File name: Pandora254s1_TubaCityAZ_20250411_L2Fit_fout2c2d20221208p1-8.txt File generation date: 20250412T073351.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Vaughn Salabye Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 254 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora254_OF_v2d20221208.txt Instrument calibration file used: Pandora254s1_CF_v2d20221208.txt Level 1 file used: Pandora254s1_TubaCityAZ_20250411_L1_smca1c2d20221208p1-8.txt Full location name: Greyhills Academy High School, Tuba City, AZ Short location name: TubaCityAZ Country of location: United States Location latitude [deg]: 36.1270 Location longitude [deg]: -111.2212 Location altitude [m]: 1470 Local noon date: 20250411 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 192 334 Nominal wavelengths inside fitting window [nm]: 305.0315 305.1725 305.3134 305.4543 305.5952 305.7361 305.8770 306.0179 306.1587 306.2996 306.4404 306.5812 306.7220 306.8629 307.0036 307.1444 307.2852 307.4260 307.5667 307.7074 307.8482 307.9889 308.1296 308.2703 308.4110 308.5516 308.6923 308.8330 308.9736 309.1142 309.2548 309.3954 309.5360 309.6766 309.8172 309.9577 310.0983 310.2388 310.3793 310.5199 310.6604 310.8009 310.9413 311.0818 311.2223 311.3627 311.5031 311.6436 311.7840 311.9244 312.0648 312.2052 312.3455 312.4859 312.6262 312.7666 312.9069 313.0472 313.1875 313.3278 313.4681 313.6083 313.7486 313.8888 314.0291 314.1693 314.3095 314.4497 314.5899 314.7301 314.8702 315.0104 315.1505 315.2906 315.4308 315.5709 315.7110 315.8511 315.9911 316.1312 316.2712 316.4113 316.5513 316.6913 316.8313 316.9713 317.1113 317.2513 317.3912 317.5312 317.6711 317.8111 317.9510 318.0909 318.2308 318.3706 318.5105 318.6504 318.7902 318.9301 319.0699 319.2097 319.3495 319.4893 319.6291 319.7688 319.9086 320.0483 320.1881 320.3278 320.4675 320.6072 320.7469 320.8865 321.0262 321.1659 321.3055 321.4451 321.5847 321.7243 321.8639 322.0035 322.1431 322.2827 322.4222 322.5617 322.7013 322.8408 322.9803 323.1198 323.2593 323.3987 323.5382 323.6776 323.8171 323.9565 324.0959 324.2353 324.3747 324.5141 324.6534 324.7928 324.9321 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 77: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 79: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 80: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 82: Atmospheric variability [%], 999=no atmospheric variability was determined Column 83: Wavelength effective temperature [°C], 999=no effective temperature given Column 84: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 85: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 86: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 87: Number of bright count cycles Column 88: Number of dark count cycles Column 89: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 90: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 91: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 92: Integration time [ms] Column 93: Temperature at electronics board [°C], 999=no temperature signal Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Humidity in head sensor [%], -9=no humidity signal