File name: Pandora254s1_TubaCityAZ_20250707_L2Fit_fout2c2d20221208p1-8.txt File generation date: 20250708T073712.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Vaughn Salabye Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 254 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora254_OF_v2d20221208.txt Instrument calibration file used: Pandora254s1_CF_v2d20221208.txt Level 1 file used: Pandora254s1_TubaCityAZ_20250707_L1_smca1c2d20221208p1-8.txt Full location name: Greyhills Academy High School, Tuba City, AZ Short location name: TubaCityAZ Country of location: United States Location latitude [deg]: 36.1270 Location longitude [deg]: -111.2212 Location altitude [m]: 1470 Local noon date: 20250707 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 192 334 Nominal wavelengths inside fitting window [nm]: 305.0315 305.1725 305.3134 305.4543 305.5952 305.7361 305.8770 306.0179 306.1587 306.2996 306.4404 306.5812 306.7220 306.8629 307.0036 307.1444 307.2852 307.4260 307.5667 307.7074 307.8482 307.9889 308.1296 308.2703 308.4110 308.5516 308.6923 308.8330 308.9736 309.1142 309.2548 309.3954 309.5360 309.6766 309.8172 309.9577 310.0983 310.2388 310.3793 310.5199 310.6604 310.8009 310.9413 311.0818 311.2223 311.3627 311.5031 311.6436 311.7840 311.9244 312.0648 312.2052 312.3455 312.4859 312.6262 312.7666 312.9069 313.0472 313.1875 313.3278 313.4681 313.6083 313.7486 313.8888 314.0291 314.1693 314.3095 314.4497 314.5899 314.7301 314.8702 315.0104 315.1505 315.2906 315.4308 315.5709 315.7110 315.8511 315.9911 316.1312 316.2712 316.4113 316.5513 316.6913 316.8313 316.9713 317.1113 317.2513 317.3912 317.5312 317.6711 317.8111 317.9510 318.0909 318.2308 318.3706 318.5105 318.6504 318.7902 318.9301 319.0699 319.2097 319.3495 319.4893 319.6291 319.7688 319.9086 320.0483 320.1881 320.3278 320.4675 320.6072 320.7469 320.8865 321.0262 321.1659 321.3055 321.4451 321.5847 321.7243 321.8639 322.0035 322.1431 322.2827 322.4222 322.5617 322.7013 322.8408 322.9803 323.1198 323.2593 323.3987 323.5382 323.6776 323.8171 323.9565 324.0959 324.2353 324.3747 324.5141 324.6534 324.7928 324.9321 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 77: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 79: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 80: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 82: Atmospheric variability [%], 999=no atmospheric variability was determined Column 83: Wavelength effective temperature [°C], 999=no effective temperature given Column 84: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 85: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 86: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 87: Number of bright count cycles Column 88: Number of dark count cycles Column 89: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 90: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 91: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 92: Integration time [ms] Column 93: Temperature at electronics board [°C], 999=no temperature signal Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Humidity in head sensor [%], -9=no humidity signal