File name: Pandora253s1_TucsonAZ_20240523_L2Fit_fout2c3d20231207p1-8.txt File generation date: 20241219T060226.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Manish Naja Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 253 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora253_OF_v2d20221208.txt Instrument calibration file used: Pandora253s1_CF_v3d20231207.txt Level 1 file used: Pandora253s1_TucsonAZ_20240523_L1_smca1c3d20231207p1-8.txt Full location name: University of Arizona Department of Chemical and Environmental Engineering Short location name: TucsonAZ Country of location: United States Location latitude [deg]: 32.2330 Location longitude [deg]: -110.9530 Location altitude [m]: 779 Local noon date: 20240523 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 2 "Clearance session based on OOB session1, absolute calibration done with an uncalibrated lamp, certificate of FEL1441 (GSFC) used"" First and last pixel inside fitting window: 192 334 Nominal wavelengths inside fitting window [nm]: 305.0168 305.1576 305.2984 305.4391 305.5798 305.7205 305.8612 306.0019 306.1426 306.2833 306.4240 306.5646 306.7052 306.8459 306.9865 307.1271 307.2677 307.4083 307.5488 307.6894 307.8299 307.9705 308.1110 308.2515 308.3920 308.5325 308.6729 308.8134 308.9539 309.0943 309.2347 309.3751 309.5156 309.6559 309.7963 309.9367 310.0771 310.2174 310.3577 310.4981 310.6384 310.7787 310.9190 311.0593 311.1995 311.3398 311.4800 311.6203 311.7605 311.9007 312.0409 312.1811 312.3212 312.4614 312.6016 312.7417 312.8818 313.0219 313.1620 313.3021 313.4422 313.5823 313.7223 313.8624 314.0024 314.1424 314.2825 314.4225 314.5624 314.7024 314.8424 314.9823 315.1223 315.2622 315.4021 315.5420 315.6819 315.8218 315.9617 316.1016 316.2414 316.3812 316.5211 316.6609 316.8007 316.9405 317.0802 317.2200 317.3598 317.4995 317.6392 317.7790 317.9187 318.0584 318.1981 318.3377 318.4774 318.6170 318.7567 318.8963 319.0359 319.1755 319.3151 319.4547 319.5943 319.7338 319.8734 320.0129 320.1524 320.2919 320.4314 320.5709 320.7104 320.8498 320.9893 321.1287 321.2681 321.4076 321.5470 321.6864 321.8257 321.9651 322.1045 322.2438 322.3831 322.5225 322.6618 322.8011 322.9404 323.0796 323.2189 323.3581 323.4974 323.6366 323.7758 323.9150 324.0542 324.1934 324.3326 324.4717 324.6109 324.7500 324.8891 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240523T125245.3Z 8909.536635 207 1 54.60 2 84.68 68.80 99.24 246.38 0.00 1 0.00 1 0 17 5.676e-01 3.375e-02 5.646e-01 3.353e-02 1.135339e+00 2.178317e-02 1.168409e-02 -6.000000e+00 3.376597e-01 230.80 -2.00 3.29 -2.00 322.63 0.00e+00 8.164892e-03 1.231751e-02 7.283488e-03 -6.000000e+00 1.604537e-02 285.45 -2.00 20.00 -2.00 322.23 0.00e+00 9.382 0.011 302.00 328.00 3 3.9368e-01 