File name: Pandora253s1_TucsonAZ_20240327_L2Fit_fwvt1c1d20230118p1-8.txt File generation date: 20240328T074018.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c1p1-8 Local principal investigator: Manish Naja Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 253 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora253_OF_v2d20221208.txt Instrument calibration file used: Pandora253s1_CF_v1d20230118.txt Level 1 file used: Pandora253s1_TucsonAZ_20240327_L1_smca1c1d20230118p1-8.txt Full location name: University of Arizona Department of Chemical and Environmental Engineering Short location name: TucsonAZ Country of location: United States Location latitude [deg]: 32.2330 Location longitude [deg]: -110.9530 Location altitude [m]: 779 Local noon date: 20240327 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Full lab calibration+OOB session, absolute calibration done with an uncalibrated lamp, certificate of FEL1441 (GSFC) used First and last pixel inside fitting window: 1616 1766 Nominal wavelengths inside fitting window [nm]: 492.0406 492.1612 492.2817 492.4022 492.5227 492.6432 492.7637 492.8841 493.0046 493.1250 493.2454 493.3658 493.4862 493.6065 493.7268 493.8472 493.9675 494.0877 494.2080 494.3283 494.4485 494.5687 494.6889 494.8091 494.9293 495.0494 495.1695 495.2897 495.4098 495.5298 495.6499 495.7700 495.8900 496.0100 496.1300 496.2500 496.3699 496.4899 496.6098 496.7297 496.8496 496.9695 497.0894 497.2092 497.3290 497.4489 497.5687 497.6884 497.8082 497.9279 498.0477 498.1674 498.2871 498.4067 498.5264 498.6460 498.7657 498.8853 499.0049 499.1244 499.2440 499.3635 499.4830 499.6025 499.7220 499.8415 499.9610 500.0804 500.1998 500.3192 500.4386 500.5580 500.6773 500.7967 500.9160 501.0353 501.1546 501.2738 501.3931 501.5123 501.6315 501.7507 501.8699 501.9891 502.1082 502.2273 502.3464 502.4655 502.5846 502.7037 502.8227 502.9417 503.0608 503.1797 503.2987 503.4177 503.5366 503.6555 503.7744 503.8933 504.0122 504.1311 504.2499 504.3687 504.4875 504.6063 504.7251 504.8438 504.9626 505.0813 505.2000 505.3187 505.4373 505.5560 505.6746 505.7932 505.9118 506.0304 506.1490 506.2675 506.3860 506.5045 506.6230 506.7415 506.8600 506.9784 507.0968 507.2152 507.3336 507.4520 507.5703 507.6887 507.8070 507.9253 508.0436 508.1619 508.2801 508.3983 508.5166 508.6348 508.7529 508.8711 508.9893 509.1074 509.2255 509.3436 509.4617 509.5797 509.6978 509.8158 509.9338 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20240327T132650.7Z 8852.560309 217 1 5.93 2 88.90 87.23 79.44 245.62 0.00 1 0.00 1 0 22 4.667e-03 4.627e-03 1.212e-03 1.210e-03 1.362347e+04 8.790571e+01 9.159967e+02 -6.000000e+00 2.694948e+02 280.57 -2.00 20.00 -2.00 505.39 0.00e+00 3.176782e-03 3.412617e-05 1.783469e-04 -6.000000e+00 1.326687e-04 280.57 -2.00 20.00 -2.00 500.86 0.00e+00 1.380978e+00 2.402676e-02 9.448030e-02 -6.000000e+00 9.462328e-02 227.48 -2.00 3.29 -2.00 502.40 0.00e+00 18.552 0.086 489.00 513.00 1 3.7466e+00 1.8434e-03 2.8263e-02 -6.0000e+00 7.2745e-03 -2.2329e-02 4.5493e-04 2.7130e-03 -6.0000e+00 1.8550e-03 3.4885e-03 4.2601e-03 1.3115e-04 1.1869e-04 -6.0000e+00 5.5996e-04 1.1252e-02 -5.9600e-05 12 9 9 12 1 1 97.72 25.08 3.07 0.01125 0.04080 6 6 1 4 0 846.190 32.75 20.00 25.08 13.84 4.5 895.78 -833 -522 -385 -49 510 818 799 987 577 566 145 -113 -264 -329 -41 -249 -159 163 273 271 465 107 426 696 784 198 -45 -99 -380 -664 -750 -878 -493 -78 149 136 -37 116 81 103 -365 145 250 110 611 381 343 285 85 -338 -673 -733 -857 -465 -285 -184 -97 205 292 245 245 407 566 448 485 412 94 -235 -29 -495 -407 -548 -263 -298 -91 -329 -373 -779 -806 -742 -569 -795 -582 -455 -461 -436 -331 -494 27 336 188 204 425 457 428 134 133 -12 -434 -744 -1036 -793 -732 -428 -302 -475 -371 -511 -213 -56 16 196 285 767 968 874 1064 825 315 439 472 223 478 423 569 474 316 329 39 136 252 62 -340 -316 -450 -122 -107 -3 96 51 375 294 255 186 262 434 12 -232 -405 -785 -793 -767 -477 -361 -47 485 793 773 961 564 549 140 -110 -254 -314 -39 -238 -155 159 270 267 460 107 426 697 790 197 -45 -100 -375 -644 -733 -846 -482 -77 149 138 -37 117 82 103 -368 147 252 112 627 387 348 291 86 -335 -667 -714 -829 -452 -282 -183 -97 208 298 250 251 419 584 455 498 419 95 -234 -30 -494 -403 -544 -263 -295 -91 -327 -366 -773 -791 -724 -554 -779 -574 -452 -454 -434 -330 -492 26 331 187 204 420 458 423 130 128 -11 -404 -698 -956 -742 -694 -413 -297 -477 -375 -517 -215 -57 16 199 292 775 984 896 1100 849 327 453 489 228 483 427 576 483 324 339 40 141 258 64 -344 -318 -456 -124 -109 -3 100 54 394 312 273 200 277 464 13 -244 -422 -817 -830 SQ 20240327T132931.2Z 8852.562167 221 1 54.80 2 88.34 87.59 79.95 246.01 0.00 1 0.00 1 0 22 3.869e-03 3.847e-03 1.093e-04 1.091e-04 1.193912e+04 7.810841e+00 8.003688e+02 -6.000000e+00 2.234162e+02 280.57 -2.00 20.00 -2.00 505.39 0.00e+00 2.772194e-03 3.080478e-06 1.605178e-04 -6.000000e+00 1.099673e-04 280.57 -2.00 20.00 -2.00 500.85 0.00e+00 1.373170e+00 2.172275e-03 8.676851e-02 -6.000000e+00 7.836973e-02 227.48 -2.00 3.29 -2.00 502.38 0.00e+00 17.064 0.067 489.00 513.00 1 1.4731e+00 1.6676e-04 2.5373e-02 -6.0000e+00 6.0262e-03 -2.2359e-02 4.1178e-05 2.4449e-03 -6.0000e+00 1.5345e-03 4.1500e-02 2.2721e-03 1.2000e-05 1.0490e-04 -6.0000e+00 4.6424e-04 -5.1733e-03 1.2389e-04 11 8 0 10 0 0 79.63 25.08 2.62 -0.00517 0.01059 752 71 1 4 0 72.870 32.75 20.00 25.08 13.88 4.5 896.01 -599 -334 -162 173 360 614 783 693 624 486 204 49 -122 -253 -241 -255 -153 53 208 141 201 260 350 333 514 250 140 6 -196 -434 -411 -333 -262 -55 35 -79 -99 -46 -42 -115 -93 80 205 306 402 408 310 