File name: Pandora255s1_VirginiaBeachVA-CBBT_20240722_L2Fit_fout2c3d20240302p1-8.txt File generation date: 20241220T094413.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: John Anderson Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 255 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora255_OF_v2d20221206.txt Instrument calibration file used: Pandora255s1_CF_v3d20240302.txt Level 1 file used: Pandora255s1_VirginiaBeachVA-CBBT_20240722_L1_smca1c3d20240302p1-8.txt Full location name: Chesapeake Bay Bridge Tunnel Virginia Short location name: VirginiaBeachVA-CBBT Country of location: United States Location latitude [deg]: 37.0367 Location longitude [deg]: -76.0766 Location altitude [m]: 20 Local noon date: 20240722 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 195 336 Nominal wavelengths inside fitting window [nm]: 305.1318 305.2728 305.4137 305.5546 305.6955 305.8364 305.9773 306.1182 306.2590 306.3999 306.5407 306.6815 306.8224 306.9632 307.1040 307.2447 307.3855 307.5263 307.6670 307.8078 307.9485 308.0892 308.2299 308.3706 308.5113 308.6520 308.7926 308.9333 309.0739 309.2146 309.3552 309.4958 309.6364 309.7770 309.9175 310.0581 310.1986 310.3392 310.4797 310.6202 310.7607 310.9012 311.0417 311.1822 311.3227 311.4631 311.6035 311.7440 311.8844 312.0248 312.1652 312.3056 312.4459 312.5863 312.7267 312.8670 313.0073 313.1476 313.2880 313.4282 313.5685 313.7088 313.8491 313.9893 314.1296 314.2698 314.4100 314.5502 314.6904 314.8306 314.9707 315.1109 315.2511 315.3912 315.5313 315.6714 315.8115 315.9516 316.0917 316.2318 316.3718 316.5119 316.6519 316.7920 316.9320 317.0720 317.2120 317.3519 317.4919 317.6319 317.7718 317.9117 318.0517 318.1916 318.3315 318.4714 318.6113 318.7511 318.8910 319.0308 319.1706 319.3105 319.4503 319.5901 319.7299 319.8696 320.0094 320.1492 320.2889 320.4286 320.5684 320.7081 320.8478 320.9874 321.1271 321.2668 321.4064 321.5461 321.6857 321.8253 321.9649 322.1045 322.2441 322.3837 322.5232 322.6628 322.8023 322.9418 323.0813 323.2208 323.3603 323.4998 323.6393 323.7787 323.9182 324.0576 324.1970 324.3364 324.4758 324.6152 324.7546 324.8940 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240722T152127.4Z 8969.639900 373 1 26.19 2 29.22 117.90 137.80 281.13 0.00 1 0.00 1 0 17 9.080e-03 7.174e-03 3.072e-03 2.257e-03 1.670424e-01 1.196283e-03 1.974265e-03 -6.000000e+00 5.363943e-03 232.30 -2.00 3.43 -2.00 314.62 0.00e+00 7.444397e-05 9.779036e-05 4.094071e-05 -6.000000e+00 2.433667e-04 291.71 -2.00 20.00 -2.00 313.92 0.00e+00 1.145 0.000 302.00 328.00 3 6.1510e+00 3.0800e-03 1.4351e-02 -6.0000e+00 1.3428e-02 4.3256e-02 3.4029e-03 8.5000e-03 -6.0000e+00 1.4499e-02 -8.5620e-03 1.9474e-03 4.1189e-03 -6.0000e+00 8.6505e-03 6.4386e-04 8.5017e-04 1.1240e-03 -6.0000e+00 