File name: Pandora254s1_TubaCityAZ_20250817_L2Fit_fout2c2d20221208p1-8.txt File generation date: 20250818T073152.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Vaughn Salabye Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 254 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora254_OF_v2d20221208.txt Instrument calibration file used: Pandora254s1_CF_v2d20221208.txt Level 1 file used: Pandora254s1_TubaCityAZ_20250817_L1_smca1c2d20221208p1-8.txt Full location name: Greyhills Academy High School, Tuba City, AZ Short location name: TubaCityAZ Country of location: United States Location latitude [deg]: 36.1270 Location longitude [deg]: -111.2212 Location altitude [m]: 1470 Local noon date: 20250817 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 192 334 Nominal wavelengths inside fitting window [nm]: 305.0315 305.1725 305.3134 305.4543 305.5952 305.7361 305.8770 306.0179 306.1587 306.2996 306.4404 306.5812 306.7220 306.8629 307.0036 307.1444 307.2852 307.4260 307.5667 307.7074 307.8482 307.9889 308.1296 308.2703 308.4110 308.5516 308.6923 308.8330 308.9736 309.1142 309.2548 309.3954 309.5360 309.6766 309.8172 309.9577 310.0983 310.2388 310.3793 310.5199 310.6604 310.8009 310.9413 311.0818 311.2223 311.3627 311.5031 311.6436 311.7840 311.9244 312.0648 312.2052 312.3455 312.4859 312.6262 312.7666 312.9069 313.0472 313.1875 313.3278 313.4681 313.6083 313.7486 313.8888 314.0291 314.1693 314.3095 314.4497 314.5899 314.7301 314.8702 315.0104 315.1505 315.2906 315.4308 315.5709 315.7110 315.8511 315.9911 316.1312 316.2712 316.4113 316.5513 316.6913 316.8313 316.9713 317.1113 317.2513 317.3912 317.5312 317.6711 317.8111 317.9510 318.0909 318.2308 318.3706 318.5105 318.6504 318.7902 318.9301 319.0699 319.2097 319.3495 319.4893 319.6291 319.7688 319.9086 320.0483 320.1881 320.3278 320.4675 320.6072 320.7469 320.8865 321.0262 321.1659 321.3055 321.4451 321.5847 321.7243 321.8639 322.0035 322.1431 322.2827 322.4222 322.5617 322.7013 322.8408 322.9803 323.1198 323.2593 323.3987 323.5382 323.6776 323.8171 323.9565 324.0959 324.2353 324.3747 324.5141 324.6534 324.7928 324.9321 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 77: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 79: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 80: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 82: Atmospheric variability [%], 999=no atmospheric variability was determined Column 83: Wavelength effective temperature [°C], 999=no effective temperature given Column 84: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 85: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 86: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 87: Number of bright count cycles Column 88: Number of dark count cycles Column 89: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 90: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 91: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 92: Integration time [ms] Column 93: Temperature at electronics board [°C], 999=no temperature signal Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Humidity in head sensor [%], -9=no humidity signal