File name: Pandora254s1_TubaCityAZ_20250624_L2Fit_fout2c2d20221208p1-8.txt File generation date: 20250625T073218.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Vaughn Salabye Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 254 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora254_OF_v2d20221208.txt Instrument calibration file used: Pandora254s1_CF_v2d20221208.txt Level 1 file used: Pandora254s1_TubaCityAZ_20250624_L1_smca1c2d20221208p1-8.txt Full location name: Greyhills Academy High School, Tuba City, AZ Short location name: TubaCityAZ Country of location: United States Location latitude [deg]: 36.1270 Location longitude [deg]: -111.2212 Location altitude [m]: 1470 Local noon date: 20250624 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 192 334 Nominal wavelengths inside fitting window [nm]: 305.0315 305.1725 305.3134 305.4543 305.5952 305.7361 305.8770 306.0179 306.1587 306.2996 306.4404 306.5812 306.7220 306.8629 307.0036 307.1444 307.2852 307.4260 307.5667 307.7074 307.8482 307.9889 308.1296 308.2703 308.4110 308.5516 308.6923 308.8330 308.9736 309.1142 309.2548 309.3954 309.5360 309.6766 309.8172 309.9577 310.0983 310.2388 310.3793 310.5199 310.6604 310.8009 310.9413 311.0818 311.2223 311.3627 311.5031 311.6436 311.7840 311.9244 312.0648 312.2052 312.3455 312.4859 312.6262 312.7666 312.9069 313.0472 313.1875 313.3278 313.4681 313.6083 313.7486 313.8888 314.0291 314.1693 314.3095 314.4497 314.5899 314.7301 314.8702 315.0104 315.1505 315.2906 315.4308 315.5709 315.7110 315.8511 315.9911 316.1312 316.2712 316.4113 316.5513 316.6913 316.8313 316.9713 317.1113 317.2513 317.3912 317.5312 317.6711 317.8111 317.9510 318.0909 318.2308 318.3706 318.5105 318.6504 318.7902 318.9301 319.0699 319.2097 319.3495 319.4893 319.6291 319.7688 319.9086 320.0483 320.1881 320.3278 320.4675 320.6072 320.7469 320.8865 321.0262 321.1659 321.3055 321.4451 321.5847 321.7243 321.8639 322.0035 322.1431 322.2827 322.4222 322.5617 322.7013 322.8408 322.9803 323.1198 323.2593 323.3987 323.5382 323.6776 323.8171 323.9565 324.0959 324.2353 324.3747 324.5141 324.6534 324.7928 324.9321 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 77: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 79: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 80: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 82: Atmospheric variability [%], 999=no atmospheric variability was determined Column 83: Wavelength effective temperature [°C], 999=no effective temperature given Column 84: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 85: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 86: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 87: Number of bright count cycles Column 88: Number of dark count cycles Column 89: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 90: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 91: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 92: Integration time [ms] Column 93: Temperature at electronics board [°C], 999=no temperature signal Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Humidity in head sensor [%], -9=no humidity