Column 98: Pressure in head sensor [hPa], -9=no pressure signal Columns 99-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250707T130338.3Z 9319.544193 111 1 53.63 2 81.93 67.96 133.78 265.96 0.00 1 0.00 1 0 25 6.736e-01 1.969e-02 4.412e-01 1.350e-02 7.678816e-01 7.859691e-03 9.571102e-03 -6.000000e+00 3.952594e-01 231.39 -2.00 3.37 -2.00 321.92 0.00e+00 6.244492e-03 4.645815e-03 1.075920e-02 -6.000000e+00 1.866225e-02 283.82 -2.00 20.00 -2.00 321.42 0.00e+00 6.678 0.005 302.00 328.00 3 2.9381e+00 3.0880e-02 8.6351e-02 -6.0000e+00 1.0009e+00 2.8050e-01 4.6634e-02 7.7066e-02 -6.0000e+00 1.0956e+00 -3.5960e-01 4.8532e-02 3.7304e-02 -6.0000e+00 6.4320e-01 1.3432e-01 2.1679e-02 9.2221e-03 -6.0000e+00 2.6680e-01 4.4758e-05 4.9739e-04 3.8695e-04 2.3750e-04 -6.0000e+00 1.8770e-02 3.5183e-02 12 8 8 10 0 0 -32.36 25.60 0.48 0.03518 0.03892 26 3 1 5 0 2062.400 34.25 20.01 25.60 24.97 3.4 955.72 -91295 -5596 -107737 900000 -289153 -192878 -246654 900000 -216170 -198968 -238367 900000 900000 -205242 -82844 900000 900000 -86424 900000 900000 900000 -65228 -76134 85799 -107463 11679 97731 -59066 -83551 900000 -48193 900000 900000 104427 117160 47283 -16209 144755 900000 44421 71996 48807 68263 -18655 132608 4267 84626 51089 29555 20825 75082 21284 20723 43488 11127 18843 22686 14878 38367 40160 3328 1084 11003 14569 10182 899 3804 15521 9409 6425 3284 560 1741 411 1107 -1979 -1444 -7808 10652 1525 -7189 -193 1364 -6204 3605 2468 -234 1205 -3673 202 -6442 -1077 722 -717 -3026 4931 -3673 725 -721 2111 -1411 -4051 -2723 1201 -3161 -3282 -465 148 2454 516 1414 -1787 -506 -405 -567 275 -533 63 2993 -609 573 1263 3335 611 181 -190 307 99 -307 312 -601 -1022 696 -1446 1150 -1017 1151 260 41 122 244 695 -2136 -1199 -73 -1415 900000 -5524 -2533 -3240 900000 -2839 -2613 -3985 900000 900000 -5146 -1088 900000 900000 -1341 900000 900000 900000 -935 -1273 1127 -2823 153 1284 -987 -1796 900000 -1036 900000 900000 1372 1539 621 -406 1901 900000 1061 1461 1340 1630 -1091 1742 209 1920 1708 1306 1094 2600 1423 1534 2804 1050 1710 2032 1421 3074 3112 389 145 1546 2258 1738 165 684 2609 1891 1544 893 162 485 108 260 -429 -296 -1784 2350 447 -2710 -78 595 -3088 1743 1284 -131 681 -2166 110 -3469 -518 334 -357 -1777 3154 -3001 656 -719 2024 -1301 -3410 -2057 890 -2645 -2892 -423 145 2614 639 1944 -2691 -756 -586 -779 363 -723 90 4383 -951 861 1795 4481 814 233 -237 371 129 -465 536 -1149 -2101 1486 -3376 2813 -2661 2993 693 107 305 567 1506 -4640 SS 20250707T132039.0Z 9319.556007 116 1 54.74 2 78.72 70.26 137.07 268.18 0.00 1 0.00 1 0 17 2.682e-01 6.507e-03 1.863e-01 3.421e-03 6.020435e-01 1.817257e-03 6.461042e-03 -6.000000e+00 1.530680e-01 231.39 -2.00 3.37 -2.00 320.98 0.00e+00 1.215309e-03 8.057798e-04 1.762424e-03 -6.000000e+00 6.727321e-03 283.82 -2.00 20.00 -2.00 320.36 0.00e+00 4.943 0.002 302.00 328.00 3 2.7939e+00 5.9645e-03 5.2277e-02 -6.0000e+00 3.8357e-01 4.8343e-02 7.9515e-03 3.2267e-02 -6.0000e+00 4.1587e-01 -5.2121e-02 7.8295e-03 1.6932e-02 -6.0000e+00 2.4711e-01 1.1207e-02 3.8003e-03 5.2080e-03 -6.0000e+00 1.0415e-01 2.5500e-04 5.7948e-04 9.5591e-05 6.1011e-05 -6.0000e+00 7.0355e-03 