Column 98: Pressure in head sensor [hPa], -9=no pressure signal Columns 99-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250817T133149.8Z 9360.563771 222 1 55.05 2 81.68 79.67 13.95 125.63 0.00 1 0.00 1 0 25 6.217e-01 1.957e-02 3.772e-01 1.132e-02 7.357556e-01 6.309401e-03 7.912785e-03 -6.000000e+00 3.583217e-01 230.26 -2.00 3.37 -2.00 321.82 0.00e+00 1.401140e-03 3.554083e-03 4.194984e-03 -6.000000e+00 1.683131e-02 284.81 -2.00 20.00 -2.00 321.28 0.00e+00 6.498 0.004 302.00 328.00 3 2.8208e+00 2.4120e-02 6.9636e-02 -6.0000e+00 8.9733e-01 3.3821e-01 3.4596e-02 4.6715e-02 -6.0000e+00 9.7679e-01 -5.3402e-01 3.3537e-02 2.4143e-02 -6.0000e+00 5.8019e-01 2.2512e-01 1.5238e-02 6.8346e-03 -6.0000e+00 2.4338e-01 6.2149e-05 4.7955e-04 3.1714e-04 1.1158e-04 -6.0000e+00 1.6692e-02 3.6790e-02 12 8 8 10 0 0 41.05 25.33 0.34 0.03679 0.04039 33 3 1 5 0 1668.040 34.00 20.00 25.33 22.49 3.4 939.27 -97400 -199217 -156447 -186892 900000 -184134 -225379 -136751 -210945 -204798 900000 -173245 -88307 900000 -25693 502 900000 900000 -20908 190430 80559 -68025 -8367 76585 47531 -54693 -7210 -79098 135120 -11530 192206 124898 44916 25413 -20164 48032 -22075 37160 66079 25782 82055 1157 48921 27544 16372 23435 63894 34759 23293 472 28492 26077 3514 15900 -2540 13619 17063 16362 2123 15976 7745 14815 6841 4154 10197 3627 12302 15652 2311 954 6916 5435 10435 7751 13202 -13191 -4211 -4661 -6544 2682 716 2323 -1017 839 -1922 187 2297 3122 2118 748 -122 -1111 -1898 -2200 -2284 -2316 -992 1519 -2946 -1732 -4169 -216 101 -914 -740 -1436 -3223 -2826 -1802 -52 116 -607 -403 -757 -143 706 189 -964 1496 -237 1060 2666 1355 2330 1181 -865 1029 1021 960 1317 563 -201 4 459 -1113 576 -542 1202 14 -357 97 -872 -1612 -1074 -4028 -2157 -3560 900000 -2954 -5875 -1645 -5921 -5749 900000 -4168 -1151 900000 -283 6 900000 900000 -335 2100 888 -1773 -126 845 524 -1590 -130 -2775 1490 -220 2120 1377 811 586 -687 819 -841 931 1524 1060 2139 72 1962 1381 919 1245 2306 1742 1378 38 1942 2039 377 1642 -334 1584 1967 2057 295 1885 1025 2026 1162 820 1979 732 2279 2934 556 269 2013 1660 2957 2103 3057 -3549 -980 -1131 -1862 837 268 981 -486 416 -1051 107 1342 1852 1261 432 -66 -571 -961 -1182 -1408 -1675 -826 1422 -3122 -1792 -4106 -182 77 -729 -638 -1313 -3181 -3004 -2107 -68 169 -942 -625 -1139 -203 960 264 -1432 2303 -383 1649 3898 1941 3189 1575 -1136 1289 1372 1488 2304 1092 -419 8 1072 -2838 1510 -1460 3229 38 -913 230 -1955 -3545 SS 20250817T134632.2Z 9360.573983 227 1 10.90 2 78.75 81.76 11.74 135.95 0.00 1 0.00 1 0 17 3.020e-01 8.827e-03 2.599e-01 6.349e-03 5.909802e-01 3.312850e-03 6.378311e-03 -6.000000e+00 1.716705e-01 230.26 -2.00 3.37 -2.00 320.59 0.00e+00 3.759612e-03 1.332414e-03 7.647150e-04 -6.000000e+00 7.608324e-03 284.81 -2.00 20.00 -2.00 319.95 0.00e+00 4.953 0.002 302.00 328.00 3 3.0178e+00 1.0369e-02 5.1341e-02 -6.0000e+00 4.2885e-01 4.8334e-02 1.3372e-02 3.0031e-02 -6.0000e+00 4.6532e-01 -5.1436e-02 1.2770e-02 1.6264e-02 -6.0000e+00 2.7692e-01 1.3919e-02 6.3523e-03 6.8769e-03 -6.0000e+00 1.1707e-01 2.0364e-04 1.5616e-04 1.7286e-04 6.5071e-05 -6.0000e+00 7.9233e-03 3.5686e-02 12 9 1 12 1 1 99.21 25.39 