File name: Pandora255s1_VirginiaBeachVA-CBBT_20241224_L2Fit_fout2c3d20240302p1-8.txt File generation date: 20250129T161040.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: John Anderson Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 255 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora255_OF_v2d20221206.txt Instrument calibration file used: Pandora255s1_CF_v3d20240302.txt Level 1 file used: Pandora255s1_VirginiaBeachVA-CBBT_20241224_L1_smca1c3d20240302p1-8.txt Full location name: Chesapeake Bay Bridge Tunnel Virginia Short location name: VirginiaBeachVA-CBBT Country of location: United States Location latitude [deg]: 37.0367 Location longitude [deg]: -76.0766 Location altitude [m]: 20 Local noon date: 20241224 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 195 336 Nominal wavelengths inside fitting window [nm]: 305.1318 305.2728 305.4137 305.5546 305.6955 305.8364 305.9773 306.1182 306.2590 306.3999 306.5407 306.6815 306.8224 306.9632 307.1040 307.2447 307.3855 307.5263 307.6670 307.8078 307.9485 308.0892 308.2299 308.3706 308.5113 308.6520 308.7926 308.9333 309.0739 309.2146 309.3552 309.4958 309.6364 309.7770 309.9175 310.0581 310.1986 310.3392 310.4797 310.6202 310.7607 310.9012 311.0417 311.1822 311.3227 311.4631 311.6035 311.7440 311.8844 312.0248 312.1652 312.3056 312.4459 312.5863 312.7267 312.8670 313.0073 313.1476 313.2880 313.4282 313.5685 313.7088 313.8491 313.9893 314.1296 314.2698 314.4100 314.5502 314.6904 314.8306 314.9707 315.1109 315.2511 315.3912 315.5313 315.6714 315.8115 315.9516 316.0917 316.2318 316.3718 316.5119 316.6519 316.7920 316.9320 317.0720 317.2120 317.3519 317.4919 317.6319 317.7718 317.9117 318.0517 318.1916 318.3315 318.4714 318.6113 318.7511 318.8910 319.0308 319.1706 319.3105 319.4503 319.5901 319.7299 319.8696 320.0094 320.1492 320.2889 320.4286 320.5684 320.7081 320.8478 320.9874 321.1271 321.2668 321.4064 321.5461 321.6857 321.8253 321.9649 322.1045 322.2441 322.3837 322.5232 322.6628 322.8023 322.9418 323.0813 323.2208 323.3603 323.4998 323.6393 323.7787 323.9182 324.0576 324.1970 324.3364 324.4758 324.6152 324.7546 324.8940 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241224T124848.8Z 9124.533898 250 1 55.06 2 85.19 124.25 48.40 195.20 0.00 1 0.00 1 0 25 7.472e-01 5.073e-02 3.169e-01 1.601e-02 1.086491e+00 9.803317e-03 1.185097e-02 -6.000000e+00 4.453698e-01 223.71 -2.00 3.43 -2.00 322.37 0.00e+00 -3.982705e-02 5.145487e-03 1.581273e-02 -6.000000e+00 2.205442e-02 279.83 -2.00 20.00 -2.00 321.90 0.00e+00 10.110 0.017 302.00 328.00 3 1.2852e-01 3.8087e-02 1.7228e-01 -6.0000e+00 1.1009e+00 1.8844e+00 4.7848e-02 1.9904e-01 -6.0000e+00 1.2080e+00 -2.3233e+00 3.5838e-02 5.0371e-02 -6.0000e+00 7.1225e-01 8.9700e-01 1.8090e-02 3.1974e-02 -6.0000e+00 