File name: Pandora255s1_VirginiaBeachVA-CBBT_20240626_L2Fit_fout2c1d20230302p1-8.txt File generation date: 20240628T120815.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: John Anderson Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 255 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora255_OF_v2d20221206.txt Instrument calibration file used: Pandora255s1_CF_v1d20230302.txt Level 1 file used: Pandora255s1_VirginiaBeachVA-CBBT_20240626_L1_smca1c1d20230302p1-8.txt Full location name: Chesapeake Bay Bridge Tunnel Virginia Short location name: VirginiaBeachVA-CBBT Country of location: United States Location latitude [deg]: 37.0367 Location longitude [deg]: -76.0766 Location altitude [m]: 20 Local noon date: 20240626 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Initial lab analysis + OoB session, absolute calibration done with an uncalibrated lamp, certificate of FEL1441 (GSFC) used First and last pixel inside fitting window: 194 335 Nominal wavelengths inside fitting window [nm]: 305.1041 305.2451 305.3862 305.5272 305.6682 305.8092 305.9502 306.0911 306.2321 306.3730 306.5140 306.6549 306.7958 306.9367 307.0776 307.2185 307.3593 307.5002 307.6410 307.7819 307.9227 308.0635 308.2043 308.3451 308.4858 308.6266 308.7674 308.9081 309.0488 309.1896 309.3303 309.4710 309.6116 309.7523 309.8930 310.0336 310.1743 310.3149 310.4555 310.5961 310.7367 310.8773 311.0178 311.1584 311.2989 311.4395 311.5800 311.7205 311.8610 312.0015 312.1420 312.2824 312.4229 312.5633 312.7038 312.8442 312.9846 313.1250 313.2654 313.4057 313.5461 313.6864 313.8268 313.9671 314.1074 314.2477 314.3880 314.5283 314.6686 314.8088 314.9491 315.0893 315.2295 315.3697 315.5099 315.6501 315.7903 315.9304 316.0706 316.2107 316.3509 316.4910 316.6311 316.7712 316.9112 317.0513 317.1914 317.3314 317.4715 317.6115 317.7515 317.8915 318.0315 318.1714 318.3114 318.4514 318.5913 318.7312 318.8712 319.0111 319.1510 319.2908 319.4307 319.5706 319.7104 319.8502 319.9901 320.1299 320.2697 320.4095 320.5492 320.6890 320.8288 320.9685 321.1082 321.2479 321.3876 321.5273 321.6670 321.8067 321.9464 322.0860 322.2256 322.3653 322.5049 322.6445 322.7841 322.9236 323.0632 323.2027 323.3423 323.4818 323.6213 323.7608 323.9003 324.0398 324.1793 324.3187 324.4582 324.5976 324.7370 324.8764 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240626T103935.6Z 8943.444162 196 1 54.39 2 81.37 67.22 55.78 207.74 0.00 1 0.00 1 0 17 5.896e-01 5.070e-02 1.905e-01 3.648e-03 8.773415e-01 2.226679e-03 1.017045e-02 -6.000000e+00 3.645822e-01 232.72 -2.00 3.43 -2.00 321.37 0.00e+00 -2.473888e-03 1.149346e-03 4.630848e-03 -6.000000e+00 1.954849e-02 289.90 -2.00 20.00 -2.00 320.82 0.00e+00 6.280 0.004 302.00 328.00 3 1.7269e+00 7.8380e-03 8.2260e-02 -6.0000e+00 9.2357e-01 3.2156e-01 