File name: Pandora253s1_TucsonAZ_20240328_L2Fit_fwvt1c3d20231207p1-8.txt File generation date: 20241219T052722.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Manish Naja Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 253 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora253_OF_v2d20221208.txt Instrument calibration file used: Pandora253s1_CF_v3d20231207.txt Level 1 file used: Pandora253s1_TucsonAZ_20240328_L1_smca1c3d20231207p1-8.txt Full location name: University of Arizona Department of Chemical and Environmental Engineering Short location name: TucsonAZ Country of location: United States Location latitude [deg]: 32.2330 Location longitude [deg]: -110.9530 Location altitude [m]: 779 Local noon date: 20240328 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 2 "Clearance session based on OOB session1, absolute calibration done with an uncalibrated lamp, certificate of FEL1441 (GSFC) used"" First and last pixel inside fitting window: 1616 1766 Nominal wavelengths inside fitting window [nm]: 492.0560 492.1767 492.2973 492.4178 492.5384 492.6590 492.7795 492.9000 493.0205 493.1410 493.2614 493.3819 493.5023 493.6227 493.7431 493.8635 493.9839 494.1042 494.2245 494.3448 494.4651 494.5854 494.7057 494.8259 494.9461 495.0664 495.1866 495.3067 495.4269 495.5470 495.6672 495.7873 495.9074 496.0274 496.1475 496.2675 496.3875 496.5076 496.6275 496.7475 496.8675 496.9874 497.1073 497.2272 497.3471 497.4670 497.5868 497.7067 497.8265 497.9463 498.0661 498.1859 498.3056 498.4253 498.5451 498.6648 498.7844 498.9041 499.0238 499.1434 499.2630 499.3826 499.5022 499.6218 499.7413 499.8608 499.9803 500.0998 500.2193 500.3388 500.4582 500.5777 500.6971 500.8165 500.9358 501.0552 501.1745 501.2939 501.4132 501.5325 501.6517 501.7710 501.8902 502.0095 502.1287 502.2478 502.3670 502.4862 502.6053 502.7244 502.8435 502.9626 503.0817 503.2007 503.3198 503.4388 503.5578 503.6768 503.7957 503.9147 504.0336 504.1525 504.2714 504.3903 504.5092 504.6280 504.7469 504.8657 504.9845 505.1032 505.2220 505.3407 505.4595 505.5782 505.6969 505.8155 505.9342 506.0528 506.1715 506.2901 506.4087 506.5272 506.6458 506.7643 506.8828 507.0013 507.1198 507.2383 507.3567 507.4752 507.5936 507.7120 507.8304 507.9487 508.0671 508.1854 508.3037 508.4220 508.5403 508.6586 508.7768 508.8950 509.0132 509.1314 509.2496 509.3678 509.4859 509.6040 509.7221 509.8402 509.9583 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20240328T132530.5Z 8853.559380 217 1 5.15 2 88.91 86.76 74.58 234.78 0.00 1 0.00 1 0 22 4.553e-03 4.521e-03 8.032e-04 8.016e-04 9.664837e+03 5.565469e+01 6.481087e+02 -6.000000e+00 2.631163e+02 280.65 -2.00 20.00 -2.00 505.39 0.00e+00 2.730019e-03 2.265096e-05 1.549291e-04 -6.000000e+00 1.294695e-04 280.65 -2.00 20.00 -2.00 500.92 0.00e+00 1.247395e+00 1.589066e-02 7.535648e-02 -6.000000e+00 9.218788e-02 227.55 -2.00 3.29 -2.00 502.44 0.00e+00 18.578 0.086 489.00 513.00 1 3.1441e+00 1.2206e-03 2.7805e-02 -6.0000e+00 7.0902e-03 -1.7608e-02 3.0163e-04 2.2747e-03 -6.0000e+00 1.8031e-03 6.5031e-03 1.5168e-03 8.9935e-05 9.3613e-05 -6.0000e+00 5.4640e-04 -1.5928e-02 9.7757e-05 12 9 1 12 1 1 -1.85 25.10 3.28 -0.01593 -0.00541 14 15 1 4 0 343.370 32.75 20.01 25.10 16.32 4.5 914.02 -1114 -751 -563 -115 253 501 762 797 876 584 264 -71 -114 -369 -261 -422 -346 99 230 300 358 247 430 476 561 329 246 4 -154 -596 -734 -386 -370 37 78 45 -67 89 -41 -33 77 249 354 241 496 384 401 387 64 -226 -524 -793 -883 -723 -358 -335 -49 68 322 299 657 611 550 608 475 251 170 -332 -278 -443 -408 -446 -389 -309 -197 -331 -388 -565 -556 -565 -737 -559 -395 -515 -474 -378 -371 -332 -217 12 97 176 594 416 448 368 137 -1 -579 -612 -1147 -697 -603 -435 -192 -308 -453 -320 -247 -118 7 273 177 770 771 894 965 986 578 401 285 193 370 401 266 445 377 461 75 321 13 -134 -182 -334 -369 -83 -31 57 161 193 447 170 185 316 277 149 -206 -406 -668 -763 -628 -1013 -691 -514 -108 244 477 738 779 855 567 254 -68 -108 -346 -251 -397 -330 97 228 293 352 244 426 474 560 330 246 4 -150 -572 -718 -377 -357 36 79 45 -67 88 -40 -33 78 246 354 244 506 394 411 393 65 -223 -521 -777 -859 -708 -357 -332 -50 69 323 300 659 616 557 615 479 251 173 -335 -277 -439 -402 -439 -386 -310 -198 -333 -387 -557 -542 -549 -718 -546 -388 -513 -476 -372 -366 -327 -214 12 96 176 597 419 446 359 134 -1 -546 -587 -1103 -657 -584 -423 -193 -315 -453 -319 -245 -118 7 278 182 797 805 914 995 1024 604 417 293 196 382 414 269 451 384 471 77 328 13 -136 -187 -343 -380 -84 -32 59 166 203 474 183 200 334 293 157 -222 -431 -703 -799 -661 SQ 20240328T132759.7Z 8853.561108 221 1 28.64 2 88.39 87.10 75.00 235.18 0.00 1 0.00 1 0 22 3.826e-03 3.812e-03 1.190e-04 1.188e-04 8.694444e+03 8.162256e+00 5.831145e+02 -6.000000e+00 2.210630e+02 280.65 -2.00 20.00 -2.00 505.38 0.00e+00 2.448541e-03 3.355253e-06 1.390554e-04 -6.000000e+00 1.087760e-04 280.65 -2.00 20.00 -2.00 500.89 0.00e+00 1.260956e+00 2.360781e-03 6.886502e-02 -6.000000e+00 7.745216e-02 227.55 -2.00 3.29 -2.00 502.42 0.00e+00 17.201 0.068 489.00 513.00 1 1.2317e+00 1.8124e-04 2.5140e-02 -6.0000e+00 5.9569e-03 -1.7204e-02 4.4849e-05 2.0617e-03 -6.0000e+00 1.5149e-03 5.2890e-02 1.3137e-03 1.3400e-05 8.4568e-05 -6.0000e+00 4.5910e-04 3.7687e-04 8.2275e-07 11 8 0 10 0 0 49.27 25.10 2.80 0.00038 0.00949 696 65 1 4 0 41.140 32.75 20.00 25.10 16.35 4.5 914.37 -797 -592 -392 -45 167 438 636 604 528 425 147 -31 -163 -298 -306 -304 -227 -3 201 136 228 259 390 344 531 298 197 51 -135 -380 -364 -303 -251 -23 76 1 -38 40 26 -48 -9 149 264 366 