File name: Pandora259s1_TylerTX_20241108_L2Fit_fout2c1d20230310p1-8.txt File generation date: 20241109T061030.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: James Flynn Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 259 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora259_OF_v3d20221229.txt Instrument calibration file used: Pandora259s1_CF_v1d20230310.txt Level 1 file used: Pandora259s1_TylerTX_20241108_L1_smca1c1d20230310p1-8.txt Full location name: Tyler Pounds Regional Airport Short location name: TylerTX Country of location: United States Location latitude [deg]: 32.3440 Location longitude [deg]: -95.4159 Location altitude [m]: 164 Local noon date: 20241108 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session and full initial 1.8 instrument lab calibration, absolute calibration done with an uncalibrated lamp, certificate of FEL1441 (GSFC) used First and last pixel inside fitting window: 195 338 Nominal wavelengths inside fitting window [nm]: 305.0230 305.1635 305.3040 305.4444 305.5849 305.7254 305.8658 306.0062 306.1467 306.2871 306.4275 306.5679 306.7082 306.8486 306.9890 307.1293 307.2696 307.4100 307.5503 307.6906 307.8309 307.9711 308.1114 308.2517 308.3919 308.5321 308.6724 308.8126 308.9528 309.0929 309.2331 309.3733 309.5134 309.6536 309.7937 309.9338 310.0739 310.2140 310.3541 310.4942 310.6343 310.7743 310.9144 311.0544 311.1944 311.3344 311.4744 311.6144 311.7544 311.8943 312.0343 312.1742 312.3141 312.4541 312.5940 312.7339 312.8737 313.0136 313.1535 313.2933 313.4332 313.5730 313.7128 313.8526 313.9924 314.1322 314.2720 314.4117 314.5515 314.6912 314.8309 314.9706 315.1103 315.2500 315.3897 315.5294 315.6690 315.8087 315.9483 316.0879 316.2275 316.3671 316.5067 316.6463 316.7859 316.9254 317.0649 317.2045 317.3440 317.4835 317.6230 317.7625 317.9020 318.0414 318.1809 318.3203 318.4597 318.5991 318.7386 318.8779 319.0173 319.1567 319.2961 319.4354 319.5747 319.7141 319.8534 319.9927 320.1320 320.2712 320.4105 320.5498 320.6890 320.8282 320.9674 321.1067 321.2458 321.3850 321.5242 321.6634 321.8025 321.9417 322.0808 322.2199 322.3590 322.4981 322.6372 322.7762 322.9153 323.0543 323.1934 323.3324 323.4714 323.6104 323.7494 323.8884 324.0273 324.1663 324.3052 324.4442 324.5831 324.7220 324.8609 324.9998 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-387: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241108T194541.1Z 9078.823392 310 1 17.77 2 54.76 209.74 83.60 121.06 0.00 1 0.00 1 0 17 1.579e-02 9.471e-03 4.745e-03 2.871e-03 1.916974e-01 1.541422e-03 2.236443e-03 -6.000000e+00 9.666633e-03 225.08 -2.00 3.31 -2.00 315.42 0.00e+00 1.121383e-04 1.543213e-04 2.368097e-05 -6.000000e+00 4.503796e-04 286.56 -2.00 20.00 -2.00 314.75 0.00e+00 1.728 0.000 302.00 328.00 3 5.5100e+00 3.9389e-03 1.9237e-02 -6.0000e+00 2.3810e-02 3.9828e-02 4.3811e-03 9.2759e-03 -6.0000e+00 2.5759e-02 6.8403e-04 2.5109e-03 4.5700e-03 -6.0000e+00 1.5420e-02 -4.2318e-03 1.1199e-03 1.3000e-03 -6.0000e+00 6.5402e-03 3.2187e-04 -4.3467e-04 9.4261e-05 2.0353e-05 -6.0000e+00 5.2342e-04 2.8492e-02 1.4557e-05 12 9 9 12 33 1 99.99 28.95 0.87 0.02849 0.02523 8 3 1 5 0 1973.680 37.25 20.00 28.95 29.20 3.3 1012.49 -5754 -592 -4205 -2389 6752 -2667 -987 237 566 -1137 2649 -1166 -713 219 -2458 -217 639 4357 -463 -1346 652 2364 2027 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-785 -292 -442 886 17 1324 2205 832 1363 -562 -1198 -489 -756 -829 49 681 -444 -1597 -948 -789 549 -111 464 494 -388 -318 300 1394 787 620 144 -265 -885 311 -316 -223 585 1469 992 1019 1181 697 186 -823 215 98 197 -53 63 397 -611 -901 -153 -890 -533 900000 SS 20241108T195236.0Z 9078.828194 316 1 7.56 2 55.51 211.54 82.38 122.03 0.00 1 0.00 1 0 25 2.310e-02 1.215e-02 1.193e-02 6.893e-03 1.925780e-01 3.685490e-03 2.251799e-03 -6.000000e+00 1.414895e-02 225.08 -2.00 3.31 -2.00 315.58 0.00e+00 3.404052e-04 3.834243e-04 2.700018e-05 -6.000000e+00 6.589144e-04 286.56 -2.00 20.00 -2.00 314.89 0.00e+00 1.760 0.000 302.00 328.00 3 5.7520e+00 9.4505e-03 1.9545e-02 -6.0000e+00 3.4851e-02 4.5686e-02 1.0521e-02 9.3623e-03 -6.0000e+00 3.7696e-02 1.9560e-03 6.0332e-03 4.6069e-03 -6.0000e+00 2.2567e-02 -6.6319e-03 2.7118e-03 1.3380e-03 -6.0000e+00 9.5774e-03 2.4394e-04 3.4740e-04 2.2622e-04 2.0100e-05 -6.0000e+00 7.6557e-04 2.6270e-02 7.9779e-05 12 9 9 12 1 1 999.00 28.98 1.06 0.02627 0.02888 1 1 1 5 0 3777.040 37.25 20.00 28.98 29.29 3.2 1012.96 -6953 856 -1082 -5062 8888 -5037 -3577 -1669 1416 -2524 11706 -1233 1384 -3944 -5529 2123 -73 4741 -968 6591 718 1753 3295 -2514 -336 864 -2219 -3832 3171 4447 5236 3338 -426 -2057 -353 1081 406 -3310 1164 -2767 -506 -1109 479 -1210 -1847 -1433 -1267 -1457 -899 -823 -279 1489 823 1108 863 -36 1704 2287 725 3981 1998 1989 1400 98 -1001 -855 2139 -467 1719 897 -1357 -556 -2014 -1269 -645 52 -777 302 1063 1816 -833 -560 -1379 -1081 -97 -48 -1084 -63 -1097 -2000 1075 1613 343 1932 2310 -42 1449 -1228 -1582 -1174 -931 -125 856 1040 -700 -1412 -667 -939 157 -498 965 603 505 249 -556 -121 655 663 -40 -513 92 128 -279 -656 -293 1209 1396 1675 971 651 127 -135 498 304 66 482 96 -480 -173 -241 -1039 -574 -464 900000 -1806 220 -285 -1330 1906 -1182 -844 -419 374 -722 2948 -364 426 -1422 -2053 785 -29 1846 -410 2658 312 761 1421 -1184 -162 421 -1100 -1855 1362 1826 2153 1470 -204 -1018 -169 506 202 -1949 705 -1845 -362 -843 369 -957 -1472 -1127 -975 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1.1058e-02 -2.1417e-03 2.4294e-04 1.3121e-03 -6.0000e+00 4.6912e-03 1.6807e-03 -1.3996e-04 2.0710e-05 2.0774e-05 -6.0000e+00 3.7528e-04 2.8155e-02 5.6901e-05 11 8 0 10 0 0 99.99 29.00 0.38 0.02815 0.02710 156 16 1 5 0 348.830 37.25 20.00 29.00 29.39 3.3 1014.48 -2449 -2736 -3916 -3905 1405 993 611 657 316 -1153 325 1768 1337 291 -480 -1080 -404 788 9 1263 863 1724 1416 411 622 39 -1331 -1408 1622 2370 2218 1477 476 -1749 -1523 1569 853 473 924 -1280 -2019 -1382 -692 -1143 -818 -909 -1130 -464 403 950 933 675 1010 703 160 508 687 409 752 1652 1764 1587 843 -348 -1254 -623 877 955 1989 1305 -608 -906 -1051 -793 -557 -42 444 937 1343 591 -951 -1482 -2092 -1452 -757 -998 -619 -375 -777 -828 42 705 607 1715 2091 946 615 29 -921 -980 -383 -399 248 1037 -82 -1300 -649 -444 -269 177 -3 -281 -320 15 297 1007 1267 823 563 -137 -621 -231 -157 -42 435 910 683 1346 1124 383 245 -222 -124 188 151 -223 -303 39 -361 -548 -201 -424 -383 900000 -750 -898 -1310 -1252 401 294 171 200 105 -404 114 629 475 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