3.6785e-03 3.0464e-04 1.5456e-04 6.5479e-05 1.5887e-05 -6.0000e+00 2.5881e-04 4.0899e-02 0.0000e+00 12 9 1 12 1 1 99.97 24.08 0.26 0.04090 0.04206 6 1 1 5 0 3741.130 31.50 20.01 24.08 33.62 4.8 1100.00 34 89 -3510 -3028 1026 2070 -1907 -333 1096 993 -367 -1306 -976 -911 723 -438 1421 -623 528 1404 131 1560 1580 1709 -792 -1082 -169 -646 920 1663 1330 986 -719 -2044 -616 572 -858 -401 -305 -518 -650 -584 -567 -378 -630 -538 -893 -771 6 463 1316 192 654 415 667 1147 821 595 359 569 569 1780 966 -47 30 565 -42 1104 -56 -823 618 348 504 440 -79 -823 -404 -418 -995 -986 -1186 -1904 -1600 -1046 -1101 109 107 -244 5 -3 -145 347 925 -244 -412 1040 480 -126 -519 -246 -473 420 84 -559 -1522 -626 -232 2530 256 121 -17 61 -118 601 -36 313 465 -207 104 -145 -100 -180 355 512 288 -16 829 561 506 21 15 33 -120 -50 54 148 270 -298 203 -473 -588 -714 13 34 -1315 -1089 329 671 -708 -135 424 411 -153 -539 -446 -462 362 -229 741 -340 292 783 73 866 909 1026 -469 -639 -100 -354 473 859 725 570 -432 -1180 -337 328 -534 -277 -243 -427 -561 -487 -475 -333 -551 -459 -735 -610 4 365 1088 169 562 367 597 1035 742 530 318 515 546 1716 987 -48 29 511 -39 980 -56 -862 637 362 536 440 -75 -755 -343 -358 -889 -981 -1227 -2009 -1763 -1220 -1313 130 132 -303 6 -3 -163 368 922 -252 -440 1204 583 -156 -640 -299 -560 468 96 -663 -1939 -788 -303 3343 348 171 -24 84 -157 759 -43 363 559 -256 138 -191 -132 -242 455 650 348 -19 978 661 632 27 19 43 -159 -67 76 215 384 -431 287 -681 -821 -975 SS 20240722T161434.9Z 8969.676792 404 1 54.52 2 20.93 140.28 147.32 292.94 0.00 1 0.00 1 0 17 7.177e-03 5.872e-03 1.483e-03 1.142e-03 1.537512e-01 6.078623e-04 1.820120e-03 -6.000000e+00 4.240280e-03 232.30 -2.00 3.43 -2.00 314.37 0.00e+00 1.350521e-04 4.733196e-05 1.644171e-05 -6.000000e+00 1.923844e-04 291.71 -2.00 20.00 -2.00 313.71 0.00e+00 1.070 0.000 302.00 328.00 3 5.8190e+00 1.5628e-03 1.3340e-02 -6.0000e+00 1.0615e-02 2.5894e-02 1.7231e-03 7.8375e-03 -6.0000e+00 1.1461e-02 -3.7097e-03 9.8744e-04 3.7956e-03 -6.0000e+00 6.8383e-03 -1.6941e-04 4.2751e-04 1.0356e-03 -6.0000e+00 2.9079e-03 4.7229e-04 2.8022e-04 3.3320e-05 1.4854e-05 -6.0000e+00 2.0459e-04 4.0768e-02 0.0000e+00 11 1 0 11 40 0 99.98 24.14 0.18 0.04077 0.04287 33 3 1 5 0 1651.980 31.50 20.00 24.14 32.26 4.8 1100.00 -408 -1084 -1912 -2646 489 1226 -417 808 377 -385 -270 200 -53 346 -9 -696 1318 -19 428 1073 72 1657 1278 793 -319 -913 -143 -245 883 1401 1097 925 -622 -1983 -351 -267 -635 95 -732 -454 -955 -814 -1095 -602 -818 -578 -893 -738 84 273 706 537 889 527 647 762 477 639 529 985 1020 1343 1163 38 -308 4 447 953 298 -163 96 -15 355 140 -49 -125 -464 54 -188 -1025 -1526 -1723 -1409 -965 -758 0 -138 -87 152 125 230 213 729 245 194 606 476 -351 -383 -39 -301 132 13 -627 -1155 -471 -192 -281 532 223 