File name: Pandora253s1_TucsonAZ_20240214_L2Fit_fout2c3d20231207p1-8.txt File generation date: 20241219T045005.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Manish Naja Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 253 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora253_OF_v2d20221208.txt Instrument calibration file used: Pandora253s1_CF_v3d20231207.txt Level 1 file used: Pandora253s1_TucsonAZ_20240214_L1_smca1c3d20231207p1-8.txt Full location name: University of Arizona Department of Chemical and Environmental Engineering Short location name: TucsonAZ Country of location: United States Location latitude [deg]: 32.2330 Location longitude [deg]: -110.9530 Location altitude [m]: 779 Local noon date: 20240214 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 2 "Clearance session based on OOB session1, absolute calibration done with an uncalibrated lamp, certificate of FEL1441 (GSFC) used"" First and last pixel inside fitting window: 192 334 Nominal wavelengths inside fitting window [nm]: 305.0168 305.1576 305.2984 305.4391 305.5798 305.7205 305.8612 306.0019 306.1426 306.2833 306.4240 306.5646 306.7052 306.8459 306.9865 307.1271 307.2677 307.4083 307.5488 307.6894 307.8299 307.9705 308.1110 308.2515 308.3920 308.5325 308.6729 308.8134 308.9539 309.0943 309.2347 309.3751 309.5156 309.6559 309.7963 309.9367 310.0771 310.2174 310.3577 310.4981 310.6384 310.7787 310.9190 311.0593 311.1995 311.3398 311.4800 311.6203 311.7605 311.9007 312.0409 312.1811 312.3212 312.4614 312.6016 312.7417 312.8818 313.0219 313.1620 313.3021 313.4422 313.5823 313.7223 313.8624 314.0024 314.1424 314.2825 314.4225 314.5624 314.7024 314.8424 314.9823 315.1223 315.2622 315.4021 315.5420 315.6819 315.8218 315.9617 316.1016 316.2414 316.3812 316.5211 316.6609 316.8007 316.9405 317.0802 317.2200 317.3598 317.4995 317.6392 317.7790 317.9187 318.0584 318.1981 318.3377 318.4774 318.6170 318.7567 318.8963 319.0359 319.1755 319.3151 319.4547 319.5943 319.7338 319.8734 320.0129 320.1524 320.2919 320.4314 320.5709 320.7104 320.8498 320.9893 321.1287 321.2681 321.4076 321.5470 321.6864 321.8257 321.9651 322.1045 322.2438 322.3831 322.5225 322.6618 322.8011 322.9404 323.0796 323.2189 323.3581 323.4974 323.6366 323.7758 323.9150 324.0542 324.1934 324.3326 324.4717 324.6109 324.7500 324.8891 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240214T143811.0Z 8810.609850 52 1 55.01 2 84.64 109.11 118.58 51.79 0.00 1 0.00 1 0 17 5.492e-01 2.186e-02 4.838e-01 1.896e-02 1.117391e+00 1.203143e-02 1.130685e-02 -6.000000e+00 3.219287e-01 224.79 -2.00 3.29 -2.00 322.65 0.00e+00 6.194200e-04 7.356915e-03 7.069230e-03 -6.000000e+00 1.541364e-02 278.21 -2.00 20.00 -2.00 322.28 0.00e+00 9.346 0.011 302.00 328.00 3 1.4247e-01 