Column 98: Pressure in head sensor [hPa], -9=no pressure signal Columns 99-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250411T132741.1Z 9232.560892 212 1 54.79 2 84.62 83.35 105.18 276.65 0.00 1 0.00 1 0 17 7.107e-01 2.585e-02 5.093e-01 1.819e-02 9.807949e-01 1.066432e-02 9.794447e-03 -6.000000e+00 4.090286e-01 227.87 -2.00 3.37 -2.00 322.51 0.00e+00 9.251625e-04 6.104069e-03 2.004246e-03 -6.000000e+00 1.754014e-02 275.05 -2.00 20.00 -2.00 322.11 0.00e+00 9.339 0.013 302.00 328.00 3 8.1764e-01 4.1713e-02 9.4365e-02 -6.0000e+00 1.0240e+00 1.2449e+00 5.7190e-02 5.3105e-02 -6.0000e+00 1.1214e+00 -1.6148e+00 5.2259e-02 2.8806e-02 -6.0000e+00 6.6037e-01 6.2971e-01 2.4415e-02 1.0021e-02 -6.0000e+00 2.7368e-01 3.3629e-05 1.1696e-04 4.8618e-04 1.4209e-04 -6.0000e+00 1.9222e-02 3.7844e-02 12 9 8 11 8 0 1.32 25.34 0.82 0.03784 0.03872 57 6 1 5 0 961.110 34.25 20.02 25.34 16.33 3.6 902.16 10381 -113211 14214 109693 159543 -89710 -132714 16177 -35988 -71081 -81215 -113480 -165984 900000 900000 87496 900000 -9730 22303 -23973 58215 -44022 15337 -19788 -83152 114517 40241 900000 25316 900000 125164 -27755 900000 900000 29922 -23294 -41956 301958 -48985 335095 233819 139255 128394 -6959 20716 231875 181629 106799 30516 38702 115942 33641 20287 150984 60808 54356 18560 22900 -988 53398 32556 26895 82061 39977 22233 33222 11426 -6318 29627 9015 26509 29471 28301 45043 22030 12183 6556 2971 16344 -8811 13 -5038 14304 9734 11369 4794 -1629 2933 11418 3869 6771 -1513 -1184 -3012 -11561 -2905 -1855 -3230 -3421 -2425 -3874 -3932 -1080 -6556 -163 -3409 -5122 -1867 -1384 1729 -2984 -758 1098 -2285 657 -1655 -128 2352 250 367 -1301 1496 2534 3636 2105 125 2785 41 1531 189 445 302 684 233 102 403 470 -449 -561 -54 -154 -111 -1890 184 -3678 252 1944 2827 -1590 -3331 287 -638 -1259 -1439 -3108 -9625 900000 900000 1550 900000 -235 395 -656 1032 -1276 272 -478 -3884 2029 713 900000 449 900000 2218 -984 900000 900000 627 -788 -1825 5350 -3156 5938 4143 2467 2275 -381 834 4109 3218 1892 1229 1559 2428 1788 1340 2919 3036 2977 1465 1660 -84 2494 1888 1820 3701 3155 2220 2943 1417 -996 3675 1581 4227 4648 4313 5268 2850 1533 836 421 2404 -2045 3 -1562 4030 3036 3707 1758 -661 1154 4067 1412 2232 -517 -407 -1158 -5736 -1590 -1196 -2478 -2885 -2015 -3027 -2703 -645 -4170 -105 -2386 -3893 -1512 -1275 1814 -3780 -1022 1494 -3182 858 -2164 -170 3201 366 546 -1885 1983 3201 4414 2521 148 3178 53 2333 341 905 670 1626 601 284 1171 1380 -1344 -1651 -147 -388 -256 -4301 SS 20250411T133855.3Z 9232.568696 215 1 54.48 2 82.36 84.98 107.39 278.30 0.00 1 0.00 1 0 17 6.239e-01 7.242e-03 2.934e-01 2.968e-03 8.104819e-01 1.637171e-03 8.457269e-03 -6.000000e+00 3.512439e-01 227.87 -2.00 3.37 -2.00 321.87 0.00e+00 4.218952e-03 8.675058e-04 3.014722e-03 -6.000000e+00 1.522742e-02 275.05 -2.00 20.00 -2.00 321.42 0.00e+00 7.008 0.005 302.00 328.00 3 6.7370e-01 5.7611e-03 7.2662e-02 -6.0000e+00 8.7530e-01 1.4630e-01 9.5367e-03 4.4760e-02 -6.0000e+00 9.5313e-01 -1.7196e-01 1.1361e-02 2.8353e-02 -6.0000e+00 5.6552e-01 5.7426e-02 5.1679e-03 1.1955e-02 -6.0000e+00 2.3952e-01 3.3977e-04 4.9593e-04 7.9446e-05 1.4406e-04 -6.0000e+00 