File name: Pandora255s1_VirginiaBeachVA-CBBT_20240915_L2Fit_fout2c3d20240302p1-8.txt File generation date: 20241220T100539.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: John Anderson Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 255 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora255_OF_v2d20221206.txt Instrument calibration file used: Pandora255s1_CF_v3d20240302.txt Level 1 file used: Pandora255s1_VirginiaBeachVA-CBBT_20240915_L1_smca1c3d20240302p1-8.txt Full location name: Chesapeake Bay Bridge Tunnel Virginia Short location name: VirginiaBeachVA-CBBT Country of location: United States Location latitude [deg]: 37.0367 Location longitude [deg]: -76.0766 Location altitude [m]: 20 Local noon date: 20240915 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 195 336 Nominal wavelengths inside fitting window [nm]: 305.1318 305.2728 305.4137 305.5546 305.6955 305.8364 305.9773 306.1182 306.2590 306.3999 306.5407 306.6815 306.8224 306.9632 307.1040 307.2447 307.3855 307.5263 307.6670 307.8078 307.9485 308.0892 308.2299 308.3706 308.5113 308.6520 308.7926 308.9333 309.0739 309.2146 309.3552 309.4958 309.6364 309.7770 309.9175 310.0581 310.1986 310.3392 310.4797 310.6202 310.7607 310.9012 311.0417 311.1822 311.3227 311.4631 311.6035 311.7440 311.8844 312.0248 312.1652 312.3056 312.4459 312.5863 312.7267 312.8670 313.0073 313.1476 313.2880 313.4282 313.5685 313.7088 313.8491 313.9893 314.1296 314.2698 314.4100 314.5502 314.6904 314.8306 314.9707 315.1109 315.2511 315.3912 315.5313 315.6714 315.8115 315.9516 316.0917 316.2318 316.3718 316.5119 316.6519 316.7920 316.9320 317.0720 317.2120 317.3519 317.4919 317.6319 317.7718 317.9117 318.0517 318.1916 318.3315 318.4714 318.6113 318.7511 318.8910 319.0308 319.1706 319.3105 319.4503 319.5901 319.7299 319.8696 320.0094 320.1492 320.2889 320.4286 320.5684 320.7081 320.8478 320.9874 321.1271 321.2668 321.4064 321.5461 321.6857 321.8253 321.9649 322.1045 322.2441 322.3837 322.5232 322.6628 322.8023 322.9418 323.0813 323.2208 323.3603 323.4998 323.6393 323.7787 323.9182 324.0576 324.1970 324.3364 324.4758 324.6152 324.7546 324.8940 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240915T114500.0Z 9024.489584 153 1 7.28 2 79.26 94.73 137.78 281.01 0.00 1 0.00 1 0 25 4.550e-01 3.207e-02 3.292e-01 1.871e-02 6.389604e-01 1.019731e-02 7.684782e-03 -6.000000e+00 2.673679e-01 229.29 -2.00 3.43 -2.00 320.69 0.00e+00 -1.299474e-02 3.947711e-03 7.800892e-04 -6.000000e+00 1.241002e-02 290.16 -2.00 20.00 -2.00 319.93 0.00e+00 5.161 0.002 302.00 328.00 3 3.9856e+00 3.2036e-02 6.1248e-02 -6.0000e+00 6.6663e-01 3.1636e-01 4.1026e-02 3.5353e-02 -6.0000e+00 7.2456e-01 -4.9586e-01 3.2782e-02 2.1641e-02 -6.0000e+00 4.2893e-01 2.3183e-01 1.5968e-02 1.6555e-02 -6.0000e+00 