1.1753e-02 5.8603e-02 -6.0000e+00 9.9967e-01 -4.1609e-01 1.2325e-02 2.6182e-02 -6.0000e+00 5.8222e-01 1.5923e-01 5.7164e-03 9.1740e-03 -6.0000e+00 2.5696e-01 7.2292e-05 -2.1499e-03 9.7470e-05 9.1771e-05 -6.0000e+00 1.7420e-02 -6.8219e-02 0.0000e+00 12 8 8 10 0 0 63.80 25.27 0.65 -0.06822 -0.08437 73 7 1 5 0 744.990 33.25 20.00 25.27 28.96 4.8 1097.96 900000 900000 900000 -251033 -327015 900000 900000 -237054 900000 900000 900000 900000 -211045 -161647 -107520 900000 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-583 866 205 1313 919 814 2001 1241 -349 2232 -874 500 1713 3141 721 180 59 -1173 -683 610 -260 647 -1015 -707 -2069 -1942 75 1822 -424 157 -303 -1034 168 -439 -1263 -2789 -2470 844 -1521 -2380 -1385 -20 498 850 -1514 -3717 -4309 -2639 -2006 53451 -2948 -2516 -1267 -39 480 1023 1342 1951 1269 266 1185 1391 -774 -860 345 -428 -1565 -190 -993 -85 -237 -638 -1467 -698 194 -454 -229 552 1235 -475 949 -1025 308 SS 20240626T105118.4Z 8943.452297 200 1 54.84 2 79.20 68.83 56.85 210.83 0.00 1 0.00 1 0 17 4.401e-01 8.784e-03 6.042e-02 1.581e-03 7.208851e-01 8.741293e-04 8.180954e-03 -6.000000e+00 2.648176e-01 232.72 -2.00 3.43 -2.00 320.48 0.00e+00 1.140689e-03 3.497757e-04 1.489658e-03 -6.000000e+00 1.173138e-02 289.91 -2.00 20.00 -2.00 319.81 0.00e+00 5.136 0.002 302.00 328.00 3 1.5058e+00 2.7140e-03 6.4138e-02 -6.0000e+00 6.6445e-01 9.3050e-02 3.5493e-03 3.8833e-02 -6.0000e+00 7.1306e-01 -1.5642e-01 3.3578e-03 1.9678e-02 -6.0000e+00 4.2483e-01 5.9187e-02 1.6752e-03 5.7031e-03 -6.0000e+00 1.8391e-01 3.2479e-04 -5.1814e-04 4.1690e-05 6.9088e-05 -6.0000e+00 1.2472e-02 -6.8743e-02 0.0000e+00 11 8 0 10 0 0 60.19 25.27 0.41 -0.06874 -0.07264 177 17 1 5 0 309.780 33.25 20.00 25.27 29.61 4.8 1100.00 -174340 -93250 -155463 -141964 -191147 -115314 -113972 -159619 -102766 -83433 -110326 -114327 -113453 -90623 -79057 -28727 -60204 31751 -51736 -24935 26410 -36130 -20505 -22010 -22779 -31858 -37989 -15960 -40679 -31688 -26100 -14085 1083 -8358 -9986 -13338 19258 -7586 -12370 -587 6369 -6062 -969 1728 -51 5489 5215 3 485 4897 1223 5102 769 1443 2272 2159 1666 820 2989 -180 3261 1576 3121 4278 1934 2659 2434 1133 2709 1470 1240 874 2173 1732 475 135 -1207 -1981 53 -900 -686 -1288 -2008 -1910 -1056 -338 828 -267 125 221 248 434 147 -71 -470 -815 487 -71 -693 -666 -616 -671 161 -448 -915 -1622 -951 -445 -553 216 123 -108 76 268 394 645 610 630 372 -3 68 -62 304 441 323 32 552 1235 766 283 71 -176 -231 12 -256 -216 -38 301 -292 -145 -374 -171 -1637 -470 -1612 -1293 -2679 -818 -861 -2190 -919 -682 -1275 -1568 -1941 -1606 -1596 -430 -1429 338 -1396 -550 362 -941 -480 -577 -664 -1090 -1423 -472 -1530 -1172 -1086 -634 49 -457 -551 -757 861 -529 -1119 -57 666 -783 -126 226 -7 719 705 1 76 794 209 952 167 341 572 574 462 231 803 -49 879 473 1053 1482 