File name: Pandora255s1_VirginiaBeachVA-CBBT_20250624_L2Fit_fwvt1c3d20240302p1-8.txt File generation date: 20250625T051524.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: John Anderson Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 255 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora255_OF_v2d20221206.txt Instrument calibration file used: Pandora255s1_CF_v3d20240302.txt Level 1 file used: Pandora255s1_VirginiaBeachVA-CBBT_20250624_L1_smca1c3d20240302p1-8.txt Full location name: Chesapeake Bay Bridge Tunnel Virginia Short location name: VirginiaBeachVA-CBBT Country of location: United States Location latitude [deg]: 37.0367 Location longitude [deg]: -76.0766 Location altitude [m]: 20 Local noon date: 20250624 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1614 1764 Nominal wavelengths inside fitting window [nm]: 492.0213 492.1424 492.2635 492.3846 492.5056 492.6266 492.7476 492.8686 492.9896 493.1105 493.2315 493.3524 493.4733 493.5942 493.7151 493.8359 493.9567 494.0776 494.1984 494.3192 494.4399 494.5607 494.6814 494.8021 494.9228 495.0435 495.1642 495.2848 495.4055 495.5261 495.6467 495.7673 495.8878 496.0084 496.1289 496.2494 496.3699 496.4904 496.6109 496.7313 496.8518 496.9722 497.0926 497.2129 497.3333 497.4537 497.5740 497.6943 497.8146 497.9349 498.0551 498.1754 498.2956 498.4158 498.5360 498.6562 498.7763 498.8965 499.0166 499.1367 499.2568 499.3769 499.4969 499.6170 499.7370 499.8570 499.9770 500.0970 500.2169 500.3369 500.4568 500.5767 500.6966 500.8164 500.9363 501.0561 501.1760 501.2958 501.4155 501.5353 501.6551 501.7748 501.8945 502.0142 502.1339 502.2536 502.3732 502.4928 502.6124 502.7320 502.8516 502.9712 503.0907 503.2103 503.3298 503.4493 503.5687 503.6882 503.8076 503.9271 504.0465 504.1659 504.2852 504.4046 504.5239 504.6432 504.7626 504.8818 505.0011 505.1204 505.2396 505.3588 505.4780 505.5972 505.7164 505.8355 505.9547 506.0738 506.1929 506.3119 506.4310 506.5501 506.6691 506.7881 506.9071 507.0261 507.1450 507.2640 507.3829 507.5018 507.6207 507.7396 507.8584 507.9773 508.0961 508.2149 508.3337 508.4525 508.5712 508.6899 508.8087 508.9274 509.0460 509.1647 509.2834 509.4020 509.5206 509.6392 509.7578 509.8763 509.9949 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20250624T100028.1Z 9306.416992 72 1 38.80 2 88.28 61.64 75.21 66.55 0.00 1 0.00 1 0 29 1.385e-02 1.366e-02 1.090e-03 1.086e-03 2.274668e+04 8.282344e+01 1.446938e+03 -6.000000e+00 7.984811e+02 289.64 -2.00 20.00 -2.00 505.42 0.00e+00 4.181065e-03 3.090722e-05 2.527847e-04 -6.000000e+00 3.969998e-04 289.64 -2.00 20.00 -2.00 501.01 0.00e+00 6.081413e-01 2.113748e-02 1.380153e-01 -6.000000e+00 2.773645e-01 232.74 -2.00 3.43 -2.00 502.51 0.00e+00 16.690 0.077 489.00 513.00 1 5.7506e+00 1.6208e-03 2.9449e-02 -6.0000e+00 2.1306e-02 -4.2465e-02 4.0439e-04 3.6542e-03 -6.0000e+00 5.5294e-03 5.0235e-04 4.3941e-03 9.6856e-05 1.6859e-04 -6.0000e+00 1.4474e-03 -3.3490e-02 3.5244e-04 12 9 9 12 1 1 43.61 24.92 9.42 -0.03349 -0.00301 13 2 1 4 0 2770.640 32.25 20.00 24.92 32.54 5.1 1100.00 -2310 -1745 -265 453 1737 2315 2917 2800 2920 2145 1121 790 -263 -1131 -1039 -956 -598 51 654 661 749 843 672 1145 1471 1389 924 597 -802 -1977 -2239 -2099 -1403 -424 294 379 202 -217 -890 -649 -698 138 466 1066 1364 1301 1216 997 133 -1085 -1800 -2671 -3009 -2339 -1195 -317 556 852 868 1172 1368 1554 1315 1189 776 699 -100 -733 -1075 -1733 -1838 -1630 -1300 -948 -668 -1215 -1587 -1995 -1872 -2076 -1842 -1616 -1343 -879 -893 -1047 -1125 -986 -671 -99 212 870 1514 125 1199 1180 264 -818 -1946 -3231 -3114 -2650 -1175 -646 -403 -110 -558 -572 -780 -629 -366 194 1269 1684 2325 2975 3078 