8.9856e-02 1.1854e-01 -6.0000e+00 8.4458e-01 2.0216e+00 1.1438e-01 1.0170e-01 -6.0000e+00 9.1528e-01 -2.2114e+00 8.3024e-02 3.5785e-02 -6.0000e+00 5.4449e-01 7.9312e-01 4.1180e-02 1.5462e-02 -6.0000e+00 2.3455e-01 1.5921e-05 -1.4378e-03 9.0496e-04 1.6848e-04 -6.0000e+00 1.6146e-02 3.4889e-03 0.0000e+00 12 8 8 10 0 0 32.59 25.50 1.23 0.00349 -0.00732 36 3 1 5 0 1516.550 33.00 20.00 25.50 24.45 4.3 967.28 82670 900000 172 23854 900000 108184 -72313 -16239 -88641 -108126 82022 156203 900000 900000 900000 -60726 900000 -35285 30201 -20970 900000 75427 900000 65990 900000 -8981 -106846 -71508 19437 900000 900000 66799 30769 72712 -28741 900000 -92739 -70552 -2037 74351 -34487 156506 900000 -27588 95954 80272 68479 111958 32841 900000 900000 186186 154209 69478 50569 126834 151620 85810 -8981 21557 17886 188796 91772 -25377 13440 20 3578 38111 79311 102053 42592 12828 13867 24259 55156 61070 35113 19781 -3709 559 13077 19663 -5577 7246 3299 30162 9172 15278 -1382 6496 8380 11548 1569 -10152 -12766 1818 -4969 2130 684 3240 -2683 -6747 -6873 5076 -8362 -5783 -2435 2177 -4557 660 -499 -6551 -1258 1245 1819 -2014 2089 -1738 -967 -2588 1311 4745 1264 937 6208 -2153 5050 -1300 3134 2024 -1952 1353 199 -1244 -737 1551 837 1392 -648 -1264 1014 -1425 -1465 2695 900000 6 778 900000 3527 -2357 -529 -2889 -4112 2674 5092 900000 900000 900000 -3464 900000 -1821 984 -911 900000 2459 900000 2151 900000 -293 -7256 -3108 634 900000 900000 2177 1003 2370 -1533 900000 -8245 -5436 -91 2424 -2657 5102 900000 -2044 3128 2617 2232 3650 1363 900000 900000 6069 5027 3088 2847 4134 4942 3306 -825 1342 1113 6154 3263 -3384 1354 2 414 3275 4936 5746 4796 2015 2096 3019 4413 3981 2705 1817 -495 88 2209 3671 -1520 1868 929 6793 2637 4211 -446 1867 2210 2772 450 -3475 -5202 776 -2753 1312 491 2387 -2021 -4750 -4212 2548 -4934 -3525 -1516 1405 -3550 575 -519 -8243 -1611 1592 2282 -2567 2561 -2306 -1340 -3763 1795 5893 1525 1094 6678 -2456 5252 -1500 4025 3167 -3717 2809 457 -3160 -2018 4422 2473 4126 -1952 -3679 2660 -3484 -3323 SS 20240523T130447.6Z 8909.544996 210 1 54.84 2 82.29 70.31 101.51 247.75 0.00 1 0.00 1 0 25 8.303e-01 8.862e-03 2.953e-01 3.923e-03 9.073084e-01 2.292002e-03 9.398614e-03 -6.000000e+00 4.870853e-01 230.80 -2.00 3.29 -2.00 322.03 0.00e+00 6.001424e-03 1.424483e-03 1.057142e-03 -6.000000e+00 2.319719e-02 285.45 -2.00 20.00 -2.00 321.58 0.00e+00 6.941 0.004 302.00 328.00 3 5.6437e-01 9.5060e-03 8.0026e-02 -6.0000e+00 1.2206e+00 3.6052e-01 1.5626e-02 5.3180e-02 -6.0000e+00 1.3191e+00 -4.1006e-01 1.7221e-02 2.8458e-02 -6.0000e+00 7.8284e-01 1.4939e-01 7.5841e-03 1.2828e-02 -6.0000e+00 3.3449e-01 2.0608e-04 -8.4376e-04 1.0692e-04 1.6025e-04 -6.0000e+00 2.3015e-02 2.8469e-03 0.0000e+00 11 8 0 10 0 0 17.39 25.50 0.53 