File name: Pandora253s1_TucsonAZ_20250301_L2Fit_fwvt1c3d20231207p1-8.txt File generation date: 20250302T074707.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Armin Sorooshian Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 253 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora253_OF_v3d20221208.txt Instrument calibration file used: Pandora253s1_CF_v3d20231207.txt Level 1 file used: Pandora253s1_TucsonAZ_20250301_L1_smca1c3d20231207p1-8.txt Full location name: University of Arizona Department of Chemical and Environmental Engineering Short location name: TucsonAZ Country of location: United States Location latitude [deg]: 32.2330 Location longitude [deg]: -110.9530 Location altitude [m]: 779 Local noon date: 20250301 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 2 "Clearance session based on OOB session1, absolute calibration done with an uncalibrated lamp, certificate of FEL1441 (GSFC) used"" First and last pixel inside fitting window: 1616 1766 Nominal wavelengths inside fitting window [nm]: 492.0560 492.1767 492.2973 492.4178 492.5384 492.6590 492.7795 492.9000 493.0205 493.1410 493.2614 493.3819 493.5023 493.6227 493.7431 493.8635 493.9839 494.1042 494.2245 494.3448 494.4651 494.5854 494.7057 494.8259 494.9461 495.0664 495.1866 495.3067 495.4269 495.5470 495.6672 495.7873 495.9074 496.0274 496.1475 496.2675 496.3875 496.5076 496.6275 496.7475 496.8675 496.9874 497.1073 497.2272 497.3471 497.4670 497.5868 497.7067 497.8265 497.9463 498.0661 498.1859 498.3056 498.4253 498.5451 498.6648 498.7844 498.9041 499.0238 499.1434 499.2630 499.3826 499.5022 499.6218 499.7413 499.8608 499.9803 500.0998 500.2193 500.3388 500.4582 500.5777 500.6971 500.8165 500.9358 501.0552 501.1745 501.2939 501.4132 501.5325 501.6517 501.7710 501.8902 502.0095 502.1287 502.2478 502.3670 502.4862 502.6053 502.7244 502.8435 502.9626 503.0817 503.2007 503.3198 503.4388 503.5578 503.6768 503.7957 503.9147 504.0336 504.1525 504.2714 504.3903 504.5092 504.6280 504.7469 504.8657 504.9845 505.1032 505.2220 505.3407 505.4595 505.5782 505.6969 505.8155 505.9342 506.0528 506.1715 506.2901 506.4087 506.5272 506.6458 506.7643 506.8828 507.0013 507.1198 507.2383 507.3567 507.4752 507.5936 507.7120 507.8304 507.9487 508.0671 508.1854 508.3037 508.4220 508.5403 508.6586 508.7768 508.8950 509.0132 509.1314 509.2496 509.3678 509.4859 509.6040 509.7221 509.8402 509.9583 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20250301T140210.1Z 9191.584839 35 1 15.40 2 88.45 99.69 101.11 81.74 0.00 1 0.00 1 0 22 4.703e-03 4.692e-03 1.180e-03 1.177e-03 6.565854e+03 7.785469e+01 4.357713e+02 -6.000000e+00 2.697571e+02 278.89 -2.00 20.00 -2.00 505.36 0.00e+00 1.945149e-03 3.304139e-05 1.106157e-04 -6.000000e+00 1.333366e-04 278.89 -2.00 20.00 -2.00 500.91 0.00e+00 1.079780e+00 2.331553e-02 5.519833e-02 -6.000000e+00 9.577559e-02 225.68 -2.00 3.29 -2.00 502.43 0.00e+00 17.391 0.071 489.00 513.00 1 5.0230e+00 1.7859e-03 2.5123e-02 -6.0000e+00 7.3496e-03 -1.4025e-02 4.4983e-04 1.8247e-03 -6.0000e+00 1.8929e-03 1.1979e-03 2.9911e-03 1.3475e-04 6.6224e-05 -6.0000e+00 5.6534e-04 -2.1921e-02 -3.0393e-04 12 9 9 12 1 1 26.57 25.28 1.76 -0.02192 -0.00117 7 3 1 4 0 1924.310 32.75 20.00 25.28 17.92 4.2 909.53 900000 736 -166 -499 -397 -167 -37 -137 -344 35 -104 -69 -52 -17 224 441 751 -110 -318 -597 -334 184 560 550 564 -260 -215 -301 -583 14 557 1296 1058 -46 -637 -1119 -606 -84 601 343 482 376 299 89 120 -231 -180 -119 -270 -419 -437 169 494 872 340 -197 -780 -665 -167 143 465 418 118 -162 -80 -81 101 -97 45 -49 203 411 212 -31 -719 -974 -639 203 222 310 86 14 -61 217 -20 -160 -346 -242 -67 375 771 