File name: Pandora254s1_TubaCityAZ_20250414_L2Fit_fout2c2d20221208p1-8.txt File generation date: 20250415T073018.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Vaughn Salabye Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 254 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora254_OF_v2d20221208.txt Instrument calibration file used: Pandora254s1_CF_v2d20221208.txt Level 1 file used: Pandora254s1_TubaCityAZ_20250414_L1_smca1c2d20221208p1-8.txt Full location name: Greyhills Academy High School, Tuba City, AZ Short location name: TubaCityAZ Country of location: United States Location latitude [deg]: 36.1270 Location longitude [deg]: -111.2212 Location altitude [m]: 1470 Local noon date: 20250414 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 192 334 Nominal wavelengths inside fitting window [nm]: 305.0315 305.1725 305.3134 305.4543 305.5952 305.7361 305.8770 306.0179 306.1587 306.2996 306.4404 306.5812 306.7220 306.8629 307.0036 307.1444 307.2852 307.4260 307.5667 307.7074 307.8482 307.9889 308.1296 308.2703 308.4110 308.5516 308.6923 308.8330 308.9736 309.1142 309.2548 309.3954 309.5360 309.6766 309.8172 309.9577 310.0983 310.2388 310.3793 310.5199 310.6604 310.8009 310.9413 311.0818 311.2223 311.3627 311.5031 311.6436 311.7840 311.9244 312.0648 312.2052 312.3455 312.4859 312.6262 312.7666 312.9069 313.0472 313.1875 313.3278 313.4681 313.6083 313.7486 313.8888 314.0291 314.1693 314.3095 314.4497 314.5899 314.7301 314.8702 315.0104 315.1505 315.2906 315.4308 315.5709 315.7110 315.8511 315.9911 316.1312 316.2712 316.4113 316.5513 316.6913 316.8313 316.9713 317.1113 317.2513 317.3912 317.5312 317.6711 317.8111 317.9510 318.0909 318.2308 318.3706 318.5105 318.6504 318.7902 318.9301 319.0699 319.2097 319.3495 319.4893 319.6291 319.7688 319.9086 320.0483 320.1881 320.3278 320.4675 320.6072 320.7469 320.8865 321.0262 321.1659 321.3055 321.4451 321.5847 321.7243 321.8639 322.0035 322.1431 322.2827 322.4222 322.5617 322.7013 322.8408 322.9803 323.1198 323.2593 323.3987 323.5382 323.6776 323.8171 323.9565 324.0959 324.2353 324.3747 324.5141 324.6534 324.7928 324.9321 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 77: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 79: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 80: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 82: Atmospheric variability [%], 999=no atmospheric variability was determined Column 83: Wavelength effective temperature [°C], 999=no effective temperature given Column 84: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 85: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 86: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 87: Number of bright count cycles Column 88: Number of dark count cycles Column 89: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 90: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 91: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 92: Integration time [ms] Column 93: Temperature at electronics board [°C], 999=no temperature signal Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Humidity in head sensor [%], -9=no humidity