File name: Pandora253s1_TucsonAZ_20240821_L2Fit_fout2c1d20230118p1-8.txt File generation date: 20240822T073255.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Armin Sorooshian Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 253 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora253_OF_v3d20221208.txt Instrument calibration file used: Pandora253s1_CF_v1d20230118.txt Level 1 file used: Pandora253s1_TucsonAZ_20240821_L1_smca1c1d20230118p1-8.txt Full location name: University of Arizona Department of Chemical and Environmental Engineering Short location name: TucsonAZ Country of location: United States Location latitude [deg]: 32.2330 Location longitude [deg]: -110.9530 Location altitude [m]: 779 Local noon date: 20240821 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Full lab calibration+OOB session, absolute calibration done with an uncalibrated lamp, certificate of FEL1441 (GSFC) used First and last pixel inside fitting window: 192 334 Nominal wavelengths inside fitting window [nm]: 305.0464 305.1873 305.3281 305.4689 305.6097 305.7505 305.8913 306.0321 306.1728 306.3136 306.4543 306.5950 306.7358 306.8765 307.0171 307.1578 307.2985 307.4391 307.5798 307.7204 307.8610 308.0016 308.1422 308.2828 308.4234 308.5639 308.7045 308.8450 308.9856 309.1261 309.2666 309.4071 309.5475 309.6880 309.8285 309.9689 310.1093 310.2498 310.3902 310.5306 310.6709 310.8113 310.9517 311.0920 311.2323 311.3727 311.5130 311.6533 311.7936 311.9339 312.0741 312.2144 312.3546 312.4948 312.6351 312.7753 312.9155 313.0556 313.1958 313.3360 313.4761 313.6162 313.7564 313.8965 314.0366 314.1767 314.3167 314.4568 314.5969 314.7369 314.8769 315.0169 315.1569 315.2969 315.4369 315.5769 315.7168 315.8568 315.9967 316.1366 316.2765 316.4164 316.5563 316.6962 316.8360 316.9759 317.1157 317.2556 317.3954 317.5352 317.6750 317.8147 317.9545 318.0942 318.2340 318.3737 318.5134 318.6531 318.7928 318.9325 319.0722 319.2118 319.3515 319.4911 319.6307 319.7703 319.9099 320.0495 320.1891 320.3286 320.4682 320.6077 320.7472 320.8868 321.0263 321.1657 321.3052 321.4447 321.5841 321.7236 321.8630 322.0024 322.1418 322.2812 322.4206 322.5600 322.6993 322.8386 322.9780 323.1173 323.2566 323.3959 323.5352 323.6744 323.8137 323.9529 324.0922 324.2314 324.3706 324.5098 324.6490 324.7882 324.9273 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240821T132304.6Z 8999.557692 214 1 53.91 2 84.51 79.47 72.27 253.16 0.00 1 0.00 1 0 25 6.307e-01 4.093e-02 5.411e-01 4.046e-02 9.956287e-01 2.495156e-02 1.080097e-02 -6.000000e+00 3.770729e-01 229.56 -2.00 3.29 -2.00 322.37 0.00e+00 -1.579816e-02 1.324870e-02 5.540766e-03 -6.000000e+00 1.958366e-02 289.55 -2.00 20.00 -2.00 321.88 0.00e+00 9.154 0.010 302.00 328.00 3 1.0220e+00 9.9727e-02 1.0032e-01 -6.0000e+00 9.4529e-01 