File name: Pandora259s1_TylerTX_20250417_L2Fit_fout2c3d20230310p1-8.txt File generation date: 20250418T062729.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: James Flynn Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 259 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora259_OF_v4d20221229.txt Instrument calibration file used: Pandora259s1_CF_v3d20230310.txt Level 1 file used: Pandora259s1_TylerTX_20250417_L1_smca1c3d20230310p1-8.txt Full location name: Tyler Pounds Regional Airport Short location name: TylerTX Country of location: United States Location latitude [deg]: 32.3440 Location longitude [deg]: -95.4159 Location altitude [m]: 164 Local noon date: 20250417 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 195 337 Nominal wavelengths inside fitting window [nm]: 305.0446 305.1851 305.3256 305.4661 305.6066 305.7470 305.8875 306.0279 306.1684 306.3088 306.4492 306.5896 306.7300 306.8704 307.0108 307.1511 307.2915 307.4318 307.5721 307.7125 307.8528 307.9930 308.1333 308.2736 308.4139 308.5541 308.6943 308.8346 308.9748 309.1150 309.2552 309.3954 309.5355 309.6757 309.8158 309.9560 310.0961 310.2362 310.3763 310.5164 310.6565 310.7966 310.9366 311.0767 311.2167 311.3567 311.4967 311.6367 311.7767 311.9167 312.0567 312.1966 312.3366 312.4765 312.6164 312.7563 312.8962 313.0361 313.1760 313.3159 313.4557 313.5955 313.7354 313.8752 314.0150 314.1548 314.2946 314.4344 314.5741 314.7139 314.8536 314.9934 315.1331 315.2728 315.4125 315.5522 315.6918 315.8315 315.9711 316.1108 316.2504 316.3900 316.5296 316.6692 316.8088 316.9484 317.0879 317.2275 317.3670 317.5065 317.6460 317.7855 317.9250 318.0645 318.2040 318.3434 318.4829 318.6223 318.7617 318.9011 319.0405 319.1799 319.3193 319.4587 319.5980 319.7373 319.8767 320.0160 320.1553 320.2946 320.4339 320.5731 320.7124 320.8516 320.9909 321.1301 321.2693 321.4085 321.5477 321.6869 321.8261 321.9652 322.1044 322.2435 322.3826 322.5217 322.6608 322.7999 322.9390 323.0780 323.2171 323.3561 323.4952 323.6342 323.7732 323.9122 324.0512 324.1901 324.3291 324.4680 324.6070 324.7459 324.8848 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250417T125505.5Z 9238.538259 238 1 54.88 2 77.20 85.35 76.91 223.19 0.00 1 0.00 1 0 33 9.250e-01 1.542e-01 3.176e-01 4.105e-02 5.960212e-01 2.479355e-02 9.324518e-03 -6.000000e+00 5.914171e-01 229.37 -2.00 3.31 -2.00 319.85 0.00e+00 1.569210e-02 6.093280e-03 6.284489e-03 -6.000000e+00 3.587028e-02 285.51 -2.00 20.00 -2.00 319.05 0.00e+00 4.394 0.001 302.00 328.00 3 6.4354e+00 6.9790e-02 5.5284e-02 -6.0000e+00 1.4847e+00 1.3730e+00 8.0105e-02 3.3193e-02 -6.0000e+00 1.6164e+00 -1.3234e+00 4.4984e-02 1.8023e-02 -6.0000e+00 9.6022e-01 4.3142e-01 2.2323e-02 7.9850e-03 -6.0000e+00 4.0715e-01 3.4986e-06 -1.8492e-03 1.4142e-03 