File name: Pandora259s1_TylerTX_20250104_L2Fit_fout2c3d20230310p1-8.txt File generation date: 20250105T063324.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: James Flynn Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 259 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora259_OF_v3d20221229.txt Instrument calibration file used: Pandora259s1_CF_v3d20230310.txt Level 1 file used: Pandora259s1_TylerTX_20250104_L1_smca1c3d20230310p1-8.txt Full location name: Tyler Pounds Regional Airport Short location name: TylerTX Country of location: United States Location latitude [deg]: 32.3440 Location longitude [deg]: -95.4159 Location altitude [m]: 164 Local noon date: 20250104 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 195 337 Nominal wavelengths inside fitting window [nm]: 305.0446 305.1851 305.3256 305.4661 305.6066 305.7470 305.8875 306.0279 306.1684 306.3088 306.4492 306.5896 306.7300 306.8704 307.0108 307.1511 307.2915 307.4318 307.5721 307.7125 307.8528 307.9930 308.1333 308.2736 308.4139 308.5541 308.6943 308.8346 308.9748 309.1150 309.2552 309.3954 309.5355 309.6757 309.8158 309.9560 310.0961 310.2362 310.3763 310.5164 310.6565 310.7966 310.9366 311.0767 311.2167 311.3567 311.4967 311.6367 311.7767 311.9167 312.0567 312.1966 312.3366 312.4765 312.6164 312.7563 312.8962 313.0361 313.1760 313.3159 313.4557 313.5955 313.7354 313.8752 314.0150 314.1548 314.2946 314.4344 314.5741 314.7139 314.8536 314.9934 315.1331 315.2728 315.4125 315.5522 315.6918 315.8315 315.9711 316.1108 316.2504 316.3900 316.5296 316.6692 316.8088 316.9484 317.0879 317.2275 317.3670 317.5065 317.6460 317.7855 317.9250 318.0645 318.2040 318.3434 318.4829 318.6223 318.7617 318.9011 319.0405 319.1799 319.3193 319.4587 319.5980 319.7373 319.8767 320.0160 320.1553 320.2946 320.4339 320.5731 320.7124 320.8516 320.9909 321.1301 321.2693 321.4085 321.5477 321.6869 321.8261 321.9652 322.1044 322.2435 322.3826 322.5217 322.6608 322.7999 322.9390 323.0780 323.2171 323.3561 323.4952 323.6342 323.7732 323.9122 324.0512 324.1901 324.3291 324.4680 324.6070 324.7459 324.8848 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250104T155221.1Z 9135.661355 117 1 5.63 2 66.22 140.99 102.40 91.69 0.00 1 0.00 1 0 25 3.739e-02 1.201e-02 2.184e-02 7.186e-03 3.068459e-01 3.783399e-03 3.539464e-03 -6.000000e+00 2.279027e-02 224.18 -2.00 3.31 -2.00 317.10 0.00e+00 2.607268e-05 5.507706e-04 6.477755e-05 -6.000000e+00 1.048318e-03 282.45 -2.00 20.00 -2.00 316.39 0.00e+00 2.462 0.000 302.00 328.00 3 4.9021e+00 9.8713e-03 2.8208e-02 -6.0000e+00 5.6099e-02 6.0180e-02 1.1091e-02 1.4782e-02 -6.0000e+00 6.0788e-02 -2.0118e-02 6.6187e-03 7.3247e-03 -6.0000e+00 3.6323e-02 3.0117e-03 3.2169e-03 2.0903e-03 -6.0000e+00 1.5351e-02 2.3909e-04 6.1549e-06 2.3255e-04 