File name: Pandora259s1_TylerTX_20231112_L2Fit_fout2c3d20230310p1-8.txt File generation date: 20250305T234527.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: James Flynn Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 259 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora259_OF_v3d20221229.txt Instrument calibration file used: Pandora259s1_CF_v3d20230310.txt Level 1 file used: Pandora259s1_TylerTX_20231112_L1_smca1c3d20230310p1-8.txt Full location name: Tyler Pounds Regional Airport Short location name: TylerTX Country of location: United States Location latitude [deg]: 32.3440 Location longitude [deg]: -95.4159 Location altitude [m]: 164 Local noon date: 20231112 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 195 337 Nominal wavelengths inside fitting window [nm]: 305.0446 305.1851 305.3256 305.4661 305.6066 305.7470 305.8875 306.0279 306.1684 306.3088 306.4492 306.5896 306.7300 306.8704 307.0108 307.1511 307.2915 307.4318 307.5721 307.7125 307.8528 307.9930 308.1333 308.2736 308.4139 308.5541 308.6943 308.8346 308.9748 309.1150 309.2552 309.3954 309.5355 309.6757 309.8158 309.9560 310.0961 310.2362 310.3763 310.5164 310.6565 310.7966 310.9366 311.0767 311.2167 311.3567 311.4967 311.6367 311.7767 311.9167 312.0567 312.1966 312.3366 312.4765 312.6164 312.7563 312.8962 313.0361 313.1760 313.3159 313.4557 313.5955 313.7354 313.8752 314.0150 314.1548 314.2946 314.4344 314.5741 314.7139 314.8536 314.9934 315.1331 315.2728 315.4125 315.5522 315.6918 315.8315 315.9711 316.1108 316.2504 316.3900 316.5296 316.6692 316.8088 316.9484 317.0879 317.2275 317.3670 317.5065 317.6460 317.7855 317.9250 318.0645 318.2040 318.3434 318.4829 318.6223 318.7617 318.9011 319.0405 319.1799 319.3193 319.4587 319.5980 319.7373 319.8767 320.0160 320.1553 320.2946 320.4339 320.5731 320.7124 320.8516 320.9909 321.1301 321.2693 321.4085 321.5477 321.6869 321.8261 321.9652 322.1044 322.2435 322.3826 322.5217 322.6608 322.7999 322.9390 323.0780 323.2171 323.3561 323.4952 323.6342 323.7732 323.9122 324.0512 324.1901 324.3291 324.4680 324.6070 324.7459 324.8848 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20231112T163016.9Z 8716.687695 217 1 12.54 2 55.07 151.94 51.88 161.47 0.00 1 0.00 1 0 25 1.228e-02 9.221e-03 1.359e-03 8.914e-04 2.166856e-01 4.811290e-04 2.529622e-03 -6.000000e+00 7.517556e-03 224.89 -2.00 3.31 -2.00 315.14 0.00e+00 -6.284950e-05 4.541873e-05 4.233010e-05 -6.000000e+00 3.498522e-04 286.27 -2.00 20.00 -2.00 314.49 0.00e+00 1.741 0.000 302.00 328.00 3 3.1225e+00 1.2252e-03 1.9955e-02 -6.0000e+00 1.8511e-02 1.6261e-02 1.3605e-03 1.0416e-02 -6.0000e+00 2.0022e-02 -1.4348e-03 7.7951e-04 5.1542e-03 -6.0000e+00 1.1987e-02 -9.9788e-04 3.4423e-04 1.4660e-03 -6.0000e+00 5.0897e-03 3.3184e-03 1.7917e-04 2.9086e-05 