2280 1921 1080 387 140 468 1137 1344 1413 1284 1056 928 781 275 -194 -301 -446 -792 -191 153 492 843 972 944 746 805 817 784 232 -698 -1700 -2068 -2019 900000 -2017 -1544 -239 421 1588 2155 2751 2668 2776 2034 1060 740 -246 -1055 -966 -895 -567 47 622 637 725 818 657 1121 1448 1374 916 587 -781 -1897 -2127 -2006 -1364 -409 290 377 200 -215 -879 -638 -691 137 468 1082 1356 1301 1214 1018 135 -1088 -1774 -2605 -2931 -2295 -1193 -314 559 865 884 1191 1394 1593 1359 1230 801 713 -101 -738 -1075 -1728 -1827 -1624 -1306 -960 -679 -1233 -1592 -1976 -1831 -2022 -1792 -1579 -1321 -872 -897 -1061 -1140 -992 -668 -98 210 869 1509 125 1181 1115 250 -760 -1797 -2996 -2908 -2460 -1129 -633 -411 -111 -567 -579 -791 -643 -379 202 1315 1742 2402 3090 3159 2396 2032 1139 403 143 487 1177 1401 1440 1319 1090 960 806 283 -198 -306 -454 -817 -200 163 517 897 1052 1036 806 874 888 849 251 -751 -1873 -2269 -2164 900000 SQ 20250624T100455.8Z 9306.420090 77 1 55.11 2 87.50 62.29 74.42 67.10 0.00 1 0.00 1 0 22 9.200e-03 9.049e-03 4.659e-04 4.643e-04 2.470098e+04 3.602798e+01 1.575124e+03 -6.000000e+00 5.301844e+02 289.64 -2.00 20.00 -2.00 505.42 0.00e+00 3.325153e-03 1.323313e-05 2.085214e-04 -6.000000e+00 2.635903e-04 289.64 -2.00 20.00 -2.00 500.96 0.00e+00 7.936302e-01 9.070929e-03 1.411094e-01 -6.000000e+00 1.840892e-01 232.74 -2.00 3.43 -2.00 502.47 0.00e+00 14.660 0.052 489.00 513.00 1 4.8251e+00 6.9577e-04 2.5816e-02 -6.0000e+00 1.4142e-02 -5.7885e-02 1.7333e-04 3.7425e-03 -6.0000e+00 3.6682e-03 1.6838e-03 2.9874e-03 4.0359e-05 1.6610e-04 -6.0000e+00 9.6134e-04 2.1293e-04 1.8740e-04 12 8 8 10 0 0 64.65 24.92 5.72 0.00021 0.02093 67 6 1 4 0 822.460 32.25 20.00 24.92 32.77 5.1 1100.00 -1312 -809 54 610 1304 1851 2132 1885 1884 1368 787 298 -177 -647 -787 -792 -367 29 406 431 566 607 594 685 930 901 649 205 -561 -1262 -1436 -1356 -829 -25 122 125 16 -246 -601 -613 -470 -145 290 590 833 805 717 402 -101 -811 -1444 -1813 -1898 -1549 -803 -215 116 470 520 675 826 989 906 849 600 304 -97 -422 -740 -1072 -1022 -978 -739 -508 -474 -744 -1147 -1320 -1204 -1382 -1205 -983 -925 -589 -537 -790 -699 -713 -468 -64 291 651 961 897 820 806 213 -447 -1350 -2189 -2303 -1823 -990 -556 -379 -329 -357 -493 -510 -259 -83 71 674 973 1408 1890 2076 1560 1032 537 226 26 340 720 925 879 914 739 653 564 138 -187 -229 -449 -600 -102 113 297 741 704 533 529 652 603 653 304 -262 -915 -1368 -1299 900000 -1167 -730 49 568 1213 1755 2006 1795 1793 1296 740 285 -168 -610 -741 -752 -345 28 397 417 551 593 583 676 923 897 646 203 -546 -1205 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-2.00 502.40 0.00e+00 12.732 0.034 489.00 513.00 1 3.7705e+00 3.8955e-04 2.2300e-02 -6.0000e+00 9.7509e-03 -5.5165e-02 9.7471e-05 3.4642e-03 -6.0000e+00 2.5284e-03 6.4221e-03 2.2513e-03 2.2683e-05 1.5290e-04 -6.0000e+00 6.6295e-04 1.4951e-03 1.9811e-04 12 9 9 12 1 1 44.09 24.92 3.50 0.00150 0.01711 155 18 1 4 0 290.140 32.25 20.00 24.92 32.96 5.1 1100.00 -771 -468 5 518 908 1325 1550 1446 1240 948 631 197 -194 -363 -502 -545 -276 71 198 163 281 428 390 564 656 649 467 81 -441 -862 -896 -875 -480 48 80 -121 -11 -189 -415 -431 -266 -86 90 349 485 458 436 174 -85 -683 -1088 -1308 -1400 -1016 -493 -230 -55 193 335 421 575 624 619 580 415 216 8 -301 -548 -741 -732 -579 -479 -272 -312 -578 -760 -816 -802 -922 -857 -651 -593 -400 -385 -511 -526 -415 -257 29 291 589 788 564 642 625 253 -313 -949 -1554 -1633 -1252 -848 -439 -403 -361 -357 -305 -323 -129 -96 10 360 634 998 1264 1398 1027 616 327 147 94 304 562 564 568 640 521 384 439 75 -180 -184 -285 -316 31 105 206 490 534 365 379 458 499 395 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