File name: Pandora255s1_VirginiaBeachVA-CBBT_20250331_L2Fit_fout2c3d20240302p1-8.txt File generation date: 20250401T151938.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: John Anderson Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 255 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora255_OF_v2d20221206.txt Instrument calibration file used: Pandora255s1_CF_v3d20240302.txt Level 1 file used: Pandora255s1_VirginiaBeachVA-CBBT_20250331_L1_smca1c3d20240302p1-8.txt Full location name: Chesapeake Bay Bridge Tunnel Virginia Short location name: VirginiaBeachVA-CBBT Country of location: United States Location latitude [deg]: 37.0367 Location longitude [deg]: -76.0766 Location altitude [m]: 20 Local noon date: 20250331 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 195 336 Nominal wavelengths inside fitting window [nm]: 305.1318 305.2728 305.4137 305.5546 305.6955 305.8364 305.9773 306.1182 306.2590 306.3999 306.5407 306.6815 306.8224 306.9632 307.1040 307.2447 307.3855 307.5263 307.6670 307.8078 307.9485 308.0892 308.2299 308.3706 308.5113 308.6520 308.7926 308.9333 309.0739 309.2146 309.3552 309.4958 309.6364 309.7770 309.9175 310.0581 310.1986 310.3392 310.4797 310.6202 310.7607 310.9012 311.0417 311.1822 311.3227 311.4631 311.6035 311.7440 311.8844 312.0248 312.1652 312.3056 312.4459 312.5863 312.7267 312.8670 313.0073 313.1476 313.2880 313.4282 313.5685 313.7088 313.8491 313.9893 314.1296 314.2698 314.4100 314.5502 314.6904 314.8306 314.9707 315.1109 315.2511 315.3912 315.5313 315.6714 315.8115 315.9516 316.0917 316.2318 316.3718 316.5119 316.6519 316.7920 316.9320 317.0720 317.2120 317.3519 317.4919 317.6319 317.7718 317.9117 318.0517 318.1916 318.3315 318.4714 318.6113 318.7511 318.8910 319.0308 319.1706 319.3105 319.4503 319.5901 319.7299 319.8696 320.0094 320.1492 320.2889 320.4286 320.5684 320.7081 320.8478 320.9874 321.1271 321.2668 321.4064 321.5461 321.6857 321.8253 321.9649 322.1045 322.2441 322.3837 322.5232 322.6628 322.8023 322.9418 323.0813 323.2208 323.3603 323.4998 323.6393 323.7787 323.9182 324.0576 324.1970 324.3364 324.4758 324.6152 324.7546 324.8940 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250331T175004.2Z 9221.743104 5 1 28.63 2 33.95 198.86 24.59 131.13 0.00 1 0.00 1 0 17 7.132e-03 5.960e-03 1.210e-04 9.468e-05 1.693852e-01 4.976179e-05 2.045185e-03 -6.000000e+00 4.154821e-03 227.88 -2.00 3.43 -2.00 314.26 0.00e+00 2.111728e-04 3.722842e-06 1.466039e-05 -6.000000e+00 1.831931e-04 281.50 -2.00 20.00 -2.00 313.75 0.00e+00 1.205 0.000 302.00 328.00 3 1.7469e-01 1.2668e-04 1.4780e-02 -6.0000e+00 1.0327e-02 9.7285e-03 1.4017e-04 8.5214e-03 -6.0000e+00 1.1197e-02 -2.6533e-03 8.0448e-05 4.1872e-03 -6.0000e+00 6.6628e-03 -3.7924e-04 3.4915e-05 1.1798e-03 -6.0000e+00 2.8411e-03 