signal Column 98: Pressure in head sensor [hPa], -9=no pressure signal Columns 99-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250414T133336.2Z 9235.565002 220 1 56.10 2 82.64 83.43 92.02 247.36 0.00 1 0.00 1 0 17 6.233e-01 3.338e-02 4.794e-01 2.614e-02 8.699790e-01 1.529359e-02 8.920770e-03 -6.000000e+00 3.600745e-01 228.09 -2.00 3.37 -2.00 322.07 0.00e+00 4.438731e-03 8.015996e-03 1.177861e-03 -6.000000e+00 1.754209e-02 275.36 -2.00 20.00 -2.00 321.63 0.00e+00 7.241 0.006 302.00 328.00 3 3.1113e+00 5.5433e-02 7.6292e-02 -6.0000e+00 9.0177e-01 8.7875e-01 7.4458e-02 4.7654e-02 -6.0000e+00 9.8943e-01 -1.1938e+00 6.8519e-02 2.4023e-02 -6.0000e+00 5.8113e-01 5.0393e-01 3.2365e-02 8.8959e-03 -6.0000e+00 2.4466e-01 1.9691e-05 -5.2832e-04 7.3243e-04 1.1445e-04 -6.0000e+00 1.7525e-02 3.8527e-02 12 9 8 11 8 0 96.08 24.90 0.57 0.03853 0.03456 16 2 1 5 0 3505.640 33.75 19.96 24.90 15.06 3.6 893.76 900000 -126627 144650 900000 900000 107254 900000 -127582 -139871 900000 -182127 59442 42641 -53595 900000 900000 -86851 900000 23828 900000 -21726 -123141 900000 900000 -43515 900000 224592 -39283 -86091 28470 -27290 900000 95596 117368 108499 900000 202428 -87719 900000 70783 189645 171684 57781 77978 -13516 50150 196206 98822 87344 21669 40640 64112 31787 33543 67751 37697 87876 -15757 18672 379 51868 45424 20048 18233 29076 16730 21016 24246 16850 14163 23729 19109 24777 33598 -6326 12367 33016 -11723 19205 4025 -3334 6576 7445 5675 -5935 -7510 -5440 2859 1288 4436 6798 -4062 -945 -1300 2388 -6298 -3334 -4083 -1768 -1040 -1514 2752 -2407 -7502 -4650 -2787 -768 3082 -2782 911 -5112 2839 -1412 -1193 -653 85 161 -61 -2085 2085 1782 548 3817 -1359 5226 2593 -79 2885 1265 1869 -692 869 -1328 1095 -35 -412 614 1504 700 270 -3734 -623 -1196 900000 -4023 3677 900000 900000 2726 900000 -3243 -3851 900000 -7715 1511 1084 -1362 900000 900000 -4415 900000 606 900000 -602 -8821 900000 900000 -1508 900000 5709 -1180 -3979 724 -946 900000 2430 2983 2758 900000 5145 -8513 900000 1963 4820 4364 2136 2342 -999 1970 4987 2512 2624 1352 2348 3259 2424 2713 4070 3136 4467 -2185 1726 40 3356 3464 2270 2401 3628 2319 2817 3305 3041 3024 5006 4323 5101 5807 -1447 2075 4280 -2503 3515 1044 -1101 2273 2801 2293 -2866 -3894 -2876 1417 642 2041 2834 -1786 -399 -592 1220 -4178 -2534 -3642 -1685 -978 -1328 2043 -1688 -5587 -3629 -2246 -644 2710 -2920 1065 -7212 3977 -2096 -1729 -900 113 218 -87 -3207 3143 2600 765 4958 -1796 6243 3078 -93 3608 1884 3188 -1349 1798 -2983 2572 -89 -1097 1638 4011 1850 672 -8912 -1331 -2475 SS 20250414T135727.8Z 9235.581572 231 1 54.06 2 77.84 86.87 96.43 250.62 0.00 1 0.00 1 0 17 3.570e-01 8.799e-03 2.394e-01 5.912e-03 6.049483e-01 3.073458e-03 6.515568e-03 -6.000000e+00 2.011029e-01 228.09 -2.00 3.37 -2.00 320.94 0.00e+00 3.859718e-03 1.292900e-03 1.318314e-03 -6.000000e+00 8.642943e-03 275.36 -2.00 20.00 -2.00 320.44 0.00e+00 4.612 0.001 302.00 328.00 3 3.7746e+00 9.6362e-03 4.9422e-02 -6.0000e+00 5.0136e-01 9.1733e-02 1.2798e-02 3.0865e-02 -6.0000e+00 5.4584e-01 -7.2097e-02 1.3323e-02 1.7839e-02 -6.0000e+00 3.2363e-01 1.8655e-02 6.5474e-03 7.8923e-03 -6.0000e+00 1.3621e-01 