File name: Pandora255s1_VirginiaBeachVA-CBBT_20241220_L2Fit_fnvs5c3d20240302p1-8.txt File generation date: 20250129T160413.8Z Data description: Level 2 spectral fitting results file Data file version: fnvs5c3p1-8 Local principal investigator: John Anderson Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 255 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora255_OF_v2d20221206.txt Instrument calibration file used: Pandora255s1_CF_v3d20240302.txt Level 1 file used: Pandora255s1_VirginiaBeachVA-CBBT_20241220_L1_smca1c3d20240302p1-8.txt Full location name: Chesapeake Bay Bridge Tunnel Virginia Short location name: VirginiaBeachVA-CBBT Country of location: United States Location latitude [deg]: 37.0367 Location longitude [deg]: -76.0766 Location altitude [m]: 20 Local noon date: 20241220 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 889 1434 Nominal wavelengths inside fitting window [nm]: 400.0594 400.1917 400.3239 400.4561 400.5883 400.7205 400.8527 400.9849 401.1170 401.2492 401.3813 401.5134 401.6455 401.7776 401.9096 402.0417 402.1737 402.3057 402.4378 402.5698 402.7017 402.8337 402.9657 403.0976 403.2295 403.3614 403.4933 403.6252 403.7571 403.8889 404.0208 404.1526 404.2844 404.4162 404.5480 404.6798 404.8115 404.9433 405.0750 405.2067 405.3384 405.4701 405.6018 405.7334 405.8651 405.9967 406.1283 406.2599 406.3915 406.5231 406.6546 406.7862 406.9177 407.0492 407.1807 407.3122 407.4437 407.5751 407.7066 407.8380 407.9694 408.1008 408.2322 408.3636 408.4949 408.6263 408.7576 408.8889 409.0202 409.1515 409.2828 409.4140 409.5453 409.6765 409.8077 409.9389 410.0701 410.2013 410.3324 410.4636 410.5947 410.7258 410.8569 410.9880 411.1191 411.2502 411.3812 411.5122 411.6432 411.7742 411.9052 412.0362 412.1672 412.2981 412.4290 412.5599 412.6908 412.8217 412.9526 413.0835 413.2143 413.3451 413.4759 413.6067 413.7375 413.8683 413.9990 414.1298 414.2605 414.3912 414.5219 414.6526 414.7833 414.9139 415.0446 415.1752 415.3058 415.4364 415.5670 415.6976 415.8281 415.9586 416.0892 416.2197 416.3502 416.4807 416.6111 416.7416 416.8720 417.0024 417.1328 417.2632 417.3936 417.5240 417.6543 417.7847 417.9150 418.0453 418.1756 418.3059 418.4361 418.5664 418.6966 418.8268 418.9570 419.0872 419.2174 419.3476 419.4777 419.6078 419.7380 419.8681 419.9982 420.1282 420.2583 420.3883 420.5184 420.6484 420.7784 420.9084 421.0383 421.1683 421.2982 421.4282 421.5581 421.6880 421.8179 421.9477 422.0776 422.2074 422.3373 422.4671 422.5969 422.7266 422.8564 422.9862 423.1159 423.2456 423.3753 423.5050 423.6347 423.7644 423.8940 424.0237 424.1533 424.2829 424.4125 424.5420 424.6716 424.8011 424.9307 425.0602 425.1897 425.3192 425.4487 425.5781 425.7076 425.8370 425.9664 426.0958 426.2252 426.3546 426.4839 426.6132 426.7426 426.8719 427.0012 427.1305 427.2597 427.3890 427.5182 427.6474 427.7766 427.9058 428.0350 428.1642 428.2933 428.4225 428.5516 428.6807 428.8098 428.9388 429.0679 429.1969 429.3260 429.4550 429.5840 429.7130 429.8419 429.9709 430.0998 430.2288 430.3577 430.4866 430.6154 430.7443 430.8732 431.0020 431.1308 431.2596 431.3884 431.5172 431.6459 431.7747 431.9034 432.0321 432.1608 432.2895 432.4182 432.5468 432.6755 432.8041 432.9327 433.0613 433.1899 433.3185 433.4470 433.5756 433.7041 433.8326 433.9611 434.0896 434.2180 434.3465 434.4749 434.6033 434.7317 434.8601 434.9885 435.1168 435.2452 435.3735 435.5018 435.6301 435.7584 435.8867 436.0149 436.1431 436.2714 436.3996 436.5278 436.6559 436.7841 436.9122 437.0404 437.1685 437.2966 437.4247 437.5527 437.6808 437.8088 437.9369 438.0649 438.1929 438.3208 438.4488 438.5768 438.7047 438.8326 438.9605 439.0884 439.2163 439.3441 