File name: Pandora253s1_TucsonAZ_20250725_L2Fit_fwvt1c3d20231207p1-8.txt
File generation date: 20250726T073727.3Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c3p1-8
Local principal investigator: Armin Sorooshian
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 253
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora253_OF_v3d20221208.txt
Instrument calibration file used: Pandora253s1_CF_v3d20231207.txt
Level 1 file used: Pandora253s1_TucsonAZ_20250725_L1_smca1c3d20231207p1-8.txt
Full location name: University of Arizona Department of Chemical and Environmental Engineering
Short location name: TucsonAZ
Country of location: United States
Location latitude [deg]: 32.2330
Location longitude [deg]: -110.9530
Location altitude [m]: 779
Local noon date: 20250725
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: Modification of session 2 "Clearance session based on OOB session1, absolute calibration done with an uncalibrated lamp, certificate of FEL1441 (GSFC) used""
First and last pixel inside fitting window: 1616 1766
Nominal wavelengths inside fitting window [nm]: 492.0560 492.1767 492.2973 492.4178 492.5384 492.6590 492.7795 492.9000 493.0205 493.1410 493.2614 493.3819 493.5023 493.6227 493.7431 493.8635 493.9839 494.1042 494.2245 494.3448 494.4651 494.5854 494.7057 494.8259 494.9461 495.0664 495.1866 495.3067 495.4269 495.5470 495.6672 495.7873 495.9074 496.0274 496.1475 496.2675 496.3875 496.5076 496.6275 496.7475 496.8675 496.9874 497.1073 497.2272 497.3471 497.4670 497.5868 497.7067 497.8265 497.9463 498.0661 498.1859 498.3056 498.4253 498.5451 498.6648 498.7844 498.9041 499.0238 499.1434 499.2630 499.3826 499.5022 499.6218 499.7413 499.8608 499.9803 500.0998 500.2193 500.3388 500.4582 500.5777 500.6971 500.8165 500.9358 501.0552 501.1745 501.2939 501.4132 501.5325 501.6517 501.7710 501.8902 502.0095 502.1287 502.2478 502.3670 502.4862 502.6053 502.7244 502.8435 502.9626 503.0817 503.2007 503.3198 503.4388 503.5578 503.6768 503.7957 503.9147 504.0336 504.1525 504.2714 504.3903 504.5092 504.6280 504.7469 504.8657 504.9845 505.1032 505.2220 505.3407 505.4595 505.5782 505.6969 505.8155 505.9342 506.0528 506.1715 506.2901 506.4087 506.5272 506.6458 506.7643 506.8828 507.0013 507.1198 507.2383 507.3567 507.4752 507.5936 507.7120 507.8304 507.9487 508.0671 508.1854 508.3037 508.4220 508.5403 508.6586 508.7768 508.8950 509.0132 509.1314 509.2496 509.3678 509.4859 509.6040 509.7221 509.8402 509.9583
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Temperature at electronics board [°C], 999=no temperature signal
Column 96: Spectrometer control temperature [°C], 999=no temperature signal
Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 98: Temperature in head sensor [°C], 999=no temperature signal
Column 99: Humidity in head sensor [%], -9=no humidity signal
Column 100: Pressure in head sensor [hPa], -9=no pressure signal
Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20250725T124353.0Z 9337.530474 33 1 15.37 2 89.00 67.42 97.52 61.16 0.00 1 0.00 1 0 22 4.026e-03 4.022e-03 4.148e-04 4.135e-04 1.929666e+04 3.219074e+01 1.216446e+03 -6.000000e+00 2.406524e+02 289.60 -2.00 20.00 -2.00 505.42 0.00e+00 4.286634e-03 1.197393e-05 2.505239e-04 -6.000000e+00 1.170850e-04 289.60 -2.00 20.00 -2.00 500.93 0.00e+00 9.369760e-01 8.187431e-03 1.220338e-01 -6.000000e+00 8.160241e-02 230.38 -2.00 3.29 -2.00 502.45 0.00e+00 18.585 0.086 489.00 513.00 1 2.8887e+00 6.2969e-04 2.9390e-02 -6.0000e+00 6.2918e-03 -3.4056e-02 1.5495e-04 3.2417e-03 -6.0000e+00 1.6042e-03 8.2217e-03 1.8322e-03 4.3174e-05 1.4357e-04 -6.0000e+00 4.8311e-04 5.6332e-03 -3.4177e-04 12 9 1 12 1 1 55.57 25.58 2.85 0.00563 0.01834 61 21 1 4 0 247.820 33.00 20.00 25.58 30.16 4.3 987.50 465 236 -33 -87 44 373 379 212 165 215 299 178 -85 -76 40 159 357 86 -220 -342 3 273 516 391 385 21 -87 -557 -556 -125 408 774 460 -158 -646 -786 -427 -53 174 246 211 213 255 145 17 -49 -81 -187 -353 -449 -623 -328 200 370 152 -433 -617 -529 -154 300 579 433 191 9 -105 -24 94 9 -200 -213 -23 205 146 -277 -600 -862 -493 -69 53 -75 -110 -5 -106 -125 -243 -384 -567 -481 -25 505 655 475 -225 -567 -474 39 372 203 -304 -549 -311 184 33 -521 -1271 -1440 -964 -146 461 595 299 -53 -176 257 668 1018 1042 611 -38 -272 -78 369 808 868 469 177 88 70 53 -120 -353 -447 10 278 309 243 -133 -95 32 162 181 -54 -81 127 48 -58 -294 -288 40 48 102 421 216 -30 -82 41 352 365 207 162 209 288 169 -80 -71 37 148 335 83 -216 -330 3 266 503 384 381 21 -87 -553 -544 -119 396 746 434 -154 -650 -777 -422 -52 175 247 212 208 253 146 17 -50 -83 -192 -358 -448 -610 -325 195 361 151 -429 -628 -548 -155 302 583 439 195 10 -107 -24 94 9 -203 -214 -23 204 145 -280 -614 -855 -500 -69 52 -74 -107 -5 -104 -124 -244 -389 -559 -473 -25 506 656 463 -223 -563 -464 38 352 194 -283 -504 -284 169 31 -499 -1236 -1449 -981 -148 465 600 305 -53 -179 262 683 1044 1081 645 -39 -283 -83 384 826 880 479 182 91 73 56 -126 -369 -464 10 282 314 249 -139 -98 34 173 196 -58 -87 137 52 -63 -316 -305 43 51 109
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SQ 20250725T125007.4Z 9337.534808 41 1 54.83 2 87.78 68.23 96.41 62.04 0.00 1 0.00 1 0 22 4.104e-03 4.086e-03 1.029e-04 1.027e-04 1.479837e+04 7.754276e+00 9.450488e+02 -6.000000e+00 2.453740e+02 289.60 -2.00 20.00 -2.00 505.36 0.00e+00 3.264721e-03 2.962307e-06 1.918806e-04 -6.000000e+00 1.193940e-04 289.60 -2.00 20.00 -2.00 500.77 0.00e+00 9.681677e-01 2.046040e-03 9.490010e-02 -6.000000e+00 8.322514e-02 230.38 -2.00 3.29 -2.00 502.31 0.00e+00 15.434 0.049 489.00 513.00 1 1.7777e+00 1.5743e-04 2.3160e-02 -6.0000e+00 6.4166e-03 -1.9598e-02 3.9016e-05 2.5158e-03 -6.0000e+00 1.6367e-03 3.8360e-02 2.2101e-03 1.1086e-05 1.1059e-04 -6.0000e+00 4.9243e-04 2.3719e-03 -3.4946e-04 11 8 0 10 0 0 32.32 25.59 1.78 0.00237 0.01770 906 85 1 4 0 60.510 33.00 19.99 25.59 30.31 4.2 988.11 827 592 49 -153 -77 82 123 -96 -177 11 34 75 -3 -7 221 427 429 100 -285 -432 -102 165 413 265 208 -55 -231 -555 -547 -1 707 993 653 -101 -737 -859 -484 -78 239 316 319 291 211 64 -89 -212 -264 -287 -372 -407 -341 24 485 648 262 -334 -713 -580 -189 231 475 315 92 -157 -240 -108 83 74 -68 -133 115 338 222 -205 -628 -805 -441 38 227 135 -10 42 -22 -22 -147 -358 -445 -317 74 497 630 315 -260 -692 -630 -159 161 146 -213 -258 113 572 327 -469 -1187 -1399 -917 -46 608 751 384 -20 -192 104 453 772 719 282 -207 -413 -74 414 854 787 301 -2 -47 -31 6 -155 -448 -414 47 434 508 415 87 -139 -81 -21 21 -54 -72 -7 -142 -279 -460 -265 187 433 409 766 554 45 -145 -75 79 120 -96 -176 11 33 73 -3 -7 217 401 408 97 -284 -438 -104 169 407 263 207 -55 -232 -553 -536 -1 686 958 640 -98 -740 -877 -494 -79 240 315 318 292 215 66 -93 -215 -268 -301 -385 -413 -338 23 480 642 255 -335 -735 -585 -191 234 481 321 95 -162 -246 -110 83 76 -69 -134 115 335 222 -208 -618 -796 -447 38 223 132 -10 41 -22 -22 -147 -349 -437 -310 73 501 636 309 -258 -692 -622 -159 156 137 -195 -243 105 535 302 -455 -1158 -1407 -930 -46 606 748 387 -21 -192 105 458 783 736 293 -217 -434 -77 421 853 782 300 -2 -47 -32 7 -158 -456 -418 47 427 517 410 88 -143 -85 -22 22 -56 -77 -8 -152 -298 -489 -277 192 440 416
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