File name: Pandora259s1_TylerTX_20250607_L2Fit_fout2c3d20230310p1-8.txt File generation date: 20250608T063458.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: James Flynn Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 259 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora259_OF_v4d20221229.txt Instrument calibration file used: Pandora259s1_CF_v3d20230310.txt Level 1 file used: Pandora259s1_TylerTX_20250607_L1_smca1c3d20230310p1-8.txt Full location name: Tyler Pounds Regional Airport Short location name: TylerTX Country of location: United States Location latitude [deg]: 32.3440 Location longitude [deg]: -95.4159 Location altitude [m]: 164 Local noon date: 20250607 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 195 337 Nominal wavelengths inside fitting window [nm]: 305.0446 305.1851 305.3256 305.4661 305.6066 305.7470 305.8875 306.0279 306.1684 306.3088 306.4492 306.5896 306.7300 306.8704 307.0108 307.1511 307.2915 307.4318 307.5721 307.7125 307.8528 307.9930 308.1333 308.2736 308.4139 308.5541 308.6943 308.8346 308.9748 309.1150 309.2552 309.3954 309.5355 309.6757 309.8158 309.9560 310.0961 310.2362 310.3763 310.5164 310.6565 310.7966 310.9366 311.0767 311.2167 311.3567 311.4967 311.6367 311.7767 311.9167 312.0567 312.1966 312.3366 312.4765 312.6164 312.7563 312.8962 313.0361 313.1760 313.3159 313.4557 313.5955 313.7354 313.8752 314.0150 314.1548 314.2946 314.4344 314.5741 314.7139 314.8536 314.9934 315.1331 315.2728 315.4125 315.5522 315.6918 315.8315 315.9711 316.1108 316.2504 316.3900 316.5296 316.6692 316.8088 316.9484 317.0879 317.2275 317.3670 317.5065 317.6460 317.7855 317.9250 318.0645 318.2040 318.3434 318.4829 318.6223 318.7617 318.9011 319.0405 319.1799 319.3193 319.4587 319.5980 319.7373 319.8767 320.0160 320.1553 320.2946 320.4339 320.5731 320.7124 320.8516 320.9909 321.1301 321.2693 321.4085 321.5477 321.6869 321.8261 321.9652 322.1044 322.2435 322.3826 322.5217 322.6608 322.7999 322.9390 323.0780 323.2171 323.3561 323.4952 323.6342 323.7732 323.9122 324.0512 324.1901 324.3291 324.4680 324.6070 324.7459 324.8848 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250607T133709.2Z 9289.567468 190 1 54.08 2 62.45 79.22 151.34 296.53 0.00 1 0.00 1 0 25 7.358e-02 1.635e-02 1.120e-02 3.237e-03 2.719268e-01 1.759036e-03 3.089315e-03 -6.000000e+00 4.607815e-02 231.57 -2.00 3.31 -2.00 317.31 0.00e+00 4.118926e-04 2.687611e-04 9.607987e-05 -6.000000e+00 2.127170e-03 289.89 -2.00 20.00 -2.00 316.45 0.00e+00 2.150 0.000 302.00 328.00 3 6.2112e+00 4.6779e-03 2.5102e-02 -6.0000e+00 1.1513e-01 6.2666e-02 5.2404e-03 1.3549e-02 -6.0000e+00 1.2396e-01 -2.1990e-03 3.1241e-03 6.5637e-03 -6.0000e+00 7.3964e-02 -9.5362e-03 1.5091e-03 1.8145e-03 -6.0000e+00 3.1029e-02 9.0234e-05 -4.3871e-04 1.0756e-04 