439.4720 439.5998 439.7276 439.8554 439.9832 440.1110 440.2387 440.3665 440.4942 440.6219 440.7496 440.8773 441.0049 441.1326 441.2602 441.3878 441.5154 441.6430 441.7706 441.8981 442.0257 442.1532 442.2807 442.4082 442.5357 442.6631 442.7906 442.9180 443.0454 443.1728 443.3002 443.4276 443.5550 443.6823 443.8096 443.9369 444.0642 444.1915 444.3188 444.4460 444.5733 444.7005 444.8277 444.9549 445.0821 445.2092 445.3364 445.4635 445.5906 445.7177 445.8448 445.9718 446.0989 446.2259 446.3529 446.4799 446.6069 446.7339 446.8609 446.9878 447.1147 447.2417 447.3686 447.4954 447.6223 447.7492 447.8760 448.0028 448.1296 448.2564 448.3832 448.5099 448.6367 448.7634 448.8901 449.0168 449.1435 449.2702 449.3968 449.5234 449.6501 449.7767 449.9033 450.0298 450.1564 450.2829 450.4095 450.5360 450.6625 450.7889 450.9154 451.0419 451.1683 451.2947 451.4211 451.5475 451.6739 451.8002 451.9266 452.0529 452.1792 452.3055 452.4318 452.5580 452.6843 452.8105 452.9367 453.0629 453.1891 453.3153 453.4414 453.5676 453.6937 453.8198 453.9459 454.0720 454.1980 454.3241 454.4501 454.5761 454.7021 454.8281 454.9541 455.0800 455.2060 455.3319 455.4578 455.5837 455.7096 455.8354 455.9613 456.0871 456.2129 456.3387 456.4645 456.5902 456.7160 456.8417 456.9674 457.0931 457.2188 457.3445 457.4701 457.5958 457.7214 457.8470 457.9726 458.0982 458.2237 458.3493 458.4748 458.6003 458.7258 458.8513 458.9768 459.1022 459.2276 459.3531 459.4785 459.6038 459.7292 459.8546 459.9799 460.1052 460.2305 460.3558 460.4811 460.6064 460.7316 460.8568 460.9821 461.1073 461.2324 461.3576 461.4828 461.6079 461.7330 461.8581 461.9832 462.1083 462.2333 462.3584 462.4834 462.6084 462.7334 462.8584 462.9833 463.1083 463.2332 463.3581 463.4830 463.6079 463.7327 463.8576 463.9824 464.1072 464.2320 464.3568 464.4816 464.6063 464.7311 464.8558 464.9805 465.1052 465.2299 465.3545 465.4792 465.6038 465.7284 465.8530 465.9776 466.1021 466.2267 466.3512 466.4757 466.6002 466.7247 466.8492 466.9736 467.0980 467.2225 467.3469 467.4713 467.5956 467.7200 467.8443 467.9686 468.0929 468.2172 468.3415 468.4658 468.5900 468.7142 468.8384 468.9626 469.0868 469.2110 469.3351 469.4592 469.5834 469.7075 469.8315 469.9556 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Molecular iodine slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of molecular iodine slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of molecular iodine slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of molecular iodine slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of molecular iodine slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Molecular iodine effective temperature [K] Column 39: Independent uncertainty of molecular iodine effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of molecular iodine effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of molecular iodine effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective molecular iodine fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for molecular iodine [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Nitrogen dioxide effective temperature [K] Column 50: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Oxygen dimer slant column amount [moles squared per meter to the 5th], -9e99=fitting not successful Column 56: Independent uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 57: Structured uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 58: Common uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 59: rms-based uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 60: Oxygen dimer effective temperature [K] Column 61: Independent uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 62: Structured uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 63: Common uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 64: Effective oxygen dimer fitting wavelength [nm], -9=fitting not successful Column 65: Diffuse correction applied before fitting at effective fitting wavelength for oxygen dimer [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 66: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 67: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 68: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 69: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 70: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 71: Ozone effective temperature [K] Column 72: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 73: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 74: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 75: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 76: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 77: Iodine dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 78: Independent uncertainty of iodine dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 79: Structured uncertainty of iodine dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 80: Common uncertainty of iodine dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 81: rms-based uncertainty of iodine dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 82: Iodine dioxide effective temperature [K] Column 83: Independent uncertainty of iodine dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 84: Structured uncertainty of iodine dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 85: Common uncertainty of iodine dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 86: Effective iodine dioxide fitting wavelength [nm], -9=fitting not successful Column 87: Diffuse correction applied before fitting at effective fitting wavelength for iodine dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 88: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 89: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 90: Lower limit used for wavelength scaling [nm] Column 91: Upper limit used for wavelength scaling [nm] Column 92: Order of smoothing polynomial Column 93: Smoothing polynomial coefficient, order 0 Column 94: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 95: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 96: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 97: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 98: Smoothing polynomial coefficient, order 1 Column 99: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 100: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 101: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 102: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 103: Smoothing polynomial coefficient, order 2 Column 104: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 105: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 106: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 107: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 108: Smoothing polynomial coefficient, order 3 Column 109: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 110: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 111: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 112: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 113: Smoothing polynomial coefficient, order 4 Column 114: Independent uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 115: Structured uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 116: Common uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 117: rms-based uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 118: Mean value of measured data inside fitting window [same units as measurements] Column 119: Offset polynomial coefficient, order 0 Column 120: Independent uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 121: Structured uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 122: Common uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 123: rms-based uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 124: Wavelength change polynomial coefficient, order 0 Column 125: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 126: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 127: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 128: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 129: Wavelength change polynomial coefficient, order 1 Column 130: Independent uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 131: Structured uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 132: Common uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 133: rms-based uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 134: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 135: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 136: Resolution change polynomial coefficient, order 0 Column 137: Independent uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 138: Structured uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 139: Common uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 140: rms-based uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 141: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 142: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 143: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 144: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 145: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 146: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 147: Atmospheric variability [%], 999=no atmospheric variability was determined Column 148: Wavelength effective temperature [°C], 999=no effective temperature given Column 149: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 150: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 151: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 152: Number of bright count cycles Column 153: Number of dark count cycles Column 154: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 155: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 156: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 157: Integration time [ms] Column 158: Temperature at electronics board [°C], 999=no temperature signal Column 159: Spectrometer control temperature [°C], 999=no temperature signal Column 160: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 161: Temperature in head sensor [°C], 999=no temperature signal Column 162: Humidity in head sensor [%], -9=no humidity signal Column 163: Pressure in head sensor [hPa], -9=no pressure signal Columns 164-709: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 710-1255: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20241220T171039.3Z 9120.715733 451 1 0.81 2 60.51 182.21 101.91 294.09 0.00 1 0.00 1 0 33 1.903e-03 1.871e-03 1.950e-03 1.926e-03 6.972207e+02 3.753501e+02 5.032947e+01 3.938557e+02 3.796032e+02 280.03 -2.00 20.00 -2.00 445.26 0.00e+00 -5.955095e-04 2.099598e-04 2.790514e-06 1.532957e-05 2.067604e-04 280.03 -2.00 20.00 -2.00 454.60 0.00e+00 1.106238e-04 1.724327e-05 7.376232e-07 1.057866e-05 1.720271e-05 226.80 -2.00 2.11 -2.00 434.61 0.00e+00 1.400342e+06 2.693158e+05 1.355638e+04 2.419672e+05 