File name: Pandora259s1_TylerTX_20241104_L2Fit_fout2c1d20230310p1-8.txt File generation date: 20241105T135541.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: James Flynn Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 259 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora259_OF_v3d20221229.txt Instrument calibration file used: Pandora259s1_CF_v1d20230310.txt Level 1 file used: Pandora259s1_TylerTX_20241104_L1_smca1c1d20230310p1-8.txt Full location name: Tyler Pounds Regional Airport Short location name: TylerTX Country of location: United States Location latitude [deg]: 32.3440 Location longitude [deg]: -95.4159 Location altitude [m]: 164 Local noon date: 20241104 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session and full initial 1.8 instrument lab calibration, absolute calibration done with an uncalibrated lamp, certificate of FEL1441 (GSFC) used First and last pixel inside fitting window: 195 338 Nominal wavelengths inside fitting window [nm]: 305.0230 305.1635 305.3040 305.4444 305.5849 305.7254 305.8658 306.0062 306.1467 306.2871 306.4275 306.5679 306.7082 306.8486 306.9890 307.1293 307.2696 307.4100 307.5503 307.6906 307.8309 307.9711 308.1114 308.2517 308.3919 308.5321 308.6724 308.8126 308.9528 309.0929 309.2331 309.3733 309.5134 309.6536 309.7937 309.9338 310.0739 310.2140 310.3541 310.4942 310.6343 310.7743 310.9144 311.0544 311.1944 311.3344 311.4744 311.6144 311.7544 311.8943 312.0343 312.1742 312.3141 312.4541 312.5940 312.7339 312.8737 313.0136 313.1535 313.2933 313.4332 313.5730 313.7128 313.8526 313.9924 314.1322 314.2720 314.4117 314.5515 314.6912 314.8309 314.9706 315.1103 315.2500 315.3897 315.5294 315.6690 315.8087 315.9483 316.0879 316.2275 316.3671 316.5067 316.6463 316.7859 316.9254 317.0649 317.2045 317.3440 317.4835 317.6230 317.7625 317.9020 318.0414 318.1809 318.3203 318.4597 318.5991 318.7386 318.8779 319.0173 319.1567 319.2961 319.4354 319.5747 319.7141 319.8534 319.9927 320.1320 320.2712 320.4105 320.5498 320.6890 320.8282 320.9674 321.1067 321.2458 321.3850 321.5242 321.6634 321.8025 321.9417 322.0808 322.2199 322.3590 322.4981 322.6372 322.7762 322.9153 323.0543 323.1934 323.3324 323.4714 323.6104 323.7494 323.8884 324.0273 324.1663 324.3052 324.4442 324.5831 324.7220 324.8609 324.9998 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-387: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241104T142203.4Z 9074.598651 84 1 42.24 2 71.76 123.00 105.98 113.49 0.00 1 0.00 1 0 25 3.007e-01 3.126e-02 8.705e-02 7.667e-03 3.581886e-01 4.132516e-03 4.616835e-03 -6.000000e+00 1.840912e-01 225.37 -2.00 3.31 -2.00 318.76 0.00e+00 9.199340e-03 9.746445e-04 1.707836e-03 -6.000000e+00 9.300573e-03 286.98 -2.00 20.00 -2.00 317.98 0.00e+00 3.153 0.000 302.00 328.00 3 5.9656e+00 1.1279e-02 3.5569e-02 -6.0000e+00 4.5372e-01 2.0139e-01 1.3057e-02 1.7856e-02 -6.0000e+00 4.9200e-01 -5.2422e-02 9.0909e-03 1.2333e-02 -6.0000e+00 2.9388e-01 -1.3149e-03 4.7262e-03 7.6093e-03 -6.0000e+00 1.2482e-01 3.6129e-05 -4.5771e-03 2.5357e-04 8.0167e-05 -6.0000e+00 1.0033e-02 3.5660e-02 -7.1871e-04 12 9 9 12 9 1 99.99 29.03 2.25 0.03566 0.00127 12 2 1 5 0 3248.980 37.25 20.01 29.03 30.53 3.2 1021.49 -65319 900000 93888 67222 900000 -46743 -2356 -52121 4075 25242 900000 -10465 33899 27788 -49958 38922 213648 156848 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2901 -2076 -2441 -508 3033 5466 -30 -1942 1161 498 -1724 -5883 -1710 637 -4386 2003 1357 7252 -172 -1569 -1063 -2982 1315 3058 647 2569 -2732 -4897 2508 3213 -4597 828 5313 -2855 2388 -5733 -2584 -1004 -5416 -814 3222 -3239 884 -5876 -1849 -1998 3077 -1153 4900 3141 -766 3308 144 7821 -3070 2137 -1039 -1704 -1025 4289 -1450 -1045 1348 4202 284 2807 882 485 -1626 -2935 1585 -1403 -1934 -683 1156 2134 -1946 -848 -984 -2370 2321 900000 SS 20241104T143042.8Z 9074.604662 90 1 5.94 2 70.24 124.51 104.38 114.43 0.00 1 0.00 1 0 25 3.140e-02 9.551e-03 1.686e-02 4.114e-03 3.384797e-01 2.174860e-03 3.866707e-03 -6.000000e+00 1.921803e-02 225.37 -2.00 3.31 -2.00 317.66 0.00e+00 4.219830e-04 3.713235e-04 9.296966e-05 -6.000000e+00 8.971323e-04 286.98 -2.00 20.00 -2.00 316.87 0.00e+00 2.925 0.000 302.00 328.00 3 3.7964e+00 5.7601e-03 3.2936e-02 -6.0000e+00 4.7358e-02 4.2012e-02 6.5059e-03 1.6463e-02 -6.0000e+00 5.1242e-02 -1.6908e-02 4.0146e-03 8.1094e-03 -6.0000e+00 3.0675e-02 1.7723e-03 2.0131e-03 2.2960e-03 -6.0000e+00 1.2991e-02 4.4856e-04 -1.6861e-03 1.3355e-04 3.1243e-05 -6.0000e+00 1.0411e-03 3.2646e-02 -1.7029e-04 12 9 9 12 1 1 99.99 29.00 0.31 0.03265 0.01998 10 10 1 5 0 539.650 37.25 20.01 29.00 30.88 3.2 1024.20 -18367 2883 -5868 -4788 9576 -10581 -8716 -13649 -9558 498 2687 -5885 -2898 -6519 -4779 835 2964 2916 49 2155 2035 4089 -1573 952 -1904 -3185 -521 -2792 -1500 1659 3796 509 -549 -1944 -3774 2547 3712 -864 3983 -1978 -2056 -550 2217 -544 -417 -38 -1857 -58 1453 1153 182 467 1760 1604 1284 -433 200 2055 -680 2638 1085 2025 2315 -739 -1301 151 1672 818 1330 1002 -618 -1178 -855 -1760 -1157 908 -326 906 1550 1404 -818 -1906 -1982 -1594 -1074 -775 -173 -591 -698 -737 -190 1332 698 1261 2423 1137 1171 -370 -1327 -1018 -864 -433 139 1821 -504 -1645 -584 -680 -205 -79 25 6 -360 232 395 1798 752 475 477 17 -620 -374 -393 156 432 1164 652 1490 697 69 269 -226 -398 127 229 -212 -288 470 -512 -390 -2 -643 -238 900000 -1540 215 -492 -388 642 -841 -706 -1281 -947 47 261 -666 -356 -960 -794 132 497 518 9 421 408 817 -340 210 -460 -807 -128 -685 -353 378 889 134 -158 -589 -1162 738 1137 -293 1517 -922 -983 -277 1129 -290 -224 -21 -1006 -30 755 613 103 281 1041 1004 841 -297 139 1408 -475 1775 761 1494 1717 -602 -1089 121 