2.4995e-05 -6.0000e+00 2.4439e-03 1.2132e-02 0.0000e+00 12 8 8 10 0 0 100.00 29.07 1.30 0.01213 0.00884 28 3 1 5 0 1931.220 37.25 19.96 29.07 32.63 3.4 1034.17 -25913 17980 4058 1183 48130 -18024 -17433 -14469 -8164 4434 32182 -9585 4463 347 -13584 7027 12003 18281 -4798 20290 4274 3280 -5620 -35 -2834 -909 1869 -9156 -2781 2346 15735 5299 133 -1947 1055 3018 4378 -4202 4314 -1262 -571 -775 1363 -1909 -3236 -3968 -4475 -181 1162 211 -2156 -1846 1007 1652 1807 185 -1561 4511 -1231 7582 2535 789 1768 -954 -2425 73 1488 2760 2354 241 -409 -601 -1022 -2026 -824 853 -2129 1942 898 4231 -1433 -1170 -1906 -2333 263 269 50 654 -789 -1891 2327 1993 -1217 2230 2378 25 1669 -1426 -1440 -1492 -1244 -572 668 -26 -171 -2186 -1331 -881 1115 -248 851 457 -994 333 269 2904 -206 963 -176 -560 -930 932 -928 -432 617 1520 919 1080 696 66 663 -475 547 -60 -197 -453 38 455 -469 -748 -369 -516 498 -3297 1601 423 123 2963 -2071 -2058 -1818 -1052 529 2997 -1425 633 58 -2950 1358 2349 3515 -1207 4112 1040 817 -1556 -10 -837 -271 537 -2841 -780 615 3726 1494 42 -643 335 940 1436 -1568 1735 -615 -304 -440 782 -1147 -1978 -2434 -2722 -104 648 120 -1303 -1181 665 1136 1285 126 -1097 3257 -855 5255 1737 583 1385 -809 -2108 59 1122 2002 1789 205 -381 -590 -1017 -1980 -749 698 -1637 1484 708 3228 -1290 -1158 -1893 -2470 289 314 62 832 -951 -2419 2686 2125 -1237 2277 2493 27 1947 -1751 -1883 -1970 -1569 -720 787 -31 -215 -2766 -1755 -1213 1581 -377 1258 694 -1503 504 379 3728 -266 1261 -247 -836 -1442 1421 -1412 -632 851 1976 1239 1435 965 91 962 -724 847 -97 -311 -757 65 798 -840 -1326 -633 -854 796 SS 20250607T134156.5Z 9289.570793 193 1 9.03 2 61.45 79.76 152.21 297.94 0.00 1 0.00 1 0 25 3.131e-02 1.115e-02 1.349e-02 5.442e-03 2.658898e-01 2.951663e-03 3.001877e-03 -6.000000e+00 1.961578e-02 231.57 -2.00 3.31 -2.00 316.63 0.00e+00 -6.357912e-04 3.814242e-04 1.380778e-04 -6.000000e+00 9.050075e-04 289.89 -2.00 20.00 -2.00 315.79 0.00e+00 2.082 0.000 302.00 328.00 3 5.4257e+00 7.7606e-03 2.4332e-02 -6.0000e+00 4.9014e-02 4.5676e-02 8.6623e-03 1.3170e-02 -6.0000e+00 5.2759e-02 -5.3314e-03 5.0237e-03 6.3422e-03 -6.0000e+00 3.1481e-02 -2.0674e-03 2.3413e-03 1.7960e-03 -6.0000e+00 1.3217e-02 2.1584e-04 5.8969e-04 1.7838e-04 2.5296e-05 -6.0000e+00 1.0397e-03 7.5261e-03 0.0000e+00 12 9 9 12 1 1 999.00 29.05 0.55 0.00753 0.01196 2 2 1 5 0 3009.760 37.25 19.94 29.05 32.73 3.4 1034.72 -14554 1608 3283 2718 17663 -14739 -7870 -6331 1713 2679 4055 -2619 -2374 911 -5738 582 2973 8056 -4634 7194 2665 3436 -1844 -654 -2205 -1446 -786 -4136 2382 4002 3350 1788 -254 -2396 -1108 3654 2495 -26 159 -549 -1649 -485 2691 -1425 -2048 -2446 -1759 -1461 241 1020 51 -300 1347 937 929 314 -832 1301 -48 4341 3442 243 1263 -353 -1802 -654 1883 1882 2287 367 13 -288 -1662 -742 -1012 