File name: Pandora253s1_TucsonAZ_20241103_L2Fit_fwvt1c3d20231207p1-8.txt File generation date: 20241219T074203.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Armin Sorooshian Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 253 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora253_OF_v3d20221208.txt Instrument calibration file used: Pandora253s1_CF_v3d20231207.txt Level 1 file used: Pandora253s1_TucsonAZ_20241103_L1_smca1c3d20231207p1-8.txt Full location name: University of Arizona Department of Chemical and Environmental Engineering Short location name: TucsonAZ Country of location: United States Location latitude [deg]: 32.2330 Location longitude [deg]: -110.9530 Location altitude [m]: 779 Local noon date: 20241103 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 2 "Clearance session based on OOB session1, absolute calibration done with an uncalibrated lamp, certificate of FEL1441 (GSFC) used"" First and last pixel inside fitting window: 1616 1766 Nominal wavelengths inside fitting window [nm]: 492.0560 492.1767 492.2973 492.4178 492.5384 492.6590 492.7795 492.9000 493.0205 493.1410 493.2614 493.3819 493.5023 493.6227 493.7431 493.8635 493.9839 494.1042 494.2245 494.3448 494.4651 494.5854 494.7057 494.8259 494.9461 495.0664 495.1866 495.3067 495.4269 495.5470 495.6672 495.7873 495.9074 496.0274 496.1475 496.2675 496.3875 496.5076 496.6275 496.7475 496.8675 496.9874 497.1073 497.2272 497.3471 497.4670 497.5868 497.7067 497.8265 497.9463 498.0661 498.1859 498.3056 498.4253 498.5451 498.6648 498.7844 498.9041 499.0238 499.1434 499.2630 499.3826 499.5022 499.6218 499.7413 499.8608 499.9803 500.0998 500.2193 500.3388 500.4582 500.5777 500.6971 500.8165 500.9358 501.0552 501.1745 501.2939 501.4132 501.5325 501.6517 501.7710 501.8902 502.0095 502.1287 502.2478 502.3670 502.4862 502.6053 502.7244 502.8435 502.9626 503.0817 503.2007 503.3198 503.4388 503.5578 503.6768 503.7957 503.9147 504.0336 504.1525 504.2714 504.3903 504.5092 504.6280 504.7469 504.8657 504.9845 505.1032 505.2220 505.3407 505.4595 505.5782 505.6969 505.8155 505.9342 506.0528 506.1715 506.2901 506.4087 506.5272 506.6458 506.7643 506.8828 507.0013 507.1198 507.2383 507.3567 507.4752 507.5936 507.7120 507.8304 507.9487 508.0671 508.1854 508.3037 508.4220 508.5403 508.6586 508.7768 508.8950 509.0132 509.1314 509.2496 509.3678 509.4859 509.6040 509.7221 509.8402 509.9583 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20241103T141358.3Z 9073.593036 53 1 5.95 2 84.69 111.87 108.71 109.23 0.00 1 0.00 1 0 22 2.061e-03 2.048e-03 1.164e-04 1.163e-04 8.538487e+03 8.138265e+00 5.670361e+02 -6.000000e+00 1.203665e+02 283.59 -2.00 20.00 -2.00 505.33 0.00e+00 1.065714e-03 3.289663e-06 7.040513e-05 -6.000000e+00 5.904760e-05 