File name: Pandora253s1_TucsonAZ_20250512_L2Fit_fout2c3d20231207p1-8.txt File generation date: 20250513T073218.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Armin Sorooshian Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 253 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora253_OF_v3d20221208.txt Instrument calibration file used: Pandora253s1_CF_v3d20231207.txt Level 1 file used: Pandora253s1_TucsonAZ_20250512_L1_smca1c3d20231207p1-8.txt Full location name: University of Arizona Department of Chemical and Environmental Engineering Short location name: TucsonAZ Country of location: United States Location latitude [deg]: 32.2330 Location longitude [deg]: -110.9530 Location altitude [m]: 779 Local noon date: 20250512 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 2 "Clearance session based on OOB session1, absolute calibration done with an uncalibrated lamp, certificate of FEL1441 (GSFC) used"" First and last pixel inside fitting window: 192 334 Nominal wavelengths inside fitting window [nm]: 305.0168 305.1576 305.2984 305.4391 305.5798 305.7205 305.8612 306.0019 306.1426 306.2833 306.4240 306.5646 306.7052 306.8459 306.9865 307.1271 307.2677 307.4083 307.5488 307.6894 307.8299 307.9705 308.1110 308.2515 308.3920 308.5325 308.6729 308.8134 308.9539 309.0943 309.2347 309.3751 309.5156 309.6559 309.7963 309.9367 310.0771 310.2174 310.3577 310.4981 310.6384 310.7787 310.9190 311.0593 311.1995 311.3398 311.4800 311.6203 311.7605 311.9007 312.0409 312.1811 312.3212 312.4614 312.6016 312.7417 312.8818 313.0219 313.1620 313.3021 313.4422 313.5823 313.7223 313.8624 314.0024 314.1424 314.2825 314.4225 314.5624 314.7024 314.8424 314.9823 315.1223 315.2622 315.4021 315.5420 315.6819 315.8218 315.9617 316.1016 316.2414 316.3812 316.5211 316.6609 316.8007 316.9405 317.0802 317.2200 317.3598 317.4995 317.6392 317.7790 317.9187 318.0584 318.1981 318.3377 318.4774 318.6170 318.7567 318.8963 319.0359 319.1755 319.3151 319.4547 319.5943 319.7338 319.8734 320.0129 320.1524 320.2919 320.4314 320.5709 320.7104 320.8498 320.9893 321.1287 321.2681 321.4076 321.5470 321.6864 321.8257 321.9651 322.1045 322.2438 322.3831 322.5225 322.6618 322.8011 322.9404 323.0796 323.2189 323.3581 323.4974 323.6366 323.7758 323.9150 324.0542 324.1934 324.3326 324.4717 324.6109 324.7500 324.8891 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250512T131128.7Z 9263.549637 220 1 54.93 2 82.14 73.30 102.90 251.66 0.00 1 0.00 1 0 17 4.542e-01 2.541e-02 4.134e-01 2.169e-02 8.635973e-01 1.343368e-02 9.728340e-03 -6.000000e+00 2.758335e-01 230.43 -2.00 3.29 -2.00 322.00 0.00e+00 8.605899e-03 7.497648e-03 6.386915e-03 -6.000000e+00 1.412538e-02 284.38 -2.00 20.00 -2.00 321.54 0.00e+00 6.827 0.004 302.00 328.00 3 2.6059e+00 5.1347e-02 8.0939e-02 -6.0000e+00 6.9466e-01 9.4808e-01 6.9949e-02 5.4369e-02 -6.0000e+00 7.5666e-01 -1.1148e+00 6.3383e-02 3.1080e-02 -6.0000e+00 4.4321e-01 4.3377e-01 2.9514e-02 1.1308e-02 -6.0000e+00 1.9167e-01 2.6242e-05 -8.0859e-04 6.3200e-04 2.3024e-04 -6.0000e+00 1.3589e-02 -3.0421e-02 0.0000e+00 12 8 8 10 0 0 99.19 25.47 0.48 -0.03042 -0.03650 24 2 1 5 0 2288.440 32.75 20.00 25.47 30.61 4.0 992.78 900000 900000 