1.6358e-02 3.7386e-02 11 8 0 10 0 0 19.54 25.35 0.44 0.03739 0.04111 219 22 1 5 0 248.750 34.25 20.02 25.35 16.81 3.6 905.73 -107267 900000 -234993 -219983 -233760 -262931 -179159 -104870 -22350 -220854 -241978 -140169 -122838 -78721 -136638 55755 -44133 -54247 24788 -111544 -84181 -70002 -81746 -8864 -52455 -76095 -67315 -77267 18147 -43910 1136 -45049 -60285 4841 81628 -17240 -25990 -1890 2216 -14270 14138 -7217 1648 -4467 -13419 19582 6737 7707 -4101 -7899 -728 5356 744 11364 -220 5438 621 7192 -3152 1770 -550 -230 4937 4909 2746 1509 5204 2281 5119 3915 2098 1862 16 -778 1769 -3126 -346 -1173 -1916 -1256 -113 -813 -1845 -320 5 123 527 907 1937 858 1669 -955 -511 -192 -1039 -958 542 1188 598 -524 -489 -914 -1671 -141 -1634 -1655 -1724 -698 -437 252 306 209 142 -264 -274 -223 165 470 347 170 396 812 965 275 717 -511 -127 791 259 56 -236 -106 -584 -131 -183 -197 263 564 -19 3 -32 -481 -49 -310 900000 -1174 -926 -1045 -1591 -518 -303 -65 -1394 -2037 -516 -517 -290 -1186 161 -221 -342 78 -1467 -864 -626 -882 -51 -511 -1001 -832 -1037 95 -497 10 -818 -1522 76 567 -324 -602 -42 58 -537 454 -311 69 -206 -691 754 308 372 -241 -533 -52 414 67 1016 -24 579 72 770 -361 190 -63 -30 707 811 493 272 920 441 1090 983 589 543 5 -211 421 -700 -72 -261 -503 -399 -42 -353 -889 -161 3 70 313 550 1154 493 885 -492 -259 -104 -659 -718 471 1189 654 -573 -495 -823 -1374 -116 -1477 -1572 -1740 -757 -530 316 432 314 215 -390 -386 -303 228 682 534 269 604 1169 1338 371 1021 -712 -173 1151 401 99 -466 -225 -1318 -315 -475 -533 721 1561 -52 9 -78 -1089 -108 SS 20250411T135640.9Z 9232.581029 220 1 54.45 2 78.78 87.55 110.86 280.99 0.00 1 0.00 1 0 17 2.386e-01 5.852e-03 3.172e-02 7.404e-04 6.057864e-01 3.811046e-04 6.461244e-03 -6.000000e+00 1.343000e-01 227.87 -2.00 3.37 -2.00 320.67 0.00e+00 2.307137e-03 1.497289e-04 1.153464e-03 -6.000000e+00 5.768996e-03 275.05 -2.00 20.00 -2.00 320.15 0.00e+00 4.967 0.002 302.00 328.00 3 4.1413e-01 1.1609e-03 5.1593e-02 -6.0000e+00 3.3468e-01 3.4586e-02 1.5164e-03 3.0706e-02 -6.0000e+00 3.6442e-01 -3.2733e-02 1.5678e-03 1.7039e-02 -6.0000e+00 2.1606e-01 3.6754e-03 7.8190e-04 6.4798e-03 -6.0000e+00 9.0977e-02 2.7469e-03 4.6613e-04 2.0035e-05 6.6282e-05 -6.0000e+00 6.2523e-03 3.7077e-02 10 0 0 10 0 0 24.61 25.38 0.32 0.03708 0.04058 706 72 1 5 0 77.110 34.00 20.01 25.38 18.23 3.6 915.65 -102328 -65402 -68616 -78963 -72303 -99236 -86947 -63925 -68210 -51544 -74821 -45693 -50106 -36727 -38830 -26566 -19376 -15725 -16967 -16219 -11757 -14084 -23521 -12686 -18063 -13143 -13931 -16326 -10228 -11007 -5184 -6059 -3904 -6770 -9291 -9369 -8125 -4794 -1806 -2370 -2402 -1794 -583 -339 979 509 258 496 -260 608 1464 1823 2128 2096 1915 2117 1045 517 262 682 1615 2358 3304 3238 887 522 459 130 1049 773 808 1030 641 399 -196 -958 -1708 -2076 -1123 -1260 -973 -1116 -2079 -1423 -688 -182 388 568 1107 912 814 143 -448 -448 -335 -86 556 1151 314 -284 -535 -865 -627 -187 -1248 -1301 -1072 -697 35 372 367 184 271 -76 -264 26 145 119 306 50 -48 480 700 305 479 -295 -65 853 259 -80 -296 -315 -435 -79 -111 -237 253 569 210 -67 -24 -342 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