1.6130e+00 1.2496e-01 5.7157e-02 -6.0000e+00 1.0285e+00 -2.0038e+00 7.8897e-02 2.9960e-02 -6.0000e+00 6.0673e-01 7.6972e-01 3.9337e-02 9.6711e-03 -6.0000e+00 2.5784e-01 1.5293e-05 -1.2810e-03 1.1234e-03 2.0498e-04 -6.0000e+00 1.8141e-02 -3.6417e-02 0.0000e+00 12 8 8 10 0 0 53.79 25.77 1.12 -0.03642 -0.04604 24 2 1 5 0 2246.150 33.00 20.00 25.77 35.98 4.0 1037.06 -55916 35070 -10755 136170 900000 900000 46461 -109779 900000 -83305 900000 900000 -63891 113340 153102 900000 900000 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-5168 176 -3061 900000 593 4052 452 4389 11394 5895 7476 2517 3271 3698 -852 307 3360 1856 2912 5296 2247 2089 1779 3318 -5727 5790 4120 -639 2839 -2362 -5339 -1860 -2571 6007 5021 2203 -5064 1140 5432 -3677 7913 3775 4989 1524 -1621 2642 -3118 991 6119 -1284 344 -6716 -116 -8875 117 -2381 -275 3384 -1916 -416 -1431 -1770 -984 -5014 -1857 -3288 -3878 -282 -212 2067 1628 2563 2194 410 -873 5519 2064 3183 1068 5862 2404 -5387 -370 1257 3195 -4178 2069 -876 3655 -2742 7324 -2419 3914 -958 -10770 SS 20240821T133510.9Z 8999.566098 217 1 54.73 2 81.99 81.03 74.62 254.98 0.00 1 0.00 1 0 25 6.965e-01 9.639e-03 3.038e-01 4.183e-03 7.847075e-01 2.370370e-03 8.422395e-03 -6.000000e+00 4.064306e-01 229.56 -2.00 3.29 -2.00 321.79 0.00e+00 5.265216e-03 1.422745e-03 1.740985e-03 -6.000000e+00 1.823223e-02 289.55 -2.00 20.00 -2.00 321.27 0.00e+00 6.710 0.004 302.00 328.00 3 8.8476e-01 9.5558e-03 7.3106e-02 -6.0000e+00 1.0117e+00 2.4762e-01 1.4509e-02 4.1533e-02 -6.0000e+00 1.0925e+00 -3.0252e-01 1.4942e-02 2.3925e-02 -6.0000e+00 6.5277e-01 1.0664e-01 6.7340e-03 9.8876e-03 -6.0000e+00 2.7986e-01 2.1729e-04 -1.0952e-03 1.1691e-04 1.3634e-04 -6.0000e+00 1.9199e-02 -3.6459e-02 0.0000e+00 12 8 8 10 0 0 -3.34 25.77 0.51 -0.03646 -0.04469 136 13 1 5 0 402.420 33.00 20.00 25.77 36.37 4.0 1039.91 -257168 -279980 -289423 15204 8082 -237070 -194772 -217858 -219090 -224842 -64448 -145232 -133525 -129663 -118404 -58052 -368 81832 -106820 -64988 -84041 87862 -19852 223032 -3780 -42733 -39069 -51141 -24433 -67235 -37124 -19340 -35613 7187 93951 -32419 -13757 20364 -10218 11034 6159 3712 18107 7358 -5158 7953 12353 4984 633 5828 2228 4489 8378 7782 5153 10271 5252 5207 -1619 3864 1319 3314 8527 3979 5552 2346 6717 7845 3174 6856 6390 1709 3997 1544 3054 3892 -37 -727 -931 -2091 186 -481 -700 -1185 -1306 -1059 -1665 -645 1370 1035 -1872 -1128 584 -848 -191 -1014 -927 497 -262 -441 -307 -593 -547 -441 -1167 -2581 -1180 -908 -521 283 164 -321 -32 75 691 607 724 91 542 128 -504 155 619 510 61 -150 -346 2107 540 305 166 230 -274 56 53 -563 -466 243 18 -99 -94 -59 89 -2003 -3426 -4400 62 33 -1934 -1083 -1696 -1950 -2335 -263 -808 -842 -1058 -1142 -387 -2 334 -1743 -747 -1215 358 -155 910 -29 -523 -478 -702 -254 -1147 -564 -308 -806 132 728 -860 -320 