File name: Pandora255s1_VirginiaBeachVA-CBBT_20250711_L2Fit_fout2c3d20240302p1-8.txt File generation date: 20250712T052109.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: John Anderson Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 255 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora255_OF_v2d20221206.txt Instrument calibration file used: Pandora255s1_CF_v3d20240302.txt Level 1 file used: Pandora255s1_VirginiaBeachVA-CBBT_20250711_L1_smca1c3d20240302p1-8.txt Full location name: Chesapeake Bay Bridge Tunnel Virginia Short location name: VirginiaBeachVA-CBBT Country of location: United States Location latitude [deg]: 37.0367 Location longitude [deg]: -76.0766 Location altitude [m]: 20 Local noon date: 20250711 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 195 336 Nominal wavelengths inside fitting window [nm]: 305.1318 305.2728 305.4137 305.5546 305.6955 305.8364 305.9773 306.1182 306.2590 306.3999 306.5407 306.6815 306.8224 306.9632 307.1040 307.2447 307.3855 307.5263 307.6670 307.8078 307.9485 308.0892 308.2299 308.3706 308.5113 308.6520 308.7926 308.9333 309.0739 309.2146 309.3552 309.4958 309.6364 309.7770 309.9175 310.0581 310.1986 310.3392 310.4797 310.6202 310.7607 310.9012 311.0417 311.1822 311.3227 311.4631 311.6035 311.7440 311.8844 312.0248 312.1652 312.3056 312.4459 312.5863 312.7267 312.8670 313.0073 313.1476 313.2880 313.4282 313.5685 313.7088 313.8491 313.9893 314.1296 314.2698 314.4100 314.5502 314.6904 314.8306 314.9707 315.1109 315.2511 315.3912 315.5313 315.6714 315.8115 315.9516 316.0917 316.2318 316.3718 316.5119 316.6519 316.7920 316.9320 317.0720 317.2120 317.3519 317.4919 317.6319 317.7718 317.9117 318.0517 318.1916 318.3315 318.4714 318.6113 318.7511 318.8910 319.0308 319.1706 319.3105 319.4503 319.5901 319.7299 319.8696 320.0094 320.1492 320.2889 320.4286 320.5684 320.7081 320.8478 320.9874 321.1271 321.2668 321.4064 321.5461 321.6857 321.8253 321.9649 322.1045 322.2441 322.3837 322.5232 322.6628 322.8023 322.9418 323.0813 323.2208 323.3603 323.4998 323.6393 323.7787 323.9182 324.0576 324.1970 324.3364 324.4758 324.6152 324.7546 324.8940 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250711T142103.5Z 9323.597957 276 1 54.36 2 39.30 100.40 134.48 270.42 0.00 1 0.00 1 0 17 1.242e-02 1.393e-02 1.890e-03 1.287e-03 1.735717e-01 6.794267e-04 1.985989e-03 -6.000000e+00 7.335081e-03 232.59 -2.00 3.43 -2.00 315.03 0.00e+00 2.632997e-04 5.968842e-05 7.077258e-05 -6.000000e+00 3.321511e-04 291.16 -2.00 20.00 -2.00 314.29 0.00e+00 1.291 0.000 302.00 328.00 3 5.7668e+00 1.7588e-03 1.5644e-02 -6.0000e+00 1.8378e-02 -1.7253e-03 1.9478e-03 8.7291e-03 -6.0000e+00 1.9852e-02 1.6716e-02 1.1112e-03 4.1975e-03 -6.0000e+00 1.1838e-02 -1.6583e-03 4.8867e-04 1.1837e-03 -6.0000e+00 