4.9946e-02 1.1182e-01 -6.0000e+00 7.9699e-01 1.6699e+00 6.7086e-02 8.2574e-02 -6.0000e+00 8.6776e-01 -2.0319e+00 6.0280e-02 3.8032e-02 -6.0000e+00 5.1583e-01 7.7973e-01 2.8595e-02 1.1338e-02 -6.0000e+00 2.2320e-01 2.6913e-05 -1.7889e-03 5.3230e-04 1.8622e-04 -6.0000e+00 1.6002e-02 6.6712e-03 0.0000e+00 12 8 8 10 0 0 14.20 24.96 1.05 0.00667 -0.00677 61 6 1 5 0 901.790 32.50 19.99 24.96 14.09 4.4 896.90 -59430 -21396 900000 900000 -55632 -113083 900000 32136 62677 900000 10024 -100624 -74759 -89698 -54051 -37773 196964 900000 32941 900000 5249 251497 -2256 900000 -52300 -70403 7075 900000 -35250 -38971 55326 -33592 -23269 -36873 -65989 -17599 -12821 900000 18225 87070 149015 19605 63374 900000 188910 -1275 163144 900000 -38660 900000 73774 900000 -1519 131722 12542 133021 10109 93581 47366 88534 90282 94983 80620 47675 32980 8563 29036 -218 25324 6515 27477 27531 33687 29695 28127 12286 23641 14546 13070 -5960 10827 -2723 21551 -1532 -1619 12472 3532 5637 3879 5383 -7374 -5123 -6209 2688 -8549 -934 2950 2953 -1365 -552 -970 949 -8737 -9364 6499 -6383 -4565 -2881 -1820 -1116 -2332 -73 -550 -302 -1775 401 -903 -964 -2033 1208 1958 2740 2812 2321 2159 -398 1503 641 1586 142 156 -473 -250 905 151 164 18 48 -63 34 182 -338 -1754 -1461 -395 900000 900000 -1026 -3128 900000 593 1156 900000 185 -2474 -1723 -3032 -1578 -1103 3632 900000 607 900000 105 4638 -42 900000 -1841 -2951 130 900000 -827 -980 1020 -1183 -858 -1669 -3761 -561 -387 900000 519 1606 2748 756 1594 900000 3484 -56 3008 900000 -2657 900000 1979 900000 -107 2650 883 2899 763 2981 2223 2523 2422 2548 2838 2717 2433 833 2336 -25 2462 874 3316 3461 3897 3285 2782 1236 1942 1341 1402 -949 1779 -607 4729 -458 -511 3588 1153 1840 1280 1688 -2461 -1578 -1912 808 -3342 -410 1507 1797 -994 -420 -715 618 -5461 -5456 3331 -3955 -2938 -1982 -1400 -1005 -2511 -88 -712 -399 -2356 508 -1161 -1288 -2886 1712 2697 3517 3386 2713 2460 -454 1649 739 2106 230 296 -1014 -585 2270 413 476 53 145 -187 96 480 -814 -3971 SS 20240214T145012.9Z 8810.618205 55 1 54.94 2 82.25 110.81 116.59 54.05 0.00 1 0.00 1 0 17 7.313e-01 9.084e-03 2.738e-01 3.461e-03 8.924449e-01 1.956695e-03 9.119383e-03 -6.000000e+00 4.185381e-01 224.79 -2.00 3.29 -2.00 321.96 0.00e+00 4.475164e-03 1.128752e-03 1.277724e-03 -6.000000e+00 1.838065e-02 278.21 -2.00 20.00 -2.00 321.54 0.00e+00 6.912 0.004 302.00 328.00 3 4.5769e-01 7.5406e-03 7.8352e-02 -6.0000e+00 1.0344e+00 3.7120e-01 1.2513e-02 5.0831e-02 -6.0000e+00 1.1235e+00 -4.1454e-01 1.4417e-02 2.8483e-02 -6.0000e+00 6.6955e-01 1.4914e-01 6.4605e-03 1.1636e-02 -6.0000e+00 2.8823e-01 2.4653e-04 -6.8443e-04 9.4657e-05 1.4448e-04 -6.0000e+00 2.0155e-02 7.3899e-03 0.0000e+00 11 8 0 10 0 0 93.68 24.96 0.46 0.00739 0.00225 215 20 1 5 0 255.490 32.50 20.01 