2.3185e-05 -6.0000e+00 4.0681e-04 -2.3140e-03 0.0000e+00 12 9 1 12 1 1 99.67 27.67 0.38 -0.00231 -0.00097 43 115 1 5 0 261.890 36.25 20.00 27.67 20.94 3.1 964.47 -1961 -3740 -4197 -4514 509 1452 639 819 329 -926 -70 1861 1204 633 -102 -949 -565 520 78 803 650 1442 1780 734 453 144 -1409 -1068 2188 3149 2211 1365 650 -1832 -733 2025 1356 812 991 -1513 -2399 -1357 -1111 -1228 -987 -802 -874 -553 231 1057 1207 733 735 585 36 443 586 417 835 1517 1567 1676 804 -618 -1243 -700 853 1048 2253 1187 -675 -1070 -1193 -768 -573 12 856 1305 1611 740 -886 -1629 -1974 -1560 -862 -1024 -950 -580 -910 -993 0 619 866 1937 2183 1264 729 78 -1016 -926 -432 -454 451 1263 14 -1217 -596 -585 -330 2 -120 -455 -382 31 267 1069 1326 914 522 -209 -627 -416 -83 -196 439 928 751 1546 1337 391 233 -111 -50 219 273 -146 -441 43 -488 -584 -342 -369 -375 -580 -1210 -1380 -1433 145 418 189 246 108 -323 -23 624 437 242 -44 -419 -261 247 36 382 315 701 872 376 232 76 -748 -544 1083 1497 1075 706 339 -1000 -390 1041 742 485 631 -1082 -1829 -1044 -880 -984 -790 -636 -682 -419 177 800 938 580 592 493 30 381 510 364 720 1296 1368 1487 742 -588 -1198 -662 767 938 1985 1113 -680 -1105 -1251 -784 -569 11 774 1144 1418 661 -862 -1645 -2089 -1691 -986 -1182 -1129 -712 -1130 -1206 0 699 922 1999 2281 1388 834 96 -1270 -1171 -536 -542 520 1446 17 -1518 -757 -757 -446 3 -169 -644 -542 42 346 1350 1667 1147 676 -283 -866 -578 -113 -265 576 1184 942 1884 1684 511 313 -151 -68 304 388 -214 -656 65 -739 -897 -510 -545 -540 SU 20231112T164939.9Z 8716.701156 230 1 29.11 2 53.31 157.20 50.86 167.14 0.00 1 0.00 1 0 25 1.744e-02 1.065e-02 5.756e-03 3.074e-03 2.085546e-01 1.643615e-03 2.425790e-03 -6.000000e+00 1.067496e-02 224.89 -2.00 3.31 -2.00 315.84 0.00e+00 2.697680e-04 1.805944e-04 3.665818e-05 -6.000000e+00 4.967753e-04 286.27 -2.00 20.00 -2.00 315.14 0.00e+00 1.669 0.000 302.00 328.00 3 5.9411e+00 4.2198e-03 1.9167e-02 -6.0000e+00 2.6285e-02 2.4050e-02 4.7050e-03 1.0069e-02 -6.0000e+00 2.8431e-02 6.5398e-03 2.7026e-03 4.9781e-03 -6.0000e+00 1.7021e-02 -7.8396e-03 1.2310e-03 1.4390e-03 -6.0000e+00 7.2276e-03 2.1394e-04 3.1971e-04 1.0023e-04 2.1358e-05 -6.0000e+00 5.7764e-04 -2.6029e-03 0.0000e+00 12 9 9 12 33 1 97.96 27.75 0.75 -0.00260 -0.00020 5 8 1 5 0 3631.270 36.25 20.00 27.75 21.66 3.1 969.25 -7214 -2351 -4949 -2681 -146 -635 131 -1665 -1233 1400 4598 466 557 -1056 -5951 690 4616 -766 -252 6252 889 3594 -329 1044 301 654 -1454 -3601 1433 1193 5208 2723 -252 -2681 -748 1647 -94 85 2255 -705 -1113 -1532 -845 -893 -1804 -1248 -1025 -1246 292 352 203 620 602 656 614 757 -450 2460 502 2948 1331 1263 525 -86 -1554 66 1071 1527 2016 576 -329 -618 -1309 -936 -688 242 -317 429 1821 2844 -1195 -1672 -2074 -1923 -235 -662 -815 -121 -891 -1125 1264 996 213 2004 2575 495 616 