390 -325 347 236 160 724 342 -278 386 595 270 38 361 160 359 721 743 547 1089 608 610 -198 435 154 410 1144 646 983 438 1195 1424 656 1572 1666 498 1149 435 777 881 -8 -158 -222 -603 63 -191 -315 -578 -679 -587 -980 -391 821 609 -1071 -599 293 -438 -108 -679 -731 451 -270 -475 -318 -563 -464 -356 -994 -2383 -1134 -933 -585 357 234 -506 -52 122 1070 903 1063 139 872 217 -861 254 965 769 89 -213 -476 2863 830 541 303 458 -584 128 129 -1468 -1254 660 50 -265 -236 -138 199 SS 20240821T135041.8Z 8999.576873 222 1 54.82 2 78.74 83.03 77.67 257.25 0.00 1 0.00 1 0 25 2.359e-01 4.943e-03 4.784e-02 1.014e-03 6.077534e-01 5.481232e-04 6.598992e-03 -6.000000e+00 1.376979e-01 229.56 -2.00 3.29 -2.00 320.76 0.00e+00 2.881120e-03 2.382241e-04 3.313608e-04 -6.000000e+00 6.176060e-03 289.55 -2.00 20.00 -2.00 320.09 0.00e+00 4.946 0.002 302.00 328.00 3 5.4751e-01 1.7926e-03 5.4444e-02 -6.0000e+00 3.4277e-01 4.9642e-02 2.3736e-03 3.1041e-02 -6.0000e+00 3.7011e-01 -5.7259e-02 2.2652e-03 1.6074e-02 -6.0000e+00 2.2115e-01 1.2186e-02 1.1114e-03 6.6182e-03 -6.0000e+00 9.4833e-02 1.7119e-03 -6.0544e-04 2.8802e-05 6.7212e-05 -6.0000e+00 6.5031e-03 -3.7732e-02 0.0000e+00 10 0 0 10 0 0 12.17 25.75 0.39 -0.03773 -0.04228 453 43 1 5 0 121.010 33.00 20.00 25.75 37.29 4.0 1047.30 -76889 -78989 -69442 -70360 -92397 -87955 -88365 -83869 -62653 -57369 -79711 -50522 -35290 -47864 -11740 -9485 -16364 -20676 -10735 -7943 -16903 -5630 -14823 -10585 -5425 -10292 -18360 -14408 -16172 -5225 -2623 -319 -5056 -845 -5681 -6596 -2354 -8531 -2365 -2053 -3087 -29 -2469 -1158 -1373 -465 85 -168 352 -273 1354 1368 995 1291 1613 1730 383 -149 385 195 -267 1540 1678 2380 2103 1016 1867 505 1162 1556 861 567 338 406 -118 -144 -187 -994 -1038 -702 -1312 -1082 -1665 -1444 -905 -618 30 143 597 567 605 899 570 648 497 349 260 737 135 -321 -467 -403 -332 125 -661 -1410 -899 -719 -328 199 -92 -43 106 202 164 370 533 417 142 -240 -577 -116 101 9 167 288 324 1167 837 186 31 -152 10 49 69 -376 -232 269 -132 -220 24 -52 16 -359 -461 -412 -430 -721 -626 -664 -680 -471 -454 -835 -429 -314 -620 -135 -130 -278 -409 -211 -163 -396 -119 -353 -262 -139 -296 -595 -444 -494 -148 -83 -12 -231 -41 -291 -330 -120 -537 -171 -180 -317 -3 -293 -141 -170 -58 11 -22 48 -40 211 239 193 272 363 408 95 -38 95 47 -66 400 491 781 749 366 646 179 436 664 418 294 178 206 -56 -62 -73 -381 -425 -333 -736 -697 -1093 -1013 -672 -490 25 124 522 485 488 672 403 454 376 302 260 840 157 -390 -545 -470 -351 127 -715 -1643 -1097 -931 -419 280 -144 -72 182 337 260 552 780 630 227 -408 -998 -195 163 14 250 414 449 1603 1257 317 58 -283 19 101 151 -881 -523 615 -306 -500 55 -114 33 SS 20240821T135629.2Z 8999.580894 225 1 54.87 2 77.53 83.77 78.81 258.08 0.00 1 0.00 1 0 25 1.375e-01 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