File name: Pandora259s1_TylerTX_20250708_L2Fit_fout2c3d20230310p1-8.txt File generation date: 20250709T064125.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: James Flynn Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 259 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora259_OF_v4d20221229.txt Instrument calibration file used: Pandora259s1_CF_v3d20230310.txt Level 1 file used: Pandora259s1_TylerTX_20250708_L1_smca1c3d20230310p1-8.txt Full location name: Tyler Pounds Regional Airport Short location name: TylerTX Country of location: United States Location latitude [deg]: 32.3440 Location longitude [deg]: -95.4159 Location altitude [m]: 164 Local noon date: 20250708 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 195 337 Nominal wavelengths inside fitting window [nm]: 305.0446 305.1851 305.3256 305.4661 305.6066 305.7470 305.8875 306.0279 306.1684 306.3088 306.4492 306.5896 306.7300 306.8704 307.0108 307.1511 307.2915 307.4318 307.5721 307.7125 307.8528 307.9930 308.1333 308.2736 308.4139 308.5541 308.6943 308.8346 308.9748 309.1150 309.2552 309.3954 309.5355 309.6757 309.8158 309.9560 310.0961 310.2362 310.3763 310.5164 310.6565 310.7966 310.9366 311.0767 311.2167 311.3567 311.4967 311.6367 311.7767 311.9167 312.0567 312.1966 312.3366 312.4765 312.6164 312.7563 312.8962 313.0361 313.1760 313.3159 313.4557 313.5955 313.7354 313.8752 314.0150 314.1548 314.2946 314.4344 314.5741 314.7139 314.8536 314.9934 315.1331 315.2728 315.4125 315.5522 315.6918 315.8315 315.9711 316.1108 316.2504 316.3900 316.5296 316.6692 316.8088 316.9484 317.0879 317.2275 317.3670 317.5065 317.6460 317.7855 317.9250 318.0645 318.2040 318.3434 318.4829 318.6223 318.7617 318.9011 319.0405 319.1799 319.3193 319.4587 319.5980 319.7373 319.8767 320.0160 320.1553 320.2946 320.4339 320.5731 320.7124 320.8516 320.9909 321.1301 321.2693 321.4085 321.5477 321.6869 321.8261 321.9652 322.1044 322.2435 322.3826 322.5217 322.6608 322.7999 322.9390 323.0780 323.2171 323.3561 323.4952 323.6342 323.7732 323.9122 324.0512 324.1901 324.3291 324.4680 324.6070 324.7459 324.8848 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250708T122431.2Z 9320.517028 152 1 45.38 2 78.70 70.52 128.87 257.88 0.00 1 0.00 1 0 25 5.948e-01 2.394e-02 2.063e-01 5.745e-03 5.948883e-01 3.322193e-03 8.148756e-03 -6.000000e+00 3.779805e-01 231.25 -2.00 3.31 -2.00 320.52 0.00e+00 1.081229e-02 1.384657e-03 6.528460e-03 -6.000000e+00 2.193668e-02 292.15 -2.00 20.00 -2.00 319.79 0.00e+00 4.927 0.002 302.00 328.00 3 3.9386e+00 1.0604e-02 6.2492e-02 -6.0000e+00 9.4808e-01 2.5971e-01 1.3491e-02 4.5199e-02 -6.0000e+00 1.0262e+00 -2.3100e-01 1.1449e-02 2.4262e-02 -6.0000e+00 6.1064e-01 7.8904e-02 5.6801e-03 7.4075e-03 -6.0000e+00 2.5830e-01 3.9262e-05 -2.3873e-04 1.8299e-04 