File name: Pandora254s1_TubaCityAZ_20250630_L2Fit_fout2c2d20221208p1-8.txt File generation date: 20250701T073626.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Vaughn Salabye Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 254 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora254_OF_v2d20221208.txt Instrument calibration file used: Pandora254s1_CF_v2d20221208.txt Level 1 file used: Pandora254s1_TubaCityAZ_20250630_L1_smca1c2d20221208p1-8.txt Full location name: Greyhills Academy High School, Tuba City, AZ Short location name: TubaCityAZ Country of location: United States Location latitude [deg]: 36.1270 Location longitude [deg]: -111.2212 Location altitude [m]: 1470 Local noon date: 20250630 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 192 334 Nominal wavelengths inside fitting window [nm]: 305.0315 305.1725 305.3134 305.4543 305.5952 305.7361 305.8770 306.0179 306.1587 306.2996 306.4404 306.5812 306.7220 306.8629 307.0036 307.1444 307.2852 307.4260 307.5667 307.7074 307.8482 307.9889 308.1296 308.2703 308.4110 308.5516 308.6923 308.8330 308.9736 309.1142 309.2548 309.3954 309.5360 309.6766 309.8172 309.9577 310.0983 310.2388 310.3793 310.5199 310.6604 310.8009 310.9413 311.0818 311.2223 311.3627 311.5031 311.6436 311.7840 311.9244 312.0648 312.2052 312.3455 312.4859 312.6262 312.7666 312.9069 313.0472 313.1875 313.3278 313.4681 313.6083 313.7486 313.8888 314.0291 314.1693 314.3095 314.4497 314.5899 314.7301 314.8702 315.0104 315.1505 315.2906 315.4308 315.5709 315.7110 315.8511 315.9911 316.1312 316.2712 316.4113 316.5513 316.6913 316.8313 316.9713 317.1113 317.2513 317.3912 317.5312 317.6711 317.8111 317.9510 318.0909 318.2308 318.3706 318.5105 318.6504 318.7902 318.9301 319.0699 319.2097 319.3495 319.4893 319.6291 319.7688 319.9086 320.0483 320.1881 320.3278 320.4675 320.6072 320.7469 320.8865 321.0262 321.1659 321.3055 321.4451 321.5847 321.7243 321.8639 322.0035 322.1431 322.2827 322.4222 322.5617 322.7013 322.8408 322.9803 323.1198 323.2593 323.3987 323.5382 323.6776 323.8171 323.9565 324.0959 324.2353 324.3747 324.5141 324.6534 324.7928 324.9321 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 77: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 79: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 80: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 82: Atmospheric variability [%], 999=no atmospheric variability was determined Column 83: Wavelength effective temperature [°C], 999=no effective temperature given Column 84: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 85: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 86: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 87: Number of bright count cycles Column 88: Number of dark count cycles Column 89: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 90: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 91: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 92: Integration time [ms] Column 93: Temperature at electronics board [°C], 999=no temperature signal Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Humidity in head sensor [%], -9=no humidity signal