signal Column 98: Pressure in head sensor [hPa], -9=no pressure signal Columns 99-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250624T125828.9Z 9306.540613 78 1 54.88 2 81.92 66.87 69.90 69.84 0.00 1 0.00 1 0 17 6.164e-01 1.418e-02 4.608e-01 1.206e-02 7.779267e-01 6.927766e-03 8.522657e-03 -6.000000e+00 3.577279e-01 231.52 -2.00 3.37 -2.00 321.93 0.00e+00 4.804714e-03 4.001312e-03 5.009055e-03 -6.000000e+00 1.695788e-02 282.69 -2.00 20.00 -2.00 321.42 0.00e+00 6.666 0.005 302.00 328.00 3 2.7274e+00 2.6821e-02 7.2720e-02 -6.0000e+00 8.9952e-01 2.4800e-01 4.0945e-02 4.9416e-02 -6.0000e+00 9.7960e-01 -3.2952e-01 4.3776e-02 2.8091e-02 -6.0000e+00 5.7691e-01 1.2917e-01 1.9671e-02 9.6048e-03 -6.0000e+00 2.4112e-01 5.6102e-05 2.8782e-04 3.4102e-04 1.6234e-04 -6.0000e+00 1.6462e-02 3.5673e-02 12 8 8 10 0 0 13.22 25.30 0.43 0.03567 0.03784 32 3 1 5 0 1714.670 34.00 20.01 25.30 20.90 3.5 931.30 -222524 -172308 -72726 -168093 900000 900000 -217962 -254825 12992 900000 -238046 -197564 900000 -61826 900000 -74620 900000 -106844 -29077 900000 47045 900000 -4523 4374 136521 141689 -7175 71043 -84454 -41406 -80738 35001 171933 58304 75416 900000 -42757 117271 11045 37627 53790 -17002 -540 -16963 6117 105760 -12426 42154 -14366 4643 12242 522 11738 15721 10864 29927 30124 -17887 11938 17251 2466 -2070 12687 18719 4672 -256 16515 8397 6835 -1882 7021 4861 4157 2367 -4774 2501 -841 4883 -1088 -1853 -4152 -5310 -2450 -5534 -1415 338 3433 2008 1453 1661 369 -66 417 -1485 -1837 -1802 -102 -534 604 -845 -328 23 -32 -1566 -1238 -4417 -731 743 -954 955 927 -1048 797 701 -1341 -1428 1733 94 1206 31 -310 1259 549 1564 -600 195 -1054 963 521 133 -139 194 -1046 -88 289 -399 -158 937 406 -193 -236 -747 -87 -2613 -2023 -854 -1974 900000 900000 -2559 -3536 153 900000 -3558 -2320 900000 -726 900000 -876 900000 -1825 -341 900000 552 900000 -53 51 1603 1664 -84 834 -1713 -619 -2241 411 2019 685 886 900000 -1324 1377 295 924 1263 -871 -25 -942 274 1806 -716 1485 -951 278 771 42 927 1309 1009 2396 2476 -2349 1234 1661 287 -282 1728 2748 834 -47 2599 1509 1405 -491 1839 1347 1133 612 -1194 520 -172 986 -271 -564 -1526 -2276 -1119 -2762 -726 181 1870 1137 822 897 188 -32 196 -755 -1081 -1251 -82 -497 604 -848 -304 19 -24 -1210 -1030 -3994 -676 732 -1067 1196 1301 -1594 1198 1021 -1895 -1954 2343 136 1830 49 -478 1817 770 2093 -790 246 -1311 1262 794 233 -268 401 -2311 -207 726 -1052 -423 2518 1085 -491 -558 -1662 -187 SS 20250624T131515.2Z 9306.552260 83 1 54.70 2 78.78 69.13 66.82 71.75 0.00 1 0.00 1 0 17 3.344e-01 7.055e-03 2.101e-01 3.261e-03 6.150555e-01 1.737789e-03 6.561528e-03 -6.000000e+00 1.909487e-01 231.52 -2.00 3.37 -2.00 321.02 0.00e+00 1.767647e-03 7.780632e-04 1.502227e-03 -6.000000e+00 8.349283e-03 282.69 -2.00 20.00 -2.00 320.42 0.00e+00 4.964 0.002 302.00 328.00 3 2.6513e+00 5.7083e-03 5.2633e-02 -6.0000e+00 4.7883e-01 5.5707e-02 7.6809e-03 3.2417e-02 -6.0000e+00 5.1920e-01 -4.9729e-02 7.7011e-03 1.7477e-02 -6.0000e+00 3.0828e-01 1.0192e-02 3.7231e-03 5.8736e-03 -6.0000e+00 1.2975e-01 2.8316e-04 5.1270e-04 9.0660e-05 6.5757e-05 -6.0000e+00 8.7735e-03 3.4356e-02 11 9 0 11 8 0 38.11 25.39 