3.0682e-01 6.9676e-06 -7.2935e-04 4.4159e-04 3.1094e-04 -6.0000e+00 2.2707e-02 2.6844e-02 0.0000e+00 12 8 8 10 0 0 34.01 24.21 1.62 0.02684 0.02136 36 3 1 5 0 1529.150 32.75 20.04 24.21 9.15 5.0 940.37 900000 157496 93875 27834 -41303 900000 29849 900000 205991 87558 900000 -13203 -23265 100096 900000 183874 900000 -6521 317165 900000 81572 10428 900000 5558 84197 45143 900000 900000 900000 -7123 369999 900000 70430 -22691 -49849 900000 -63237 -32093 108535 900000 2886 10176 -8243 -11249 110205 900000 88628 81241 900000 154552 900000 -32975 -14666 12685 13706 147030 14042 96816 -3766 15215 -11338 168257 65228 46521 140647 78742 66880 143977 55636 38242 101918 204812 5784 -24442 17175 -41476 -4935 24466 17482 71519 15488 2994 896 -5388 9057 64010 3723 8969 -3981 1044 6487 16397 4438 -14558 -10798 28742 -2242 -7565 -8988 2816 1321 25689 1819 -8353 -14856 -8802 5545 900000 -5044 -2918 -1501 -825 -5893 1959 5756 490 1834 3074 5650 10162 -4541 2898 3012 995 -4543 -4707 -4371 3428 8594 -212 -2469 338 -2271 307 -758 -1228 2577 -1507 949 -4314 1283 4449 900000 2449 2068 938 -2462 900000 1160 900000 3203 2723 900000 -1129 -2171 2724 900000 2860 900000 -465 4932 900000 1903 514 900000 418 3452 2617 900000 900000 900000 -403 5754 900000 2191 -1668 -4440 900000 -7689 -3584 3683 900000 339 1065 -932 -1145 2960 900000 2631 2642 900000 2841 900000 -4895 -1991 1435 1666 4989 1787 4928 -458 1377 -1331 3568 4334 4012 4772 5010 5106 5699 6135 5569 8213 5791 1104 -5563 2234 -8854 -740 3044 2768 7887 3525 880 293 -1996 3060 12941 1395 3132 -1508 351 1972 4544 1500 -6895 -5847 12353 -1528 -6085 -7586 2019 865 11731 1013 -5421 -10964 -6483 3849 900000 -5177 -3440 -1969 -1148 -8065 2664 7357 661 2528 4384 8060 13490 -6580 3699 3738 1230 -5800 -5909 -5790 4910 13912 -396 -5251 762 -5725 820 -2002 -3334 6775 -4078 2577 -11305 2896 9156 SS 20241224T131829.9Z 9124.554512 259 1 49.72 2 80.44 129.16 50.47 204.27 0.00 1 0.00 1 0 17 4.920e-01 8.553e-03 5.273e-02 1.294e-03 7.651968e-01 6.843090e-04 8.465892e-03 -6.000000e+00 2.818817e-01 223.71 -2.00 3.43 -2.00 320.70 0.00e+00 2.343683e-03 2.905762e-04 7.602169e-04 -6.000000e+00 1.254878e-02 279.83 -2.00 20.00 -2.00 320.16 0.00e+00 5.742 0.003 302.00 328.00 3 6.5375e-01 2.1321e-03 6.8936e-02 -6.0000e+00 6.9440e-01 1.5194e-01 2.8663e-03 3.9373e-02 -6.0000e+00 7.5559e-01 -1.8022e-01 2.9605e-03 2.1115e-02 -6.0000e+00 4.5065e-01 6.7025e-02 1.4544e-03 7.3507e-03 -6.0000e+00 1.9336e-01 4.2038e-04 -7.3080e-04 3.3406e-05 8.1769e-05 -6.0000e+00 1.3987e-02 2.8367e-02 0.0000e+00 12 9 1 12 1 1 99.99 24.20 0.35 0.02837 0.02288 333 36 1 5 0 148.830 32.75 20.23 24.20 9.50 5.0 943.37 -164776 -166547 -161840 -193540 -191118 -131764 -186236 -67495 -127478 -155429 -112900 -141088 -126480 -55026 -40810 -37161 -25349 -50667 -43382 10198 -37100 -49429 -34934 -39744 -36587 -41612 -22659 -32849 -31787 -25147 -13901 534 -14578 -20351 -20288 4096 -16132 -9472 -650 4243 -4102 -263 -1274 -38 2829 4476 1226 1742 6047 4359 5283 2271 4604 3660 3766 3629 1420 1210 -42 1180 2944 3064 4050 2646 2541 1743 782 2118 2024 1403 1188 1641 369 -83 128 -1429 -1503 -1168 -1074 -221 -1033 -1442 -1623 -982 -691 199 -23 322 179 254 299 -174 283 -397 -519 449 197 -565 -669 -369 -466 222 -68 -1161 -1718 -1041 -752 -418 131 -48 -89 136 223 177 944 779 470 108 -173 -333 84 384 291 366 205 496 1270 798 353 98 -79 -70 4 -205 -426 -131 186 -335 -202 -150 20 -61 -1209 -1394 -1318 -2042 -2097 -848 -2349 -298 -1142 -2000 -1082 -2278 -2345 -652 -525 -544 -374 -1067 -908 130 -767 -1203 -806 -1063 -1020 -1265 -566 -903 -930 -825 -505 20 -712 -1058 -1036 176 -995 -674 -52 373 -431 -28 -144 -4 321 517 153 231 834 686 851 422 921 799 867 870 351 292 -10 281 751 894 1343 973 872 602 283 830 914 715 593 816 191 -39 55 -574 -610 -526 -576 -130 -708 -1031 -1250 -801 -559 168 -20 282 152 203 240 -136 226 -334 -510 480 230 -697 -849 -445 -538 243 -73 -1243 -1969 -1251 -914 -558 187 -74 -140 220 354 282 1433 1178 740 171 -287 -548 133 604 444 538 307 718 1883 1273 618 183 -153 -139 9 -444 -940 -296 425 -768 -445 -322 43 -122 SS 20241224T132716.5Z 9124.560607 264 1 54.76 2 79.10 130.69 51.25 206.83 0.00 1 0.00 1 0 25 3.507e-01 8.175e-03 1.683e-02 6.953e-04 6.902145e-01 3.617529e-04 7.779876e-03 -6.000000e+00 2.009391e-01 223.71 -2.00 3.43 -2.00 320.11 0.00e+00 2.281057e-03 1.268497e-04 5.065233e-04 -6.000000e+00 8.944156e-03 279.83 -2.00 20.00 -2.00 319.54 0.00e+00 5.096 0.002 302.00 328.00 3 2.9311e-01 1.0587e-03 6.1325e-02 -6.0000e+00 4.9500e-01 9.8061e-02 1.3203e-03 3.4865e-02 -6.0000e+00 5.3859e-01 -1.2205e-01 1.2482e-03 1.8086e-02 -6.0000e+00 3.2122e-01 4.6047e-02 6.3989e-04 6.2173e-03 -6.0000e+00 1.3785e-01 1.1997e-03 -5.7067e-04 1.8333e-05 6.8044e-05 -6.0000e+00 9.9690e-03 2.7100e-02 0.0000e+00 11 8 0 10 0 0 99.89 24.18 0.34 0.02710 0.02281 622 60 1 5 0 88.020 32.75 20.20 24.18 10.34 5.1 950.82 -119695 -121652 -121167 -134686 -130826 -106755 -124323 -95527 -98169 -95821 -97614 -86691 -67816 -48620 -32364 -29069 -21430 -27736 -21700 -11962 -26015 -25043 -22448 -19678 -18090 -18774 -12519 -19557 -18882 -14394 -5607 -1661 -4933 -9825 -9313 -2933 -5449 -3359 170 1313 -1218 1068 467 1422 1845 2719 701 2154 2692 3330 3453 2202 2688 2328 2405 2089 1026 597 511 1401 1740 2735 2550 1886 1524 1751 1288 2086 1838 750 694 450 179 -20 -199 -408 -811 -412 -784 -831 -1178 -1741 -1898 -1460 -1019 -567 -352 -131 13 61 505 399 381 259 -176 132 22 -421 -481 -236 -425 27 378 -928 -1382 -844 -596 -191 43 -110 -184 -43 201 361 886 915 582 135 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