1.7486e-04 -6.0000e+00 2.0364e-02 1.1742e-02 0.0000e+00 12 9 9 12 1 1 99.12 28.95 0.73 0.01174 0.00995 12 2 1 5 0 3490.560 37.00 20.01 28.95 32.25 3.5 1030.11 -165472 900000 900000 900000 900000 -184543 -113737 -173823 -31407 900000 900000 -60247 234609 -1454 -85552 298154 900000 900000 -53132 900000 295619 135347 -17968 105198 -49984 -18733 900000 -50579 -43579 4700 900000 201834 14429 6755 77119 33225 35445 -19398 29507 -2767 18176 8 22789 9871 -7402 -6575 -6018 5773 12204 5566 -6180 4812 4955 10179 10638 700 -8807 22060 -5401 27275 9477 1214 5110 2606 687 9413 12359 9649 8237 -2197 2108 -1921 -3446 -4818 -2797 2822 -9201 2301 744 8003 -936 -3662 -2128 -4286 380 2588 -1 868 -3663 -2479 3635 5060 -3219 221 3309 -1714 2929 -3059 -3084 -1704 -2908 -471 1224 -1731 -159 -4211 -2296 -1638 2525 -1729 1588 -640 -969 836 545 4798 -58 3184 97 -240 -211 2340 105 -1091 1357 1036 1258 765 735 906 561 -680 220 -644 -382 -255 -364 674 -855 -703 -49 -1231 936 -4373 900000 900000 900000 900000 -6753 -2081 -6184 -287 900000 900000 -949 1312 -22 -3391 1667 900000 900000 -2703 900000 1653 1135 -703 1235 -2878 -806 900000 -3026 -2509 181 900000 1467 774 415 2371 1597 1783 -1941 2128 -317 1880 1 2574 1319 -1212 -1099 -1030 907 1876 971 -1316 1009 1130 2356 2569 193 -2703 4958 -1579 5764 2490 377 1703 980 253 3505 4408 3603 3361 -1007 1013 -1007 -1832 -2485 -1311 1256 -3919 959 341 3575 -530 -2416 -1519 -3352 302 2136 -1 725 -3217 -2094 2982 3832 -2528 169 2655 -1507 2825 -3548 -3599 -2006 -3603 -525 1242 -1775 -168 -4895 -2773 -2100 3106 -2445 2377 -1038 -1483 1317 821 6627 -83 4572 151 -392 -349 3700 164 -1665 1937 1426 1680 1041 1086 1483 940 -1236 418 -1213 -762 -535 -792 1479 -1912 -1532 -100 -2440 1874 SS 20250708T122938.8Z 9320.520588 155 1 14.02 2 77.68 71.13 129.88 258.36 0.00 1 0.00 1 0 25 2.959e-01 1.729e-02 9.124e-02 6.026e-03 5.562624e-01 3.319320e-03 6.587124e-03 -6.000000e+00 1.852544e-01 231.25 -2.00 3.31 -2.00 319.92 0.00e+00 6.342089e-03 1.119108e-03 3.024835e-03 -6.000000e+00 8.915775e-03 292.15 -2.00 20.00 -2.00 319.11 0.00e+00 4.549 0.001 302.00 328.00 3 3.4565e+00 9.8585e-03 5.3498e-02 -6.0000e+00 4.6193e-01 2.1058e-01 1.1996e-02 3.0716e-02 -6.0000e+00 4.9724e-01 -2.2955e-01 9.2427e-03 1.7036e-02 -6.0000e+00 2.9726e-01 8.6522e-02 4.6838e-03 6.0601e-03 -6.0000e+00 1.2586e-01 9.8697e-05 -2.4703e-04 1.8754e-04 9.5131e-05 -6.0000e+00 9.8771e-03 9.1478e-03 0.0000e+00 12 9 9 12 33 1 89.03 29.00 0.16 0.00915 0.00729 7 3 1 5 0 1752.180 37.00 20.01 29.00 32.35 3.5 1030.65 -146414 900000 -26267 900000 -66027 -121577 -82656 -113899 -95619 -37763 2874 -68570 -47368 -26065 -55553 19447 89959 102024 -37546 81133 7071 12918 -2352 4676 -27990 -41259 1611 -25427 -12641 -6125 44232 27420 -2290 -349 23534 155 11664 -3609 7426 -4028 2404 9104 13436 