File name: Pandora259s1_TylerTX_20241224_L2Fit_fwvt1c3d20230310p1-8.txt File generation date: 20241225T062821.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: James Flynn Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 259 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora259_OF_v3d20221229.txt Instrument calibration file used: Pandora259s1_CF_v3d20230310.txt Level 1 file used: Pandora259s1_TylerTX_20241224_L1_smca1c3d20230310p1-8.txt Full location name: Tyler Pounds Regional Airport Short location name: TylerTX Country of location: United States Location latitude [deg]: 32.3440 Location longitude [deg]: -95.4159 Location altitude [m]: 164 Local noon date: 20241224 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0816 492.2022 492.3228 492.4434 492.5639 492.6845 492.8050 492.9255 493.0460 493.1665 493.2869 493.4074 493.5278 493.6482 493.7686 493.8890 494.0094 494.1297 494.2500 494.3703 494.4906 494.6109 494.7312 494.8514 494.9716 495.0918 495.2120 495.3322 495.4524 495.5725 495.6926 495.8127 495.9328 496.0529 496.1730 496.2930 496.4130 496.5330 496.6530 496.7730 496.8929 497.0129 497.1328 497.2527 497.3726 497.4924 497.6123 497.7321 497.8519 497.9717 498.0915 498.2113 498.3310 498.4508 498.5705 498.6902 498.8099 498.9295 499.0492 499.1688 499.2884 499.4080 499.5276 499.6472 499.7667 499.8862 500.0057 500.1252 500.2447 500.3642 500.4836 500.6030 500.7224 500.8418 500.9612 501.0806 501.1999 501.3192 501.4385 501.5578 501.6771 501.7963 501.9156 502.0348 502.1540 502.2732 502.3923 502.5115 502.6306 502.7497 502.8688 502.9879 503.1070 503.2260 503.3451 503.4641 503.5831 503.7020 503.8210 503.9399 504.0589 504.1778 504.2967 504.4156 504.5344 504.6532 504.7721 504.8909 505.0097 505.1284 505.2472 505.3659 505.4846 505.6033 505.7220 505.8407 505.9593 506.0780 506.1966 506.3152 506.4338 506.5523 506.6709 506.7894 506.9079 507.0264 507.1449 507.2634 507.3818 507.5002 507.6186 507.7370 507.8554 507.9737 508.0921 508.2104 508.3287 508.4470 508.5653 508.6835 508.8017 508.9200 509.0382 509.1563 509.2745 509.3926 509.5108 509.6289 509.7470 509.8651 509.9831 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20241224T133205.0Z 9124.563946 222 1 15.54 2 88.71 118.97 42.67 183.72 0.00 1 0.00 1 0 22 8.849e-03 8.701e-03 6.665e-04 6.645e-04 2.449095e+04 5.031364e+01 1.576343e+03 -6.000000e+00 4.936955e+02 282.91 -2.00 20.00 -2.00 505.41 0.00e+00 2.630123e-03 1.853950e-05 1.835562e-04 -6.000000e+00 2.486536e-04 282.91 -2.00 20.00 -2.00 500.94 0.00e+00 9.021144e-01 1.290724e-02 1.511853e-01 -6.000000e+00 1.756958e-01 224.09 -2.00 3.31 -2.00 502.45 0.00e+00 17.969 0.080 489.00 513.00 1 3.9890e+00 9.8592e-04 3.0841e-02 -6.0000e+00 1.3459e-02 -4.8488e-02 2.4815e-04 4.0741e-03 -6.0000e+00 3.5160e-03 2.5363e-03 -2.2051e-04 5.6073e-05 1.7518e-04 -6.0000e+00 9.0319e-04 1.0772e-02 4.1157e-05 12 9 9 12 1 1 -26.59 27.01 5.89 0.01077 0.00924 27 10 1 4 0 554.820 35.75 19.99 27.01 19.95 3.6 947.85 -1201 -496 213 1019 1209 1900 2051 1840 1436 1211 864 197 -203 -441 -510 -546 -69 349 528 450 476 565 457 837 761 765 669 85 -932 -1207 -1365 -1226 -848 81 73 27 57 -368 -711 -667 -376 -236 102 525 800 695 623 306 -284 -884 -1518 -1917 -1945 -1396 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1733 2175 1817 1059 988 359 310 430 1054 1047 892 931 703 672 667 230 -206 -251 -487 -830 -164 -36 79 453 563 467 519 491 637 754 496 183 -629 -1085 -1442 900000 SQ 20241224T133447.3Z 9124.565826 226 1 54.48 2 88.21 119.34 42.72 184.69 0.00 1 0.00 1 0 22 7.106e-03 6.994e-03 1.843e-04 1.838e-04 2.328591e+04 1.385280e+01 1.523110e+03 -6.000000e+00 3.963716e+02 282.91 -2.00 20.00 -2.00 505.43 0.00e+00 2.205319e-03 5.117043e-06 1.547781e-04 -6.000000e+00 