File name: Pandora255s1_VirginiaBeachVA-CBBT_20250131_L2Fit_fout2c3d20240302p1-8.txt File generation date: 20250207T173238.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: John Anderson Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 255 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora255_OF_v2d20221206.txt Instrument calibration file used: Pandora255s1_CF_v3d20240302.txt Level 1 file used: Pandora255s1_VirginiaBeachVA-CBBT_20250131_L1_smca1c3d20240302p1-8.txt Full location name: Chesapeake Bay Bridge Tunnel Virginia Short location name: VirginiaBeachVA-CBBT Country of location: United States Location latitude [deg]: 37.0367 Location longitude [deg]: -76.0766 Location altitude [m]: 20 Local noon date: 20250131 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 195 336 Nominal wavelengths inside fitting window [nm]: 305.1318 305.2728 305.4137 305.5546 305.6955 305.8364 305.9773 306.1182 306.2590 306.3999 306.5407 306.6815 306.8224 306.9632 307.1040 307.2447 307.3855 307.5263 307.6670 307.8078 307.9485 308.0892 308.2299 308.3706 308.5113 308.6520 308.7926 308.9333 309.0739 309.2146 309.3552 309.4958 309.6364 309.7770 309.9175 310.0581 310.1986 310.3392 310.4797 310.6202 310.7607 310.9012 311.0417 311.1822 311.3227 311.4631 311.6035 311.7440 311.8844 312.0248 312.1652 312.3056 312.4459 312.5863 312.7267 312.8670 313.0073 313.1476 313.2880 313.4282 313.5685 313.7088 313.8491 313.9893 314.1296 314.2698 314.4100 314.5502 314.6904 314.8306 314.9707 315.1109 315.2511 315.3912 315.5313 315.6714 315.8115 315.9516 316.0917 316.2318 316.3718 316.5119 316.6519 316.7920 316.9320 317.0720 317.2120 317.3519 317.4919 317.6319 317.7718 317.9117 318.0517 318.1916 318.3315 318.4714 318.6113 318.7511 318.8910 319.0308 319.1706 319.3105 319.4503 319.5901 319.7299 319.8696 320.0094 320.1492 320.2889 320.4286 320.5684 320.7081 320.8478 320.9874 321.1271 321.2668 321.4064 321.5461 321.6857 321.8253 321.9649 322.1045 322.2441 322.3837 322.5232 322.6628 322.8023 322.9418 323.0813 323.2208 323.3603 323.4998 323.6393 323.7787 323.9182 324.0576 324.1970 324.3364 324.4758 324.6152 324.7546 324.8940 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250131T150407.2Z 9162.627862 130 1 6.87 2 62.71 143.70 74.37 116.08 0.00 1 0.00 1 0 17 1.799e-02 8.384e-03 1.239e-02 5.057e-03 2.817699e-01 2.585834e-03 3.362725e-03 -6.000000e+00 1.036332e-02 224.65 -2.00 3.43 -2.00 316.62 0.00e+00 -3.524992e-05 3.149927e-04 7.618267e-05 -6.000000e+00 4.563320e-04 278.55 -2.00 20.00 -2.00 316.00 0.00e+00 2.170 0.000 302.00 328.00 3 5.0553e+00 6.7029e-03 2.5710e-02 -6.0000e+00 2.5595e-02 3.0393e-02 7.5169e-03 1.4004e-02 -6.0000e+00 2.7820e-02 -1.1073e-02 4.4323e-03 6.9485e-03 -6.0000e+00 1.6567e-02 -1.4556e-03 2.1370e-03 1.9841e-03 -6.0000e+00 