2.9846e-05 -6.0000e+00 1.2388e-03 9.7882e-03 0.0000e+00 12 9 9 12 1 1 999.00 26.13 0.51 0.00979 0.00983 1 2 1 5 0 2814.240 35.00 20.06 26.13 18.91 3.5 938.23 -17680 7035 -16081 -3263 14751 -5805 -3357 -4976 -5913 10057 11430 -1167 -989 -1357 -10219 4947 -3797 14813 281 5062 1229 1675 1088 388 -93 2655 919 -7324 -1333 5417 4236 1166 438 -6138 347 2259 1679 -4027 730 -3435 -2295 -624 714 -199 -54 -275 -465 -898 1126 1865 -475 -1896 719 1932 1080 -219 -518 394 1239 2317 1344 2275 775 -300 -442 -55 1175 1097 2653 1145 -123 -1004 -915 -1712 -1129 1789 1143 1192 1082 659 -1202 -1497 -2797 -2300 -825 -1319 557 -650 -508 -1251 848 439 790 2549 3320 567 1433 -1151 -1511 -749 -316 -599 506 366 -672 -1010 -483 -1124 -367 334 1480 63 -611 -327 575 1473 734 1040 146 -1126 -566 94 -369 -738 169 592 -111 2137 1266 188 188 -414 384 150 559 695 -110 -778 -64 -405 -911 -494 203 -2243 759 -2029 -386 1385 -647 -379 -628 -825 1262 1466 -180 -168 -241 -2253 1031 -924 3143 72 1277 330 454 302 113 -29 829 290 -2431 -403 1515 1247 383 155 -2187 115 803 589 -1719 350 -1818 -1326 -351 410 -117 -32 -162 -271 -519 682 1138 -288 -1243 489 1368 747 -158 -381 287 887 1635 982 1747 650 -252 -378 -45 961 881 2197 991 -117 -956 -878 -1607 -1051 1479 928 924 863 580 -1131 -1472 -3012 -2473 -930 -1508 660 -805 -632 -1525 1006 483 849 2605 3483 630 1657 -1429 -2011 -998 -402 -749 591 428 -837 -1274 -637 -1569 -511 492 2171 96 -927 -491 798 1999 981 1420 203 -1672 -823 142 -548 -1062 241 802 -145 2851 1692 259 276 -606 574 233 907 1135 -187 -1310 -107 -676 -1540 -802 332 SS 20250104T162810.1Z 9135.686228 142 1 44.88 2 61.86 148.80 95.03 96.13 0.00 1 0.00 1 0 25 2.452e-02 1.068e-02 4.960e-03 2.042e-03 2.635145e-01 1.080986e-03 3.018343e-03 -6.000000e+00 1.493891e-02 224.18 -2.00 3.31 -2.00 316.61 0.00e+00 -5.295780e-05 1.393014e-04 5.721433e-05 -6.000000e+00 6.873485e-04 282.45 -2.00 20.00 -2.00 315.93 0.00e+00 2.110 0.000 302.00 328.00 3 5.4553e+00 2.7980e-03 2.4141e-02 -6.0000e+00 3.6772e-02 6.0819e-02 3.1330e-03 1.2582e-02 -6.0000e+00 3.9850e-02 -9.4609e-03 1.8341e-03 6.2382e-03 -6.0000e+00 2.3811e-02 -1.2648e-03 8.6580e-04 1.7840e-03 -6.0000e+00 1.0060e-02 2.0545e-04 4.3265e-05 6.6798e-05 2.5433e-05 -6.0000e+00 8.1228e-04 1.1857e-02 0.0000e+00 12 9 9 12 33 1 99.99 26.25 0.59 0.01186 0.01218 23 3 1 5 0 1869.660 35.00 20.00 26.25 19.90 3.5 945.84 -12574 -1364 -3344 -3341 12397 -7763 -3317 -4607 -1031 1813 4365 -1248 2254 -570 -6073 948 4651 6853 -1940 4666 1230 2261 469 1939 -1953 -369 249 -5242 -1249 1536 5280 1815 -1473 -2417 -1085 1573 1430 -1112 3670 -440 -1394 -761 -43 -1428 -1575 -1705 -1228 -768 436 716 -267 89 1530 879 -437 798 112 1444 267 2898 2397 656 1025 -443 -1753 303 1041 1715 2193 590 -1015 -824 -1121 -939 -1210 17 1505 1846 1699 2355 -1259 -1825 -2375 -1654 -520 -387 -370 -243 -872 -702 1017 950 552 2371 2505 446 1101 -622 -1291 -1026 -827 -292 643 873 -551 -1133 -1247 -729 2 -39 224 -466 -649 -223 415 1846 1057 1178 142 -240 -666 -27 -538 -357 505 1067 989 1212 1174 175 182 -369 315 199 351 -224 -584 334 -418 -652 -84 -575 -51 -2055 -215 -545 -525 1572 -1159 -490 -756 -178 319 770 -244 466 -124 -1573 249 1249 1877 -601 1396 389 715 153 651 -719 -137 91 -1956 -430 505 1720 655 -583 -986 -432 609 592 -497 1834 -242 -851 -489 -28 -965 -1067 -1150 -812 -495 274 453 -177 62 1121 631 -329 607 87 1108 205 2165 1845 544 907 -390 -1576 256 878 1400 1860 520 -987 -840 -1156 -938 -1140 16 1234 1432 1348 2028 -1169 -1877 -2481 -1819 -601 -448 -452 -307 -1112 -869 1164 1064 573 2478 2690 497 1267 -798 -1675 -1337 -1089 -357 738 1003 -678 -1490 -1630 -994 2 -56 335 -717 -981 -317 574 2358 1408 1517 195 -351 -959 -38 -758 -511 685 1449 1285 1553 1565 237 261 -522 454 297 547 -351 -951 551 -703 -1083 -134 -893 -81 SS 20250104T164632.0Z 9135.698982 151 1 54.24 2 59.98 153.14 91.27 98.42 0.00 1 0.00 1 0 25 1.242e-02 8.934e-03 2.182e-04 1.313e-04 2.454146e-01 7.024283e-05 2.839003e-03 -6.000000e+00 7.568713e-03 224.18 -2.00 3.31 -2.00 315.55 0.00e+00 2.635860e-05 7.105232e-06 4.835129e-05 -6.000000e+00 3.481643e-04 282.45 -2.00 20.00 -2.00 314.92 0.00e+00 1.990 0.000 302.00 328.00 3 6.0503e-01 1.7936e-04 2.2686e-02 -6.0000e+00 1.8630e-02 1.1884e-02 1.9977e-04 1.1707e-02 -6.0000e+00 2.0188e-02 -8.9515e-03 1.1454e-04 5.8003e-03 -6.0000e+00 1.2063e-02 1.6451e-03 5.1094e-05 1.6588e-03 -6.0000e+00 5.0979e-03 3.1049e-02 2.0140e-04 4.2821e-06 2.5278e-05 -6.0000e+00 4.1145e-04 1.0271e-02 0.0000e+00 11 8 0 10 0 0 95.10 26.32 0.38 0.01027 0.01178 2581 265 1 5 0 21.010 35.25 20.01 26.32 21.38 3.5 956.84 -2537 -4038 -4954 -4368 -202 1423 375 679 -341 -1699 -522 1789 1135 401 61 -1131 -697 533 279 625 845 1688 1897 466 758 122 -1643 -820 2072 2901 1663 1319 474 -2082 -941 1818 957 1057 753 -1477 -2141 -1172 -914 -1150 -506 -555 -780 -247 372 1127 1336 688 977 661 4 538 593 197 874 1592 1742 1586 706 -580 -1367 -408 985 1060 2171 950 -856 -1086 -1235 -793 -643 34 913 1238 1464 297 -1060 -1586 -2194 -1422 -836 -1145 -801 -605 -863 -832 20 678 823 1908 1992 1010 596 -48 -1053 -973 -338 -361 577 1343 -173 -1176 -549 -519 -291 200 -278 -527 -427 27 460 1184 1443 964 546 -217 -720 -323 -104 -48 469 835 708 1643 1150 252 195 -253 -69 317 207 -260 -328 44 -476 -536 -199 -426 -394 -675 -1096 -1371 -1157 -52 345 95 188 -97 -511 -159 557 363 137 23 -449 -291 229 118 271 373 746 850 220 357 59 -804 -384 951 1293 769 620 238 -1040 -482 904 488 590 472 -996 -1535 -850 -682 -870 -381 -416 -576 -177 272 821 970 513 769 528 3 440 493 165 718 1341 1454 1357 632 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