0.00285 -0.00349 165 16 1 5 0 332.350 33.00 20.00 25.50 24.78 4.3 969.56 -313988 -305645 -278482 -286367 -306996 -201621 -298037 -242232 -243862 900000 -263324 900000 -46272 900000 -149150 -174989 -90023 -81216 -144437 -77912 -83213 -83470 -88784 37484 14039 -86665 -538 -54942 -62876 -16106 -70841 -53094 11205 -2037 27916 -10364 -58976 32236 -33389 44096 4715 -15404 -19859 8279 -3175 -4207 20467 3246 21723 3704 6059 -214 9314 7344 14619 10532 5274 -822 9674 4489 -351 -613 5618 10036 11389 4264 4600 6944 4191 7308 2647 7100 4476 4982 -2122 -2724 -1049 -477 -1610 -2216 819 83 1330 -1249 -236 577 1249 180 1505 258 637 736 -1007 -1375 -1420 -2346 -247 158 367 -846 -829 -510 26 -1197 -1857 -1568 -2325 -140 -560 -284 -509 169 125 197 -97 284 666 302 148 -237 187 182 310 358 181 -59 678 1205 864 168 133 62 -98 135 -13 -588 -162 339 13 -39 -108 -92 -228 -2074 -2337 -1839 -2090 -2561 -771 -2279 -1179 -1356 900000 -2105 900000 -177 900000 -1089 -2129 -563 -536 -2008 -596 -694 -696 -802 143 54 -964 -3 -458 -568 -101 -960 -775 105 -25 252 -133 -1312 336 -824 613 113 -498 -718 260 -114 -158 626 125 756 170 308 -13 595 531 1068 846 464 -77 795 376 -31 -59 591 1182 1481 615 668 1036 708 1386 594 1621 1051 1101 -458 -527 -184 -85 -326 -547 238 28 512 -534 -106 274 621 94 776 131 304 331 -447 -634 -740 -1463 -180 135 354 -863 -813 -452 20 -895 -1456 -1306 -2059 -130 -581 -336 -695 254 197 311 -149 418 971 459 236 -395 310 286 463 516 253 -80 884 1599 1301 298 243 126 -214 316 -32 -1582 -447 944 37 -106 -273 -215 -503 SS 20240523T132213.2Z 8909.557098 215 1 54.87 2 78.80 72.43 104.83 249.68 0.00 1 0.00 1 0 25 3.714e-01 4.954e-03 5.086e-02 9.423e-04 6.806877e-01 5.160202e-04 7.217319e-03 -6.000000e+00 2.176224e-01 230.80 -2.00 3.29 -2.00 320.98 0.00e+00 2.932284e-03 2.364715e-04 4.876611e-04 -6.000000e+00 9.555064e-03 285.46 -2.00 20.00 -2.00 320.40 0.00e+00 4.971 0.002 302.00 328.00 3 4.1098e-01 1.7023e-03 5.7085e-02 -6.0000e+00 5.4415e-01 9.3940e-02 2.3442e-03 3.5263e-02 -6.0000e+00 5.8753e-01 -8.5523e-02 2.3950e-03 1.8531e-02 -6.0000e+00 3.4977e-01 2.3182e-02 1.1528e-03 7.5977e-03 -6.0000e+00 1.4898e-01 1.7142e-03 -5.0458e-04 2.6223e-05 7.5334e-05 -6.0000e+00 1.0243e-02 2.6233e-03 0.0000e+00 10 0 0 10 0 0 9.62 25.47 0.38 0.00262 -0.00117 531 50 1 5 0 103.330 32.75 19.99 25.47 25.48 4.3 974.70 -129602 -148350 -117100 -106070 -145713 -136984 -126737 -108304 -93055 -98764 -71463 -100927 -81569 -66926 -46727 -36499 -34593 -27968 -26869 -21668 -19438 -27331 -23378 -17145 -17430 -28492 -14792 -14969 -18971 -9686 -10425 -9165 255 -6054 -6122 -10878 -4936 -4737 -5248 -1284 -2611 -747 -339 -1927 -546 2457 936 -1880 133 714 2470 2167 2079 2969 1166 2201 1365 56 -482 272 190 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