File name: Pandora255s1_VirginiaBeachVA-CBBT_20250629_L2Fit_fout2c3d20240302p1-8.txt File generation date: 20250630T052147.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: John Anderson Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 255 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora255_OF_v2d20221206.txt Instrument calibration file used: Pandora255s1_CF_v3d20240302.txt Level 1 file used: Pandora255s1_VirginiaBeachVA-CBBT_20250629_L1_smca1c3d20240302p1-8.txt Full location name: Chesapeake Bay Bridge Tunnel Virginia Short location name: VirginiaBeachVA-CBBT Country of location: United States Location latitude [deg]: 37.0367 Location longitude [deg]: -76.0766 Location altitude [m]: 20 Local noon date: 20250629 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 195 336 Nominal wavelengths inside fitting window [nm]: 305.1318 305.2728 305.4137 305.5546 305.6955 305.8364 305.9773 306.1182 306.2590 306.3999 306.5407 306.6815 306.8224 306.9632 307.1040 307.2447 307.3855 307.5263 307.6670 307.8078 307.9485 308.0892 308.2299 308.3706 308.5113 308.6520 308.7926 308.9333 309.0739 309.2146 309.3552 309.4958 309.6364 309.7770 309.9175 310.0581 310.1986 310.3392 310.4797 310.6202 310.7607 310.9012 311.0417 311.1822 311.3227 311.4631 311.6035 311.7440 311.8844 312.0248 312.1652 312.3056 312.4459 312.5863 312.7267 312.8670 313.0073 313.1476 313.2880 313.4282 313.5685 313.7088 313.8491 313.9893 314.1296 314.2698 314.4100 314.5502 314.6904 314.8306 314.9707 315.1109 315.2511 315.3912 315.5313 315.6714 315.8115 315.9516 316.0917 316.2318 316.3718 316.5119 316.6519 316.7920 316.9320 317.0720 317.2120 317.3519 317.4919 317.6319 317.7718 317.9117 318.0517 318.1916 318.3315 318.4714 318.6113 318.7511 318.8910 319.0308 319.1706 319.3105 319.4503 319.5901 319.7299 319.8696 320.0094 320.1492 320.2889 320.4286 320.5684 320.7081 320.8478 320.9874 321.1271 321.2668 321.4064 321.5461 321.6857 321.8253 321.9649 322.1045 322.2441 322.3837 322.5232 322.6628 322.8023 322.9418 323.0813 323.2208 323.3603 323.4998 323.6393 323.7787 323.9182 324.0576 324.1970 324.3364 324.4758 324.6152 324.7546 324.8940 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250629T103858.6Z 9311.443734 72 1 54.02 2 81.67 67.16 123.33 34.31 0.00 1 0.00 1 0 25 5.175e-01 4.489e-02 2.057e-01 7.961e-03 7.996231e-01 4.648861e-03 9.654968e-03 -6.000000e+00 3.134767e-01 232.70 -2.00 3.43 -2.00 321.53 0.00e+00 -2.905753e-03 2.319141e-03 9.264268e-03 -6.000000e+00 1.607090e-02 290.08 -2.00 20.00 -2.00 320.92 0.00e+00 6.475 0.004 302.00 328.00 3 2.9370e+00 1.6675e-02 9.5164e-02 -6.0000e+00 7.8674e-01 8.4233e-01 2.1629e-02 8.8360e-02 -6.0000e+00 8.5164e-01 -1.2147e+00 1.6332e-02 2.6171e-02 -6.0000e+00 5.0533e-01 5.1596e-01 7.6991e-03 1.1836e-02 -6.0000e+00 2.1697e-01 