146 145 41 177 376 504 264 195 156 -382 -260 -123 418 564 532 535 870 803 264 40 -233 0 165 -29 -59 39 150 -354 -108 -460 -367 -438 -179 -486 -812 -1007 181 461 -162 342 168 -171 -118 92 -25 182 -5 -383 721 -11 248 628 42 960 769 500 -197 -563 -88 -139 504 803 617 550 -383 -1172 -196 -158 -406 67 -572 -387 -808 -704 -956 -519 -701 -508 -756 -599 66 221 600 455 781 476 592 706 442 581 479 909 947 1333 1156 38 -299 3 391 858 286 -164 102 -16 366 142 -47 -115 -397 46 -169 -977 -1601 -1838 -1568 -1088 -875 0 -174 -110 186 149 260 229 734 254 208 678 559 -440 -475 -45 -342 149 15 -753 -1419 -600 -243 -370 701 307 203 193 52 215 445 586 319 242 199 -510 -347 -160 541 690 646 615 1029 948 331 50 -299 0 220 -40 -80 54 215 -515 -154 -640 -516 -602 SS 20240722T162441.1Z 8969.683809 407 1 19.21 2 19.72 146.17 149.04 295.72 0.00 1 0.00 1 0 17 7.528e-03 6.321e-03 1.146e-03 9.198e-04 1.481300e-01 4.908814e-04 1.760766e-03 -6.000000e+00 4.447011e-03 232.30 -2.00 3.43 -2.00 314.10 0.00e+00 1.302577e-04 3.652782e-05 1.102834e-05 -6.000000e+00 2.017669e-04 291.71 -2.00 20.00 -2.00 313.48 0.00e+00 1.062 0.000 302.00 328.00 3 4.4204e+00 1.2590e-03 1.3102e-02 -6.0000e+00 1.1133e-02 -1.4524e-03 1.3864e-03 7.5646e-03 -6.0000e+00 1.2020e-02 -1.2823e-03 7.9644e-04 3.6620e-03 -6.0000e+00 7.1718e-03 -7.3035e-04 3.4289e-04 1.0033e-03 -6.0000e+00 3.0497e-03 1.9704e-03 2.6131e-04 2.6714e-05 1.4848e-05 -6.0000e+00 2.1457e-04 4.0916e-02 0.0000e+00 12 1 1 12 1 1 99.81 24.14 0.37 0.04092 0.04288 28 8 1 5 0 662.160 31.50 19.99 24.14 32.61 4.8 1100.00 -644 -1320 -2357 -2127 695 724 988 715 363 -978 160 321 499 -198 -13 -385 664 220 730 872 755 1384 654 395 117 -303 -560 315 1304 1460 1560 1288 -766 -1896 -467 -346 -434 -267 -604 -1435 -986 -885 -1058 -759 -782 -1055 -735 -815 197 711 669 656 711 441 776 931 469 647 598 1146 1132 1254 918 -50 -372 196 161 1084 579 -375 -100 29 106 -2 52 143 187 638 -287 -946 -1439 -1718 -1411 -838 -861 -447 -372 -292 -72 83 246 471 1293 815 266 456 134 -250 -337 -168 -283 278 423 -497 -1033 -513 -635 -320 438 -6 -109 -16 143 104 661 776 536 252 -183 -492 -131 -142 291 582 537 571 1275 730 288 44 -141 -19 228 -17 -55 -148 38 -326 -301 -274 -387 -385 -303 -633 -1074 -911 285 303 428 324 173 -466 74 158 257 -108 -8 -222 384 131 443 538 463 846 417 252 77 -199 -364 187 764 861 963 800 -496 -1175 -288 -215 -296 -198 -480 -1210 -864 -764 -922 -680 -694 -915 -633 -675 158 583 580 574 647 398 708 859 434 589 541 1057 1069 1225 945 -51 -367 181 146 975 563 -390 -106 31 110 -2 49 130 163 558 -268 -919 -1486 -1835 -1524 -930 -996 -530 -457 -361 -86 98 271 498 1324 831 286 520 159 -304 -408 -198 -318 305 477 -592 -1242 -642 -803 -419 582 -8 -149 -21 182 128 775 895 644 307 -233 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