1.1399e-01 -4.1828e-05 2.7516e-06 1.7081e-05 -6.0000e+00 2.0293e-04 2.0713e-02 0.0000e+00 10 0 0 10 0 0 56.76 25.53 0.31 0.02071 0.02040 3067 296 1 5 0 9.330 32.50 19.97 25.53 25.95 5.8 1084.44 -1035 -1206 -1848 -2159 -261 254 1174 955 39 -774 -247 437 114 349 66 -324 332 772 770 838 544 1255 964 621 254 -170 -536 89 936 1515 1540 1362 130 -1676 -746 -625 -622 -5 -559 -1153 -1081 -954 -1084 -806 -647 -939 -793 -609 -190 539 543 487 782 485 617 752 398 506 799 1046 1139 1167 943 238 -500 11 86 681 925 16 -45 -55 95 225 11 229 128 305 -25 -788 -1168 -1697 -1621 -990 -955 -659 -369 -265 13 66 333 295 848 942 434 419 385 -2 -347 -159 -300 -22 383 -241 -920 -637 -586 -381 135 60 16 -42 110 186 581 697 538 323 40 -409 -188 27 177 417 665 479 1082 816 273 110 -135 -167 72 -14 -154 -173 27 -250 -248 -172 -298 -434 -466 -533 -822 -905 -103 101 481 414 17 -345 -113 201 56 182 36 -185 192 438 448 497 322 739 588 383 162 -106 -331 52 537 867 891 836 80 -1050 -441 -385 -405 -3 -440 -950 -910 -824 -947 -700 -557 -793 -664 -505 -154 442 456 418 681 436 563 676 360 463 721 959 1072 1120 936 239 -486 10 77 619 882 16 -47 -58 98 230 10 207 113 268 -22 -761 -1183 -1807 -1765 -1111 -1099 -785 -447 -323 15 77 368 309 869 980 466 472 456 -3 -425 -193 -345 -25 427 -285 -1118 -791 -742 -490 178 81 21 -57 145 233 687 821 640 403 51 -541 -249 36 229 523 808 565 1268 975 340 141 -174 -217 94 -18 -216 -244 38 -360 -353 -242 -416 -590 SS 20250331T175033.0Z 9221.743438 5 2 28.63 2 33.98 199.07 24.52 131.33 0.00 1 0.00 1 0 17 7.129e-03 5.947e-03 1.213e-04 9.480e-05 1.695300e-01 4.982256e-05 2.046894e-03 -6.000000e+00 4.153221e-03 227.88 -2.00 3.43 -2.00 314.26 0.00e+00 2.164772e-04 3.730502e-06 1.518276e-05 -6.000000e+00 1.831257e-04 281.50 -2.00 20.00 -2.00 313.76 0.00e+00 1.205 0.000 302.00 328.00 3 1.7628e-01 1.2684e-04 1.4788e-02 -6.0000e+00 1.0324e-02 9.7237e-03 1.4035e-04 8.5289e-03 -6.0000e+00 1.1193e-02 -2.5466e-03 8.0549e-05 4.1908e-03 -6.0000e+00 6.6603e-03 -4.2421e-04 3.4963e-05 1.1815e-03 -6.0000e+00 2.8400e-03 1.1372e-01 -4.5039e-05 2.7547e-06 1.7093e-05 -6.0000e+00 2.0286e-04 2.0820e-02 0.0000e+00 10 0 0 10 0 0 73.15 25.53 0.32 0.02082 0.02048 3067 296 1 5 0 9.330 32.75 19.97 25.53 25.95 5.8 1084.44 -1014 -1188 -1844 -2155 -309 221 1206 990 34 -778 -269 435 124 345 81 -310 284 765 750 814 526 1264 981 641 247 -179 -543 63 941 1528 1560 1387 145 -1677 -745 -634 -607 -21 -584 -1175 -1068 -954 -1054 -805 -618 -954 -757 -616 -208 529 542 531 762 485 617 749 419 511 791 1025 1145 1128 943 240 -483 12 82 666 928 -6 -44 -42 78 229 20 229 150 319 -5 -782 -1185 -1700 -1625 -1004 -958 -654 -359 -264 10 56 321 303 831 931 439 418 390 -11 -329 -162 -318 -1 374 -237 -885 -639 -578 -375 136 52 8 -49 108 178 593 701 543 322 34 -402 -191 10 181 