1.8598e-05 -2.8199e-03 2.2536e-04 8.1190e-05 -6.0000e+00 1.5066e-02 3.8415e-02 0.0000e+00 12 8 8 10 0 0 -79.44 24.67 1.10 0.03841 0.01722 22 2 1 5 0 2455.140 32.00 20.00 24.67 33.00 5.0 1100.00 900000 94351 -23411 -125661 900000 -6602 -147903 -88326 900000 900000 -68476 -44987 12516 -59041 152934 -50006 900000 -29166 -21417 900000 46307 900000 900000 900000 -18749 -46006 244319 -67229 900000 130708 19151 114107 75942 59972 106528 900000 164382 14453 83572 900000 23060 57982 45111 101863 96256 900000 14235 50119 45995 49829 169213 24353 27233 32715 43346 25666 25860 53748 -50 26457 16002 38619 30045 6362 31954 29152 28077 24685 -4769 -3621 4369 12108 20081 7784 -999 -9639 -2338 12037 5881 4985 -4036 1969 -9112 -7235 3295 10056 -4123 -8952 13 -4035 -1700 1922 -188 -9496 -8820 3903 -1520 -5882 -4617 97 -216 763 -7443 -5721 -8736 -3222 -1830 37070 -2694 -4420 507 -579 -52 2214 -971 85 1540 1045 1887 3781 641 -1338 3865 2595 1245 709 670 3319 73 426 -1428 253 -259 -965 1320 -427 1250 82 439 -2158 43 -2514 900000 797 -593 -7606 900000 -107 -10514 -3730 900000 900000 -2603 -1552 291 -3324 1184 -3203 900000 -1642 -1115 900000 1141 900000 900000 900000 -1003 -3173 1892 -4921 900000 1619 845 2209 2293 2043 2144 900000 2164 1018 3494 900000 2107 3816 3353 4180 4099 900000 1378 3492 3525 4012 4585 3073 3605 4356 5403 3915 3904 5867 -9 3544 2515 5412 5164 1492 5814 5372 5369 5313 -1573 -1315 1542 3937 5690 2266 -282 -2724 -612 3001 1844 1872 -1922 988 -4990 -4140 1807 5422 -2644 -6036 8 -2363 -913 1058 -99 -6122 -6599 3016 -1438 -6487 -5196 99 -202 638 -6569 -5247 -8818 -3257 -1961 29692 -3344 -6325 754 -900 -80 3193 -1392 121 2235 1612 3016 5911 995 -2029 5389 3539 1665 926 901 4893 127 769 -2853 528 -581 -2171 3073 -1039 3027 201 1029 -4848 95 -5379 SS 20250629T105817.7Z 9311.457149 81 1 54.51 2 78.08 69.82 121.18 39.01 0.00 1 0.00 1 0 17 3.064e-01 9.522e-03 4.363e-02 1.743e-03 6.192851e-01 9.305461e-04 6.926777e-03 -6.000000e+00 1.813429e-01 232.70 -2.00 3.43 -2.00 320.15 0.00e+00 1.151326e-03 3.295441e-04 1.154322e-03 -6.000000e+00 8.157101e-03 290.08 -2.00 20.00 -2.00 319.39 0.00e+00 4.690 0.002 302.00 328.00 3 2.4352e+00 2.8073e-03 5.7050e-02 -6.0000e+00 4.5471e-01 4.4473e-02 3.4989e-03 3.2714e-02 -6.0000e+00 4.9087e-01 -1.1293e-01 3.0381e-03 1.6163e-02 -6.0000e+00 2.9246e-01 4.5285e-02 1.5409e-03 4.5340e-03 -6.0000e+00 1.2412e-01 2.2613e-04 -3.7712e-04 4.8015e-05 5.2814e-05 -6.0000e+00 8.7354e-03 3.7780e-02 0.0000e+00 12 8 8 10 0 0 8.93 24.68 0.49 0.03778 0.03495 112 11 1 5 0 486.620 32.00 20.00 24.68 33.45 5.0 1100.00 -64026 -103137 -119602 -145387 -57169 -68653 -139935 -104460 -12408 -50574 -101629 -83870 -64758 -57900 -31296 -43520 44820 -29123 -27269 13997 -15415 -307 8207 -3805 -28513 -31932 -9888 -25203 -8467 -3163 -14954 1821 -3877 -5508 -3404 15153 47 -5048 1910 4070 -1138 2064 2643 2680 3976 8425 1089 253 3565 2980 6969 946 2784 1669 3388 1743 796 2513 326 2348 1932 3180 2648 804 1275 2021 1475 2482 291 -764 226 380 743 17 -695 -1619 -419 502 -945 -807 -1483 -2161 -2232 -1288 -454 224 -347 -302 703 0 650 339 318 -369 -262 349 -76 -580 -805 -506 -602 -23 -303 -761 -1628 -390 -523 -233 198 154 36 -174 152 463 688 918 836 323 45 21 -122 28 367 465 507 371 1136 897 6 -74 -371 -57 120 -106 -40 -219 155 -256 -239 -151 -106 -352 -598 -1560 -2134 -3137 -495 -712 -3376 -2023 -105 -670 -2487 -2095 -1694 -1771 -883 -1582 746 -1108 -1084 383 -574 -10 273 -156 -1604 -1910 -465 -1353 -403 -164 -1042 124 -306 -437 -261 1043 4 -617 263 627 -183 339 445 457 683 1553 202 49 714 662 1666 265 835 541 1133 614 285 867 113 817 671 1232 1156 381 594 914 685 1244 158 -467 145 244 454 9 -359 -844 -214 278 -573 -532 -1128 -1706 -1885 -1152 -431 210 -337 -295 660 0 570 284 270 -346 -265 381 -90 -756 -1067 -634 -728 -26 -333 -896 -1945 -486 -695 -319 284 245 58 -283 239 719 1017 1351 1283 504 74 35 -195 43 571 695 728 542 1691 1409 10 -132 -674 -108 232 -219 -84 -473 340 -541 -509 -304 -210 -675 SS 20250629T110952.3Z 9311.465189 84 1 54.69 2 75.90 71.38 119.78 41.70 0.00 1 0.00 1 0 25 1.334e-01 7.311e-03 1.328e-02 9.248e-04 5.439653e-01 4.873036e-04 6.168205e-03 -6.000000e+00 7.896292e-02 232.70 -2.00 3.43 -2.00 319.38 0.00e+00 8.250535e-04 1.341263e-04 7.236583e-04 -6.000000e+00 3.551930e-03 290.08 -2.00 20.00 -2.00 318.56 0.00e+00 4.013 0.001 302.00 328.00 3 1.9921e+00 1.3907e-03 4.9191e-02 -6.0000e+00 1.9800e-01 1.9964e-02 1.6387e-03 2.8384e-02 -6.0000e+00 2.1374e-01 -6.4953e-02 1.2579e-03 1.3778e-02 -6.0000e+00 1.2735e-01 2.3239e-02 6.5814e-04 3.7758e-03 -6.0000e+00 5.4046e-02 7.2190e-04 -3.4759e-04 2.5990e-05 4.2319e-05 -6.0000e+00 3.8037e-03 3.7924e-02 0.0000e+00 11 8 0 10 0 0 54.34 24.69 0.38 0.03792 0.03531 239 23 1 5 0 228.790 32.00 20.00 24.69 33.94 5.0 1100.00 -31758 -40316 -45288 -61625 -40086 -44666 -63182 -44768 -24481 -28156 -39962 -34363 -20852 -20218 -10247 -13177 2054 -10634 -5202 884 -5493 -712 295 -1719 -6787 -11339 -3097 -12516 -4832 -1369 -3111 -873 -778 -3847 -2933 -382 -395 -867 -194 817 -366 -546 440 1959 1259 1531 -276 -116 953 2078 2144 1678 1500 1328 1485 1415 755 1085 416 1432 1311 2028 2059 692 604 1437 518 1403 1006 166 -35 117 244 -122 -424 -402 -544 -187 -697 -1288 -1426 -1813 -1968 -1010 -691 -225 -318 -245 312 164 453 359 592 298 -365 380 73 -588 -787 -399 -511 -17 104 -1081 -1456 -879 -751 2399 5 -144 -34 78 324 346 782 854 390 321 -130 -312 -12 24 228 262 314 413 908 545 10 -2 -205 -86 38 -121 -122 -30 290 -250 -204 -139 -190 -328 -535 -803 -943 -1406 -712 -882 -1709 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