735 1003 915 449 1169 740 643 479 1170 888 245 63 -532 -892 26 -492 -443 -893 -1555 -1582 -866 -294 749 -251 117 200 211 346 122 -57 -424 -805 520 -87 -891 -866 -754 -786 171 -476 -1043 -1977 -1150 -575 -745 310 197 -175 125 429 629 986 938 1012 603 -5 114 -100 493 690 488 47 819 1805 1210 487 130 -344 -458 25 -558 -476 -85 686 -666 -318 -801 -357 SS 20240626T110138.7Z 8943.459476 203 1 54.78 2 77.27 70.24 57.88 213.47 0.00 1 0.00 1 0 25 2.483e-01 7.266e-03 2.161e-02 9.344e-04 6.355333e-01 5.063096e-04 7.206757e-03 -6.000000e+00 1.494267e-01 232.72 -2.00 3.43 -2.00 319.81 0.00e+00 1.888428e-03 1.613604e-04 7.896144e-04 -6.000000e+00 6.619538e-03 289.91 -2.00 20.00 -2.00 319.08 0.00e+00 4.413 0.001 302.00 328.00 3 1.3063e+00 1.4713e-03 5.5369e-02 -6.0000e+00 3.7492e-01 5.7244e-02 1.7894e-03 3.3268e-02 -6.0000e+00 4.0235e-01 -1.0493e-01 1.5421e-03 1.6798e-02 -6.0000e+00 2.3971e-01 3.9574e-02 8.0599e-04 5.2476e-03 -6.0000e+00 1.0377e-01 8.5297e-04 -3.7497e-04 2.5111e-05 5.5284e-05 -6.0000e+00 7.0371e-03 -6.8948e-02 0.0000e+00 11 8 0 10 0 0 69.35 25.28 0.35 -0.06895 -0.07177 306 30 1 5 0 179.000 33.25 20.00 25.28 29.84 4.8 1100.00 -88151 -67843 -79635 -75611 -101902 -91618 -70148 -100532 -69080 -63782 -60140 -55776 -60016 -46356 -26166 -13422 -20105 -335 -16324 -14580 -2634 -12360 -12687 -9310 -12169 -14067 -16813 -8599 -16012 -12914 -11384 -4556 -997 -2778 -6512 -9600 -996 -4025 -3616 -191 1385 -583 664 -130 553 1355 2229 560 -127 1862 922 2054 1481 1601 2007 1481 1268 334 1499 652 1577 1925 2716 2938 1595 1696 1764 486 1345 1137 520 636 639 311 -128 87 -868 -1155 -636 -1051 -767 -1674 -2129 -1718 -1098 -785 -49 -205 82 419 368 609 206 452 28 -260 172 137 -283 -633 -538 -569 -2 51 -936 -1326 -649 -484 -91 114 28 -23 -6 49 396 882 860 497 216 -173 -228 -81 224 337 457 282 492 1185 621 109 64 -200 -60 151 -106 -175 -105 166 -285 -212 -292 -302 -996 -748 -1081 -985 -1616 -1277 -844 -1869 -1070 -1029 -997 -991 -1373 -1183 -687 -374 -685 -10 -650 -607 -101 -529 -569 -439 -645 -810 -1020 -472 -932 -773 -782 -350 -86 -264 -634 -954 -99 -488 -488 -30 244 -114 135 -27 118 292 487 128 -31 471 260 589 471 554 739 574 509 126 590 255 628 769 1219 1475 798 838 920 245 737 668 342 439 439 204 -78 51 -475 -635 -385 -700 -559 -1325 -1864 -1509 -1024 -780 -48 -209 84 410 356 548 189 398 28 -279 202 167 -378 -853 -683 -685 -3 59 -1113 -1681 -823 -655 -128 170 45 -37 -9 76 608 1342 1312 763 340 -284 -373 -129 354 514 695 413 727 1727 975 186 115 -371 -113 289 -217 -365 -219 349 -600 -444 -598 -581 SS 20240626T111135.9Z 8943.466388 206 1 54.77 2 75.39 71.58 58.95 215.94 0.00 1 0.00 1 0 25 1.463e-01 6.833e-03 8.684e-03 6.042e-04 5.654441e-01 3.229629e-04 6.462225e-03 -6.000000e+00 8.802602e-02 232.72 -2.00 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