File name: Pandora253s1_TucsonAZ_20240507_L2Fit_fwvt1c1d20230118p1-8.txt
File generation date: 20240516T070238.2Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c1p1-8
Local principal investigator: Manish Naja
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 253
Spectrometer number: 1
Processing software version used: BlickP v1.8.59
Instrument operation file used: Pandora253_OF_v2d20221208.txt
Instrument calibration file used: Pandora253s1_CF_v1d20230118.txt
Level 1 file used: Pandora253s1_TucsonAZ_20240507_L1_smca1c1d20230118p1-8.txt
Full location name: University of Arizona Department of Chemical and Environmental Engineering
Short location name: TucsonAZ
Country of location: United States
Location latitude [deg]: 32.2330
Location longitude [deg]: -110.9530
Location altitude [m]: 779
Local noon date: 20240507
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: Full lab calibration+OOB session, absolute calibration done with an uncalibrated lamp, certificate of FEL1441 (GSFC) used
First and last pixel inside fitting window: 1616 1766
Nominal wavelengths inside fitting window [nm]: 492.0406 492.1612 492.2817 492.4022 492.5227 492.6432 492.7637 492.8841 493.0046 493.1250 493.2454 493.3658 493.4862 493.6065 493.7268 493.8472 493.9675 494.0877 494.2080 494.3283 494.4485 494.5687 494.6889 494.8091 494.9293 495.0494 495.1695 495.2897 495.4098 495.5298 495.6499 495.7700 495.8900 496.0100 496.1300 496.2500 496.3699 496.4899 496.6098 496.7297 496.8496 496.9695 497.0894 497.2092 497.3290 497.4489 497.5687 497.6884 497.8082 497.9279 498.0477 498.1674 498.2871 498.4067 498.5264 498.6460 498.7657 498.8853 499.0049 499.1244 499.2440 499.3635 499.4830 499.6025 499.7220 499.8415 499.9610 500.0804 500.1998 500.3192 500.4386 500.5580 500.6773 500.7967 500.9160 501.0353 501.1546 501.2738 501.3931 501.5123 501.6315 501.7507 501.8699 501.9891 502.1082 502.2273 502.3464 502.4655 502.5846 502.7037 502.8227 502.9417 503.0608 503.1797 503.2987 503.4177 503.5366 503.6555 503.7744 503.8933 504.0122 504.1311 504.2499 504.3687 504.4875 504.6063 504.7251 504.8438 504.9626 505.0813 505.2000 505.3187 505.4373 505.5560 505.6746 505.7932 505.9118 506.0304 506.1490 506.2675 506.3860 506.5045 506.6230 506.7415 506.8600 506.9784 507.0968 507.2152 507.3336 507.4520 507.5703 507.6887 507.8070 507.9253 508.0436 508.1619 508.2801 508.3983 508.5166 508.6348 508.7529 508.8711 508.9893 509.1074 509.2255 509.3436 509.4617 509.5797 509.6978 509.8158 509.9338
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Temperature at electronics board [°C], 999=no temperature signal
Column 96: Spectrometer control temperature [°C], 999=no temperature signal
Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 98: Temperature in head sensor [°C], 999=no temperature signal
Column 99: Humidity in head sensor [%], -9=no humidity signal
Column 100: Pressure in head sensor [hPa], -9=no pressure signal
Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20240507T123852.5Z 8893.526997 30 1 28.42 2 89.39 70.14 83.46 75.17 0.00 1 0.00 1 0 22 6.149e-03 6.108e-03 4.469e-04 4.451e-04 9.585965e+03 3.115452e+01 6.310774e+02 -6.000000e+00 3.599759e+02 284.03 -2.00 20.00 -2.00 505.42 0.00e+00 6.463859e-03 1.266592e-05 3.549530e-04 -6.000000e+00 1.762400e-04 284.03 -2.00 20.00 -2.00 501.06 0.00e+00 1.200321e+00 8.784071e-03 8.957253e-02 -6.000000e+00 1.247901e-01 230.19 -2.00 3.29 -2.00 502.56 0.00e+00 19.569 0.101 489.00 513.00 1 3.1824e+00 6.7462e-04 3.0992e-02 -6.0000e+00 9.6041e-03 -3.8799e-02 1.6647e-04 2.3793e-03 -6.0000e+00 2.4469e-03 5.2330e-03 3.4671e-03 5.0872e-05 1.6367e-04 -6.0000e+00 7.3806e-04 3.6403e-03 1.1321e-05 