Column 98: Pressure in head sensor [hPa], -9=no pressure signal Columns 99-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250630T130222.1Z 9312.543311 56 1 54.34 2 81.58 67.45 134.16 25.37 0.00 1 0.00 1 0 17 5.736e-01 2.947e-02 4.217e-01 2.282e-02 7.432736e-01 1.293554e-02 8.677159e-03 -6.000000e+00 3.332480e-01 231.46 -2.00 3.37 -2.00 321.89 0.00e+00 1.033919e-02 6.943159e-03 5.244416e-03 -6.000000e+00 1.584487e-02 283.21 -2.00 20.00 -2.00 321.37 0.00e+00 6.431 0.004 302.00 328.00 3 3.7142e+00 4.8017e-02 6.8891e-02 -6.0000e+00 8.3591e-01 6.1049e-01 6.3924e-02 4.3394e-02 -6.0000e+00 9.0785e-01 -9.4987e-01 5.4702e-02 2.6723e-02 -6.0000e+00 5.3546e-01 4.0499e-01 2.5485e-02 1.1751e-02 -6.0000e+00 2.2757e-01 2.4929e-05 -1.0561e-03 6.4453e-04 1.9364e-04 -6.0000e+00 1.5729e-02 3.4189e-02 12 8 8 10 0 0 39.34 25.63 0.40 0.03419 0.02625 16 2 1 5 0 3395.590 34.25 20.00 25.63 24.45 3.4 952.80 900000 -112451 63788 900000 -12282 900000 -82536 900000 -87612 -161689 900000 -171078 175137 90926 -76323 900000 180089 -92872 12541 82740 98272 900000 -48118 900000 -51000 23190 182215 -48211 -77913 900000 -44982 290360 -39424 -28202 -17489 6452 24818 66973 -20386 52569 -17925 130317 100449 71380 -12237 78894 32947 50964 40287 73963 40536 89804 49962 44315 58147 28402 55399 9050 45823 48386 35064 49676 27334 13595 3994 -7835 25210 25728 10186 22338 8954 2110 -1241 27401 691 -5738 20584 -12584 1104 9805 -3663 949 -3745 1126 5294 -1938 -853 6150 -401 3499 -3886 -3849 8387 -867 -8674 -5358 -492 685 -4694 -524 -3957 -5589 -3061 -1680 -2582 -3039 1851 -121 -96 -1177 -1319 1394 774 -1617 -577 -1540 1216 -1365 154 615 1960 1537 2794 3208 1908 784 297 -1023 -1093 2285 -627 -210 1437 763 -606 1889 -1250 1205 -520 -182 -127 -829 -2336 900000 -3539 1417 900000 -273 900000 -1833 900000 -1946 -6857 900000 -8637 3890 2020 -3083 900000 4000 -6189 304 1838 2183 900000 -1943 900000 -2163 515 4048 -1850 -3933 900000 -2180 6450 -2468 -1652 -848 235 802 1623 -1400 2017 -1520 2895 2840 2739 -1087 2868 1929 2573 2359 3286 2783 4171 3733 3759 4462 2982 4475 1133 3794 3811 3257 4414 3477 2251 766 -1645 4144 4344 2217 4962 2486 647 -383 5904 175 -1377 3566 -3131 275 2701 -1359 386 -1747 528 2540 -1063 -485 3347 -233 1873 -2080 -1932 3614 -429 -5318 -3749 -384 615 -4870 -520 -3797 -4867 -2353 -1287 -2162 -2700 1661 -120 -105 -1491 -1879 2059 1159 -2407 -807 -2101 1643 -1995 236 973 3001 2256 3910 4319 2505 1006 372 -1377 -1697 3909 -1220 -436 3092 1763 -1523 4854 -3369 3214 -1401 -463 -301 -1848 -5096 SS 20250630T131720.2Z 9312.553706 61 1 54.46 2 78.77 69.46 132.87 29.96 0.00 1 0.00 1 0 17 3.847e-01 9.757e-03 2.738e-01 5.971e-03 6.125879e-01 3.181130e-03 6.726723e-03 -6.000000e+00 2.196488e-01 231.46 -2.00 3.37 -2.00 321.18 0.00e+00 4.138733e-03 1.495662e-03 2.143324e-03 -6.000000e+00 9.744601e-03 283.21 -2.00 20.00 -2.00 320.59 0.00e+00 4.960 0.002 302.00 328.00 3 3.4448e+00 1.0757e-02 5.2846e-02 -6.0000e+00 5.5062e-01 5.7612e-02 1.4594e-02 3.2801e-02 -6.0000e+00 5.9703e-01 -9.1976e-02 1.4573e-02 1.8867e-02 -6.0000e+00 3.5465e-01 2.9076e-02 6.9691e-03 7.5529e-03 -6.0000e+00 1.4949e-01 1.2998e-04 5.7636e-04 1.6785e-04 9.6729e-05 -6.0000e+00 1.0117e-02 3.4618e-02 12 8 8 10 0 0 46.96 25.67 0.28 0.03462 0.03895 39 4 1 5 0 1396.240 34.25 20.00 25.67 25.25 3.4 957.98 -197779 -197556 -138900 -77776 -55133 -42577 91095 -83510 -144589 -15509 -92589 -130311 900000 -39733 -26077 -28629 -48395 -10173 100916 -39215 -4035 -45811 -38633 39115 -1559 35368 284 -42612 -13801 -17669 -41846 17886 -1521 -26450 -5169 -974 569 7092 -5804 2339 -111 -2262 3029 11296 -817 4740 748 4608 19 5267 9240 2228 6555 4768 6483 2539 395 -4502 -1508 2287 8434 2863 2747 3784 2492 291 2900 -2196 1660 1702 1250 3028 1002 1177 787 -3013 1339 -1838 -4228 -1209 -3167 310 -2870 -110 -276 -1219 1228 -139 775 1466 -39 736 -1259 316 -794 -1126 751 8 565 -174 534 -1466 -711 -955 -1042 -1616 -453 -794 -635 552 544 -15 52 -259 -1170 926 -112 -165 718 -258 -43 764 1072 153 903 92 -152 1280 602 72 -464 -344 -508 -347 9 -190 343 1201 303 9 -251 -926 -320 -3141 -3660 -1544 -453 -321 -248 530 -575 -2066 -90 -882 -2069 900000 -421 -304 -409 -948 -151 588 -893 -66 -1140 -941 476 -31 505 6 -1308 -314 -458 -1661 464 -56 -1448 -217 -39 25 351 -402 178 -10 -216 289 1019 -85 477 80 491 2 622 1173 338 1042 838 1182 500 82 -970 -306 443 1606 640 701 1071 740 85 814 -669 541 642 520 1284 426 470 287 -1023 408 -589 -1568 -517 -1608 173 -1795 -71 -190 -907 936 -110 607 1091 -27 476 -798 204 -583 -961 726 8 673 -205 582 -1462 -648 -899 -1064 -1745 -511 -962 -841 807 874 -26 86 -414 -1768 1317 -164 -253 1164 -439 -72 1220 1652 229 1284 127 -202 1778 953 128 -901 -705 -1090 -790 19 -442 805 2848 720 20 -594 -2081 -699 SS 20250630T132356.5Z 9312.558293 64 1 54.26 2 77.51 70.34 132.23 31.92 0.00 1 0.00 1 0 17 3.394e-01 6.721e-03 2.251e-01 3.940e-03 5.638504e-01 2.061170e-03 6.043711e-03 -6.000000e+00 1.937475e-01 231.46 -2.00 3.37 -2.00 320.83 0.00e+00 1.285567e-03 8.785127e-04 1.501610e-03 -6.000000e+00 8.491637e-03 283.21 -2.00 20.00 -2.00 320.21 0.00e+00 4.499 0.001 302.00 328.00 3 3.3200e+00 6.5753e-03 4.7912e-02 -6.0000e+00 4.8569e-01 -1.0660e-02 8.7128e-03 2.9769e-02 -6.0000e+00 5.2661e-01 -1.4836e-02 8.6195e-03 1.5609e-02 -6.0000e+00 3.1279e-01 3.0122e-04 4.2230e-03 4.8388e-03 -6.0000e+00 1.3174e-01 2.2901e-04 4.2884e-04 1.1083e-04 5.2192e-05 -6.0000e+00 8.9034e-03 3.4061e-02 11 9 0 11 8 0 51.56 25.71 0.43 0.03406 0.03728 53 5 1 5 0 1023.560 34.25 20.00 25.71 25.53 3.4 959.46 -131274 -74238 98764 -106265 -39042 86167 -102055 248996 -108860 51198 -50897 -77105 -259 -8145 59031 -8188 -1859 -2531 -15754 -21829 -17446 38964 20479 -5719 5129 -10246 -7346 -25211 -19518 -3368 -13112 4576 -4499 704 -1573 2356 -6078 -6722 7826 149 819 -3997 -310 -252 -537 -7158 6944 -1085 -2931 -1947 -109 3390 -850 937 325 3717 1286 1005 2521 315 1075 3822 1707 4448 775 762 -292 -1134 1497 1390 709 1782 253 361 294 -1057 -1235 -1956 -780 -909 -883 -1333 -2132 -2702 -1736 -96 621 630 1665 589 761 -351 -645 -322 -238 -126 1025 1101 323 -185 -347 -496 -766 -668 -786 -1097 -1294 -120 -149 478 704 118 347 -77 -94 -233 155 161 22 34 -57 672 943 277 -120 -378 -184 481 227 -144 -97 -330 -635 -167 -15 -300 204 768 63 -38 7 -521 -14 -1467 -545 380 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