File name: Pandora259s1_TylerTX_20241102_L2Fit_fout2c3d20230310p1-8.txt File generation date: 20241210T190032.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: James Flynn Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 259 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora259_OF_v3d20221229.txt Instrument calibration file used: Pandora259s1_CF_v3d20230310.txt Level 1 file used: Pandora259s1_TylerTX_20241102_L1_smca1c3d20230310p1-8.txt Full location name: Tyler Pounds Regional Airport Short location name: TylerTX Country of location: United States Location latitude [deg]: 32.3440 Location longitude [deg]: -95.4159 Location altitude [m]: 164 Local noon date: 20241102 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 195 337 Nominal wavelengths inside fitting window [nm]: 305.0446 305.1851 305.3256 305.4661 305.6066 305.7470 305.8875 306.0279 306.1684 306.3088 306.4492 306.5896 306.7300 306.8704 307.0108 307.1511 307.2915 307.4318 307.5721 307.7125 307.8528 307.9930 308.1333 308.2736 308.4139 308.5541 308.6943 308.8346 308.9748 309.1150 309.2552 309.3954 309.5355 309.6757 309.8158 309.9560 310.0961 310.2362 310.3763 310.5164 310.6565 310.7966 310.9366 311.0767 311.2167 311.3567 311.4967 311.6367 311.7767 311.9167 312.0567 312.1966 312.3366 312.4765 312.6164 312.7563 312.8962 313.0361 313.1760 313.3159 313.4557 313.5955 313.7354 313.8752 314.0150 314.1548 314.2946 314.4344 314.5741 314.7139 314.8536 314.9934 315.1331 315.2728 315.4125 315.5522 315.6918 315.8315 315.9711 316.1108 316.2504 316.3900 316.5296 316.6692 316.8088 316.9484 317.0879 317.2275 317.3670 317.5065 317.6460 317.7855 317.9250 318.0645 318.2040 318.3434 318.4829 318.6223 318.7617 318.9011 319.0405 319.1799 319.3193 319.4587 319.5980 319.7373 319.8767 320.0160 320.1553 320.2946 320.4339 320.5731 320.7124 320.8516 320.9909 321.1301 321.2693 321.4085 321.5477 321.6869 321.8261 321.9652 322.1044 322.2435 322.3826 322.5217 322.6608 322.7999 322.9390 323.0780 323.2171 323.3561 323.4952 323.6342 323.7732 323.9122 324.0512 324.1901 324.3291 324.4680 324.6070 324.7459 324.8848 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241102T151958.7Z 9072.638874 124 1 54.43 2 61.70 133.60 74.95 130.14 0.00 1 0.00 1 0 25 1.438e-02 8.405e-03 2.406e-03 1.095e-03 2.425383e-01 5.849124e-04 2.789227e-03 -6.000000e+00 8.818013e-03 225.51 -2.00 3.31 -2.00 316.34 0.00e+00 -3.764483e-05 7.167794e-05 4.465204e-05 -6.000000e+00 4.111171e-04 287.18 -2.00 20.00 -2.00 315.59 0.00e+00 2.099 0.000 302.00 328.00 3 4.5427e+00 1.5134e-03 2.3605e-02 -6.0000e+00 2.1737e-02 2.6506e-02 1.6902e-03 1.1725e-02 -6.0000e+00 2.3503e-02 -1.8901e-03 9.7779e-04 5.7654e-03 -6.0000e+00 1.4071e-02 -2.8754e-03 4.5531e-04 1.6295e-03 -6.0000e+00 5.9689e-03 5.4388e-04 6.3037e-05 3.5949e-05 