File name: Pandora255s1_VirginiaBeachVA-CBBT_20250715_L2Fit_fout2c3d20240302p1-8.txt File generation date: 20250716T052328.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: John Anderson Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 255 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora255_OF_v2d20221206.txt Instrument calibration file used: Pandora255s1_CF_v3d20240302.txt Level 1 file used: Pandora255s1_VirginiaBeachVA-CBBT_20250715_L1_smca1c3d20240302p1-8.txt Full location name: Chesapeake Bay Bridge Tunnel Virginia Short location name: VirginiaBeachVA-CBBT Country of location: United States Location latitude [deg]: 37.0367 Location longitude [deg]: -76.0766 Location altitude [m]: 20 Local noon date: 20250715 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 195 336 Nominal wavelengths inside fitting window [nm]: 305.1318 305.2728 305.4137 305.5546 305.6955 305.8364 305.9773 306.1182 306.2590 306.3999 306.5407 306.6815 306.8224 306.9632 307.1040 307.2447 307.3855 307.5263 307.6670 307.8078 307.9485 308.0892 308.2299 308.3706 308.5113 308.6520 308.7926 308.9333 309.0739 309.2146 309.3552 309.4958 309.6364 309.7770 309.9175 310.0581 310.1986 310.3392 310.4797 310.6202 310.7607 310.9012 311.0417 311.1822 311.3227 311.4631 311.6035 311.7440 311.8844 312.0248 312.1652 312.3056 312.4459 312.5863 312.7267 312.8670 313.0073 313.1476 313.2880 313.4282 313.5685 313.7088 313.8491 313.9893 314.1296 314.2698 314.4100 314.5502 314.6904 314.8306 314.9707 315.1109 315.2511 315.3912 315.5313 315.6714 315.8115 315.9516 316.0917 316.2318 316.3718 316.5119 316.6519 316.7920 316.9320 317.0720 317.2120 317.3519 317.4919 317.6319 317.7718 317.9117 318.0517 318.1916 318.3315 318.4714 318.6113 318.7511 318.8910 319.0308 319.1706 319.3105 319.4503 319.5901 319.7299 319.8696 320.0094 320.1492 320.2889 320.4286 320.5684 320.7081 320.8478 320.9874 321.1271 321.2668 321.4064 321.5461 321.6857 321.8253 321.9649 322.1045 322.2441 322.3837 322.5232 322.6628 322.8023 322.9418 323.0813 323.2208 323.3603 323.4998 323.6393 323.7787 323.9182 324.0576 324.1970 324.3364 324.4758 324.6152 324.7546 324.8940 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250715T141201.2Z 9327.591680 270 1 32.54 2 41.48 99.37 83.50 260.41 0.00 1 0.00 1 0 17 7.712e-03 6.164e-03 1.080e-03 7.875e-04 1.856541e-01 4.182415e-04 2.192004e-03 -6.000000e+00 4.553557e-03 232.55 -2.00 3.43 -2.00 314.72 0.00e+00 1.525127e-04 3.458746e-05 1.796518e-05 -6.000000e+00 2.065688e-04 291.51 -2.00 20.00 -2.00 314.01 0.00e+00 1.333 0.000 302.00 328.00 3 4.2917e+00 1.0781e-03 1.6440e-02 -6.0000e+00 1.1407e-02 1.5939e-02 1.1918e-03 9.4774e-03 -6.0000e+00 1.2322e-02 -1.4818e-03 6.8176e-04 4.5809e-03 -6.0000e+00 7.3493e-03 -1.1395e-03 2.9657e-04 1.2482e-03 -6.0000e+00 3.1161e-03 