900000 -85925 900000 -160103 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2861 1377 490 900000 1114 2203 837 -2346 2056 900000 1015 2122 3385 2006 2365 1073 2824 2641 1303 1481 3188 1704 3133 1729 1643 1362 1170 2908 98 -1988 3126 4399 2236 -96 611 -1307 433 2783 4999 2072 4041 3448 4232 -2130 -3886 1335 1037 -679 1987 368 1346 1258 1065 964 -2047 403 -260 1142 393 -609 -718 607 -305 -1266 -995 -95 -2549 1 -5002 -1741 -138 -4487 -2555 -2858 -1224 -2287 -852 -2477 -174 736 -4332 -1412 -1211 2480 3906 1948 872 -1543 3608 3511 5094 -705 2461 402 6606 -2763 -1037 2048 -1656 3301 2458 3635 -3578 -3276 -952 1143 -61 2062 -3457 -2105 SS 20250512T133334.2Z 9263.564980 228 1 38.29 2 77.63 76.03 107.24 254.12 0.00 1 0.00 1 0 25 1.994e-01 7.283e-03 8.871e-02 2.062e-03 6.062207e-01 1.119352e-03 6.501480e-03 -6.000000e+00 1.171394e-01 230.43 -2.00 3.29 -2.00 320.61 0.00e+00 3.550741e-03 4.459631e-04 6.164396e-04 -6.000000e+00 5.119983e-03 284.38 -2.00 20.00 -2.00 320.00 0.00e+00 4.537 0.001 302.00 328.00 3 1.9998e+00 3.4472e-03 5.1676e-02 -6.0000e+00 2.9280e-01 1.1751e-01 4.4982e-03 3.1635e-02 -6.0000e+00 3.1596e-01 -7.8347e-02 4.3811e-03 1.6214e-02 -6.0000e+00 1.8789e-01 1.8239e-02 2.1789e-03 7.3434e-03 -6.0000e+00 8.0915e-02 5.4245e-04 -2.8142e-04 5.8702e-05 6.5424e-05 -6.0000e+00 5.5338e-03 -2.9758e-02 0.0000e+00 12 9 1 12 1 1 99.92 25.46 0.33 -0.02976 -0.03187 96 13 1 5 0 394.670 32.75 20.00 25.46 30.61 4.0 992.88 900000 -101349 -23978 -53242 -48024 -81564 -89820 -46770 -36647 -39625 -98050 -47315 -22972 -34334 -37728 -4638 -27934 -10796 -12003 -17849 -12392 -11283 -2698 -10989 -5555 -18036 -5796 -6871 -2386 -8997 -8516 -1069 743 -1979 -4132 -7897 -4954 -12036 -5896 -5814 -3637 -3370 -2150 522 330 1652 -265 -912 922 954 3914 4298 730 1802 652 2088 1542 -199 -1369 399 44 1844 2169 2017 591 1427 442 1617 2735 1777 729 759 -345 -151 305 -560 530 -81 498 557 -782 -873 -1537 -1384 -467 -788 -441 -630 -363 -175 573 794 57 1888 1214 131 365 476 -153 -599 -594 -414 1003 1482 -402 -1502 -946 -1063 -373 20 -131 -542 -381 -27 321 1097 1232 1056 751 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0.00e+00 2.950408e-03 1.493033e-04 4.883046e-04 -6.000000e+00 3.750201e-03 284.38 -2.00 20.00 -2.00 319.67 0.00e+00 4.246 0.001 302.00 328.00 3 8.7243e-01 1.2393e-03 4.8317e-02 -6.0000e+00 2.1450e-01 8.8093e-02 1.5585e-03 2.9309e-02 -6.0000e+00 2.3144e-01 -5.6967e-02 1.4471e-03 1.4943e-02 -6.0000e+00 1.3763e-01 1.0174e-02 7.3468e-04 6.4900e-03 -6.0000e+00 5.9287e-02 2.2717e-03 1.1672e-04 2.2040e-05 5.6952e-05 -6.0000e+00 4.0524e-03 -3.1709e-02 0.0000e+00 11 8 0 10 0 0 18.75 25.47 0.32 -0.03171 -0.03083 488 46 1 5 0 112.460 32.75 20.00 25.47 30.83 4.0 995.65 900000 -55669 -46713 -38052 -46578 -52173 -54887 -48733 -50420 -36008 -40285 -52704 -28220 -20087 -26057 -15900 -13191 -5376 -8224 -11550 -6897 -4862 -5963 -9452 -12474 -11173 -8006 -10056 -9781 -6144 -5645 -3865 -1900 -2560 -2676 -3578 -4414 -2217 -3711 -1771 -2875 -1042 -1323 -1848 -172 -223 -402 89 780 628 1589 1694 1839 1702 1407 1602 755 -70 -454 -54 835 1574 2173 1577 414 675 1598 1094 2808 1791 174 73 -201 99 -400 -155 262 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