2.3825e-05 -6.0000e+00 4.7655e-04 1.8764e-03 0.0000e+00 11 8 0 10 0 0 99.99 29.29 0.60 0.00188 0.00235 170 17 1 5 0 320.110 37.50 20.01 29.29 28.15 3.4 1006.09 -5332 -3010 -5048 -6283 3472 -1813 -997 -2623 -635 -888 1799 -673 2177 46 -2125 -142 350 1529 -356 2924 988 1724 996 -190 -188 -5 -1797 -2611 1779 2347 3116 1951 483 -1882 -1303 1087 1140 -305 1291 -1039 -1737 -979 -162 -863 -939 -1147 -1953 -580 736 894 682 431 821 778 443 685 494 622 777 2045 1805 1753 1075 -351 -1090 -505 795 1299 1700 1228 -394 -812 -1079 -951 -494 90 408 1012 1187 957 -1003 -1511 -2089 -1480 -618 -763 -695 -355 -734 -823 268 1088 524 1505 2225 831 571 -208 -1042 -989 -754 -506 250 868 -49 -1365 -516 -580 -150 126 13 -286 -441 128 322 1242 1022 938 455 -268 -483 -206 -162 -258 517 1068 487 1360 1222 298 148 -222 125 79 227 -295 -90 117 -361 -617 -181 -482 -257 -887 -528 -917 -1116 581 -307 -172 -502 -118 -174 352 -141 480 12 -615 -44 114 511 -125 1029 332 582 343 -69 -72 -2 -711 -1005 684 877 1179 728 194 -791 -539 437 486 -151 681 -642 -1106 -658 -111 -606 -661 -805 -1360 -390 480 583 461 309 622 576 340 538 395 498 616 1597 1447 1484 919 -321 -1011 -446 693 1091 1475 1097 -390 -800 -1079 -927 -480 80 351 816 967 848 -946 -1485 -2226 -1571 -691 -911 -832 -439 -919 -1006 322 1197 565 1533 2299 939 674 -257 -1384 -1261 -969 -606 297 1027 -59 -1759 -693 -776 -210 176 20 -433 -657 180 437 1647 1322 1242 608 -384 -686 -293 -237 -366 695 1428 626 1704 1588 394 208 -323 178 116 348 -456 -144 192 -601 -1020 -289 -747 -406 SS 20241102T180300.5Z 9072.752090 223 1 12.48 2 47.42 179.27 57.09 165.46 0.00 1 0.00 1 0 25 1.144e-02 9.038e-03 1.165e-03 8.739e-04 1.714807e-01 4.756068e-04 2.014881e-03 -6.000000e+00 7.018901e-03 225.50 -2.00 3.31 -2.00 314.44 0.00e+00 1.279719e-06 3.954013e-05 2.761151e-05 -6.000000e+00 3.272029e-04 287.17 -2.00 20.00 -2.00 313.86 0.00e+00 1.475 0.000 302.00 328.00 3 3.4954e+00 1.2049e-03 1.6624e-02 -6.0000e+00 1.7302e-02 1.9353e-02 1.3321e-03 8.2977e-03 -6.0000e+00 1.8707e-02 1.9324e-03 7.6574e-04 4.0933e-03 -6.0000e+00 1.1200e-02 -2.7805e-03 3.3168e-04 1.1613e-03 -6.0000e+00 4.7515e-03 3.2203e-03 8.2504e-05 2.8597e-05 1.9223e-05 -6.0000e+00 3.7928e-04 1.1070e-03 0.0000e+00 12 9 1 12 1 1 99.97 29.22 0.43 0.00111 0.00173 45 21 1 5 0 271.210 37.50 20.01 29.22 30.00 3.3 1020.07 -1848 -3034 -3985 -3457 558 1832 1225 1409 344 -768 -129 1825 1280 475 167 -1102 -465 497 425 881 728 1233 1557 223 494 598 -1573 -1286 1650 2868 1801 1421 1067 -1673 -1170 1789 1087 592 832 -1384 -2301 -1447 -998 -1243 -947 -927 -1277 -567 389 896 1279 545 817 738 95 532 552 457 589 1623 1615 1511 685 -397 -1350 -684 810 982 1955 1244 -707 -944 -1043 -717 -542 -154 479 972 1227 609 -999 -1487 -2075 -1492 -756 -952 -753 -491 -866 -814 40 635 766 1767 2097 1138 