1.5778e-03 1.1658e-04 2.2938e-05 1.7520e-05 -6.0000e+00 2.1985e-04 5.3377e-02 0.0000e+00 12 1 1 12 1 1 98.30 24.73 0.39 0.05338 0.05425 44 7 1 5 0 722.880 32.00 20.00 24.73 35.68 4.9 1100.00 -1278 -1274 -2462 -2658 183 313 943 738 -185 -443 217 260 105 380 -107 -592 963 901 306 843 580 1624 1027 757 -156 -513 -359 298 1149 1660 1544 1342 -833 -1715 -587 -657 -592 72 -723 -1292 -983 -1044 -1044 -419 -633 -883 -726 -735 -67 369 590 628 743 594 843 594 221 577 901 1081 1180 1227 880 -157 -550 303 428 1209 687 -271 -175 23 181 111 -2 5 134 554 -214 -1016 -1357 -1795 -1523 -834 -823 -485 -241 -209 3 69 428 494 1156 658 285 472 320 -358 -453 -155 -362 147 269 -624 -1165 -584 -547 7 198 45 14 35 62 292 639 759 478 183 -140 -415 -117 -11 217 582 448 585 1322 669 321 47 -187 8 102 -7 -174 -216 69 -282 -217 -240 -267 -460 -490 -495 -910 -938 59 104 345 280 -74 -176 86 111 47 180 -55 -301 493 475 167 465 318 892 561 435 -93 -305 -201 162 594 874 862 758 -490 -963 -333 -380 -376 49 -554 -1044 -796 -866 -873 -347 -521 -710 -584 -572 -53 291 493 531 655 518 746 535 199 510 789 971 1086 1172 887 -159 -533 276 375 1100 654 -276 -181 24 187 111 -2 5 114 479 -199 -985 -1400 -1916 -1649 -956 -953 -592 -295 -256 3 80 480 518 1191 683 313 536 389 -449 -561 -186 -413 164 310 -738 -1428 -743 -706 10 272 63 20 47 81 360 779 915 585 234 -187 -558 -156 -14 285 743 544 694 1548 829 412 62 -243 10 138 -9 -249 -311 102 -418 -315 -347 -374 -649 SS 20250715T184205.4Z 9327.779229 324 1 39.24 2 25.28 238.13 132.19 307.81 0.00 1 0.00 1 0 17 7.367e-03 6.259e-03 2.541e-04 2.045e-04 1.539356e-01 1.091802e-04 1.826417e-03 -6.000000e+00 4.349951e-03 232.55 -2.00 3.43 -2.00 314.10 0.00e+00 1.852262e-04 8.088920e-06 1.136492e-05 -6.000000e+00 1.973201e-04 291.53 -2.00 20.00 -2.00 313.47 0.00e+00 1.106 0.000 302.00 328.00 3 2.1215e+00 2.8003e-04 1.3636e-02 -6.0000e+00 1.0897e-02 7.3409e-03 3.0880e-04 7.8667e-03 -6.0000e+00 1.1770e-02 -5.6896e-04 1.7725e-04 3.8032e-03 -6.0000e+00 7.0205e-03 -1.2437e-03 7.5901e-05 1.0411e-03 -6.0000e+00 2.9771e-03 1.8513e-02 1.0430e-04 5.9353e-06 1.5296e-05 -6.0000e+00 2.1000e-04 5.2585e-02 0.0000e+00 12 1 1 12 1 1 99.15 24.86 0.34 0.05259 0.05337 567 77 1 5 0 68.900 32.00 20.00 24.86 36.20 5.0 1100.00 -1195 -1247 -2225 -1595 344 680 1451 745 -179 -753 222 471 150 382 -169 -322 451 621 670 581 507 1375 789 569 117 -362 -484 437 1174 1771 1452 1192 -658 -1733 -373 -677 -383 -78 -851 -1305 -1040 -988 -1126 -693 -781 -1035 -733 -591 94 631 544 607 747 405 753 628 351 542 875 1173 1164 1123 794 -130 -363 223 328 1128 732 -153 -18 -161 173 95 52 291 211 574 -220 -962 -1324 -1828 -1358 -893 -924 -543 -363 -244 -33 136 348 376 1117 891 377 468 323 -263 -415 -192 -324 220 359 -548 -1021 -578 -630 -209 165 40 -51 -12 124 293 721 777 487 