450 466 388 181 9 -221 -522 -688 -699 -582 -328 -126 -15 104 227 306 463 479 462 374 313 180 48 -166 -234 -371 -376 -350 -303 -226 -149 -331 -433 -501 -452 -539 -615 -505 -520 -429 -353 -350 -372 -365 -212 -15 47 155 355 443 371 317 152 -72 -413 -661 -815 -700 -595 -367 -233 -379 -403 -266 -198 -97 14 188 319 663 785 848 890 857 648 386 304 230 297 403 374 294 312 238 203 219 139 -100 -209 -252 -281 -224 -67 -22 12 110 263 210 239 306 208 113 -155 -379 -518 -610 -553 -723 -544 -369 -42 159 426 628 602 526 421 144 -30 -157 -285 -291 -291 -221 -3 195 134 225 257 388 345 533 301 198 51 -132 -365 -345 -288 -243 -23 77 1 -38 41 26 -49 -9 152 261 366 454 472 393 182 9 -224 -519 -672 -677 -567 -326 -122 -15 105 231 311 472 490 474 385 321 182 48 -164 -229 -361 -363 -339 -296 -222 -148 -327 -424 -485 -433 -514 -588 -485 -503 -419 -348 -348 -371 -364 -211 -15 47 157 362 452 375 314 148 -68 -399 -632 -778 -677 -568 -362 -236 -377 -402 -264 -196 -96 14 191 327 685 817 890 906 879 666 395 308 238 306 414 386 306 326 239 204 220 140 -104 -214 -257 -287 -231 -68 -23 12 117 281 219 251 323 220 119 -162 -405 -547 -642 -585 SQ 20240328T132828.4Z 8853.561440 221 2 28.64 2 88.29 87.16 75.08 235.25 0.00 1 0.00 1 0 22 3.655e-03 3.638e-03 1.132e-04 1.129e-04 8.452284e+03 7.733197e+00 5.640924e+02 -6.000000e+00 2.111974e+02 280.65 -2.00 20.00 -2.00 505.38 0.00e+00 2.390336e-03 3.178927e-06 1.361011e-04 -6.000000e+00 1.039217e-04 280.65 -2.00 20.00 -2.00 500.89 0.00e+00 1.249023e+00 2.235671e-03 6.781576e-02 -6.000000e+00 7.399628e-02 227.55 -2.00 3.29 -2.00 502.42 0.00e+00 16.927 0.065 489.00 513.00 1 1.1742e+00 1.7169e-04 2.4635e-02 -6.0000e+00 5.6911e-03 -1.5380e-02 4.2603e-05 2.0214e-03 -6.0000e+00 1.4473e-03 5.8176e-02 1.3252e-03 1.2754e-05 8.0741e-05 -6.0000e+00 4.3861e-04 5.6174e-04 -1.0652e-06 10 0 0 10 0 0 28.28 25.10 2.66 0.00056 0.00975 696 65 1 4 0 41.140 32.75 20.00 25.10 16.44 4.5 914.69 -751 -541 -336 -49 175 411 615 587 540 395 133 -22 -181 -314 -299 -295 -236 -10 154 113 197 262 371 339 507 277 179 47 -110 -367 -350 -297 -244 -32 72 -18 -35 53 39 -6 13 147 257 371 436 462 392 168 11 -194 -504 -657 -649 -539 -305 -156 0 102 214 296 447 450 434 369 305 192 45 -191 -243 -323 -354 -302 -286 -233 -147 -311 -403 -449 -441 -461 -578 -505 -499 -378 -340 -318 -348 -347 -204 -18 86 176 319 409 376 288 133 -72 -408 -651 -771 -657 -565 -379 -226 -376 -373 -225 -172 -94 43 168 297 638 751 815 864 832 613 358 322 223 322 379 346 293 285 252 170 204 98 -94 -186 -242 -288 -231 -74 -22 23 101 247 187 219 273 187 92 -144 -383 -513 -606 -524 -699 -487 -311 -46 171 393 597 576 530 385 129 -21 -171 -295 -279 -278 -225 -10 153 114 200 266 364 334 501 275 177 46 -110 -361 -340 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