395 675 481 1081 816 268 121 -136 -169 76 -14 -161 -166 32 -252 -237 -172 -295 -449 -455 -523 -819 -901 -122 88 493 429 15 -346 -123 200 60 179 44 -177 164 433 436 483 312 743 598 395 158 -112 -334 37 539 874 902 851 90 -1049 -440 -391 -394 -15 -460 -969 -899 -823 -921 -698 -531 -806 -633 -510 -168 433 455 456 663 436 563 673 378 467 713 940 1077 1082 935 242 -470 11 74 606 884 -6 -46 -44 80 235 19 207 133 280 -5 -755 -1201 -1810 -1769 -1126 -1103 -780 -434 -323 12 65 355 317 852 969 472 471 463 -14 -403 -197 -365 -2 417 -280 -1075 -793 -732 -482 180 71 12 -67 143 223 701 826 646 401 44 -532 -253 14 235 496 820 566 1268 975 334 154 -175 -219 100 -19 -225 -235 45 -363 -337 -243 -411 -611 SS 20250331T175507.0Z 9221.746609 8 1 28.81 2 34.30 201.02 23.85 133.30 0.00 1 0.00 1 0 17 7.269e-03 5.870e-03 1.169e-03 8.833e-04 1.712600e-01 4.632065e-04 2.056470e-03 -6.000000e+00 4.235168e-03 227.88 -2.00 3.43 -2.00 314.45 0.00e+00 1.569234e-04 3.587862e-05 1.494396e-05 -6.000000e+00 1.867283e-04 281.50 -2.00 20.00 -2.00 313.93 0.00e+00 1.210 0.000 302.00 328.00 3 4.5524e+00 1.1809e-03 1.4866e-02 -6.0000e+00 1.0527e-02 3.7639e-02 1.3070e-03 8.5957e-03 -6.0000e+00 1.1414e-02 -2.2185e-03 7.5011e-04 4.2235e-03 -6.0000e+00 6.7916e-03 -8.8683e-04 3.2773e-04 1.1834e-03 -6.0000e+00 2.8961e-03 1.4040e-03 3.0426e-05 2.5686e-05 1.7117e-05 -6.0000e+00 2.0685e-04 2.0470e-02 0.0000e+00 12 1 1 12 1 1 100.00 25.71 0.34 0.02047 0.02070 87 16 1 5 0 327.360 33.50 20.00 25.71 27.57 5.4 1090.23 -930 -1358 -2167 -2654 -535 427 982 1048 -19 -695 103 313 -289 377 490 -174 694 639 600 1043 588 1442 1082 924 88 -164 -169 -352 815 1287 1207 1575 -19 -1673 -599 -209 -536 -51 -540 -1096 -1118 -1007 -1012 -945 -719 -841 -967 -813 -349 622 504 159 707 283 649 831 263 597 553 921 1088 1183 1108 426 -467 46 163 795 989 -29 3 83 161 315 -52 2 133 244 -266 -704 -1126 -1762 -1654 -1140 -750 -584 -11 -172 187 145 209 250 744 750 237 454 502 33 -363 -130 -351 -93 390 -307 -870 -622 -579 -427 168 111 14 136 107 149 477 609 487 239 103 -322 -85 51 91 407 602 391 981 861 183 170 -222 -173 113 -60 -161 -136 5 -225 -251 -139 -234 -399 -391 -548 -903 -994 -194 154 358 424 -8 -303 44 131 -135 184 259 -96 388 345 332 587 331 805 626 560 53 -99 -102 -197 453 715 705 914 -12 -991 -355 -121 -335 -36 -421 -904 -926 -855 -868 -806 -607 -729 -808 -654 -287 493 422 134 620 257 596 771 245 548 502 848 1010 1178 1120 436 -451 44 146 723 952 -30 4 88 166 320 -50 2 116 211 -240 -682 -1155 -1871 -1839 -1286 -871 -720 -13 -214 226 170 231 270 750 768 252 511 598 41 -451 -158 -412 -107 433 -369 -1082 -778 -754 -557 221 153 19 185 139 184 563 727 578 303 135 -429 -114 67 118 518 727 464 1132 1035 226 213 -285 -225 150 -80 -222 -194 7 -322 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