0.48 0.03569 0.03686 9 5 1 5 0 1089.690 34.00 20.01 25.39 23.91 3.3 947.75 -128304 -90354 -155097 -65280 -117502 -82638 -4755 64085 20466 28157 -99133 -129454 -54361 24468 -10668 80473 -25843 -15657 -7533 862 -40468 -8871 42713 17134 2956 12889 16955 -8624 -25273 -33952 4167 -8194 -2730 -7027 -20871 5899 -5283 -13479 -4471 1678 3430 -1278 -1061 -4526 7332 4485 10548 1441 7096 320 -1763 3524 304 -1152 -374 5238 1854 -2509 4626 -691 833 1683 119 3674 2861 2316 1625 -60 -896 1371 711 1047 1827 1345 -1823 854 -1166 -2143 -3436 55 -1231 -1558 -1639 -1219 -569 -169 1385 1237 404 410 1093 287 -1223 -934 -692 -551 26 1145 851 -626 -959 -127 -1710 -679 -122 -362 -1380 -960 163 473 -278 432 -176 287 -110 398 -288 -34 -34 -443 -140 823 720 339 552 438 -172 663 876 -619 588 -399 -22 99 10 -490 712 284 5 -344 -42 -827 -94 -1444 -814 -2881 -478 -1323 -651 -29 397 127 174 -1596 -3206 -808 212 -165 598 -624 -378 -182 20 -1478 -236 714 403 86 359 462 -294 -1002 -1598 160 -421 -154 -439 -1422 307 -343 -1135 -424 179 401 -168 -146 -664 972 628 1417 219 1059 55 -342 722 70 -293 -100 1369 515 -724 1209 -189 234 519 42 1413 1148 898 623 -24 -402 632 362 552 941 657 -921 376 -490 -921 -1683 28 -739 -1065 -1218 -952 -474 -150 1267 1164 382 372 911 224 -928 -728 -603 -554 28 1363 1091 -802 -1147 -136 -1861 -690 -133 -418 -1699 -1259 231 686 -446 717 -290 449 -162 605 -412 -51 -55 -740 -230 1292 1095 498 839 640 -243 980 1345 -1076 1095 -734 -42 200 23 -1121 1639 668 12 -774 -90 -1667 -184 SS 20250817T135223.8Z 9360.578054 230 1 8.89 2 77.58 82.59 10.97 141.07 0.00 1 0.00 1 0 17 1.891e-01 7.379e-03 1.234e-01 4.906e-03 5.461919e-01 2.509995e-03 5.944028e-03 -6.000000e+00 1.074627e-01 230.26 -2.00 3.37 -2.00 320.10 0.00e+00 1.706343e-03 8.694818e-04 9.051164e-04 -6.000000e+00 4.762617e-03 284.81 -2.00 20.00 -2.00 319.41 0.00e+00 4.519 0.001 302.00 328.00 3 2.9259e+00 7.4801e-03 4.7045e-02 -6.0000e+00 2.6845e-01 2.6997e-02 9.2266e-03 2.7620e-02 -6.0000e+00 2.9128e-01 -3.5442e-02 8.1831e-03 1.4162e-02 -6.0000e+00 1.7335e-01 8.2579e-03 4.1850e-03 4.6276e-03 -6.0000e+00 7.3288e-02 3.3578e-04 5.5438e-04 1.3253e-04 4.7698e-05 -6.0000e+00 4.9597e-03 3.5500e-02 12 9 1 12 1 1 91.23 25.42 0.26 0.03550 0.03967 9 6 1 5 0 888.520 34.00 20.00 25.42 24.30 3.3 950.12 -77487 -13315 -49233 -70964 -54777 -87071 -77732 -69886 -72838 -57500 -36909 -4768 -9818 -12943 -21274 -13239 -14779 -2774 15240 10240 4591 21888 -17323 1184 -4640 -8145 -13543 3160 5570 -12843 -3409 -1159 1612 -14828 -9044 -2805 -12017 -9583 -2748 478 1136 295 4515 2273 2652 1043 3419 2067 -3554 2010 -86 -237 -1116 1805 907 1987 68 1482 -2718 1366 2975 1692 2123 3018 415 1120 3140 667 1184 509 59 1146 -814 -95 -637 -6 1207 -1169 -972 -1523 -1834 -751 -2996 -978 -693 488 210 1189 920 683 513 148 -796 258 -625 -224 539 999 326 -481 -528 -845 -812 -619 -303 -826 -453 -970 -767 535 355 115 363 -821 -282 635 61 580 758 -162 -407 409 643 320 1045 -345 -96 814 198 -237 -48 13 83 -134 -386 -68 114 283 121 54 68 -341 -578 -944 -98 -612 -1053 -629 -1375 -1227 -1170 -1429 -1045 -565 -59 -160 -272 -601 -405 -509 -93 459 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