577 92 -821 -833 -358 -380 298 1234 209 -1268 -642 -576 -386 219 -166 -309 -380 33 149 1138 1363 887 346 -103 -613 -249 -138 -100 489 969 752 1422 1258 324 339 -240 -104 79 255 -202 -357 70 -485 -683 -311 -264 -384 -732 -1217 -1619 -1419 206 676 463 540 144 -319 -54 764 573 222 82 -584 -255 263 231 489 411 698 885 132 290 359 -951 -780 922 1604 1020 801 631 -1028 -702 1032 666 377 589 -1049 -1854 -1221 -830 -1045 -793 -798 -1079 -461 317 719 1043 451 709 641 85 486 492 408 540 1470 1443 1422 667 -394 -1351 -668 748 898 1819 1179 -718 -980 -1099 -736 -543 -151 440 861 1085 560 -959 -1517 -2212 -1620 -865 -1096 -916 -601 -1072 -984 47 715 813 1813 2165 1226 662 109 -1012 -1034 -437 -448 343 1413 247 -1578 -811 -738 -501 296 -228 -432 -518 43 190 1377 1646 1067 430 -134 -812 -332 -186 -130 619 1195 912 1675 1524 404 431 -315 -135 106 346 -282 -504 101 -713 -999 -441 -373 -531 SS 20241102T201244.8Z 9072.842185 298 1 22.01 2 56.41 217.74 58.74 199.97 0.00 1 0.00 1 0 25 1.196e-02 8.750e-03 1.053e-03 6.906e-04 2.096244e-01 3.731430e-04 2.440216e-03 -6.000000e+00 7.335293e-03 225.49 -2.00 3.31 -2.00 315.15 0.00e+00 2.084612e-05 3.526860e-05 3.129693e-05 -6.000000e+00 3.419600e-04 287.16 -2.00 20.00 -2.00 314.48 0.00e+00 1.801 0.000 302.00 328.00 3 3.2223e+00 9.5144e-04 2.0290e-02 -6.0000e+00 1.8081e-02 7.3684e-03 1.0555e-03 1.0117e-02 -6.0000e+00 1.9550e-02 -1.0882e-03 6.0474e-04 4.9824e-03 -6.0000e+00 1.1705e-02 -1.7818e-03 2.6720e-04 1.4115e-03 -6.0000e+00 4.9655e-03 2.8919e-03 5.2126e-05 2.2580e-05 2.2466e-05 -6.0000e+00 3.9641e-04 1.4183e-03 0.0000e+00 12 9 1 12 1 1 99.85 29.12 0.41 0.00142 0.00181 78 20 1 5 0 278.550 37.25 20.01 29.12 30.60 3.3 1022.86 -2781 -3454 -4675 -4148 385 1531 656 1287 362 -1231 -211 1730 1122 575 -487 -960 -573 710 345 819 772 1702 1719 366 355 216 -1219 -1235 1833 2905 2036 1403 836 -1972 -1020 1573 1091 979 925 -1368 -2155 -1423 -856 -1177 -922 -658 -1188 -357 188 983 1054 491 943 698 166 498 647 436 696 1531 1715 1588 679 -405 -1265 -627 821 1157 1955 1251 -584 -928 -1018 -774 -668 -115 559 982 1377 430 -952 -1578 -1981 -1547 -868 -1051 -745 -502 -763 -880 -116 667 738 1687 2063 1012 715 -5 -847 -927 -352 -503 337 1181 8 -1166 -572 -555 -348 132 -32 -401 -337 54 397 1015 1191 905 458 -170 -633 -269 -109 -34 409 942 780 1558 1272 272 237 -196 -126 206 121 -241 -320 51 -430 -488 -218 -439 -440 -813 -1090 -1507 -1279 114 429 190 402 116 -419 -72 602 396 227 -203 -434 -256 324 163 396 381 839 858 181 184 115 -653 -637 923 1403 1005 735 440 -1085 -548 818 604 588 590 -976 -1633 -1089 -672 -937 -733 -518 -923 -268 143 740 815 386 749 580 143 422 555 376 592 1291 1478 1445 641 -391 -1238 -582 753 1019 1763 1194 -577 -938 -1044 -799 -651 -109 500 852 1199 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