283.59 -2.00 20.00 -2.00 500.59 0.00e+00 8.955227e-01 2.326277e-03 6.125279e-02 -6.000000e+00 4.150862e-02 225.10 -2.00 3.29 -2.00 502.17 0.00e+00 9.399 0.011 489.00 513.00 1 7.2033e-01 1.7913e-04 1.3524e-02 -6.0000e+00 3.1972e-03 -9.0255e-04 4.4542e-05 1.5968e-03 -6.0000e+00 8.1162e-04 2.5471e-01 9.3595e-04 1.2989e-05 5.8543e-05 -6.0000e+00 2.4736e-04 9.6601e-04 7.9664e-06 10 0 0 10 0 0 8.81 25.32 1.49 0.00097 0.00746 538 51 1 4 0 11.040 32.75 20.00 25.32 20.54 4.0 926.29 -385 -216 -179 -53 38 200 342 278 253 184 33 -43 -114 -163 -124 -149 -143 -23 82 -25 49 112 222 189 332 141 51 17 -70 -166 -101 -22 -73 46 48 -102 -121 24 62 25 14 94 169 217 246 255 212 76 -23 -88 -290 -373 -323 -254 -132 -82 -68 -26 100 169 279 257 242 177 170 127 32 -105 -110 -162 -164 -117 -143 -134 -48 -203 -288 -272 -182 -197 -353 -255 -315 -257 -210 -206 -238 -241 -98 35 33 94 177 217 137 171 70 -3 -227 -336 -419 -320 -342 -218 -135 -328 -289 -122 -31 43 87 128 131 393 455 493 533 507 342 159 188 159 218 323 253 126 142 94 36 141 56 -154 -144 -132 -142 -109 18 -3 -5 28 129 96 80 179 116 34 -93 -248 -296 -354 -298 -367 -208 -177 -52 38 205 345 283 258 186 33 -44 -115 -163 -124 -150 -145 -23 83 -26 51 117 232 198 349 148 53 18 -71 -165 -99 -22 -72 47 50 -104 -123 25 64 26 14 98 171 221 253 264 219 78 -23 -89 -288 -363 -311 -246 -130 -82 -68 -26 101 171 283 262 247 180 172 127 32 -106 -110 -160 -162 -115 -142 -133 -48 -204 -286 -267 -176 -189 -340 -246 -307 -253 -209 -207 -232 -235 -95 34 33 93 176 215 134 169 68 -3 -210 -318 -395 -295 -324 -214 -132 -326 -288 -121 -30 42 87 128 133 389 453 493 537 513 346 161 187 162 218 323 253 127 138 92 35 142 56 -153 -142 -129 -138 -107 18 -3 -5 29 133 100 81 181 117 35 -96 -252 -296 -353 -298 SQ 20241103T141404.3Z 9073.593105 53 2 5.95 2 84.67 111.89 108.69 109.25 0.00 1 0.00 1 0 22 2.071e-03 2.061e-03 1.161e-04 1.160e-04 8.500922e+03 8.107630e+00 5.664809e+02 -6.000000e+00 1.209574e+02 283.59 -2.00 20.00 -2.00 505.32 0.00e+00 1.064480e-03 3.277931e-06 7.014407e-05 -6.000000e+00 5.933769e-05 283.59 -2.00 20.00 -2.00 500.58 0.00e+00 8.962301e-01 2.320455e-03 6.070703e-02 -6.000000e+00 4.171374e-02 225.10 -2.00 3.29 -2.00 502.16 0.00e+00 9.373 0.011 489.00 513.00 1 7.1727e-01 1.7862e-04 1.3474e-02 -6.0000e+00 3.2130e-03 -9.4842e-04 4.4468e-05 1.5876e-03 -6.0000e+00 8.1567e-04 2.5637e-01 9.8330e-04 1.2961e-05 5.7969e-05 -6.0000e+00 2.4857e-04 1.8251e-03 -1.7007e-07 10 0 0 10 0 0 -3.85 25.32 1.49 0.00183 0.00865 538 51 1 4 0 11.040 32.75 20.00 25.32 20.61 4.0 926.29 -358 -228 -180 -55 9 192 369 280 249 191 27 -34 -87 -171 -94 -141 -144 -13 95 -22 52 112 223 166 330 143 65 4 -54 -177 -94 -13 -87 31 41 -108 -127 37 36 -8 30 118 177 215 260 283 237 71 -29 -117 -280 -370 -327 -273 -134 -72 -64 -23 103 140 280 273 236 209 180 99 47 -116 -110 -175 -162 -127 -150 -138 -63 -215 -289 -251 -186 -198 -336 -248 -292 -258 -208 -207 -270 -263 -112 12 43 86 206 220 152 161 78 -24 -220 -332 -416 -350 -331 -225 -132 -295 -276 -103 -23 42 74 108 145 396 447 489 530 516 325 172 157 151 233 311 268 150 155 60 61 119 64 -130 -136 -148 -142 -95 29 -5 -21 26 149 81 91 198 129 45 -89 -257 -312 -361 -307 -342 -220 -178 -55 9 191 373 286 254 194 27 -35 -88 -172 -94 -142 -147 -13 98 -23 55 117 233 175 336 146 68 4 -55 -177 -92 -13 -87 32 41 -111 -131 38 36 -9 31 119 180 221 269 293 245 72 -29 -120 -278 -361 -316 -265 -132 -73 -64 -23 104 143 285 279 242 214 183 100 47 -118 -111 -174 -159 -126 -149 -138 -63 -216 -287 -246 -180 -191 -325 -241 -286 -255 -207 -201 -264 -257 -109 11 42 85 205 218 150 155 75 -23 -204 -315 -393 -324 -315 -222 -129 -295 -276 -103 -23 41 74 109 143 393 447 491 535 524 331 174 157 149 234 311 270 147 152 59 59 116 64 -130 -134 -145 -139 -93 28 -5 -21 26 153 82 92 201 131 46 -89 -262 -313 -360 -308 SQ 20241103T141410.3Z 9073.593174 53 3 5.95 2 84.65 111.90 108.67 109.26 0.00 1 0.00 1 0 22 2.027e-03 2.019e-03 1.160e-04 1.159e-04 8.475139e+03 8.089013e+00 5.645665e+02 -6.000000e+00 1.184017e+02 283.59 -2.00 20.00 -2.00 505.32 0.00e+00 1.069842e-03 3.272910e-06 7.020512e-05 -6.000000e+00 5.808413e-05 283.59 -2.00 20.00 -2.00 500.59 0.00e+00 8.943183e-01 2.315978e-03 6.061515e-02 -6.000000e+00 4.083333e-02 225.10 -2.00 3.29 -2.00 502.17 0.00e+00 9.347 0.011 489.00 513.00 1 7.1859e-01 1.7828e-04 1.3438e-02 -6.0000e+00 3.1452e-03 -9.3532e-04 4.4396e-05 1.5845e-03 -6.0000e+00 7.9847e-04 2.5694e-01 1.0363e-03 1.2959e-05 5.8243e-05 -6.0000e+00 2.4332e-04 1.6736e-03 -1.3290e-06 10 0 0 10 0 0 -1.55 25.32 1.49 0.00167 0.00886 538 51 1 4 0 11.040 32.75 20.00 25.32 20.61 4.0 926.29 -372 -224 -186 -20 31 173 344 265 240 197 31 -36 -89 -157 -126 -147 -152 -13 83 -18 61 102 220 193 322 113 31 -3 -71 -174 -93 1 -89 69 36 -95 -96 27 50 9 13 120 161 213 241 265 234 83 -5 -95 -291 -336 -330 -262 -128 -81 -67 -13 75 138 285 271 220 187 181 121 47 -123 -99 -164 -159 -128 -130 -135 -62 -220 -296 -257 -166 -189 -332 -246 -296 -246 -234 -200 -249 -253 -112 57 34 81 187 215 151 160 67 -23 -222 -308 -411 -332 -325 -213 -133 -305 -285 -129 -7 31 86 114 135 392 452 494 527 509 338 163 172 154 224 318 242 140 128 90 51 109 32 -105 -120 -124 -166 -105 -9 -26 -3 27 142 69 81 183 118 35 -116 -227 -303 -345 -257 -356 -217 -178 -20 32 172 348 271 246 200 31 -35 -90 -158 -126 -148 -155 -13 85 -19 63 107 231 204 328 115 32 -3 -72 -173 -92 1 -89 71 36 -98 -99 28 50 9 14 121 164 218 249 275 241 85 -5 -97 -290 -329 -320 -254 -127 -82 -67 -13 77 140 290 277 226 192 184 122 47 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