2404 -1554 1548 418 5378 10242 5123 -1461 2749 8914 4263 6086 1658 -553 10178 -539 9849 4240 -563 4709 1942 -234 4616 3010 4791 1355 -1703 -987 1937 -1572 -2218 -1513 426 -2826 3597 -859 3128 -2595 -1911 -2607 -2992 -1060 216 -1122 -184 -1694 -41 2265 1043 -1821 343 165 -1235 505 -1674 -1420 -2460 -1480 -1302 230 13 -754 -2903 -1439 -705 1322 540 811 -164 -168 1326 736 1983 448 1663 434 176 -408 1295 376 -571 452 512 659 1124 1472 314 444 -205 528 -220 -337 -480 -234 478 -327 -883 -6 -433 -555 -6255 900000 -407 900000 -1590 -4480 -2331 -4750 -3595 -843 46 -2497 -1669 -919 -3198 617 1585 1738 -2757 1906 357 622 -134 258 -2253 -3902 99 -2046 -906 -435 2131 1804 -227 -36 1922 16 1158 -481 1047 -736 459 1754 2605 537 -335 363 92 1264 2370 1195 -393 777 2575 1379 2031 598 -208 3435 -200 3287 1547 -233 2042 947 -122 2295 1492 2364 681 -982 -619 1239 -1044 -1424 -897 226 -1573 1855 -456 1821 -1844 -1409 -2125 -2626 -972 208 -1072 -180 -1689 -39 2155 939 -1604 296 153 -1220 559 -1997 -1838 -3289 -1883 -1528 265 14 -900 -3511 -1814 -941 1748 790 1289 -262 -271 2046 1154 2930 665 2509 698 280 -663 2037 578 -909 682 743 925 1586 2232 501 773 -362 973 -430 -663 -996 -501 986 -684 -1814 -13 -846 -1107 SS 20250708T123439.5Z 9320.524068 158 1 54.17 2 76.68 71.72 130.87 258.84 0.00 1 0.00 1 0 25 2.262e-01 9.690e-03 6.695e-02 1.610e-03 5.328415e-01 8.781096e-04 5.870642e-03 -6.000000e+00 1.415000e-01 231.25 -2.00 3.31 -2.00 319.51 0.00e+00 2.960268e-03 2.630491e-04 7.262342e-04 -6.000000e+00 6.600309e-03 292.15 -2.00 20.00 -2.00 318.68 0.00e+00 4.230 0.001 302.00 328.00 3 2.7969e+00 2.5339e-03 4.9293e-02 -6.0000e+00 3.5300e-01 9.7095e-02 3.0160e-03 2.6619e-02 -6.0000e+00 3.7996e-01 -8.3720e-02 2.3088e-03 1.3493e-02 -6.0000e+00 2.2710e-01 2.3935e-02 1.1967e-03 4.7120e-03 -6.0000e+00 9.5607e-02 2.7105e-04 -3.4008e-04 4.9912e-05 5.8955e-05 -6.0000e+00 7.5114e-03 1.0309e-02 0.0000e+00 12 9 8 11 8 0 99.91 29.05 0.51 0.01031 0.00775 94 10 1 5 0 576.180 37.25 20.01 29.05 32.41 3.5 1031.70 -100366 -14177 -20142 -47443 172502 -81124 -67062 -60893 -45727 -9808 56712 -32921 -18913 -15084 -34544 5511 24553 22613 -14276 29585 2112 1394 -12769 -6135 -8408 -10990 -7865 -17487 -8754 -3548 18539 8980 -2650 -3597 -1585 -1286 4691 -6296 6233 -1083 -3054 -1613 1808 1936 -2019 -1778 -4406 1933 2619 2968 -156 428 3044 2672 1922 1049 -1135 1917 -378 5110 2421 2593 1813 596 -154 1185 1697 2555 2215 849 195 -516 -631 -917 -643 266 -454 952 504 1464 -1040 -1514 -2321 -1665 -867 -646 -596 -365 -867 -1003 1060 1535 -22 1178 1572 474 558 -535 -1227 -1041 -702 -483 542 668 -621 -2108 -801 -653 218 -63 212 -166 -456 364 395 1713 761 1022 251 -341 -475 71 -33 -306 436 639 681 1490 946 38 217 -343 151 29 -33 -276 -289 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