5.0179e-03 3.8467e-04 7.1538e-04 3.7618e-05 1.5384e-05 -6.0000e+00 3.5405e-04 5.2405e-02 0.0000e+00 12 8 8 10 0 0 99.97 24.61 0.37 0.05241 0.05778 41 4 1 5 0 1325.690 31.75 20.00 24.61 32.15 5.1 1100.00 -252 -1222 -2596 -3055 1211 1838 840 715 1416 688 -822 883 592 -647 -451 -1095 2291 -395 380 1922 529 2417 1373 1161 -520 -1022 -531 -810 504 1413 623 1022 -1209 -2492 -417 195 19 -335 -785 -678 -1238 -1355 -1272 -278 -270 -660 -1410 -1325 -197 334 890 171 646 118 548 193 40 487 672 1294 1772 1334 1253 -428 -740 -48 223 973 481 -106 179 131 543 134 92 -127 -109 896 -16 -715 -1281 -1538 -1286 -536 -211 279 241 103 529 437 458 450 1176 867 447 1251 674 -111 -641 -215 -601 299 588 192 -355 421 136 -9888 1144 661 421 2 3 -123 39 561 562 641 379 229 222 231 669 930 935 837 1404 1099 516 222 -317 -133 -55 -174 -330 -41 162 -296 -321 -413 -350 -248 -86 -428 -865 -912 355 509 260 245 503 243 -296 336 234 -288 -216 -506 1127 -191 187 948 263 1190 711 631 -296 -580 -282 -400 254 722 315 546 -672 -1325 -211 105 11 -234 -596 -528 -1011 -1135 -1072 -231 -223 -532 -1104 -1002 -155 255 714 146 538 102 477 171 35 421 579 1140 1655 1273 1257 -431 -688 -43 191 865 456 -110 185 136 572 133 87 -114 -92 767 -14 -684 -1351 -1643 -1437 -604 -254 338 302 129 640 513 512 481 1191 914 490 1427 810 -142 -810 -267 -692 343 662 234 -442 544 176 -14080 1602 928 593 3 4 -153 47 678 708 826 501 313 302 307 886 1163 1162 988 1640 1353 646 290 -424 -180 -74 -247 -471 -60 242 -448 -477 -594 -487 -353 SS 20250711T165830.7Z 9323.707299 306 1 54.94 2 15.24 169.87 162.32 312.46 0.00 1 0.00 1 0 17 7.337e-03 6.146e-03 8.790e-04 6.960e-04 1.497804e-01 3.716239e-04 1.767299e-03 -6.000000e+00 4.333418e-03 232.59 -2.00 3.43 -2.00 314.18 0.00e+00 1.068559e-04 2.794605e-05 1.462296e-05 -6.000000e+00 1.962097e-04 291.17 -2.00 20.00 -2.00 313.55 0.00e+00 1.036 0.000 302.00 328.00 3 4.9146e+00 9.5433e-04 1.2944e-02 -6.0000e+00 1.0858e-02 3.0700e-02 1.0524e-03 7.6229e-03 -6.0000e+00 1.1728e-02 -6.2568e-04 6.0333e-04 3.6874e-03 -6.0000e+00 6.9935e-03 -1.3478e-03 2.5929e-04 1.0039e-03 -6.0000e+00 2.9648e-03 1.2139e-03 1.2263e-04 2.0139e-05 1.4764e-05 -6.0000e+00 2.0914e-04 5.1634e-02 0.0000e+00 10 0 0 10 0 0 99.95 24.76 0.35 0.05163 0.05256 121 12 1 5 0 453.960 31.75 20.00 24.76 34.61 5.0 1100.00 -1063 -992 -2413 -1917 323 1053 1247 557 269 -467 63 533 -18 89 -165 -368 696 587 326 712 643 1492 906 764 42 -688 -524 -22 919 1716 1423 1139 -555 -1795 -218 -623 -302 -242 -727 -1171 -894 -975 -1142 -587 -633 -884 -930 -760 -124 544 670 441 790 610 756 387 359 666 812 1156 1265 1195 843 -138 -403 441 220 1114 632 -259 87 46 335 111 -67 22 414 452 -420 -1094 -1429 -1719 -1370 -925 -873 -470 -327 -252 43 15 395 476 1047 814 153 570 455 -196 -413 -167 -341 159 333 -596 -967 -499 -634 -131 225 17 90 7 21 163 503 772 406 285 -190 -359 -145 -48 306 676 591 529 1112 583 134 15 -176 -51 233 -96 -97 40 115 -267 -299 -243 -406 -417 -489 -459 -1060 -797 123 408 531 246 124 -214 28 255 -9 49 -92 -211 401 346 198 437 391 905 572 476 27 -442 -335 -13 540 1013 831 703 -353 -1091 -134 -386 -203 -182 -603 -1013 -766 -855 -1008 -512 -547 -779 -787 -647 -104 462 572 395 700 554 695 361 334 608 737 1073 1191 1206 856 -140 -392 404 202 1007 612 -266 93 50 349 113 -64 20 365 404 -397 -1054 -1509 -1854 -1480 -1061 -1032 -563 -405 -313 51 18 428 505 1048 842 165 647 545 -240 -499 -197 -388 180 372 -697 -1160 -622 -823 -170 305 24 122 9 28 199 594 898 475 359 -248 -469 -188 -63 383 830 716 607 1256 693 163 19 -218 -63 300 -126 -134 54 162 -379 -417 -329 -553 -557 SS 20250711T174850.8Z 9323.742255 315 1 5.69 2 17.24 211.91 166.91 350.89 0.00 1 0.00 1 0 17 7.486e-03 6.375e-03 9.692e-04 7.913e-04 1.498240e-01 4.228558e-04 1.779749e-03 -6.000000e+00 4.420894e-03 232.59 -2.00 3.43 -2.00 313.98 0.00e+00 2.057415e-04 3.076531e-05 1.111070e-05 -6.000000e+00 2.001971e-04 291.17 -2.00 20.00 -2.00 313.38 0.00e+00 1.047 0.000 302.00 328.00 3 2.9317e+00 1.0838e-03 1.3044e-02 -6.0000e+00 1.1077e-02 1.6081e-02 1.1940e-03 7.6583e-03 -6.0000e+00 1.1965e-02 -5.1934e-04 6.8615e-04 3.7048e-03 -6.0000e+00 7.1349e-03 -1.1516e-03 2.9352e-04 1.0163e-03 -6.0000e+00 3.0244e-03 8.7668e-03 1.0334e-06 2.2961e-05 1.5115e-05 -6.0000e+00 2.1338e-04 5.2293e-02 0.0000e+00 12 1 1 12 1 1 83.65 24.87 0.36 0.05229 0.05230 34 33 1 5 0 162.390 32.00 20.00 24.87 35.64 4.9 1100.00 -1133 -1399 -2156 -1600 556 594 1438 1028 -255 -654 296 653 124 152 -393 -451 581 460 895 581 376 1324 921 548 204 -498 -454 466 1351 1677 1434 1271 -487 -1736 -322 -679 -409 55 -935 -1555 -1029 -967 -1185 -716 -719 -924 -786 -537 50 545 675 657 782 261 792 624 286 473 798 1061 1259 1023 759 -13 -393 221 186 1161 804 -84 -57 16 103 224 76 350 106 683 -334 -995 -1377 -1730 -1415 -848 -1011 -499 -344 -263 92 3 254 447 1107 962 309 447 261 -303 -463 -243 -209 258 322 -513 -1078 -498 -624 -149 123 -28 -4 -48 130 324 725 829 507 398 -170 -467 -195 -66 165 553 615 683 1245 740 209 15 -170 -35 211 -5 -237 -117 40 -475 -188 -169 -361 -404 -561 -701 -1018 -699 233 256 645 487 -128 -323 144 337 68 85 -237 -268 348 282 560 371 239 836 582 363 134 -327 -291 283 806 1010 873 816 -311 -1101 -202 -439 -282 41 -776 -1332 -913 -852 -1052 -629 -644 -806 -677 -443 41 450 587 582 699 240 735 587 269 437 732 997 1219 1007 784 -13 -383 205 170 1063 779 -88 -60 17 107 223 72 316 92 597 -305 -990 -1424 -1860 -1548 -960 -1173 -595 -424 -318 109 3 280 467 1118 977 334 505 308 -371 -559 -290 -235 284 365 -605 -1296 -621 -793 -192 162 -37 -6 -64 164 390 851 961 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