2.730028e+05 261.46 -2.00 11.01 -2.00 457.65 0.00e+00 2.215173e-01 5.516505e-02 1.488885e-03 9.267385e-03 5.916226e-02 223.63 -2.00 3.43 -2.00 453.99 0.00e+00 6.477090e-06 6.972536e-06 3.133307e-07 1.211472e-06 7.255997e-06 280.03 -2.00 20.00 -2.00 455.35 0.00e+00 2.022 0.000 397.00 473.00 4 3.8462e+00 2.0256e-03 5.1467e-03 4.1366e-04 1.9289e-03 5.1857e-02 2.4088e-03 1.0751e-03 2.3864e-04 2.3787e-03 -2.5113e-03 1.3891e-03 1.4170e-04 9.4698e-05 1.3624e-03 6.4012e-04 4.6927e-04 3.0942e-05 2.4776e-05 4.6341e-04 1.3263e-03 2.3798e-04 2.1322e-05 1.4249e-05 2.3162e-04 2.6669e-02 1.9525e-02 1.3239e-03 1.0939e-05 2.9134e-05 1.1344e-03 -5.9633e-06 1.9953e-05 2.3062e-07 3.5275e-07 1.9258e-05 -2.9052e-05 2.6732e-05 2.5302e-07 4.4277e-07 2.6070e-05 2.8736e-02 -1.1827e-04 6.8711e-01 1.8790e-01 7.2121e-04 1.6463e-03 1.7601e-01 12 9 9 12 1 1 999.00 24.66 1.47 0.02874 0.03107 2 20 2 4 0 267.440 33.00 19.92 24.66 13.36 5.0 974.60 -31 199 14 218 -150 95 -457 -194 294 238 -155 379 -147 -66 238 216 119 -53 13 -45 -83 145 -48 -214 -236 -93 238 -70 109 -87 95 93 -41 125 119 -246 182 -231 -28 224 18 26 163 159 -671 117 -224 -467 525 -46 -30 -32 26 -10 49 224 -24 -454 100 168 51 -227 -283 -511 55 170 -59 -253 -144 35 -140 -192 -197 -49 138 -127 109 -6 375 92 -12 1 -137 -63 188 28 26 235 -187 -331 278 11 -174 -250 -95 25 119 -150 385 -310 -121 -1 -119 274 -132 -40 397 175 199 371 -202 -74 -107 60 -127 151 -136 -223 282 -360 -229 278 -209 -113 77 305 233 196 125 301 265 288 193 -196 -118 383 -187 191 223 84 68 223 -326 1 147 -99 102 -216 59 68 -26 32 215 136 21 171 458 -137 -95 -93 -50 -89 14 144 -91 194 -41 -85 -173 183 -203 -124 -193 -310 148 111 -334 260 29 -223 -10 -20 -170 65 210 -15 -11 168 3 -171 -109 -188 -122 -12 82 91 -31 -230 147 -211 -329 -80 17 199 -105 90 -348 393 192 73 -365 427 -259 121 29 -117 -10 -11 -13 -166 -1 141 -208 56 -78 162 -130 599 8 332 -291 -248 156 -200 -86 17 15 200 -156 68 -101 206 98 -117 93 -231 -492 -186 273 417 -256 170 120 -288 -8 45 -10 79 50 59 15 252 -290 -20 140 53 321 37 40 -200 -90 -320 239 191 12 -119 -210 -39 -207 200 -232 -285 -221 -273 119 -37 -56 -73 -38 47 -175 -1 -33 -22 288 -232 -110 -356 33 232 109 45 174 141 111 -13 -217 -209 -217 -184 93 -20 473 183 159 -13 0 117 -228 -444 -77 247 119 92 64 80 -94 -174 83 -19 -14 60 -20 23 282 71 -149 -91 203 15 224 -64 49 281 -157 34 -167 86 -11 97 -110 -239 -88 -28 -142 327 -31 -302 -33 -36 -53 9 203 -507 -374 -113 -222 538 24 -176 -80 53 -396 -49 305 222 294 500 33 348 243 225 35 241 520 -73 20 8 -114 2 289 -172 145 211 -120 -44 80 -102 4 -57 323 -132 -147 -33 21 -31 -116 -123 74 -96 221 -326 44 -216 11 107 128 293 329 -1 -10 179 165 -149 -88 -83 -167 -343 -186 9 -25 134 97 71 -161 31 -96 -402 -133 -163 106 -160 -95 370 -217 -4 299 -200 171 426 -61 42 69 -51 -234 -48 -397 -53 -290 -147 -101 -279 149 -189 -25 -113 103 -45 68 -133 440 -246 23 171 -78 53 -54 216 -254 -215 13 51 192 -180 141 87 87 249 -77 33 -95 76 90 -204 81 -14 -141 -119 253 -36 173 -119 187 293 77 -32 -62 -28 226 -224 70 28 66 -81 188 40 9 -45 -274 -33 -129 -15 -37 -158 33 -35 60 120 176 -131 71 -143 57 -212 127 56 29 -34 51 -131 14 -39 -40 259 -73 -12 -28 178 12 188 -129 82 -408 -177 265 216 -142 347 -135 -60 220 199 110 -49 12 -42 -78 134 -43 -189 -207 -82 214 -66 104 -83 92 87 -36 109 103 -216 167 -220 -26 211 17 24 147 144 -624 107 -203 -415 460 -41 -28 -30 24 -10 46 207 -22 -414 91 154 48 -220 -276 -497 54 167 -59 -254 -146 34 -139 -188 -188 -46 125 -112 94 -5 333 85 -12 1 -133 -61 186 28 26 240 -190 -332 278 11 -175 -251 -96 25 118 -148 375 -301 -116 -1 -118 274 -135 -41 401 174 194 357 -199 -73 -107 60 -127 149 -133 -216 275 -354 -228 278 -214 -117 80 310 236 196 125 292 255 276 183 -189 -115 372 -184 186 218 82 66 215 -318 1 143 -100 102 -215 58 66 -25 30 200 127 20 167 455 -138 -96 -95 -51 -90 14 144 -90 190 -40 -85 -173 182 -193 -112 -170 -278 138 108 -335 256 28 -213 -10 -19 -164 63 206 -15 -10 165 3 -162 -103 -178 -117 -11 79 89 -30 -218 139 -198 -315 -78 17 199 -103 85 -317 347 170 65 -340 409 -251 117 28 -112 -10 -10 -12 -152 -1 128 -189 52 -72 149 -118 514 6 267 -233 -197 126 -161 -69 13 12 157 -127 59 -93 201 98 -121 95 -232 -479 -172 241 368 -235 164 118 -291 -8 45 -10 77 46 52 13 216 -258 -18 135 51 321 37 39 -193 -85 -306 233 189 12 -119 -209 -40 -211 204 -236 -290 -221 -272 117 -36 -54 -70 -37 46 -172 -1 -32 -19 254 -205 -100 -330 31 220 105 43 168 139 110 -13 -215 -205 -209 -174 87 -19 444 174 157 -13 0 118 -228 -437 -76 247 121 93 65 80 -93 -174 83 -19 -14 60 -20 23 275 70 -150 -93 204 15 220 -64 49 282 -159 35 -168 86 -11 94 -105 -226 -83 -26 -134 312 -30 -294 -33 -36 -52 9 201 -508 -378 -115 -229 551 24 -176 -78 52 -389 -49 307 225 297 497 32 348 241 224 35 242 522 -74 21 8 -119 2 303 -182 152 220 -124 -46 82 -105 4 -58 332 -137 -153 -34 22 -31 -115 -120 72 -93 216 -320 43 -215 12 109 131 304 341 -1 -11 184 170 -151 -89 -85 -170 -352 -192 10 -26 139 103 75 -172 33 -100 -425 -141 -173 112 -170 -103 397 -233 -4 323 -218 184 453 -64 44 73 -54 -250 -52 -430 -58 -316 -159 -107 -302 161 -204 -27 -122 111 -49 75 -145 485 -276 25 193 -88 59 -60 240 -284 -241 14 57 217 -205 160 98 99 282 -88 38 -109 87 103 -232 92 -16 -160 -136 289 -41 197 -135 208 327 86 -37 -71 -32 258 -256 80 33 76 -94 219 46 10 -51 -305 -36 -143 -17 -42 -181 38 -41 70 138 203 -150 80 -165 65 -247 148 65 34 -39 59 -152 16 -46 -47 297 -84 -14 SQ 20241220T192353.3Z 9120.808256 540 1 10.22 2 69.06 214.69 122.87 319.76 0.00 1 0.00 1 0 33 1.207e-03 1.169e-03 1.086e-03 1.070e-03 9.169610e+02 2.087448e+02 9.064211e+01 3.938463e+02 2.406973e+02 280.03 -2.00 20.00 -2.00 445.47 0.00e+00 -2.480445e-04 1.171540e-04 2.148510e-06 1.543948e-05 1.310835e-04 280.03 -2.00 20.00 -2.00 454.80 0.00e+00 2.123281e-04 9.589542e-06 1.399386e-06 1.058974e-05 1.091965e-05 227.14 -2.00 2.11 -2.00 434.99 0.00e+00 1.146462e+06 1.493341e+05 1.788104e+04 2.419445e+05 1.730241e+05 261.46 -2.00 11.01 -2.00 457.79 0.00e+00 1.513832e-01 3.040722e-02 1.081366e-03 9.219628e-03 3.750409e-02 223.63 -2.00 3.43 -2.00 454.17 0.00e+00 -5.173849e-06 3.851791e-06 2.501383e-07 1.212400e-06 4.600000e-06 280.03 -2.00 20.00 -2.00 455.50 0.00e+00 2.771 0.000 397.00 473.00 4 6.4569e+00 1.1276e-03 7.0524e-03 4.1382e-04 1.2239e-03 7.9563e-02 1.3465e-03 1.4726e-03 2.4021e-04 1.5110e-03 -8.9910e-03 7.7394e-04 1.9349e-04 9.5521e-05 8.6299e-04 3.0848e-04 2.6196e-04 3.0283e-05 2.4928e-05 2.9404e-04 1.5630e-03 1.3307e-04 1.7190e-05 1.4335e-05 1.4684e-04 1.6248e-03 1.1074e-02 7.2935e-04 1.2996e-05 3.0331e-05 7.2268e-04 -1.8254e-05 1.1033e-05 2.3878e-07 3.5512e-07 1.2208e-05 -7.3008e-05 1.4839e-05 2.4763e-07 4.4915e-07 1.6529e-05 2.3364e-02 -4.9568e-05 3.5155e-01 1.0490e-01 1.0981e-03 1.6428e-03 1.1151e-01 12 9 1 12 1 1 99.96 24.73 1.49 0.02336 0.02917 9 5 1 4 0 1021.020 33.00 19.96 24.73 13.08 5.0 972.18 -204 -124 135 -42 -260 73 102 294 218 -4 214 163 -9 146 321 -71 47 -56 -14 -332 49 -271 -66 154 -70 35 45 247 -74 173 127 -259 106 105 137 -59 -67 -51 -28 -308 7 -14 -26 81 70 -231 42 -1 -95 88 -76 59 -90 -413 35 -5 -164 -79 -63 63 -152 -101 229 -11 -63 24 111 179 33 -152 -76 -58 -374 142 -92 -37 -161 -295 37 -281 -80 154 -97 20 106 67 -89 115 -116 0 -51 -23 -88 -80 112 -38 76 43 227 -64 59 -168 -36 -109 155 49 -37 200 38 118 -91 59 59 -116 41 109 -71 83 75 234 -69 65 -80 61 105 -85 80 69 79 -59 82 -108 158 45 154 47 -209 24 51 90 136 135 23 31 -85 -152 48 79 15 77 22 -48 127 -100 0 -77 105 -71 260 -55 46 47 31 41 85 -11 -80 -52 58 -32 61 -158 -52 58 15 59 -94 -52 -124 -25 -20 -123 -9 48 181 -116 133 239 40 86 -27 -149 -128 -59 -36 -2 -138 -11 -54 13 12 -52 -192 56 -14 191 -117 196 -19 -6 126 51 96 -46 3 -117 -218 120 -3 -31 15 -441 258 -127 81 -119 158 67 189 -39 235 98 -11 281 141 -199 214 420 142 289 78 -18 -262 22 -70 -50 0 -27 60 -36 44 -70 -85 135 48 53 -90 146 60 41 -487 -204 -141 -116 -26 -47 -13 -70 -49 -116 -16 -139 -143 -68 -61 -41 -41 33 -113 -79 -54 -85 -83 -31 7 64 -64 -223 -87 -132 67 21 -140 -188 -168 41 -71 -38 -100 18 33 48 53 -136 111 -33 27 195 -15 176 109 78 -35 127 132 2 19 -40 -86 288 -144 15 53 -100 -58 77 11 -74 -77 39 87 8 -66 -71 -15 16 -112 -89 46 -117 45 244 -82 142 44 26 17 -46 -49 22 74 45 -101 -182 45 253 -148 75 -5 -19 -124 -82 81 -110 -151 -86 94 83 -235 241 -13 21 1 124 53 67 -59 33 29 -88 -33 305 165 153 44 221 148 43 147 -103 192 -59 13 93 -75 245 -53 11 47 301 85 45 286 64 -10 40 280 91 -50 -35 -43 13 61 145 31 123 -78 -78 -73 -98 -1 -68 -152 -123 -1 -112 -142 -62 90 -52 -202 0 -21 -121 -4 -25 -52 -4 -58 9 110 -103 -47 152 -116 -114 -173 -37 -111 -1 54 -14 -330 -180 -211 34 -94 -59 8 -151 -49 -48 -313 -34 67 -2 -12 -2 75 -64 27 -83 86 12 59 72 164 40 177 -40 55 125 -12 -63 22 -12 35 67 -18 -102 50 80 -110 74 -3 -195 6 188 19 58 7 72 -131 -26 -124 -7 68 21 111 -25 182 17 154 151 111 79 -116 -36 30 -100 171 -103 37 -9 -109 -44 159 -113 51 184 15 -84 6 -82 -44 -143 -41 -6 53 30 -110 116 54 -72 -125 -3 -177 -108 115 -35 -218 62 88 258 194 -4 192 145 -8 131 288 -65 43 -51 -13 -308 45 -245 -58 135 -60 30 41 224 -70 161 121 -237 93 91 117 -50 -61 -47 -26 -284 7 -13 -23 72 64 -209 37 -1 -83 78 -69 54 -83 -384 32 -4 -149 -71 -57 57 -141 -95 217 -11 -60 23 109 179 32 -150 -75 -56 -357 133 -83 -33 -137 -252 33 -256 -76 147 -93 20 104 66 -89 116 -115 0 -50 -23 -87 -80 112 -37 74 42 220 -61 57 -159 -35 -107 159 50 -38 197 36 113 -87 58 59 -115 40 106 -69 80 71 227 -67 65 -81 62 108 -86 80 69 78 -58 78 -104 149 42 148 45 -202 23 50 86 132 129 22 30 -82 -150 48 78 15 75 21 -45 118 -94 0 -76 105 -71 261 -56 47 47 31 40 83 -11 -79 -53 59 -31 57 -142 -45 52 14 57 -93 -51 -120 -24 -19 -117 -8 47 176 -115 132 233 39 82 -25 -142 -121 -56 -35 -2 -133 -10 -50 13 12 -51 -193 56 -13 177 -106 174 -16 -5 118 48 93 -45 2 -111 -205 113 -3 -28 13 -394 232 -116 74 -109 143 57 156 -31 185 79 -9 223 111 -153 166 327 116 251 72 -17 -267 23 -73 -51 0 -25 53 -32 41 -67 -84 135 48 53 -89 140 55 36 -418 -173 -125 -108 -25 -46 -13 -70 -48 -111 -16 -131 -138 -67 -61 -40 -42 33 -116 -82 -55 -85 -84 -31 7 63 -62 -213 -83 -129 66 21 -134 -171 -147 35 -63 -36 -96 17 31 47 52 -133 111 -33 27 192 -14 165 103 74 -33 120 130 2 19 -41 -85 283 -142 15 54 -103 -59 77 12 -73 -78 39 88 8 -65 -70 -15 16 -113 -90 47 -117 45 243 -82 144 44 26 17 -46 -48 21 71 42 -94 -172 43 243 -143 73 -5 -19 -124 -82 80 -111 -152 -88 97 85 -242 240 -13 21 1 123 54 67 -60 33 30 -88 -33 303 165 154 45 225 152 44 152 -109 203 -63 14 98 -78 257 -55 12 49 312 88 47 294 66 -11 41 280 90 -48 -34 -43 13 61 144 32 127 -80 -82 -76 -101 -1 -71 -156 -126 -1 -114 -145 -64 93 -54 -212 0 -22 -129 -4 -27 -55 -5 -62 9 117 -111 -50 165 -125 -124 -189 -41 -119 -1 56 -15 -352 -193 -226 37 -103 -65 8 -163 -53 -52 -343 -37 73 -2 -13 -2 83 -72 30 -93 98 13 67 81 187 45 202 -45 63 144 -14 -72 26 -13 40 78 -21 -119 58 93 -127 84 -3 -225 6 216 22 68 8 82 -149 -29 -141 -8 79 25 129 -29 210 20 181 178 131 94 -134 -41 33 -111 191 -115 43 -10 -128 -51 187 -132 59 213 18 -97 7 -96 -52 -170 -48 -8 63 35 -130 138 64 -84 -144 -4