132 -45 -259 -587 -719 -697 -582 -336 -146 -34 62 190 273 421 436 383 339 286 159 17 -194 -243 -375 -386 -344 -333 -252 -203 -360 -438 -492 -462 -508 -623 -516 -526 -446 -386 -369 -417 -385 -199 -28 23 146 298 401 365 306 165 -63 -423 -703 -862 -771 -698 -482 -317 -402 -411 -250 -164 -97 6 137 292 627 763 844 930 893 660 425 368 278 352 455 402 319 337 268 206 249 211 -52 -111 -205 -276 -237 -94 -23 18 104 261 215 213 316 250 181 -21 -269 -441 -587 -516 -550 -310 -151 166 346 601 760 679 611 473 197 47 -118 -243 -231 -246 -150 52 207 138 199 259 349 334 517 253 141 6 -192 -428 -400 -325 -255 -55 35 -80 -99 -46 -42 -114 -93 80 207 313 415 414 313 136 -45 -257 -586 -705 -678 -570 -335 -146 -34 62 193 278 428 446 394 349 293 162 17 -192 -243 -373 -381 -340 -332 -254 -200 -355 -438 -486 -451 -493 -606 -503 -517 -443 -378 -364 -413 -381 -197 -28 23 146 300 403 361 296 159 -59 -399 -657 -805 -730 -665 -465 -316 -400 -412 -249 -163 -97 6 140 295 636 778 867 964 933 679 435 380 284 356 458 407 326 345 275 212 256 216 -53 -112 -205 -278 -240 -95 -23 19 108 275 229 229 333 264 194 -22 -283 -459 -609 -538 SQ 20240327T133221.2Z 8852.564134 225 1 28.64 2 87.74 87.96 80.49 246.41 0.00 1 0.00 1 0 22 3.279e-03 3.265e-03 1.124e-04 1.122e-04 9.910551e+03 7.866540e+00 6.678016e+02 -6.000000e+00 1.893665e+02 280.57 -2.00 20.00 -2.00 505.37 0.00e+00 2.461111e-03 3.160726e-06 1.424221e-04 -6.000000e+00 9.320386e-05 280.57 -2.00 20.00 -2.00 500.78 0.00e+00 1.334261e+00 2.239456e-03 7.414250e-02 -6.000000e+00 6.641562e-02 227.48 -2.00 3.29 -2.00 502.33 0.00e+00 15.446 0.050 489.00 513.00 1 1.1107e+00 1.7201e-04 2.2390e-02 -6.0000e+00 5.1071e-03 -1.6383e-02 4.2605e-05 2.0924e-03 -6.0000e+00 1.3002e-03 7.4378e-02 1.9352e-03 1.2525e-05 9.0074e-05 -6.0000e+00 3.9349e-04 -7.4356e-03 1.4961e-04 10 0 0 10 0 0 72.24 25.08 2.10 -0.00744 0.00599 703 66 1 4 0 40.730 32.75 20.00 25.08 13.99 4.5 896.55 -477 -248 -107 144 260 493 657 564 501 373 148 21 -86 -214 -181 -209 -166 36 175 81 135 196 325 285 461 214 99 -14 -148 -360 -311 -223 -206 -24 40 -113 -113 -3 2 -91 -75 81 190 252 320 374 275 103 -54 -221 -478 -598 -590 -500 -277 -158 -61 36 132 217 362 385 311 293 231 166 36 -166 -184 -313 -343 -298 -284 -231 -136 -288 -388 -403 -360 -427 -544 -455 -462 -393 -339 -339 -366 -355 -205 -28 21 94 248 334 297 262 131 -54 -340 -602 -687 -659 -600 -431 -283 -408 -366 -194 -121 -66 29 139 259 578 666 735 797 767 560 351 351 286 332 416 343 250 286 188 194 225 189 -44 -118 -160 -215 -198 -74 -41 -8 56 212 172 177 272 221 131 -55 -254 -378 -468 -420 -443 -234 -101 137 252 490 648 561 498 369 145 20 -85 -208 -176 -204 -160 36 176 81 135 198 329 289 469 219 101 -14 -147 -358 -306 -219 -201 -24 40 -115 -115 -3 2 -91 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