12 9 9 12 1 1 28.51 25.39 4.90 0.00364 0.02769 59 11 1 4 0 473.520 33.00 20.00 25.39 19.69 4.5 936.92 -1197 -886 -456 34 443 840 1156 943 939 646 353 7 -242 -549 -543 -495 -389 -82 222 266 405 421 625 552 833 489 364 150 -291 -677 -774 -733 -491 -68 158 72 73 69 21 -111 16 202 385 477 708 719 637 378 77 -266 -805 -1014 -1128 -930 -548 -307 23 236 466 457 604 708 693 662 527 312 112 -233 -433 -515 -617 -561 -502 -422 -235 -563 -649 -654 -729 -1003 -1019 -863 -883 -721 -623 -584 -576 -576 -391 -199 -19 229 494 650 616 563 286 -29 -574 -989 -1312 -1273 -1000 -632 -358 -419 -457 -302 -366 -236 -3 240 625 1012 1214 1380 1342 1322 1067 823 712 467 439 533 535 501 472 371 291 321 233 -170 -306 -426 -539 -513 -316 -215 -3 94 353 269 284 470 305 265 -5 -415 -613 -911 -792 -1050 -788 -416 31 413 799 1081 891 886 606 328 7 -227 -512 -505 -463 -358 -77 211 256 393 410 611 528 800 473 352 144 -275 -648 -733 -697 -475 -65 155 72 73 68 21 -110 16 197 380 478 718 734 651 385 77 -263 -785 -974 -1079 -895 -538 -309 23 239 475 468 620 730 719 688 545 320 114 -235 -432 -509 -608 -553 -498 -422 -236 -567 -647 -644 -711 -976 -992 -843 -869 -714 -622 -586 -579 -578 -392 -199 -19 227 493 650 612 564 281 -28 -542 -949 -1257 -1198 -963 -626 -355 -423 -463 -305 -369 -240 -3 244 644 1052 1274 1424 1399 1390 1126 866 742 482 450 546 552 520 493 390 307 338 245 -177 -317 -439 -556 -535 -334 -225 -3 102 384 289 307 510 331 287 -6 -451 -660 -978 -854
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SQ 20240507T124454.2Z 8893.531183 38 1 54.87 2 88.19 70.94 82.25 75.88 0.00 1 0.00 1 0 15 3.683e-03 3.672e-03 1.185e-04 1.183e-04 7.260807e+03 8.075844e+00 4.869657e+02 -6.000000e+00 2.156201e+02 284.03 -2.00 20.00 -2.00 505.37 0.00e+00 5.328225e-03 3.357984e-06 2.946477e-04 -6.000000e+00 1.055538e-04 284.03 -2.00 20.00 -2.00 500.87 0.00e+00 1.304245e+00 2.351361e-03 6.992532e-02 -6.000000e+00 7.469701e-02 230.19 -2.00 3.29 -2.00 502.40 0.00e+00 16.609 0.062 489.00 513.00 1 1.6427e+00 1.8071e-04 2.4943e-02 -6.0000e+00 5.7497e-03 -1.7127e-02 4.4925e-05 1.8570e-03 -6.0000e+00 1.4635e-03 3.6250e-02 2.0438e-03 1.3642e-05 1.3609e-04 -6.0000e+00 4.4209e-04 -8.3369e-03 1.4262e-04 10 0 0 10 0 0 55.01 25.39 2.53 -0.00834 0.00584 640 60 1 4 0 85.720 32.75 20.00 25.39 19.85 4.5 937.65 -621 -398 -243 46 216 461 661 608 544 428 180 3 -146 -266 -242 -302 -233 -10 146 128 202 238 377 352 505 302 196 58 -106 -358 -362 -304 -274 -58 16 -43 -71 21 22 -54 -15 121 217 298 381 435 345 178 9 -182 -473 -635 -653 -566 -338 -199 -53 67 199 279 408 410 365 314 283 180 48 -158 -194 -315 -379 -321 -334 -266 -158 -288 -386 -431 -406 -506 -638 -534 -541 -452 -387 -367 -382 -365 -214 -67 -27 109 292 380 372 327 172 -36 -370 -606 -786 -738 -692 -473 -305 -399 -394 -215 -176 -53 48 166 312 660 749 808 859 869 677 457 433 324 351 422 342 269 289 234 199 257 184 -52 -130 -182 -274 -254 -139 -62 -60 53 203 174 169 282 219 135 -63 -271 -438 -553 -524 -564 -366 -229 44 210 446 650 603 538 421 175 3 -139 -257 -233 -285 -222 -10 145 125 199 236 374 352 507 305 197 58 -104 -344 -352 -296 -265 -58 16 -44 -71 21 21 -53 -15 121 220 299 386 444 352 180 9 -183 -467 -616 -645 -549 -334 -197 -53 69 206 288 413 418 373 321 288 182 49 -160 -194 -311 -373 -316 -330 -265 -159 -289 -382 -422 -393 -500 -617 -518 -528 -444 -383 -366 -382 -364 -214 -67 -27 108 292 381 371 320 170 -34 -358 -577 -746 -707 -662 -466 -301 -400 -396 -214 -176 -53 49 167 318 680 762 830 889 904 706 474 444 329 361 435 347 275 296 241 205 264 189 -52 -131 -182 -274 -257 -142 -64 -62 55 215 182 178 297 232 142 -66 -285 -454 -570 -543
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