2.8943e-04 -6.0000e+00 3.2897e-02 -7.0601e-03 0.0000e+00 12 9 8 11 8 0 99.99 29.71 1.07 -0.00706 -0.02096 57 6 2 5 0 962.750 37.75 20.00 29.71 25.10 3.5 982.35 10344 900000 900000 900000 900000 -13305 6272 14149 207613 900000 900000 45651 900000 900000 17204 900000 900000 900000 22095 900000 900000 900000 -20518 900000 -7654 61198 900000 -53477 17011 900000 900000 900000 162792 227267 321157 130682 900000 -8213 900000 240232 107199 186175 389083 263854 -5724 -12260 -55168 60246 133581 101396 -23094 11338 54563 92772 364486 59149 -14064 900000 7559 900000 69128 16720 53319 19027 -18123 141030 22010 270752 44141 13980 72557 34364 23997 -9395 15437 46049 -41341 82333 43857 188728 28855 12482 -8199 -11821 38627 24618 18762 36757 3379 -8662 84104 90990 -18453 43903 81988 -22708 28867 -18071 -15893 -505 -17631 11020 24218 -12532 -9142 -22013 -5031 -7923 26531 -20102 28499 11150 61 7273 -5784 86944 -13381 -2866 -871 1943 4090 32627 -7873 -8139 13042 13832 21464 -1233 -5079 -81 12959 3137 11390 -9247 -3726 5004 8082 3673 -5453 -3160 -6046 -7683 12975 3056 900000 900000 900000 900000 -3578 1228 2396 8271 900000 900000 5456 900000 900000 4299 900000 900000 900000 6482 900000 900000 900000 -7282 900000 -2107 7979 900000 -19367 2957 900000 900000 900000 8844 9054 12794 8992 900000 -2379 900000 9570 12424 10114 15500 10511 -2135 -4840 -33166 11346 12095 12853 -10538 3860 12647 15119 14520 13496 -6520 900000 2601 900000 13770 5928 14232 7029 -10108 17417 8593 10786 14068 6516 20234 14511 11090 -5726 6703 13208 -25857 14432 11881 13533 11725 6713 -5912 -9371 19389 14907 12557 21087 2706 -7591 27474 25737 -14629 18365 24823 -21983 19090 -21669 -20451 -575 -23039 9966 17559 -12581 -9105 -26308 -5351 -9217 23570 -31232 29860 14836 93 10054 -8686 49184 -20256 -3997 -1249 2841 5964 35225 -12326 -12321 15328 15485 21548 -1558 -7142 -120 18637 5361 18921 -19856 -8015 10426 16935 8210 -13448 -7478 -14067 -17201 22588 SS 20250417T141614.5Z 9238.594612 283 1 0.79 2 60.08 96.37 89.53 235.15 0.00 1 0.00 1 0 25 1.511e-02 9.947e-03 8.383e-03 4.337e-03 2.691234e-01 2.355725e-03 3.057884e-03 -6.000000e+00 9.405367e-03 229.38 -2.00 3.31 -2.00 316.03 0.00e+00 -3.623565e-05 2.613131e-04 5.047951e-05 -6.000000e+00 4.291692e-04 285.51 -2.00 20.00 -2.00 315.31 0.00e+00 1.996 0.000 302.00 328.00 3 2.9449e+00 6.1122e-03 2.3620e-02 -6.0000e+00 2.3411e-02 1.7165e-02 6.7872e-03 1.3085e-02 -6.0000e+00 2.5248e-02 -1.1492e-02 3.8958e-03 6.3889e-03 -6.0000e+00 1.5054e-02 8.5124e-04 1.7679e-03 1.7786e-03 -6.0000e+00 6.3281e-03 2.8132e-03 3.9496e-04 1.4118e-04 2.6281e-05 -6.0000e+00 5.0132e-04 -1.4010e-03 0.0000e+00 12 9 9 12 9 1 99.58 29.56 0.34 -0.00140 0.00157 3 29 1 5 0 195.390 37.75 20.01 29.56 26.41 3.4 991.41 -1698 -6609 -4549 -6967 3115 1434 -644 1411 -3339 