1.8128e-01 2.9646e-05 -1.1645e-02 5.4448e-04 1.5717e-04 -6.0000e+00 1.3379e-02 8.4717e-02 0.0000e+00 12 9 9 12 1 1 99.99 25.47 0.48 0.08472 -0.00279 4 4 1 5 0 1454.850 33.25 19.99 25.47 27.75 4.9 1085.85 -71470 -59517 -728 -138225 38062 900000 -163127 900000 158738 73944 -96760 -108257 -91624 -80105 96479 22636 111032 33356 -52444 900000 67481 180576 40839 -3338 9461 -61494 171840 -24673 7064 -16660 7287 186756 7929 12670 14340 900000 42543 13198 21688 37070 9716 -815 14371 8379 34819 53356 -1580 -10123 25795 20093 24023 24543 11916 16512 -6699 10607 4317 37634 825 5029 6832 12396 12848 -10351 16806 8748 2829 4044 -10103 3435 6133 7062 773 -196 2584 -9252 -8975 2212 1006 -48 -2809 851 -9369 -5167 720 5436 -1669 -2630 60 -618 1466 2151 5001 -3293 -7142 3365 -2956 -2805 -3249 -2153 -1719 3142 -223 -105 -5002 -767 -1246 4414 746 -2237 -29 -233 947 1861 -696 -149 966 974 1688 4265 -177 884 -132 1101 1496 821 -2011 1601 2835 -616 -1836 -994 156 1799 1405 -1379 2120 -1609 -49 -1532 -1013 -507 -1659 -1283 -13 -5728 694 900000 -10005 900000 2894 1348 -4651 -6460 -5316 -4780 1759 660 2024 973 -3390 900000 1477 3293 1340 -195 535 -7288 3133 -1755 348 -1094 425 3405 564 855 915 900000 2482 1275 2373 4056 1524 -147 2227 1344 4190 5253 -268 -1901 3527 3151 4030 4520 2716 3884 -2113 2959 1307 7960 241 1376 1906 3594 4123 -4084 5547 3031 1047 1585 -4723 1583 2948 3418 384 -91 1159 -4234 -3944 916 483 -25 -1714 560 -7361 -4154 585 4460 -1527 -2450 53 -519 1125 1555 3498 -2697 -6902 3084 -3292 -3460 -4172 -2634 -1920 3041 -217 -107 -5761 -892 -1545 5580 1001 -3439 -46 -388 1529 2832 -1031 -215 1419 1510 2734 6826 -288 1374 -201 1589 2242 1191 -3004 2322 4573 -1135 -3417 -1927 315 3816 3177 -3087 4656 -3682 -108 -3447 -2125 -1008 SS 20240915T115257.2Z 9024.495106 159 1 54.54 2 77.68 95.96 139.24 282.54 0.00 1 0.00 1 0 25 3.475e-01 2.119e-02 1.241e-01 5.778e-03 5.681408e-01 3.115525e-03 6.734508e-03 -6.000000e+00 2.075712e-01 229.29 -2.00 3.43 -2.00 320.39 0.00e+00 -2.696310e-03 1.171487e-03 3.210436e-03 -6.000000e+00 9.765331e-03 290.16 -2.00 20.00 -2.00 319.66 0.00e+00 4.550 0.001 302.00 328.00 3 4.4493e+00 9.6552e-03 5.6729e-02 -6.0000e+00 5.1613e-01 1.6076e-01 1.2151e-02 3.8784e-02 -6.0000e+00 5.5905e-01 -2.0708e-01 1.0220e-02 1.4827e-02 -6.0000e+00 3.3219e-01 9.4355e-02 5.1248e-03 6.8311e-03 -6.0000e+00 1.4250e-01 3.5122e-05 -2.2623e-05 1.7048e-04 4.7025e-05 -6.0000e+00 9.9841e-03 1.3556e-04 0.0000e+00 12 8 8 10 0 0 100.00 25.47 0.59 0.00014 -0.00003 74 7 1 5 0 736.850 33.00 20.00 25.47 27.88 4.9 1087.19 900000 -94061 -121577 -174722 900000 900000 -115644 -75134 33545 21031 -77034 -74191 -58475 -91033 48234 -51139 900000 -18527 -19920 900000 -2151 52319 117895 -8846 -24226 -53330 102521 -56584 -13328 25344 4543 38867 2730 -3296 -1461 107065 1166 3660 11737 40374 -4399 1790 7846 9802 21717 44456 930 -3971 4098 10226 16646 -5954 332 3070 9553 8239 -2087 14063 -804 2849 3205 8008 7637 -2612 6795 5185 2427 6180 -828 -2226 -2138 2015 2106 2936 369 -5336 860 3371 2072 1161 -2909 -1072 -3541 -3742 -642 2980 -2223 -4735 176 -242 1543 2317 316 -3024 -3538 4551 910 -1919 -2122 -706 -1269 249 -1675 -1714 -3274 -173 271 -952 -712 -767 582 182 583 1851 55 454 1119 810 1257 2115 -1317 -904 1932 1337 -26 1194 651 2580 1135 -205 -301 -241 -151 -1027 127 -721 667 -277 223 -1550 -88 -136 900000 -1973 -3359 -7599 900000 900000 -3077 -1538 257 194 -2010 -2164 -1942 -4611 787 -2533 900000 -772 -886 900000 -84 1207 1526 -448 -1541 -4682 1846 -4745 -720 1013 258 1794 198 -254 -107 2772 100 375 1348 4022 -748 300 1267 1556 3068 5029 164 -751 745 1888 3195 -1575 90 862 2640 2397 -682 3839 -248 847 1005 2655 2832 -1150 2708 2022 971 2532 -413 -1150 -1180 1084 1094 1548 181 -2511 366 1472 1050 629 -1882 -756 -2745 -3094 -551 2614 -2137 -4716 163 -213 1237 1734 238 -2514 -3343 4547 984 -2363 -2702 -851 -1410 271 -1808 -1957 -3726 -201 331 -1268 -1042 -1142 915 291 903 2898 83 669 1686 1293 1948 3304 -2086 -1490 2991 1998 -37 1645 901 3799 1895 -352 -550 -461 -302 -2054 267 -1574 1463 -618 483 -3243 -183 -273 SS 20240915T120558.6Z 9024.504150 165 1 3.94 2 75.10 98.00 141.61 285.20 0.00 1 0.00 1 0 25 1.151e-01 8.351e-03 4.651e-02 4.244e-03 5.023651e-01 2.207067e-03 5.755751e-03 -6.000000e+00 6.756940e-02 229.29 -2.00 3.43 -2.00 319.05 0.00e+00 3.531575e-04 5.499155e-04 1.966422e-04 -6.000000e+00 3.064771e-03 290.16 -2.00 20.00 -2.00 318.22 0.00e+00 3.812 0.001 302.00 328.00 3 2.5546e+00 6.1576e-03 4.5907e-02 -6.0000e+00 1.6802e-01 3.4046e-02 7.1896e-03 2.5749e-02 -6.0000e+00 1.8157e-01 -4.4689e-02 5.3013e-03 1.2577e-02 -6.0000e+00 1.0850e-01 1.5703e-02 2.7957e-03 3.5612e-03 -6.0000e+00 4.6629e-02 5.1645e-04 -4.4492e-04 1.2010e-04 3.9043e-05 -6.0000e+00 3.2763e-03 5.5311e-03 0.0000e+00 12 9 1 12 1 1 99.98 25.48 0.37 0.00553 0.00219 11 16 1 5 0 327.480 33.25 20.00 25.48 28.29 4.8 1089.38 -33643 -32379 -16420 -45584 -60799 -27262 -51949 -23882 -35221 -35398 -21568 -12721 -35733 -12791 4273 -9479 10514 -2482 -1231 17834 -2462 -3751 56 -6248 -5966 -4411 -156 -8569 -10446 -2026 3730 -8285 -1831 3284 -1379 2786 -3617 96 -415 3409 -1786 -333 1047 1633 2619 577 -1466 374 1731 2835 1076 1884 1966 255 1062 1566 -438 2043 1360 2319 2512 2830 732 1451 11 993 373 1374 63 -1207 -207 -350 -448 -160 -397 -993 172 -522 -59 -1532 -1191 -2601 -1812 -1178 -1053 66 137 -441 106 -256 503 1332 965 319 -289 810 247 -127 -813 -284 -270 259 773 23 -1328 -595 -298 -360 101 -438 -606 215 -369 375 863 1093 851 267 86 -317 -685 -90 -171 603 960 -111 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