1.992466e-04 282.91 -2.00 20.00 -2.00 500.94 0.00e+00 1.023006e+00 3.548590e-03 1.400987e-01 -6.000000e+00 1.396248e-01 224.09 -2.00 3.31 -2.00 502.46 0.00e+00 16.643 0.063 489.00 513.00 1 2.9122e+00 2.7174e-04 2.8035e-02 -6.0000e+00 1.0720e-02 -4.4887e-02 6.7334e-05 3.8323e-03 -6.0000e+00 2.7576e-03 8.9581e-03 1.9939e-03 1.5624e-05 1.6384e-04 -6.0000e+00 7.2278e-04 1.3748e-03 -1.9165e-06 12 8 8 10 0 0 94.40 27.01 4.43 0.00137 0.01521 337 35 1 4 0 161.640 35.75 19.99 27.01 20.02 3.6 948.09 -963 -480 262 614 1089 1582 1608 1450 1236 889 711 218 -281 -453 -472 -359 -50 342 358 358 511 418 379 629 614 633 631 57 -806 -895 -1040 -1062 -552 136 11 6 21 -227 -533 -496 -321 -224 149 357 548 508 469 259 -162 -828 -1239 -1490 -1611 -1140 -585 -255 -5 244 269 401 555 617 598 584 391 207 -18 -326 -638 -883 -759 -677 -567 -271 -294 -501 -687 -808 -932 -985 -732 -665 -651 -451 -348 -587 -600 -550 -436 -137 177 487 724 674 702 609 200 -257 -928 -1706 -1803 -1493 -1066 -611 -416 -382 -470 -596 -377 -165 -167 -89 333 709 919 1360 1681 1389 838 580 303 181 371 807 827 835 803 572 512 594 200 -143 -83 -412 -571 17 35 13 391 569 344 407 526 517 609 462 130 -406 -772 -989 -777 -871 -434 241 575 1043 1519 1548 1410 1201 857 689 209 -268 -428 -447 -344 -48 334 353 352 505 415 378 629 609 631 627 57 -791 -869 -1004 -1034 -540 135 12 6 21 -227 -531 -499 -320 -225 151 363 562 523 481 263 -162 -828 -1228 -1452 -1564 -1116 -577 -255 -5 248 275 408 567 634 610 595 402 210 -18 -330 -639 -877 -750 -672 -568 -271 -295 -501 -688 -797 -921 -966 -718 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12 9 9 12 1 1 99.93 27.01 3.14 -0.00641 0.00152 229 53 1 4 0 105.530 35.75 20.00 27.01 20.19 3.5 948.63 -803 -411 124 386 787 1178 1178 1065 894 735 512 103 -293 -308 -350 -277 -29 243 219 207 423 336 327 545 489 572 494 96 -671 -657 -700 -765 -385 233 -37 -58 66 -141 -388 -354 -210 -156 99 273 413 369 353 215 -150 -714 -1008 -1206 -1271 -886 -466 -261 -81 133 98 283 464 502 464 430 304 125 -29 -227 -478 -703 -513 -453 -383 -115 -140 -388 -508 -538 -691 -716 -566 -519 -538 -314 -217 -442 -439 -403 -290 -64 138 461 581 461 524 520 209 -133 -648 -1300 -1416 -1179 -849 -463 -400 -434 -484 -516 -310 -49 -155 -130 275 505 656 1047 1327 1111 624 442 246 190 357 690 618 570 610 395 379 528 165 -89 23 -267 -463 89 19 -15 228 425 241 334 458 416 421 274 0 -371 -569 -714 -580 -740 -380 117 372 764 1150 1156 1055 884 719 503 100 -282 -297 -334 -267 -28 240 219 207 425 339 330 552 493 577 497 97 -665 -641 -678 -748 -379 233 -38 -60 67 -143 -389 -359 -211 -157 101 279 426 377 363 219 -151 -714 -995 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20241224T202443.8Z 9124.850507 440 2 15.83 2 63.01 211.80 107.62 267.22 0.00 1 0.00 1 0 15 2.345e-03 2.343e-03 1.432e-04 1.430e-04 3.294944e+03 8.773843e+00 2.438972e+02 -6.000000e+00 1.308071e+02 282.90 -2.00 20.00 -2.00 505.28 0.00e+00 4.494776e-04 3.927653e-06 3.042490e-05 -6.000000e+00 6.575471e-05 282.90 -2.00 20.00 -2.00 500.51 0.00e+00 8.973572e-02 2.795326e-03 2.205650e-02 -6.000000e+00 4.608041e-02 224.09 -2.00 3.31 -2.00 502.09 0.00e+00 2.191 0.000 489.00 513.00 1 3.3393e+00 2.1443e-04 3.6901e-03 -6.0000e+00 3.5379e-03 -4.2965e-03 5.4842e-05 5.7403e-04 -6.0000e+00 9.1008e-04 5.0238e-02 1.3243e-03 1.4039e-05 2.9738e-05 -6.0000e+00 2.3854e-04 -1.2671e-03 1.4582e-05 12 1 1 12 1 1 99.83 29.00 1.76 -0.00127 0.00792 434 54 1 4 0 36.370 37.25 20.00 29.00 27.88 3.3 1002.81 -372 -203 -32 -25 218 529 440 308 281 315 302 42 -163 -23 -142 -74 88 176 -13 -54 208 207 184 360 244 319 358 5 -404 -52 -109 -279 13 245 -233 -155 138 -10 -141 -107 -58 -183 22 59 102 57 106 96 -128 -473 -511 -572 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