433 -301 -634 -856 -432 -177 86 -154 126 446 857 522 -260 -1244 -1589 -859 -325 459 772 761 272 -79 21 203 522 527 271 -305 -150 97 477 864 744 208 -145 49 65 252 30 -389 -785 -162 279 673 500 325 -204 -201 -316 -66 -102 7 84 -292 -483 -716 -474 168 409 373 900000 655 -153 -474 -370 -160 -36 -136 -342 35 -101 -67 -50 -16 210 413 708 -106 -316 -578 -326 180 547 539 556 -259 -214 -297 -569 14 541 1245 1031 -44 -634 -1140 -617 -84 598 340 476 374 301 91 123 -241 -187 -124 -276 -422 -429 161 464 817 325 -195 -793 -658 -166 143 462 417 119 -164 -80 -81 99 -99 46 -49 200 403 209 -31 -699 -952 -647 201 218 301 83 13 -61 216 -20 -156 -339 -238 -66 367 757 430 -305 -648 -875 -434 -174 82 -151 121 422 812 507 -251 -1253 -1643 -889 -333 465 780 775 281 -80 21 210 541 550 286 -324 -158 102 490 875 752 212 -149 50 67 260 31 -403 -810 -164 279 669 500 330 -213 -213 -327 -69 -107 7 90 -315 -522 -769 -501 174 417 381 SQ 20250301T140503.6Z 9191.586847 39 1 44.51 2 87.85 100.08 100.52 82.11 0.00 1 0.00 1 0 22 4.839e-03 4.812e-03 1.752e-04 1.749e-04 6.568006e+03 1.161173e+01 4.359924e+02 -6.000000e+00 2.775487e+02 278.89 -2.00 20.00 -2.00 505.36 0.00e+00 1.879590e-03 4.915898e-06 1.088379e-04 -6.000000e+00 1.371830e-04 278.89 -2.00 20.00 -2.00 500.86 0.00e+00 1.056035e+00 3.489782e-03 5.489840e-02 -6.000000e+00 9.852281e-02 225.68 -2.00 3.29 -2.00 502.39 0.00e+00 15.752 0.053 489.00 513.00 1 2.6820e+00 2.6767e-04 2.2347e-02 -6.0000e+00 7.5607e-03 -1.3761e-02 6.7206e-05 1.7111e-03 -6.0000e+00 1.9468e-03 1.5436e-02 2.1871e-03 2.0002e-05 6.6972e-05 -6.0000e+00 5.8182e-04 3.0806e-03 -4.3746e-04 12 9 9 12 1 1 98.02 25.28 1.47 0.00308 0.01825 288 33 1 4 0 154.000 32.75 20.00 25.28 18.09 4.2 909.49 900000 838 150 -283 -188 -38 -31 -270 -387 -128 11 60 37 27 306 521 646 274 -352 -605 -252 100 404 283 191 -108 -246 -581 -615 52 863 1360 959 95 -820 -1012 -550 -79 311 419 471 381 291 85 -123 -288 -356 -305 -378 -362 -297 135 719 935 511 -290 -861 -813 -360 189 490 309 51 -243 -333 -151 80 134 22 -65 251 466 389 -78 -689 -956 -514 167 459 363 104 11 -29 36 -92 -300 -345 -258 47 377 529 350 -206 -717 -777 -424 -166 -5 -175 25 492 959 662 -332 -1239 -1536 -972 -71 678 889 565 79 -184 -44 169 505 492 132 -263 -318 35 473 857 720 188 -83 -112 -51 136 -16 -418 -504 -62 444 787 735 259 -144 -273 -249 -96 -52 -17 -28 -277 -603 -805 -487 175 621 639 900000 750 139 -270 -177 -36 -30 -270 -389 -127 11 59 36 25 288 492 615 267 -353 -594 -249 99 400 282 191 -109 -248 -583 -608 50 841 1313 941 92 -826 -1041 -565 -81 314 419 470 383 295 87 -124 -291 -360 -306 -376 -366 -294 130 680 881 490 -287 -847 -814 -362 190 491 312 52 -248 -340 -152 79 132 22 -65 248 459 385 -78 -675 -942 -501 166 450 354 101 11 -29 35 -89 -294 -340 -255 46 372 523 349 -209 -737 -796 -427 -163 -5 -171 24 464 905 640 -321 -1251 -1531 -972 -70 687 898 555 79 -187 -45 176 525 516 135 -271 -326 36 488 870 730 192 -85 -116 -53 141 -16 -433 -519 -63 444 781 733 263 -149 -279 -259 -100 -55 -18 -30 -290 -631 -868 -516 181 634 651 SQ 20250301T141036.8Z 9191.590704 45 1 19.38 2 86.69 100.83 99.38 82.83 0.00 1 0.00 1 0 22 5.031e-03 5.016e-03 1.262e-04 1.260e-04 5.178438e+03 8.202154e+00 3.432464e+02 -6.000000e+00 2.885665e+02 278.89 -2.00 20.00 -2.00 505.33 0.00e+00 1.545283e-03 3.524595e-06 8.922623e-05 -6.000000e+00 1.426326e-04 278.89 -2.00 20.00 -2.00 500.76 0.00e+00 9.356133e-01 2.516999e-03 4.441919e-02 -6.000000e+00 1.024466e-01 225.68 -2.00 3.29 -2.00 502.30 0.00e+00 12.904 0.029 489.00 513.00 1 1.5929e+00 1.9297e-04 1.7809e-02 -6.0000e+00 7.8616e-03 -8.7211e-03 4.8706e-05 1.3660e-03 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