7.1023e-03 2.7725e-04 -6.9273e-05 1.4783e-04 2.4795e-05 -6.0000e+00 5.1129e-04 1.3412e-02 0.0000e+00 12 9 1 12 1 1 999.00 24.80 0.44 0.01341 0.01289 2 2 1 5 0 2288.050 33.25 19.97 24.80 17.97 5.0 1010.48 -1501 -9089 852 -1899 -3170 9091 -4773 1376 -874 379 4099 -3799 -3255 609 2695 -872 358 -2417 3049 3394 -946 164 2513 -4174 212 100 -29 1930 642 1305 2913 3080 2164 -4008 -1531 -543 -2712 987 -901 284 -1905 -808 -1418 -1394 729 256 -1818 -1336 1510 1013 1290 131 121 -406 760 1531 1154 1513 445 1966 836 1352 1536 108 -417 741 301 -12 1039 225 -405 -478 -313 284 187 545 -645 -422 -691 -638 -1362 -1602 -1610 -848 -1573 -426 -446 -514 164 316 -134 887 518 42 303 1386 309 -385 -568 -107 -204 -378 808 -310 -1816 -379 -265 2378 545 493 61 199 136 225 986 210 -442 -482 272 -627 -271 -383 222 337 108 -507 596 577 186 -141 -54 -506 186 420 -348 144 1099 -536 683 -335 -841 -481 -222 -1524 126 -262 -452 1165 -706 215 -151 66 693 -756 -738 153 681 -244 103 -748 926 1056 -308 53 834 -1574 80 38 -11 655 212 443 1055 1210 835 -1601 -619 -210 -1221 475 -523 170 -1246 -507 -911 -896 488 171 -1210 -869 953 667 851 93 91 -301 571 1167 887 1140 334 1476 672 1110 1354 99 -367 631 246 -10 917 211 -405 -486 -310 263 166 460 -514 -339 -582 -607 -1376 -1669 -1769 -935 -1874 -508 -554 -645 199 378 -148 928 543 44 341 1637 392 -507 -758 -135 -249 -451 953 -378 -2299 -496 -348 3192 763 733 90 301 193 308 1298 271 -594 -659 395 -914 -393 -542 314 453 144 -649 776 757 253 -205 -78 -748 283 646 -549 233 1807 -907 1123 -537 -1353 -748 SS 20250131T163943.4Z 9162.694252 192 1 54.63 2 54.95 168.87 58.87 134.65 0.00 1 0.00 1 0 17 7.669e-03 5.704e-03 5.951e-04 3.713e-04 2.210960e-01 1.910343e-04 2.668475e-03 -6.000000e+00 4.418071e-03 224.65 -2.00 3.43 -2.00 315.40 0.00e+00 2.013007e-04 1.776732e-05 2.509133e-05 -6.000000e+00 1.945613e-04 278.55 -2.00 20.00 -2.00 314.84 0.00e+00 1.736 0.000 302.00 328.00 3 2.9339e+00 4.8831e-04 2.0452e-02 -6.0000e+00 1.0912e-02 1.8869e-03 5.4402e-04 1.0983e-02 -6.0000e+00 1.1861e-02 -1.7447e-03 3.1251e-04 5.4449e-03 -6.0000e+00 7.0630e-03 -5.7273e-04 1.4184e-04 1.5614e-03 -6.0000e+00 3.0276e-03 3.9368e-03 3.0877e-05 1.0809e-05 2.0657e-05 -6.0000e+00 2.1799e-04 1.3988e-02 0.0000e+00 10 0 0 10 0 0 99.99 24.91 0.33 0.01399 0.01422 551 53 1 5 0 99.140 33.25 20.00 24.91 18.74 5.0 1016.64 -1419 -1851 -2255 -3068 -1069 -481 446 748 -369 -1165 -559 -1 -85 396 135 -183 637 524 869 989 636 1132 1285 789 451 26 -130 106 876 1421 1644 1546 277 -1785 -998 -558 -561 28 -477 -1033 -1089 -851 -1050 -711 -449 -889 -786 -570 -205 553 537 468 664 459 551 697 405 432 702 946 1087 1209 1101 301 -434 48 174 762 896 19 -49 -111 38 143 -103 93 62 302 -66 -789 -1190 -1647 -1698 -1064 -868 -592 -349 -196 100 46 375 384 799 935 448 462 370 -43 -369 -212 -402 -38 426 -243 -909 -647 -476 -367 161 84 7 -32 45 156 587 697 544 297 -33 -437 -210 -14 87 355 577 542 1112 837 345 142 -140 -103 109 -17 -167 -187 101 -273 -258 -224 -283 -378 -420 -531 -676 -836 -263 -119 120 224 -111 -356 -169 0 -31 152 54 -77 275 234 399 464 299 533 590 384 229 13 -64 51 404 663 817 776 147 -936 -495 -287 -311 17 -317 -734 -820 -660 -792 -558 -350 -686 -588 -414 -147 404 417 368 548 377 462 594 348 365 585 799 969 1118 1046 293 -402 42 151 675 845 19 -50 -113 39 138 -99 83 53 260 -60 -749 -1209 -1747 -1830 -1209 -1022 -716 -424 -241 124 53 423 408 826 985 497 530 454 -55 -465 -261 -475 -43 486 -289 -1130 -841 -625 -489 220 120 11 -46 62 204 732 873 682 385 -44 -601 -289 -19 116 462 734 676 1352 1066 457 193 -192 -143 155 -25 -252 -282 155 -418 -400 -335 -421 -548 SS 20250131T164417.6Z 9162.697426 195 1 54.63 2 54.78 170.19 58.23 135.70 0.00 1 0.00 1 0 17 7.482e-03 5.754e-03 3.266e-04 2.130e-04 2.204303e-01 1.095955e-04 2.663022e-03 -6.000000e+00 4.310222e-03 224.65 -2.00 3.43 -2.00 315.25 0.00e+00 2.597718e-04 9.893225e-06 2.477544e-05 -6.000000e+00 1.898146e-04 278.55 -2.00 20.00 -2.00 314.70 0.00e+00 1.729 0.000 302.00 328.00 3 1.8612e+00 2.7958e-04 2.0375e-02 -6.0000e+00 1.0645e-02 -2.1692e-03 3.1138e-04 1.0955e-02 -6.0000e+00 1.1571e-02 -2.8720e-03 1.7889e-04 5.4243e-03 -6.0000e+00 6.8906e-03 -2.3107e-04 8.0490e-05 1.5551e-03 -6.0000e+00 2.9537e-03 1.1625e-02 3.8803e-07 6.1909e-06 2.0979e-05 -6.0000e+00 2.1267e-04 1.4072e-02 0.0000e+00 10 0 0 10 0 0 99.83 24.92 0.31 0.01407 0.01407 1035 100 1 5 0 52.770 33.25 20.00 24.92 18.90 5.0 1017.87 -1204 -1481 -2315 -2838 -1094 -333 436 701 -260 -1049 -507 157 38 331 216 -144 416 748 756 980 640 1341 1151 689 485 5 -412 118 940 1444 1572 1374 114 -1656 -887 -671 -654 -20 -506 -1071 -1001 -871 -995 -716 -484 -814 -721 -598 -132 549 513 519 743 478 555 674 364 386 721 1058 1130 1249 999 244 -406 27 145 726 971 42 -78 -82 -11 156 -56 155 125 268 -79 -795 -1217 -1676 -1663 -1019 -924 -642 -336 -222 7 72 345 386 876 973 498 456 379 -39 -387 -279 -379 -71 406 -258 -933 -639 -515 -215 140 89 8 -76 119 174 596 749 563 309 8 -476 -240 -50 149 350 590 498 1128 849 341 137 -121 -122 124 -20 -147 -173 41 -279 -270 -205 -270 -372 -381 -458 -744 -827 -309 -94 125 224 -84 -346 -166 55 14 130 94 -63 187 346 361 478 313 654 555 351 246 3 -214 57 450 700 771 724 61 -866 -461 -362 -366 -12 -348 -794 -756 -678 -759 -564 -379 -630 -542 -453 -98 418 400 413 599 401 475 586 308 332 612 910 993 1148 951 239 -377 24 124 634 909 41 -79 -85 -11 152 -53 136 105 226 -71 -756 -1248 -1756 -1831 -1151 -1060 -761 -414 -270 8 84 388 417 914 1004 545 523 456 -49 -497 -349 -450 -81 463 -309 -1176 -820 -674 -286 192 126 11 -108 162 226 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