295 -1236 -1427 -923 -57 426 104 4 -1838 -573 -739 133 339 714 -659 -319 248 309 694 935 1280 289 -489 -921 238 -307 -646 726 1047 1032 1391 1214 517 538 -549 23 -242 682 -340 -127 562 -836 -328 -271 -632 -472 -1620 -540 -1180 -601 -30 -125 26 -368 -295 341 1104 121 155 -332 -2185 256 1732 -288 -97 2321 355 1410 -135 438 133 296 -666 -1621 585 474 2195 1137 -114 -1267 -342 730 -45 46 1288 -474 -766 -1124 -634 -678 -1385 -946 -761 -904 204 244 145 465 476 541 488 614 -375 1990 411 2349 1102 1103 493 -80 -1471 63 937 1279 1732 546 -322 -638 -1379 -960 -665 227 -271 366 1544 2404 -1165 -1686 -2259 -2086 -266 -802 -989 -152 -1133 -1399 1533 1113 234 2050 2655 559 718 356 -1615 -1887 -1166 -71 499 123 5 -2341 -757 -970 182 484 1010 -963 -455 348 424 885 1154 1609 388 -667 -1315 338 -431 -881 982 1342 1262 1758 1497 679 742 -751 32 -347 1012 -509 -197 889 -1294 -526 -423 -959 -697 SU 20231112T170822.4Z 8716.714148 242 1 30.34 2 51.95 162.54 50.25 172.75 0.00 1 0.00 1 0 25 1.556e-02 9.556e-03 3.236e-03 1.923e-03 2.024875e-01 1.030809e-03 2.349898e-03 -6.000000e+00 9.527244e-03 224.88 -2.00 3.31 -2.00 315.49 0.00e+00 -2.221236e-04 1.046739e-04 2.771638e-05 -6.000000e+00 4.433494e-04 286.27 -2.00 20.00 -2.00 314.82 0.00e+00 1.619 0.000 302.00 328.00 3 5.6357e+00 2.6373e-03 1.8577e-02 -6.0000e+00 2.3459e-02 2.4392e-02 2.9361e-03 9.7310e-03 -6.0000e+00 2.5374e-02 2.7818e-03 1.6818e-03 4.8130e-03 -6.0000e+00 1.5191e-02 -4.1181e-03 7.5301e-04 1.3697e-03 -6.0000e+00 6.4508e-03 3.0920e-04 2.7472e-04 6.2817e-05 2.1111e-05 -6.0000e+00 5.1550e-04 -2.9246e-03 0.0000e+00 12 9 8 11 32 0 99.96 27.84 0.47 -0.00292 -0.00086 13 13 1 5 0 2333.180 36.50 20.00 27.84 22.69 3.1 976.99 -5147 -3554 -5438 -3611 6120 -2106 -434 -1320 155 2162 2845 -456 594 -55 -3040 3 -580 4742 284 3401 1370 519 174 1291 -692 20 -1120 -2778 43 2919 3622 2362 385 -2388 -994 1535 1899 223 1607 -1009 -1591 -689 -338 -1101 -1462 -1542 -1345 -1087 118 1027 112 377 957 796 831 684 88 1356 679 1557 1325 1322 927 -331 -1711 -294 1221 1240 1776 736 -340 -862 -1203 -1037 -644 -81 -565 1652 1893 217 -1415 -1493 -2442 -1524 -589 -470 -442 182 -690 -754 817 953 75 1875 2410 935 936 7 -933 -910 -843 -468 498 684 -34 -1633 -560 -350 31 -43 605 -400 -514 108 336 730 864 1343 73 -149 -1024 -70 -252 -244 542 934 918 1225 972 45 455 -290 -205 -27 491 -266 -128 78 -585 -382 -324 -315 -199 -1353 -984 -1549 -970 1402 -499 -103 -344 43 620 825 -141 194 -18 -1161 1 -244 1955 126 1502 581 224 76 577 -331 10 -546 -1323 20 1310 1627 1129 182 -1182 -478 714 929 126 974 -669 -1167 -531 -267 -831 -1107 -1235 -1055 -827 87 743 84 296 739 642 691 583 76 1164 582 1319 1150 1208 852 -323 -1700 -274 1111 1083 1589 682 -346 -879 -1248 -1049 -650 -74 -504 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