File name: Pandora253s1_TucsonAZ_20240916_L2Fit_fout2c1d20230118p1-8.txt
File generation date: 20240917T072629.7Z
Data description: Level 2 spectral fitting results file
Data file version: fout2c1p1-8
Local principal investigator: Armin Sorooshian
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 253
Spectrometer number: 1
Processing software version used: BlickP v1.8.59
Instrument operation file used: Pandora253_OF_v3d20221208.txt
Instrument calibration file used: Pandora253s1_CF_v1d20230118.txt
Level 1 file used: Pandora253s1_TucsonAZ_20240916_L1_smca1c1d20230118p1-8.txt
Full location name: University of Arizona Department of Chemical and Environmental Engineering
Short location name: TucsonAZ
Country of location: United States
Location latitude [deg]: 32.2330
Location longitude [deg]: -110.9530
Location altitude [m]: 779
Local noon date: 20240916
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: Full lab calibration+OOB session, absolute calibration done with an uncalibrated lamp, certificate of FEL1441 (GSFC) used
First and last pixel inside fitting window: 192 334
Nominal wavelengths inside fitting window [nm]: 305.0464 305.1873 305.3281 305.4689 305.6097 305.7505 305.8913 306.0321 306.1728 306.3136 306.4543 306.5950 306.7358 306.8765 307.0171 307.1578 307.2985 307.4391 307.5798 307.7204 307.8610 308.0016 308.1422 308.2828 308.4234 308.5639 308.7045 308.8450 308.9856 309.1261 309.2666 309.4071 309.5475 309.6880 309.8285 309.9689 310.1093 310.2498 310.3902 310.5306 310.6709 310.8113 310.9517 311.0920 311.2323 311.3727 311.5130 311.6533 311.7936 311.9339 312.0741 312.2144 312.3546 312.4948 312.6351 312.7753 312.9155 313.0556 313.1958 313.3360 313.4761 313.6162 313.7564 313.8965 314.0366 314.1767 314.3167 314.4568 314.5969 314.7369 314.8769 315.0169 315.1569 315.2969 315.4369 315.5769 315.7168 315.8568 315.9967 316.1366 316.2765 316.4164 316.5563 316.6962 316.8360 316.9759 317.1157 317.2556 317.3954 317.5352 317.6750 317.8147 317.9545 318.0942 318.2340 318.3737 318.5134 318.6531 318.7928 318.9325 319.0722 319.2118 319.3515 319.4911 319.6307 319.7703 319.9099 320.0495 320.1891 320.3286 320.4682 320.6077 320.7472 320.8868 321.0263 321.1657 321.3052 321.4447 321.5841 321.7236 321.8630 322.0024 322.1418 322.2812 322.4206 322.5600 322.6993 322.8386 322.9780 323.1173 323.2566 323.3959 323.5352 323.6744 323.8137 323.9529 324.0922 324.2314 324.3706 324.5098 324.6490 324.7882 324.9273
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Ozone effective temperature [K]
Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Sulfur dioxide effective temperature [K]
Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 46: Lower limit used for wavelength scaling [nm]
Column 47: Upper limit used for wavelength scaling [nm]
Column 48: Order of smoothing polynomial
Column 49: Smoothing polynomial coefficient, order 0
Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 54: Smoothing polynomial coefficient, order 1
Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 59: Smoothing polynomial coefficient, order 2
Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 64: Smoothing polynomial coefficient, order 3
Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 69: Mean value of measured data inside fitting window [same units as measurements]
Column 70: Wavelength change polynomial coefficient, order 0
Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 84: Wavelength effective temperature [°C], 999=no effective temperature given
Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 88: Number of bright count cycles
Column 89: Number of dark count cycles
Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 93: Integration time [ms]
Column 94: Temperature at electronics board [°C], 999=no temperature signal
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Humidity in head sensor [%], -9=no humidity signal
Column 99: Pressure in head sensor [hPa], -9=no pressure signal
Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SS 20240916T140537.2Z 9025.587236 198 1 52.79 2 78.81 94.38 123.69 274.86 0.00 1 0.00 1 0 25 1.843e-01 4.754e-03 5.380e-02 1.215e-03 5.814434e-01 6.556565e-04 6.318624e-03 -6.000000e+00 1.070964e-01 228.32 -2.00 3.29 -2.00 320.67 0.00e+00 2.880381e-03 2.715147e-04 3.279388e-04 -6.000000e+00 4.797609e-03 288.20 -2.00 20.00 -2.00 320.00 0.00e+00 4.975 0.002 302.00 328.00 3 8.8358e-01 2.0842e-03 5.3747e-02 -6.0000e+00 2.6593e-01 5.9011e-02 2.7270e-03 2.9525e-02 -6.0000e+00 2.8746e-01 -5.6662e-02 2.5833e-03 1.5246e-02 -6.0000e+00 1.7179e-01 1.2076e-02 1.2788e-03 6.2419e-03 -6.0000e+00 7.3771e-02 1.2308e-03 -8.3739e-04 3.5107e-05 6.2192e-05 -6.0000e+00 5.0788e-03 -3.8779e-02 0.0000e+00 12 1 1 12 1 1 99.69 25.68 0.41 -0.03878 -0.04507 280 27 1 5 0 187.840 33.00 20.00 25.68 32.56 4.0 1011.89 -65959 -72367 -55232 -59667 -65375 -49939 -66243 -14764 -62210 -52013 -59625 -54354 -49682 -16585 -21737 -4183 -18964 -396 -15813 -8806 -1890 -10878 -15897 -9656 -13294 -13424 -13656 -12817 -5254 -10985 -4102 -4909 -4467 -4303 -3168 -4782 -6609 -6859 -4969 -821 -1124 -2025 -682 -255 -131 65 485 14 -2030 -694 1202 1585 2222 2440 1417 506 812 1285 -657 -790 314 1892 1550 2389 2091 1396 1349 550 1271 1230 883 457 226 293 -86 48 -511 -460 -987 -201 -1210 -1024 -1179 -1466 -1037 -422 -423 -97 259 316 833 671 462 740 713 -111 126 502 73 -452 -241 -501 -65 321 -371 -1234 -756 -697 -313 336 23 -12 -123 247 185 525 533 522 295 -262 -709 -294 97 120 174 241 177 1152 828 115 40 -49 -166 29 -19 -285 -196 250 -14 -143 -108 -44 25 -355 -507 -363 -459 -496 -308 -502 -75 -582 -487 -636 -592 -624 -191 -332 -65 -395 -8 -388 -215 -45 -286 -450 -277 -430 -464 -492 -453 -167 -380 -151 -216 -229 -245 -178 -263 -392 -473 -410 -79 -125 -249 -88 -34 -18 9 68 2 -308 -109 202 297 456 543 342 129 213 340 -174 -205 82 521 481 829 786 527 492 203 495 545 443 246 124 155 -42 21 -208 -182 -416 -97 -693 -672 -784 -1047 -784 -340 -361 -86 231 277 684 512 333 524 542 -97 126 573 93 -549 -306 -585 -68 326 -401 -1439 -923 -904 -399 469 36 -20 -209 406 288 771 767 774 464 -438 -1211 -490 156 186 259 344 243 1561 1221 191 74 -90 -318 58 -40 -649 -462 598 -35 -341 -245 -95 50
SS 20240916T141511.6Z 9025.593885 204 1 54.86 2 76.80 95.70 125.59 276.26 0.00 1 0.00 1 0 25 1.089e-01 5.255e-03 2.637e-02 1.033e-03 5.070726e-01 5.411274e-04 5.534150e-03 -6.000000e+00 6.327821e-02 228.32 -2.00 3.29 -2.00 320.12 0.00e+00 1.934412e-03 1.879743e-04 2.373915e-04 -6.000000e+00 2.834841e-03 288.20 -2.00 20.00 -2.00 319.39 0.00e+00 4.268 0.001 302.00 328.00 3 1.3793e+00 1.6274e-03 4.6200e-02 -6.0000e+00 1.5713e-01 3.7788e-02 2.0112e-03 2.5260e-02 -6.0000e+00 1.6985e-01 -2.7521e-02 1.7377e-03 1.2685e-02 -6.0000e+00 1.0150e-01 1.6332e-03 8.9072e-04 4.4026e-03 -6.0000e+00 4.3585e-02 1.5051e-03 -8.1443e-04 3.0127e-05 4.4655e-05 -6.0000e+00 3.0010e-03 -3.8380e-02 0.0000e+00 10 0 0 10 0 0 99.94 25.68 0.39 -0.03838 -0.04450 259 24 1 5 0 211.780 33.00 20.00 25.68 32.93 3.9 1015.08 -27717 -33695 -33528 -26691 -34633 -53398 -40557 -29749 -36417 -40318 -23300 -20147 -23097 -18054 -6814 -14342 -6706 -8226 -3926 -4581 -4454 -3151 -7497 -8361 -9141 -6505 -4867 -6981 -7669 -9300 -4391 -2361 201 -2335 -3569 -3524 -3984 -2881 -1542 -1856 -2460 -1340 -1246 21 -274 428 -543 -326 1146 297 1448 1423 1319 1512 922 1233 724 250 -17 432 1219 1802 1891 1733 1615 1226 1274 -3 943 1072 247 497 489 402 31 115 -122 -679 -427 -240 -979 -1062 -1527 -1823 -900 -855 -445 -173 218 334 643 805 651 849 853 105 217 527 76 -530 -554 -444 -237 410 -603 -1154 -864 -963 -387 159 88 126 -137 126 215 515 624 473 157 -166 -658 -333 48 142 158 310 179 1316 931 181 119 -115 -179 125 105 -297 -90 214 -91 -263 -167 -124 -66 -246 -380 -415 -312 -405 -710 -494 -366 -547 -694 -354 -315 -437 -404 -168 -457 -224 -304 -151 -188 -190 -134 -340 -410 -490 -362 -276 -397 -421 -525 -262 -161 15 -201 -308 -292 -351 -290 -186 -272 -417 -244 -239 4 -54 86 -111 -67 239 65 336 365 371 459 300 416 254 89 -6 148 420 660 771 789 787 591 587 -2 455 532 139 298 298 237 17 63 -61 -328 -215 -138 -599 -742 -1186 -1514 -787 -802 -441 -178 227 339 614 711 537 682 726 102 238 602 96 -696 -699 -514 -273 456 -657 -1354 -1063 -1254 -537 240 134 205 -225 200 346 778 920 719 253 -263 -1073 -532 74 230 245 460 254 1833 1399 304 202 -208 -337 245 219 -614 -192 465 -201 -572 -346 -262 -134
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