File name: Pandora255s1_VirginiaBeachVA-CBBT_20250205_L2Fit_fwvt1c3d20240302p1-8.txt File generation date: 20250207T174435.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: John Anderson Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 255 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora255_OF_v2d20221206.txt Instrument calibration file used: Pandora255s1_CF_v3d20240302.txt Level 1 file used: Pandora255s1_VirginiaBeachVA-CBBT_20250205_L1_smca1c3d20240302p1-8.txt Full location name: Chesapeake Bay Bridge Tunnel Virginia Short location name: VirginiaBeachVA-CBBT Country of location: United States Location latitude [deg]: 37.0367 Location longitude [deg]: -76.0766 Location altitude [m]: 20 Local noon date: 20250205 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1614 1764 Nominal wavelengths inside fitting window [nm]: 492.0213 492.1424 492.2635 492.3846 492.5056 492.6266 492.7476 492.8686 492.9896 493.1105 493.2315 493.3524 493.4733 493.5942 493.7151 493.8359 493.9567 494.0776 494.1984 494.3192 494.4399 494.5607 494.6814 494.8021 494.9228 495.0435 495.1642 495.2848 495.4055 495.5261 495.6467 495.7673 495.8878 496.0084 496.1289 496.2494 496.3699 496.4904 496.6109 496.7313 496.8518 496.9722 497.0926 497.2129 497.3333 497.4537 497.5740 497.6943 497.8146 497.9349 498.0551 498.1754 498.2956 498.4158 498.5360 498.6562 498.7763 498.8965 499.0166 499.1367 499.2568 499.3769 499.4969 499.6170 499.7370 499.8570 499.9770 500.0970 500.2169 500.3369 500.4568 500.5767 500.6966 500.8164 500.9363 501.0561 501.1760 501.2958 501.4155 501.5353 501.6551 501.7748 501.8945 502.0142 502.1339 502.2536 502.3732 502.4928 502.6124 502.7320 502.8516 502.9712 503.0907 503.2103 503.3298 503.4493 503.5687 503.6882 503.8076 503.9271 504.0465 504.1659 504.2852 504.4046 504.5239 504.6432 504.7626 504.8818 505.0011 505.1204 505.2396 505.3588 505.4780 505.5972 505.7164 505.8355 505.9547 506.0738 506.1929 506.3119 506.4310 506.5501 506.6691 506.7881 506.9071 507.0261 507.1450 507.2640 507.3829 507.5018 507.6207 507.7396 507.8584 507.9773 508.0961 508.2149 508.3337 508.4525 508.5712 508.6899 508.8087 508.9274 509.0460 509.1647 509.2834 509.4020 509.5206 509.6392 509.7578 509.8763 509.9949 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20250205T140934.1Z 9167.589978 136 1 3.88 2 68.97 130.84 108.15 43.96 0.00 1 0.00 1 0 15 2.250e-03 2.246e-03 1.836e-03 1.834e-03 2.667675e+03 1.092391e+02 1.913537e+02 -6.000000e+00 1.241106e+02 278.51 -2.00 20.00 -2.00 505.26 0.00e+00 5.035944e-04 5.012679e-05 3.261522e-05 -6.000000e+00 6.276274e-05 278.51 -2.00 20.00 -2.00 500.49 0.00e+00 1.800525e-01 3.626937e-02 2.110199e-02 -6.000000e+00 4.491868e-02 224.81 -2.00 3.43 -2.00 502.07 0.00e+00 2.760 0.000 489.00 513.00 1 6.4149e+00 2.7741e-03 4.3965e-03 -6.0000e+00 3.4384e-03 4.9515e-03 7.1867e-04 5.3672e-04 -6.0000e+00 8.9476e-04 2.1151e-03 1.6810e-04 1.8560e-04 2.7406e-05 -6.0000e+00 2.3486e-04 2.8463e-02 -8.1120e-05 12 1 1 12 1 1 999.00 24.38 1.46 0.02846 0.02963 2 4 1 4 0 1289.430 32.75 20.21 24.38 11.74 5.1 960.41 -92 -144 -23 -82 37 -122 491 312 -7 191 212 362 -208 -21 184 -98 43 42 -78 3 -343 106 318 297 323 63 -19 -171 110 -513 187 124 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101 15 190 167 -160 180 -88 153 233 424 -507 273 5 -256 290 148 -505 258 102 518 -145 498 439 -65 -126 -273 -338 -293 -286 900000 SQ 20250205T141832.5Z 9167.596209 139 1 5.95 2 67.63 132.66 106.92 45.61 0.00 1 0.00 1 0 15 1.915e-03 1.913e-03 1.010e-04 1.009e-04 2.464639e+03 5.961060e+00 1.734227e+02 -6.000000e+00 1.055988e+02 278.51 -2.00 20.00 -2.00 505.28 0.00e+00 5.148927e-04 2.758891e-06 3.248082e-05 -6.000000e+00 5.339412e-05 278.51 -2.00 20.00 -2.00 500.56 0.00e+00 1.065875e-01 1.989169e-03 2.065095e-02 -6.000000e+00 3.820767e-02 224.81 -2.00 3.43 -2.00 502.14 0.00e+00 2.606 0.000 489.00 513.00 1 1.4909e+00 1.5213e-04 4.1785e-03 -6.0000e+00 2.9248e-03 -9.9410e-03 3.9367e-05 5.1275e-04 -6.0000e+00 7.6084e-04 2.9910e-01 -1.7042e-05 1.0251e-05 2.5187e-05 -6.0000e+00 1.9982e-04 2.5575e-02 -4.1866e-05 10 0 0 10 0 0 99.26 24.39 1.44 0.02558 0.02546 1207 116 1 4 0 4.920 32.75 20.03 24.39 11.93 5.0 962.31 -186 -192 -130 -3 22 305 461 299 283 216 142 69 -142 -196 -214 -243 -162 -54 -15 -131 4 219 191 259 326 273 161 110 -155 -225 -62 -36 -80 168 28 -179 5 103 -23 -54 26 40 65 135 188 156 162 55 -34 -232 -392 -388 -437 -357 -205 -252 -255 -138 19 142 254 298 212 202 187 158 135 46 -76 -197 -129 -48 -138 -92 -69 -217 -208 -102 -127 -208 -266 -268 -315 -122 -63 -217 -208 -72 -86 -57 12 132 126 20 106 170 23 -155 -155 -256 -292 -255 -201 -145 -309 -299 -97 -48 2 65 10 -31 69 203 290 385 409 327 219 224 214 182 166 256 58 37 228 211 149 221 67 -57 3 -47 -93 41 -26 -208 -81 89 91 127 219 130 15 -70 -178 -217 -228 -238 900000 -177 -185 -127 -3 22 309 469 307 292 221 145 69 -143 -195 -212 -241 -163 -55 -15 -135 4 225 197 268 338 283 167 112 -157 -225 -61 -36 -80 170 29 -184 6 105 -23 -55 26 41 66 139 193 160 166 57 -34 -232 -387 -379 -422 -346 -200 -250 -256 -140 19 144 257 303 216 207 189 159 135 46 -75 -192 -125 -46 -136 -90 -68 -214 -205 -99 -124 -202 -256 -260 -308 -118 -62 -216 -207 -72 -85 -57 12 133 127 21 106 170 23 -150 -149 -245 -279 -243 -194 -143 -309 -302 -97 -48 2 64 10 -32 70 207 293 391 417 334 223 227 214 181 165 254 58 37 228 211 149 220 66 -55 3 -45 -90 40 -26 -206 -82 89 92 128 223 131 15 -72 -178 -215 -225 -233 900000 SQ 20250205T141838.5Z 9167.596279 139 2 5.95 2 67.62 132.69 106.91 45.63 0.00 1 0.00 1 0 15 1.827e-03 1.827e-03 3.277e-04 3.273e-04 2.493366e+03 1.941932e+01 1.760075e+02 -6.000000e+00 1.007793e+02 278.51 -2.00 20.00 -2.00 505.28 0.00e+00 4.906582e-04 8.945307e-06 3.148509e-05 -6.000000e+00 5.095694e-05 278.51 -2.00 20.00 -2.00 500.54 0.00e+00 1.236392e-01 6.458276e-03 2.066591e-02 -6.000000e+00 3.646344e-02 224.81 -2.00 3.43 -2.00 502.12 0.00e+00 2.604 0.000 489.00 513.00 1 3.7534e+00 4.9395e-04 4.1735e-03 -6.0000e+00 2.7913e-03 -5.4841e-03 1.2761e-04 5.1540e-04 -6.0000e+00 7.2610e-04 3.1107e-02 -1.7213e-05 3.3133e-05 2.5211e-05 -6.0000e+00 1.9070e-04 2.6107e-02 -4.4073e-05 10 0 0 10 0 0 99.35 24.39 1.46 0.02611 0.02599 1207 116 1 4 0 4.920 32.75 20.03 24.39 11.93 5.0 962.31 -184 -183 -143 -15 40 312 439 230 291 193 159 68 -167 -145 -172 -167 -147 -28 11 -87 -11 184 125 223 341 200 145 58 -164 -305 -31 -10 -126 171 23 -158 92 121 -10 -52 29 23 38 99 170 96 216 19 51 -216 -367 -364 -454 -398 -190 -241 -304 -202 45 192 206 328 210 217 134 148 157 46 -78 -173 -136 -27 -169 -80 -24 -268 -261 -78 -87 -133 -260 -284 -251 -78 -22 -186 -159 -83 -84 -20 14 136 137 -78 36 185 28 -130 -139 -195 -263 -251 -203 -112 -306 -294 -30 -37 -27 7 -8 -54 62 174 267 343 362 318 185 250 199 170 182 191 41 68 188 149 185 175 65 -91 18 -17 -73 26 45 -206 -59 176 152 67 161 136 0 -165 -145 -176 -196 -224 900000 -178 -179 -139 -15 40 319 456 234 297 201 163 69 -167 -143 -168 -164 -146 -28 11 -89 -11 190 130 230 353 208 150 59 -170 -307 -30 -10 -127 176 24 -165 95 124 -11 -52 30 23 39 102 177 100 224 20 51 -220 -364 -352 -433 -382 -186 -244 -305 -206 46 194 209 333 214 222 136 149 155 46 -77 -170 -133 -26 -166 -80 -23 -261 -258 -75 -83 -128 -250 -275 -246 -77 -22 -181 -156 -81 -83 -20 14 136 139 -80 37 184 27 -127 -134 -184 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