File name: Pandora253s1_TucsonAZ_20250727_L2Fit_fwvt1c3d20231207p1-8.txt
File generation date: 20250728T073701.0Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c3p1-8
Local principal investigator: Armin Sorooshian
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 253
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora253_OF_v3d20221208.txt
Instrument calibration file used: Pandora253s1_CF_v3d20231207.txt
Level 1 file used: Pandora253s1_TucsonAZ_20250727_L1_smca1c3d20231207p1-8.txt
Full location name: University of Arizona Department of Chemical and Environmental Engineering
Short location name: TucsonAZ
Country of location: United States
Location latitude [deg]: 32.2330
Location longitude [deg]: -110.9530
Location altitude [m]: 779
Local noon date: 20250727
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: Modification of session 2 "Clearance session based on OOB session1, absolute calibration done with an uncalibrated lamp, certificate of FEL1441 (GSFC) used""
First and last pixel inside fitting window: 1616 1766
Nominal wavelengths inside fitting window [nm]: 492.0560 492.1767 492.2973 492.4178 492.5384 492.6590 492.7795 492.9000 493.0205 493.1410 493.2614 493.3819 493.5023 493.6227 493.7431 493.8635 493.9839 494.1042 494.2245 494.3448 494.4651 494.5854 494.7057 494.8259 494.9461 495.0664 495.1866 495.3067 495.4269 495.5470 495.6672 495.7873 495.9074 496.0274 496.1475 496.2675 496.3875 496.5076 496.6275 496.7475 496.8675 496.9874 497.1073 497.2272 497.3471 497.4670 497.5868 497.7067 497.8265 497.9463 498.0661 498.1859 498.3056 498.4253 498.5451 498.6648 498.7844 498.9041 499.0238 499.1434 499.2630 499.3826 499.5022 499.6218 499.7413 499.8608 499.9803 500.0998 500.2193 500.3388 500.4582 500.5777 500.6971 500.8165 500.9358 501.0552 501.1745 501.2939 501.4132 501.5325 501.6517 501.7710 501.8902 502.0095 502.1287 502.2478 502.3670 502.4862 502.6053 502.7244 502.8435 502.9626 503.0817 503.2007 503.3198 503.4388 503.5578 503.6768 503.7957 503.9147 504.0336 504.1525 504.2714 504.3903 504.5092 504.6280 504.7469 504.8657 504.9845 505.1032 505.2220 505.3407 505.4595 505.5782 505.6969 505.8155 505.9342 506.0528 506.1715 506.2901 506.4087 506.5272 506.6458 506.7643 506.8828 507.0013 507.1198 507.2383 507.3567 507.4752 507.5936 507.7120 507.8304 507.9487 508.0671 508.1854 508.3037 508.4220 508.5403 508.6586 508.7768 508.8950 509.0132 509.1314 509.2496 509.3678 509.4859 509.6040 509.7221 509.8402 509.9583
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Temperature at electronics board [°C], 999=no temperature signal
Column 96: Spectrometer control temperature [°C], 999=no temperature signal
Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 98: Temperature in head sensor [°C], 999=no temperature signal
Column 99: Humidity in head sensor [%], -9=no humidity signal
Column 100: Pressure in head sensor [hPa], -9=no pressure signal
Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20250727T124519.0Z 9339.531470 33 1 32.85 2 88.97 67.98 120.93 54.20 0.00 1 0.00 1 0 22 4.171e-03 4.169e-03 2.857e-04 2.847e-04 2.228328e+04 2.279530e+01 1.396850e+03 -6.000000e+00 2.493613e+02 289.62 -2.00 20.00 -2.00 505.41 0.00e+00 6.886577e-03 8.277131e-06 3.913508e-04 -6.000000e+00 1.213220e-04 289.62 -2.00 20.00 -2.00 500.92 0.00e+00 8.455491e-01 5.671206e-03 1.418845e-01 -6.000000e+00 8.454382e-02 230.33 -2.00 3.29 -2.00 502.43 0.00e+00 18.508 0.085 489.00 513.00 1 2.8323e+00 4.3644e-04 3.0728e-02 -6.0000e+00 6.5187e-03 -3.4377e-02 1.0701e-04 3.5845e-03 -6.0000e+00 1.6621e-03 8.4818e-03 2.0303e-03 2.9315e-05 1.9640e-04 -6.0000e+00 5.0049e-04 -3.6610e-04 -3.0877e-04 12 9 1 12 1 1 74.64 25.66 2.96 -0.00037 0.01372 141 22 1 4 0 231.280 33.00 19.99 25.66 31.31 4.2 995.10 467 298 -35 -102 170 400 512 282 187 308 266 164 -60 -191 25 157 198 51 -240 -302 73 299 600 459 356 117 -84 -490 -637 -203 346 624 334 -218 -685 -793 -423 -97 208 278 225 238 210 147 53 -23 -130 -198 -317 -463 -589 -305 81 274 6 -371 -611 -420 -35 371 594 530 231 -43 -72 -18 85 -22 -151 -258 -144 87 11 -247 -623 -801 -470 -59 -13 -49 -153 -10 -27 39 -254 -540 -627 -496 0 536 806 502 -140 -599 -441 158 530 364 -433 -708 -470 31 -63 -654 -1242 -1414 -885 -79 530 626 287 -162 -248 223 699 1150 1111 628 -70 -470 -222 269 795 915 513 274 184 81 49 -143 -439 -497 11 290 202 101 -116 -142 130 219 151 -33 -62 68 51 30 -195 -253 -8 117 112 410 264 -32 -96 158 380 496 277 183 301 257 156 -56 -178 23 146 186 49 -235 -287 70 287 576 444 348 115 -83 -482 -617 -192 334 599 313 -210 -682 -804 -429 -98 208 277 225 240 206 147 54 -24 -133 -203 -321 -462 -577 -304 80 270 6 -370 -626 -437 -37 389 624 538 237 -45 -74 -19 89 -23 -155 -261 -145 87 11 -251 -641 -825 -479 -59 -13 -48 -148 -10 -26 38 -253 -544 -634 -500 0 529 794 499 -141 -607 -440 152 511 341 -397 -640 -421 28 -58 -611 -1219 -1380 -874 -77 520 616 287 -165 -256 231 725 1197 1171 648 -74 -496 -232 275 828 945 533 277 187 83 51 -147 -452 -508 11 301 210 102 -119 -149 138 236 160 -35 -67 73 55 32 -209 -268 -9 121 117
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SQ 20250727T125143.8Z 9339.535924 41 1 54.82 2 87.71 68.82 119.88 55.49 0.00 1 0.00 1 0 22 4.099e-03 4.081e-03 1.104e-04 1.101e-04 1.730104e+04 8.511554e+00 1.100367e+03 -6.000000e+00 2.450881e+02 289.62 -2.00 20.00 -2.00 505.37 0.00e+00 4.646147e-03 3.189909e-06 2.681950e-04 -6.000000e+00 1.192549e-04 289.62 -2.00 20.00 -2.00 500.77 0.00e+00 8.964248e-01 2.199970e-03 1.098574e-01 -6.000000e+00 8.311882e-02 230.33 -2.00 3.29 -2.00 502.32 0.00e+00 15.250 0.048 489.00 513.00 1 1.9240e+00 1.6940e-04 2.3778e-02 -6.0000e+00 6.4084e-03 -2.1586e-02 4.1785e-05 2.8053e-03 -6.0000e+00 1.6347e-03 3.3320e-02 2.3215e-03 1.1717e-05 1.4571e-04 -6.0000e+00 4.9182e-04 5.4445e-03 -3.7212e-04 11 8 0 10 0 0 40.61 25.66 1.83 0.00544 0.02155 806 76 1 4 0 68.010 33.00 20.00 25.66 31.49 4.2 995.72 849 565 79 -110 -26 146 197 -91 -141 32 80 71 4 -9 199 390 416 89 -299 -453 -111 186 410 297 199 -81 -244 -576 -537 -19 639 939 600 -105 -750 -861 -465 -45 266 328 307 269 217 61 -90 -186 -244 -264 -356 -410 -370 -5 455 585 239 -352 -703 -572 -180 244 503 341 92 -166 -229 -81 82 29 -94 -146 92 321 224 -208 -613 -776 -422 55 212 122 -4 63 1 32 -143 -382 -468 -375 113 573 691 383 -264 -700 -627 -92 232 170 -216 -330 10 501 266 -482 -1207 -1429 -881 -28 609 744 374 -72 -242 80 481 791 767 333 -230 -486 -159 367 817 809 357 46 10 -23 18 -200 -487 -430 69 411 468 338 54 -126 -44 13 44 -77 -106 -14 -147 -237 -390 -233 185 414 372 778 524 72 -104 -26 145 192 -90 -140 32 77 68 4 -9 193 376 406 85 -293 -452 -112 187 413 301 203 -83 -240 -589 -540 -18 611 892 580 -104 -742 -866 -468 -45 263 322 303 267 218 62 -94 -194 -255 -275 -365 -414 -365 -5 449 578 232 -352 -722 -598 -181 246 508 347 94 -171 -235 -82 82 29 -95 -146 91 318 224 -210 -626 -794 -427 55 208 118 -4 61 1 31 -142 -384 -473 -378 113 568 686 384 -259 -688 -632 -90 219 163 -201 -303 9 457 250 -456 -1197 -1406 -875 -28 597 729 371 -72 -248 82 497 820 774 341 -239 -505 -163 369 837 823 365 48 10 -23 18 -202 -491 -429 70 415 472 345 54 -129 -46 14 47 -80 -112 -15 -155 -250 -409 -241 195 431 388
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