389 251 1229 486 799 -1316 -1837 -1997 -1882 534 189 -1034 -291 -312 -1040 125 1444 661 1734 2252 677 779 -873 -1022 -1178 -781 -1118 221 578 198 -1607 -517 -1165 76 62 657 430 -334 607 -220 1574 609 863 96 -253 -526 83 -489 -252 966 744 490 1245 861 -83 685 -103 -62 -80 -26 -74 -311 388 -366 -777 -342 -583 347 -2356 239 486 391 2072 -2307 -1194 -1042 284 463 712 -516 -463 194 -1462 151 800 2149 -1455 2076 823 1068 -616 -225 -815 -546 -292 -1532 793 1286 1114 645 -99 -978 -442 1391 1028 -12 83 -305 -1022 -316 1748 -976 -1413 -1684 -1184 -961 154 651 34 -199 931 682 701 245 -667 1022 -38 3271 2682 193 1062 -317 -1656 -569 1608 1568 1849 332 12 -281 -1659 -714 -979 340 214 987 402 671 -1258 -1822 -2138 -2011 593 225 -1240 -359 -386 -1262 149 1568 709 1769 2350 732 929 -1097 -1368 -1591 -1006 -1348 264 692 238 -2085 -697 -1570 106 87 965 647 -497 889 -301 2097 801 1160 130 -365 -750 124 -720 -358 1288 1000 631 1571 1134 -111 964 -151 -93 -118 -40 -115 -503 638 -613 -1289 -548 -949 546 SS 20250607T142647.1Z 9289.601934 218 1 54.44 2 52.07 84.94 159.62 315.70 0.00 1 0.00 1 0 25 1.186e-02 8.886e-03 1.523e-04 1.046e-04 2.064230e-01 5.763386e-05 2.351423e-03 -6.000000e+00 7.426199e-03 231.57 -2.00 3.31 -2.00 314.96 0.00e+00 -8.819289e-06 5.191153e-06 3.356787e-05 -6.000000e+00 3.427048e-04 289.89 -2.00 20.00 -2.00 314.26 0.00e+00 1.623 0.000 302.00 328.00 3 5.0713e-01 1.4857e-04 1.8913e-02 -6.0000e+00 1.8556e-02 7.3072e-03 1.6401e-04 1.0130e-02 -6.0000e+00 1.9975e-02 -3.6691e-03 9.3585e-05 4.9091e-03 -6.0000e+00 1.1919e-02 -3.2078e-04 4.0511e-05 1.3516e-03 -6.0000e+00 5.0027e-03 5.1727e-02 1.0299e-04 3.4240e-06 2.1493e-05 -6.0000e+00 3.9372e-04 9.3236e-03 0.0000e+00 11 8 0 10 0 0 99.99 28.94 0.37 0.00932 0.01010 3633 373 1 5 0 14.980 37.00 19.98 28.94 33.59 3.4 1041.48 -1790 -3510 -4312 -3771 402 2211 1133 1297 172 -1338 -450 2114 1375 633 211 -1128 -793 470 230 518 752 1470 1743 426 670 77 -1594 -815 2003 2882 1718 1384 642 -1880 -939 1836 928 991 615 -1577 -2302 -1326 -1031 -1303 -714 -725 -1024 -465 198 938 1210 689 897 652 -35 535 620 194 829 1442 1651 1513 676 -476 -1279 -472 948 1055 2140 1112 -733 -991 -1160 -747 -644 -21 805 1188 1490 395 -980 -1517 -2056 -1389 -773 -1079 -735 -548 -799 -771 5 620 752 1789 2003 1050 580 16 -943 -900 -324 -375 479 1261 -66 -1170 -563 -553 -361 205 -212 -466 -395 -11 404 1035 1340 925 552 -182 -682 -353 -91 -25 487 924 662 1513 1141 248 202 -251 -96 281 246 -237 -322 42 -392 -506 -207 -415 -468 -602 -1208 -1504 -1255 128 662 352 439 60 -495 -168 794 528 258 96 -529 -389 224 113 261 385 755 904 221 363 43 -893 -435 1038 1437 879 749 352 -1070 -521 986 535 599 402 -1158 -1736 -1048 -808 -1033 -564 -587 -815 -358 153 720 921 555 735 541 -30 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