24.96 14.85 4.4 902.37 -227133 900000 -14816 -294135 -216332 -213325 -90307 -204504 -192485 -295058 -251694 -243926 -187470 -209238 12233 -136898 -71113 -108740 -47166 -115118 -83608 -84212 -97955 -72387 -23053 -81499 18216 -108119 -67075 -60225 21160 -35098 -41723 5243 -21538 -7072 -12782 -985 -1651 -387 19515 16898 8483 19400 26476 -5247 -3543 11178 8636 4652 12614 19079 10566 11611 11320 7375 9599 5656 12140 -5118 -1002 3024 2532 7032 8346 4862 8160 7470 1140 5258 4870 4497 4670 1519 858 -358 -2441 -4688 -3556 -544 -311 -238 -370 -938 616 879 -1016 33 -97 -102 626 1413 -709 -2067 483 -987 -250 4 444 -748 -847 -744 -173 150 -1454 -1997 -1216 -1431 -791 -294 19 -19 -170 559 58 -33 393 323 480 199 -240 61 461 269 470 243 481 1277 1083 -305 261 -337 -21 87 34 -375 -87 86 -86 -82 46 13 -228 -836 900000 -50 -2978 -929 -851 -305 -878 -827 -3893 -2317 -2395 -1380 -2632 41 -1428 -458 -1168 -304 -1554 -847 -853 -1172 -733 -156 -1050 89 -1858 -761 -702 136 -506 -781 69 -370 -102 -208 -17 -34 -10 467 502 292 622 804 -225 -155 449 385 237 673 1095 742 893 947 677 894 550 1069 -516 -98 308 300 930 1214 753 1237 1198 215 1098 1149 1128 1166 369 190 -71 -461 -922 -781 -141 -97 -87 -153 -421 289 437 -541 18 -53 -54 310 653 -326 -1000 258 -634 -189 3 442 -784 -851 -674 -138 113 -1164 -1710 -1090 -1385 -843 -358 26 -29 -273 893 90 -50 582 495 773 334 -400 97 689 389 656 329 631 1712 1651 -551 484 -691 -46 206 86 -1008 -241 239 -239 -220 115 31 -501 SS 20240214T150738.0Z 8810.630301 60 1 54.87 2 78.83 113.36 113.63 57.14 0.00 1 0.00 1 0 25 3.458e-01 5.056e-03 4.323e-02 8.019e-04 6.822358e-01 4.283782e-04 7.282345e-03 -6.000000e+00 1.979724e-01 224.79 -2.00 3.29 -2.00 320.92 0.00e+00 3.352455e-03 1.887244e-04 6.897059e-04 -6.000000e+00 8.628572e-03 278.21 -2.00 20.00 -2.00 320.42 0.00e+00 4.986 0.002 302.00 328.00 3 1.8278e-01 1.3714e-03 5.6682e-02 -6.0000e+00 4.8929e-01 1.0708e-01 1.8789e-03 3.5154e-02 -6.0000e+00 5.3139e-01 -8.8176e-02 2.0067e-03 1.8656e-02 -6.0000e+00 3.1647e-01 2.4234e-02 9.7756e-04 7.9038e-03 -6.0000e+00 1.3548e-01 2.1568e-03 -4.7402e-04 2.2268e-05 8.0880e-05 -6.0000e+00 9.5223e-03 6.5277e-03 0.0000e+00 10 0 0 10 0 0 16.55 24.93 0.38 0.00653 0.00297 689 65 1 5 0 79.630 32.50 20.01 24.93 16.23 4.4 914.11 -123037 -111274 -114292 -101632 -139632 -109897 -110529 -115718 -93373 -100456 -88968 -95973 -71128 -57764 -36602 -32041 -33909 -30747 -12380 -16270 -21732 -22360 -21121 -24308 -14738 -17273 -23303 -24709 -20700 -23973 -14778 -7689 -3717 -3341 -6245 -8987 -10909 -6394 -3878 -45 -1513 -1238 503 338 1199 514 214 91 1453 -166 2785 1461 2186 1923 1180 1892 1106 -207 645 -313 862 1443 1960 2759 1962 1546 952 908 1377 1380 1085 913 330 85 -225 -596 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