298 -149 -451 -176 34 198 550 631 683 1211 623 209 53 -230 -24 151 -21 -206 -74 26 -344 -253 -179 -367 -378 -575 -605 -1021 -678 140 285 635 345 -87 -364 106 228 78 209 -96 -189 267 376 415 352 305 858 495 373 77 -235 -307 264 697 1061 881 737 -421 -1098 -226 -423 -265 -58 -687 -1119 -900 -874 -1004 -612 -684 -884 -616 -492 76 526 465 529 676 366 688 582 325 493 791 1086 1114 1122 813 -133 -350 205 296 1025 707 -159 -19 -172 179 94 50 261 181 500 -207 -955 -1369 -1970 -1489 -1015 -1076 -653 -441 -297 -40 158 384 394 1133 911 410 533 384 -325 -507 -226 -369 244 402 -639 -1242 -715 -794 -274 217 54 -68 -16 159 358 840 895 587 369 -191 -585 -232 43 248 681 759 797 1393 738 257 67 -295 -30 197 -27 -281 -101 37 -489 -354 -248 -503 -508 SS 20250715T193953.8Z 9327.819373 336 1 10.22 2 35.88 254.69 139.64 324.64 0.00 1 0.00 1 0 17 7.377e-03 6.131e-03 8.696e-04 6.696e-04 1.719963e-01 3.565901e-04 2.032500e-03 -6.000000e+00 4.356051e-03 232.55 -2.00 3.43 -2.00 314.40 0.00e+00 1.152911e-04 2.787742e-05 1.831135e-05 -6.000000e+00 1.975980e-04 291.53 -2.00 20.00 -2.00 313.73 0.00e+00 1.233 0.000 302.00 328.00 3 2.9656e+00 9.1654e-04 1.5209e-02 -6.0000e+00 1.0912e-02 8.8099e-03 1.0121e-03 8.7690e-03 -6.0000e+00 1.1787e-02 -8.1163e-04 5.7983e-04 4.2415e-03 -6.0000e+00 7.0303e-03 -1.3342e-03 2.5010e-04 1.1549e-03 -6.0000e+00 2.9813e-03 6.7584e-03 5.2441e-05 1.9460e-05 1.6677e-05 -6.0000e+00 2.1029e-04 5.2526e-02 0.0000e+00 12 1 1 12 1 1 98.33 24.91 0.32 0.05253 0.05292 57 30 1 5 0 176.100 32.00 19.99 24.91 36.14 4.9 1100.00 -1506 -936 -2366 -1855 411 533 1139 937 -214 -773 275 290 462 202 -171 -487 705 746 761 638 488 1332 853 579 111 -506 -514 316 856 1635 1327 1214 -735 -1866 -614 -490 -423 -63 -967 -1136 -1003 -743 -1071 -653 -749 -1072 -657 -743 93 680 588 580 924 396 779 580 439 582 979 1091 1133 1194 863 -19 -389 231 348 890 726 -125 -18 -110 219 89 80 231 112 649 -348 -922 -1335 -1846 -1388 -772 -965 -623 -318 -274 -103 5 308 402 969 887 313 518 296 -168 -458 -185 -372 239 365 -532 -1005 -609 -608 -166 198 99 37 -13 128 363 631 722 507 247 -88 -467 -137 28 240 589 579 615 1207 653 264 -122 -209 1 50 -48 -281 -75 15 -298 -244 -80 -304 -419 -646 -404 -972 -711 152 203 453 392 -95 -340 119 135 228 106 -93 -275 384 417 437 373 283 774 497 354 70 -320 -306 180 484 935 770 747 -451 -1140 -359 -294 -281 -46 -769 -927 -853 -626 -911 -550 -646 -904 -549 -598 74 551 489 507 814 350 696 526 397 518 890 987 1059 1164 862 -18 -380 211 312 807 696 -129 -19 -116 224 90 75 206 97 567 -319 -895 -1385 -1996 -1526 -877 -1123 -747 -393 -332 -124 5 341 425 996 919 337 597 357 -209 -567 -221 -431 270 414 -627 -1234 -760 -773 -219 269 137 51 -18 164 444 755 855 612 314 -114 -619 -180 37 307 729 697 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