100275 -84802 -47839 -11504 -49910 -54227 -73238 -48496 -5448 -5981 -20548 -5749 -42301 -52768 1360 -14258 3018 -9878 5540 -9417 450 8846 6277 2366 6768 -2054 -1924 2344 283 10889 7702 4571 4172 11245 7103 1699 4172 3495 3615 7835 5688 7222 2332 3163 4745 5044 3822 4852 4793 2525 2362 1852 -1565 -1007 -3576 -5847 -1163 105 -581 -495 -623 -1187 607 1013 -525 -171 2250 1009 575 -902 -972 -860 -1312 -1553 264 1022 329 -330 -867 -977 -953 -537 -1600 -1323 -1689 -842 48 175 288 135 142 -114 -806 -66 -145 256 385 32 337 789 1610 381 532 -221 17 710 215 131 -179 11 -413 -79 -203 -219 241 704 263 -109 -131 -494 -382 -2413 -1886 -452 -2406 -3 -1102 -403 -922 -1332 -1359 -1236 -1118 -2627 -1752 -824 -1186 -831 -762 -907 -1185 -873 -484 -1389 -1109 -466 -83 -538 -598 -995 -597 -56 -84 -400 -104 -1050 -1459 25 -362 80 -359 195 -417 19 357 266 108 309 -110 -111 143 20 796 645 436 426 1120 759 189 437 362 391 915 794 1147 414 552 833 938 815 1192 1293 720 656 480 -377 -216 -754 -1338 -299 32 -215 -212 -293 -595 320 565 -311 -103 1314 570 303 -458 -488 -464 -828 -1167 230 1024 360 -360 -882 -880 -775 -442 -1437 -1246 -1695 -911 58 221 408 205 217 -170 -1152 -91 -204 378 599 51 519 1144 2232 516 764 -309 24 1046 339 237 -360 24 -950 -193 -536 -605 616 1818 733 -287 -322 -1131 -852 SS 20250409T135920.2Z 9230.582872 195 1 54.51 2 78.77 88.48 117.89 304.80 0.00 1 0.00 1 0 17 2.720e-01 5.772e-03 3.307e-02 7.222e-04 6.233227e-01 3.722471e-04 6.652309e-03 -6.000000e+00 1.530088e-01 227.72 -2.00 3.37 -2.00 320.74 0.00e+00 2.254923e-03 1.501444e-04 1.148653e-03 -6.000000e+00 6.571103e-03 274.85 -2.00 20.00 -2.00 320.23 0.00e+00 4.966 0.002 302.00 328.00 3 3.5090e-01 1.1430e-03 5.2176e-02 -6.0000e+00 3.8119e-01 2.7040e-02 1.5126e-03 3.1720e-02 -6.0000e+00 4.1515e-01 -2.5228e-02 1.5937e-03 1.7604e-02 -6.0000e+00 2.4614e-01 6.9730e-04 7.8988e-04 6.6824e-03 -6.0000e+00 1.0364e-01 2.8755e-03 5.0527e-04 1.9447e-05 6.9069e-05 -6.0000e+00 7.1281e-03 3.8031e-02 11 1 0 11 8 0 31.50 25.21 0.33 0.03803 0.04183 754 76 1 5 0 72.280 34.00 19.96 25.21 16.25 3.6 902.11 -110474 -87398 -93635 -96921 -85854 -90847 -89053 -73875 -69117 -66762 -86068 -69152 -56156 -43001 -34869 -30756 -23124 -23893 -19627 -22259 -17974 -14319 -15494 -14473 -15005 -11050 -17147 -18177 -15832 -11846 -10941 -7749 -3141 -7224 -10146 -8513 -8408 -8067 -2792 -2549 -1512 -465 -964 -716 736 977 213 417 -166 482 1407 1553 2150 2168 2410 2073 989 911 256 -61 1324 2252 3000 3161 1242 807 -174 145 1349 1054 1060 994 538 200 -365 -834 -1354 -2172 -1046 -1227 -986 -1033 -2158 -1668 -684 -209 392 636 1131 870 726 141 -340 -213 -308 -94 634 994 333 -167 -582 -823 -635 -102 -1220 -1219 -1178 -714 25 349 457 233 236 -57 -320 5 41 185 334 31 -85 347 662 310 470 -192 -1 813 240 -95 -189 -274 -425 -101 -105 -286 263 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