0.42 0.03436 0.03821 72 7 1 5 0 759.660 34.00 20.00 25.39 22.29 3.4 939.87 -164303 -151326 -160193 -10892 31444 -129313 -68271 -28907 -28817 -125830 -104663 35033 -86421 -66050 -12549 54414 -953 63623 -3268 10545 -11733 -3034 -26624 -18028 -4693 -23248 -19293 -15169 -42303 4903 -12369 -14705 -5050 -11091 -12947 -9384 -7578 1800 -1340 3698 -943 768 -836 -3716 4271 2276 1113 2368 5063 777 3986 4486 -27 2331 2018 -616 1646 1915 538 -2018 914 2296 2258 4246 253 2136 1855 1582 1927 862 1190 1430 1265 1737 -496 -1968 -1678 -2053 -1942 -1205 -1582 -1028 -2067 -2748 -259 -40 122 402 656 1014 2052 -107 -143 127 -150 -181 306 1219 66 -162 -806 -1058 -723 173 -945 -1077 -855 -653 -2 130 573 13 422 -319 -236 -158 -118 183 441 157 60 269 615 304 263 175 227 510 348 -282 -72 -252 -511 -250 170 -239 168 669 143 180 -20 -640 -438 -1805 -1706 -2130 -35 100 -1121 -355 -117 -133 -1673 -1180 111 -1174 -936 -131 346 -12 460 -50 149 -214 -51 -600 -412 -102 -710 -577 -420 -1507 118 -425 -613 -222 -550 -622 -436 -388 101 -96 302 -91 78 -90 -423 455 253 128 277 602 103 574 719 -5 455 418 -137 369 425 118 -447 204 561 628 1296 83 664 570 503 681 356 539 671 585 753 -200 -721 -574 -716 -763 -558 -856 -629 -1390 -1965 -194 -32 102 344 556 820 1521 -75 -97 88 -118 -165 319 1309 77 -186 -955 -1128 -707 173 -1033 -1239 -1035 -768 -3 185 892 21 680 -494 -343 -220 -166 270 691 256 96 417 917 436 362 255 319 753 529 -482 -134 -495 -1050 -544 396 -583 416 1679 358 430 -45 -1370 -914 SS 20250624T132150.2Z 9306.556831 86 1 54.61 2 77.53 70.00 65.59 72.49 0.00 1 0.00 1 0 17 1.472e-01 5.919e-03 1.060e-01 2.280e-03 5.600686e-01 1.194102e-03 6.103699e-03 -6.000000e+00 8.406788e-02 231.52 -2.00 3.37 -2.00 320.62 0.00e+00 1.765641e-03 4.718223e-04 1.552024e-03 -6.000000e+00 3.675995e-03 282.69 -2.00 20.00 -2.00 320.00 0.00e+00 4.504 0.001 302.00 328.00 3 2.6263e+00 3.7451e-03 4.7902e-02 -6.0000e+00 2.1081e-01 3.9297e-02 4.8062e-03 2.9559e-02 -6.0000e+00 2.2859e-01 -3.8630e-02 4.5751e-03 1.5480e-02 -6.0000e+00 1.3573e-01 6.5915e-03 2.2696e-03 4.9373e-03 -6.0000e+00 5.7122e-02 4.4807e-04 4.6076e-04 6.3629e-05 6.1162e-05 -6.0000e+00 3.8629e-03 3.4729e-02 11 1 0 11 8 0 30.08 25.43 0.30 0.03473 0.03819 95 10 1 5 0 574.790 34.00 20.01 25.43 22.80 3.5 942.89 -5315 -16921 -36865 -21314 -68735 -64156 -66835 -439 -65953 -20071 -16447 -54387 -60640 619 -6374 -5452 -3426 -18333 -11457 -17052 -2315 -18362 -1387 -9677 -10655 -13354 -7977 -12024 -10072 -10938 -7963 7678 -1635 -3263 -6636 -5257 -5924 -3273 -2313 -4516 -1529 -722 -36 -1599 152 -467 861 -284 -3502 839 1136 1812 911 2669 2150 1839 547 31 931 427 520 1820 3163 2826 1699 60 -196 -578 930 1627 1252 1501 327 402 531 -129 -1073 -2745 -786 -892 -1539 -830 -1933 -1617 -729 -597 555 414 1091 795 503 282 -360 -192 -463 -33 672 826 429 -83 -888 -909 -764 -52 -936 -1356 -1062 -541 -142 388 476 203 269 208 -401 -120 401 142 225 -55 52 569 569 260 524 -489 -36 497 250 129 -330 -487 -537 -135 89 -448 153 809 215 -196 51 -471 -152 -21 -89 -253 -121 -570 -506 -594 -2 -760 -158 -130 -704 -1042 7 -99 -109 -75 -510 -321 -535 -64 -600 -40 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