1688 -641 2056 -1417 -1476 -148 115 135 310 -475 2851 -1027 2251 320 -296 1682 1138 -1095 -1126 1256 310 304 1845 34 -2733 -255 2687 346 443 1836 -849 -2424 -1494 11 -1003 -203 8 -1649 -414 737 772 -138 1860 2445 1113 1064 927 -453 6 64 1844 1828 839 1999 -668 -2181 -1122 1364 447 1747 1337 -380 -1212 -1507 -351 296 -422 501 1233 829 151 -278 -1170 -1713 -2109 -827 -1088 -946 -1148 -779 -1198 -391 1343 1005 1920 2210 1664 696 242 -430 -698 -866 -255 -283 937 137 -616 -909 -1262 -620 801 -191 -591 -559 -155 840 1336 1245 632 823 -294 -1235 -498 40 80 1158 1026 642 1974 1413 -138 -138 -226 153 -20 337 -212 -703 -20 -374 -886 187 -98 -470 -347 -1419 -975 -1482 615 276 -131 307 -769 389 -156 510 -397 -434 -48 38 48 114 -183 1101 -395 850 125 -121 712 500 -489 -486 508 124 125 800 15 -1276 -115 1249 164 228 1036 -537 -1637 -1016 7 -711 -143 5 -1160 -283 513 541 -97 1357 1802 872 829 743 -374 5 53 1475 1498 704 1778 -619 -2000 -1017 1180 379 1520 1230 -373 -1221 -1541 -346 283 -387 432 1041 714 137 -261 -1182 -1815 -2304 -918 -1251 -1149 -1405 -957 -1443 -454 1509 1081 2030 2305 1824 824 297 -551 -908 -1085 -315 -331 1116 168 -786 -1187 -1684 -840 1134 -273 -867 -807 -217 1144 1746 1586 828 1105 -412 -1765 -710 57 110 1550 1348 835 2493 1808 -185 -191 -326 219 -30 508 -330 -1113 -33 -597 -1407 292 -152 -712 SS 20250417T143339.4Z 9238.606706 292 1 3.85 2 56.43 99.00 92.49 237.38 0.00 1 0.00 1 0 17 1.347e-02 9.249e-03 7.299e-03 3.957e-03 2.437364e-01 2.156150e-03 2.842898e-03 -6.000000e+00 8.349489e-03 229.38 -2.00 3.31 -2.00 315.87 0.00e+00 -1.665893e-04 2.295141e-04 1.003143e-04 -6.000000e+00 3.823269e-04 285.51 -2.00 20.00 -2.00 315.15 0.00e+00 1.803 0.000 302.00 328.00 3 4.5225e+00 5.5835e-03 2.1434e-02 -6.0000e+00 2.0780e-02 3.1750e-02 6.1962e-03 1.2035e-02 -6.0000e+00 2.2444e-02 -3.7549e-03 3.5540e-03 5.8794e-03 -6.0000e+00 1.3380e-02 -2.3737e-03 1.5976e-03 1.6860e-03 -6.0000e+00 5.5950e-03 7.2329e-04 -3.6309e-03 1.2916e-04 2.5677e-05 -6.0000e+00 4.4722e-04 2.9593e-02 0.0000e+00 12 9 1 12 1 1 99.54 29.54 0.64 0.02959 0.00231 3 6 1 5 0 959.810 37.75 19.93 29.54 27.10 3.4 996.71 -5418 -2634 -901 -5292 850 -1002 243 -2390 -258 -3391 2318 2108 856 -213 -958 -1702 612 209 1354 525 1811 2032 -78 636 252 1541 -902 -1786 890 3807 2217 1314 1453 -2020 -1964 720 832 581 671 -1182 -2209 -1474 -834 -500 -1041 -978 -1358 338 -108 753 654 773 704 1597 -445 785 449 763 182 2203 1995 2072 876 -161 -1412 -430 1522 1245 1739 813 -858 -1321 -964 -737 -779 303 373 1127 1570 821 -1407 -1255 -2534 -838 -941 -511 -1150 40 -585 -997 625 1003 407 1461 1121 955 897 -210 -760 -1188 -1287 -684 568 837 71 -1592 -1013 64 -242 180 -32 -522 -195 103 108 1598 1375 1968 814 -40 -581 -108 -396 -228 105 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