1256 609 1035 807 -552 -1116 -816 -1647 -1011 760 -253 665 1165 1164 -732 -1804 -2037 -1642 -1171 -898 -199 -710 -845 -869 -222 1422 738 1284 2529 1242 1348 -455 -1768 -1372 -1117 -547 164 2105 -627 -2092 -775 -950 -287 -118 38 10 -562 343 572 2532 1045 645 684 24 -936 -563 -578 232 610 1638 885 1986 981 100 397 -352 -639 201 381 -358 -506 838 -894 -700 -3 -1075 -402 900000 SS 20241104T144756.3Z 9074.616624 100 1 2.60 2 67.30 127.65 101.23 116.35 0.00 1 0.00 1 0 25 1.276e-02 8.268e-03 2.318e-03 1.008e-03 2.981934e-01 5.389542e-04 3.420881e-03 -6.000000e+00 7.820061e-03 225.37 -2.00 3.31 -2.00 316.53 0.00e+00 9.383475e-05 6.827208e-05 6.490269e-05 -6.000000e+00 3.645605e-04 286.98 -2.00 20.00 -2.00 315.76 0.00e+00 2.570 0.000 302.00 328.00 3 8.0373e-01 1.3954e-03 2.8910e-02 -6.0000e+00 1.9272e-02 1.0004e-02 1.5598e-03 1.4378e-02 -6.0000e+00 2.0843e-02 -1.1522e-02 9.0552e-04 7.0715e-03 -6.0000e+00 1.2478e-02 2.4900e-03 4.2495e-04 2.0045e-03 -6.0000e+00 5.2919e-03 1.3492e-02 -3.2886e-04 3.2719e-05 2.9343e-05 -6.0000e+00 4.2297e-04 2.8838e-02 4.8976e-05 12 9 1 12 1 1 99.97 29.10 0.39 0.02884 0.02637 69 150 1 5 0 37.120 37.25 20.01 29.10 31.58 3.2 1029.09 -3978 -5094 -5516 -4567 -968 1137 -1036 -313 -965 -1890 -1707 1187 635 943 -49 -900 19 623 2 1023 977 892 1213 75 614 64 -1716 -963 772 2553 1535 840 561 -2291 -1330 915 743 957 1046 -1129 -1908 -1063 -835 -1001 -409 -504 -731 -137 0 1204 1136 439 1035 987 273 556 618 257 954 1501 1742 1942 979 -88 -865 -359 901 952 1976 1202 -688 -1001 -1272 -777 -800 237 903 1141 1438 133 -1070 -1607 -2029 -1490 -856 -1238 -747 -572 -740 -777 -92 827 1019 1835 1853 1195 449 -160 -861 -987 -370 -412 354 1173 -131 -1281 -573 -475 -446 85 -114 -455 -451 -9 433 1015 1355 1069 406 -266 -756 -372 -194 18 382 818 621 1425 1317 330 223 -155 -57 182 329 -138 -298 26 -385 -503 -181 -315 -519 900000 -606 -858 -955 -762 -148 179 -158 -52 -178 -371 -347 248 136 229 -13 -259 6 199 1 328 322 298 413 27 232 23 -642 -370 282 905 570 318 228 -988 -566 381 330 458 557 -637 -1143 -674 -548 -669 -273 -336 -484 -89 0 776 765 303 724 728 202 422 479 200 732 1143 1355 1534 808 -78 -755 -313 763 787 1690 1053 -647 -961 -1239 -760 -737 214 768 921 1184 117 -990 -1600 -2123 -1597 -939 -1412 -897 -690 -902 -924 -105 927 1091 1876 1952 1333 526 -197 -1106 -1288 -475 -507 421 1381 -160 -1633 -744 -629 -607 119 -165 -682 -667 -13 592 1369 1776 1439 565 -385 -1109 -545 -278 25 530 1107 807 1866 1751 461 324 -229 -84 279 515 -224 -490 43 -642 -830 -294 -508 -816 900000 SS 20241104T150715.8Z 9074.630044 114 1 54.42 2 64.16 131.41 97.76 118.59 0.00 1 0.00 1 0 25 1.233e-02 8.483e-03 3.323e-04 1.741e-04 2.645436e-01 9.323718e-05 3.053599e-03 -6.000000e+00 7.554095e-03 225.37 -2.00 3.31 -2.00 316.03 0.00e+00 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