3.3999e-02 11 8 0 10 0 0 63.39 25.64 0.32 0.03400 0.03835 65 7 1 5 0 842.050 34.25 20.00 25.64 25.89 3.4 962.13 -151582 -55303 -65154 46590 -66431 -53722 -102398 -62846 -105924 -91775 -53659 3614 -91157 -59271 -37132 -27857 -27505 -20854 -5897 -31873 -43534 -1986 -5584 4399 -15345 -1966 -20523 -24398 -14768 271 -13031 -17695 -18090 -13287 -9323 -2774 -1569 -4522 2112 -7416 -4630 874 609 84 -1870 4659 653 6680 -608 74 3963 2191 6297 1286 2614 1010 516 -1604 2289 554 2479 5464 2462 3391 1573 47 -201 -39 911 -345 1760 2600 435 483 -406 -1375 -1333 -1722 -912 -1900 -691 -1371 -1503 -1193 -469 21 231 1498 364 667 956 -50 48 -122 -342 -615 -137 980 198 -516 -983 -602 -835 539 -1603 -684 -595 -747 -243 437 499 257 424 -143 -274 -422 -26 30 467 201 119 690 473 64 626 -411 -290 802 42 3 42 -147 -454 -162 -32 -289 247 457 328 200 -94 -487 -530 -1655 -268 -375 155 -343 -244 -839 -400 -1189 -974 -407 18 -1438 -863 -541 -439 -484 -380 -100 -744 -1175 -36 -110 87 -400 -52 -671 -798 -429 7 -478 -803 -954 -709 -454 -127 -80 -284 154 -713 -485 93 68 10 -221 529 78 778 -79 10 590 371 1118 261 555 227 120 -380 506 123 562 1329 701 1069 522 15 -64 -13 331 -147 805 1226 206 216 -167 -510 -462 -608 -359 -896 -374 -850 -1014 -847 -355 17 195 1279 313 547 723 -36 33 -86 -272 -564 -144 1056 231 -597 -1168 -640 -820 538 -1774 -788 -723 -883 -312 621 779 419 683 -221 -397 -588 -37 44 731 329 192 1064 708 93 861 -604 -410 1182 64 4 77 -287 -929 -350 -74 -703 608 1146 817 477 -211 -1041 -1107 SS 20250707T132714.7Z 9319.560587 119 1 54.65 2 77.47 71.13 138.34 269.07 0.00 1 0.00 1 0 17 1.958e-01 5.920e-03 8.422e-02 2.454e-03 5.500587e-01 1.283429e-03 6.021922e-03 -6.000000e+00 1.117405e-01 231.39 -2.00 3.37 -2.00 320.62 0.00e+00 2.054601e-03 5.087733e-04 1.433540e-03 -6.000000e+00 4.910989e-03 283.82 -2.00 20.00 -2.00 319.97 0.00e+00 4.483 0.001 302.00 328.00 3 2.7547e+00 4.0417e-03 4.7399e-02 -6.0000e+00 2.8001e-01 3.0392e-02 5.1555e-03 2.8811e-02 -6.0000e+00 3.0358e-01 -2.8220e-02 4.8197e-03 1.5084e-02 -6.0000e+00 1.8039e-01 2.0856e-03 2.3935e-03 4.9363e-03 -6.0000e+00 7.6031e-02 4.0518e-04 4.6980e-04 6.9042e-05 6.0239e-05 -6.0000e+00 5.1360e-03 3.3993e-02 11 1 0 11 8 0 28.97 25.68 0.29 0.03399 0.03752 86 9 1 5 0 635.420 34.25 20.00 25.68 26.37 3.4 965.81 -67813 -70917 -48961 -97710 -77095 -65305 -66117 -47605 -52960 -29356 -58816 -49153 -16202 -39958 -18658 -14616 -7269 -8634 -5486 -11494 -14864 -1267 -7942 -4800 -18926 -12068 -3936 -9745 -4835 -3014 -4074 -5376 -2784 -8325 -12049 -8523 -584 298 -4728 3655 1406 -242 -1270 744 3100 1630 1049 805 -3010 380 1850 505 1113 1884 956 2009 50 337 -1466 154 2360 2131 3646 2338 315 175 874 -894 1485 1598 1129 1493 60 -364 189 -629 -801 -2360 -200 -1590 -1059 -376 -2186 -1094 -1118 -268 432 392 1148 920 1194 -331 -355 -805 -211 9 290 1002 209 -91 -431 -1314 -880 -118 -811 -795 -874 -569 -390 301 707 206 331 -79 -235 -214 161 440 186 23 -153 362 765 279 475 -284 -313 602 373 -81 -291 -179 -583 -270 -75 -191 289 594 253 101 51 -396 -387 -531 -663 -394 -1233 -721 -540 -604 -414 -553 -262 -729 -620 -183 -722 -337 -299 -169 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