1.2170e-04 5.9463e-04 1.6360e-04 8.7587e-05 -6.0000e+00 9.3573e-03 3.8611e-02 11 8 0 10 0 0 98.94 24.90 0.19 0.03861 0.04308 26 3 1 5 0 2079.050 33.75 19.95 24.90 15.60 3.6 896.63 -134580 -103105 -145845 183398 -74349 -169851 -139832 -82596 -49904 -85741 -12409 -39291 -43453 -51920 -62097 -41933 -19361 -22967 -7133 4087 15474 -36495 -12359 -43746 10048 -4922 2832 -20250 -10022 -13862 -16233 -7618 560 -4512 -6768 -26399 -996 -6502 6646 3251 10222 -1939 4714 2448 7082 5071 -3722 4498 3180 10265 -1001 235 2282 22 2889 -273 39 -26 -324 1513 1754 -487 6011 2909 4208 2163 3190 2395 -192 -1360 197 1381 1270 808 -1492 -2903 -1438 -3460 -2099 -20 -2384 -1908 -3874 -799 287 2107 400 140 681 1758 717 -1511 948 -316 -78 860 768 -223 771 -1 -566 -1346 -1062 -155 -1430 -1159 -1007 -1160 155 133 1250 -62 -149 91 -703 -76 -323 21 -254 400 -186 1147 1285 329 487 -490 -466 -69 641 75 -22 162 -584 -134 -35 141 205 203 -38 165 469 -806 -381 -1411 -919 -2140 1057 -468 -2760 -1832 -693 -340 -899 -72 -309 -455 -762 -1269 -835 -345 -469 -135 73 251 -995 -279 -1467 211 -126 68 -594 -263 -414 -655 -334 26 -234 -339 -1613 -53 -435 479 289 943 -216 516 281 788 591 -483 555 414 1332 -162 42 434 5 623 -63 9 -6 -74 334 403 -127 1674 934 1376 693 997 777 -71 -589 92 658 593 356 -611 -1078 -493 -1235 -836 -9 -1311 -1185 -2655 -560 213 1636 331 119 572 1393 531 -1066 625 -218 -60 765 788 -264 964 -1 -652 -1398 -1014 -151 -1529 -1297 -1186 -1465 211 202 2059 -108 -255 148 -1080 -112 -482 33 -423 686 -315 1843 1994 495 700 -684 -626 -98 1021 134 -42 329 -1138 -276 -78 322 476 480 -88 369 985 -1777 -819 SS 20250414T140238.3Z 9235.585166 234 1 19.26 2 76.79 87.62 97.39 251.31 0.00 1 0.00 1 0 17 3.052e-01 1.018e-02 1.637e-01 6.097e-03 5.679677e-01 3.098658e-03 6.208527e-03 -6.000000e+00 1.719335e-01 228.09 -2.00 3.37 -2.00 320.48 0.00e+00 8.544487e-04 1.130774e-03 1.739200e-03 -6.000000e+00 7.389379e-03 275.36 -2.00 20.00 -2.00 319.94 0.00e+00 4.272 0.001 302.00 328.00 3 3.8141e+00 9.2269e-03 4.6212e-02 -6.0000e+00 4.2864e-01 7.6932e-02 1.1657e-02 2.9634e-02 -6.0000e+00 4.6667e-01 -8.5699e-02 1.1236e-02 1.5514e-02 -6.0000e+00 2.7669e-01 3.3504e-02 5.6774e-03 4.7774e-03 -6.0000e+00 1.1645e-01 1.6258e-04 6.2907e-04 1.6654e-04 5.6841e-05 -6.0000e+00 8.0002e-03 3.8810e-02 12 9 9 12 9 1 97.41 24.90 0.33 0.03881 0.04354 9 3 1 5 0 1925.590 33.75 20.00 24.90 15.58 3.6 896.53 -82819 -104910 -114483 -137647 -56947 -123603 -114088 29620 -114014 -85895 -70330 -89019 23094 -56260 35926 21875 -17960 -39281 -26284 5020 -6071 -14598 -15195 -19984 -16247 -1452 -32402 12955 -11016 131 -1899 7653 10699 6057 6701 5827 376 1141 -2696 -1375 569 -112 60 4627 -963 -712 3941 2195 2366 1717 659 1202 1562 4141 4567 -970 1568 -767 825 3412 254 2814 6356 5901 2709 834 -826 1777 169 2593 2254 465 1239 389 1139 -211 -1521 -2662 -3588 -952 -1314 -188 -1151 -1854 -1375 -639 578 -442 928 610 227 -38 335 -1156 -709 -405 -252 428 -142 -941 -1449 -303 -794 475 -681 -1293 -1948 -787 -355 689 1080 146 -55 142 -316 100 149 979 5 192 -575 1070 888 -45 1036 -89 956 595 362 -108 397 -226 -497 37 -338 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