File name: Pandora159s1_Wakkerstroom_20200924_L2Fit_fout2c6d20191220p1-8.txt File generation date: 20240926T164405.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: B. Scholes Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 159 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora159_OF_v5d20191004.txt Instrument calibration file used: Pandora159s1_CF_v6d20191220.txt Level 1 file used: Pandora159s1_Wakkerstroom_20200924_L1_smca1c6d20191220p1-8.txt Full location name: Global Change Institute, University of Witwatersrand field site in Wakkerstroom Short location name: Wakkerstroom Country of location: South Africa Location latitude [deg]: -27.3493 Location longitude [deg]: 30.1438 Location altitude [m]: 1760 Local noon date: 20200924 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Update session 4 based on session2 for SO2 First and last pixel inside fitting window: 222 364 Nominal wavelengths inside fitting window [nm]: 305.0490 305.1898 305.3306 305.4713 305.6121 305.7529 305.8936 306.0343 306.1750 306.3157 306.4564 306.5971 306.7378 306.8785 307.0191 307.1597 307.3004 307.4410 307.5816 307.7222 307.8628 308.0033 308.1439 308.2845 308.4250 308.5655 308.7060 308.8465 308.9870 309.1275 309.2680 309.4084 309.5489 309.6893 309.8297 309.9701 310.1105 310.2509 310.3913 310.5317 310.6720 310.8124 310.9527 311.0930 311.2333 311.3736 311.5139 311.6542 311.7944 311.9347 312.0749 312.2152 312.3554 312.4956 312.6358 312.7760 312.9161 313.0563 313.1964 313.3366 313.4767 313.6168 313.7569 313.8970 314.0371 314.1771 314.3172 314.4572 314.5973 314.7373 314.8773 315.0173 315.1573 315.2973 315.4372 315.5772 315.7171 315.8570 315.9969 316.1369 316.2767 316.4166 316.5565 316.6964 316.8362 316.9760 317.1159 317.2557 317.3955 317.5352 317.6750 317.8148 317.9545 318.0943 318.2340 318.3737 318.5134 318.6531 318.7928 318.9325 319.0721 319.2118 319.3514 319.4910 319.6307 319.7703 319.9098 320.0494 320.1890 320.3285 320.4681 320.6076 320.7471 320.8866 321.0261 321.1656 321.3051 321.4445 321.5840 321.7234 321.8628 322.0023 322.1417 322.2810 322.4204 322.5598 322.6991 322.8385 322.9778 323.1171 323.2564 323.3957 323.5350 323.6743 323.8135 323.9528 324.0920 324.2312 324.3704 324.5096 324.6488 324.7880 324.9272 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200924T041734.5Z 7572.178871 5 1 50.92 2 83.90 87.55 129.00 174.34 0.00 1 0.00 1 0 25 7.748e-01 9.456e-02 4.832e-01 4.417e-02 8.249807e-01 2.726067e-02 1.039114e-02 -6.000000e+00 4.618265e-01 227.69 -2.00 3.06 -2.00 322.21 0.00e+00 -9.395462e-03 1.468694e-02 2.386847e-02 -6.000000e+00 2.662653e-02 277.76 -2.00 20.00 -2.00 321.78 0.00e+00 8.464 0.004 302.00 328.00 3 3.0152e+00 1.0323e-01 1.6429e-01 -6.0000e+00 1.1545e+00 7.5075e-01 1.2623e-01 1.9325e-01 -6.0000e+00 1.2717e+00 -1.3320e+00 9.8237e-02 4.6766e-02 -6.0000e+00 7.3982e-01 5.9130e-01 4.9350e-02 2.0854e-02 -6.0000e+00 3.1706e-01 1.2774e-05 8.5150e-04 1.4083e-03 1.0397e-04 -6.0000e+00 2.3447e-02 6.0506e-03 0.0000e+00 12 8 8 10 0 0 47.00 18.39 1.37 0.00605 0.01245 13 3 4 8 0 3914.150 15.08 18.39 6.41 20.87 20.87 13.4 856.08 900000 -158984 900000 900000 900000 -24811 900000 -106783 900000 -84525 13636 900000 -104405 226938 186287 900000 44992 900000 -86554 900000 900000 900000 900000 900000 900000 900000 900000 214426 -70796 -29899 900000 60960 900000 -22417 117038 900000 900000 900000 900000 53428 900000 398895 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1.3213e-04 7.7061e-05 -6.0000e+00 1.3968e-02 3.9766e-03 0.0000e+00 12 9 8 11 8 0 -2.96 18.48 0.31 0.00398 -0.00400 91 20 4 8 0 542.530 15.08 18.48 8.91 20.96 20.87 12.3 864.67 -82219 900000 -207235 900000 -271768 900000 -245476 12099 -163177 -25254 -133729 -126947 -123918 -114956 900000 -38301 900000 -107325 60316 -86295 900000 -25719 62001 -46729 -28676 -14681 -32193 84609 -65569 104666 -38444 70659 1389 60910 -24305 9991 -19600 2254 10680 4865 14118 -7847 28422 -2092 16121 -10350 17026 696 15356 8868 8242 1542 5481 10158 -993 4305 -1218 8320 -6009 9286 -929 8625 2450 8050 3047 3832 4558 248 2185 -65 3060 -1924 2000 -1223 2121 1150 4916 -125 -459 -208 -669 284 -3405 -1343 -1430 223 -1317 1139 -7 812 1210 549 1630 314 164 -1515 1025 -623 376 -1131 385 -152 1951 8 -739 -1475 -2420 -617 -1083 135 -1296 -173 -636 381 -22 1432 945 678 -98 -1101 -331 -202 657 -345 1253 -428 1598 1262 1222 230 635 -131 187 681 -304 -124 -399 360 -748 -216 -265 127 97 -374 900000 -2098 900000 -4768 900000 -3447 55 -1302 -115 -916 -937 -1156 -1320 900000 -339 900000 -2410 298 -1858 900000 -322 344 -793 -441 -209 -554 467 -1559 534 -948 753 34 921 -811 236 -665 73 388 224 673 -501 1361 -140 926 -792 1042 52 1067 702 736 166 624 1214 -140 603 -185 1152 -933 1221 -139 1293 448 1594 681 851 993 58 553 -19 983 -682 676 -405 623 307 1175 -32 -132 -71 -272 131 -1796 -738 -837 137 -865 753 -4 521 728 312 880 177 104 -1131 868 -616 405 -1258 400 -144 1631 7 -665 -1420 -2476 -659 -1272 176 -1915 -270 -1013 588 -33 1996 1330 993 -153 -1804 -533 -313 971 -503 1738 -582 2060 1684 1828 394 1196 -265 395 1516 -725 -311 -1023 930 -1955 -544 -630 282 208 SS 20200924T044255.8Z 7572.196479 13 1 51.51 2 78.28 84.58 128.13 167.39 0.00 1 0.00 1 0 25 1.662e-01 5.794e-03 1.113e-01 1.776e-03 6.025314e-01 9.389020e-04 6.010128e-03 -6.000000e+00 9.458860e-02 227.69 -2.00 3.06 -2.00 320.89 0.00e+00 2.740915e-03 3.909728e-04 1.588890e-03 -6.000000e+00 4.099397e-03 277.76 -2.00 20.00 -2.00 320.36 0.00e+00 4.773 0.001 302.00 328.00 3 1.4498e+00 2.9595e-03 4.8756e-02 -6.0000e+00 2.3542e-01 2.6061e-02 3.9370e-03 3.1395e-02 -6.0000e+00 2.5575e-01 -2.6077e-02 4.0892e-03 1.4674e-02 -6.0000e+00 1.5192e-01 -4.5117e-04 2.0143e-03 5.7364e-03 -6.0000e+00 6.4461e-02 1.2703e-03 -7.2894e-04 5.0338e-05 5.4204e-05 -6.0000e+00 4.4388e-03 3.4338e-03 0.0000e+00 10 0 0 10 0 0 2.97 18.53 0.29 0.00343 -0.00204 230 49 2 8 0 214.580 15.03 18.53 10.58 20.96 20.96 12.2 873.41 -31504 -78668 26471 -71077 17664 -66126 -55929 -67094 -44375 -49360 -54293 -24079 -38452 -17747 -35353 1163 -17165 -2288 -4220 3669 -859 -7875 -6795 -11423 -6836 -18526 -6892 -10212 -1581 -4296 -406 -4295 6717 -2747 -1692 372 -3360 811 -2843 -464 -4241 -157 -3015 25 -2657 -1681 -273 -48 -622 283 1714 -448 1613 72 803 -421 906 -1730 1008 455 1665 1594 1457 998 511 1882 1135 1502 1895 1629 -463 -88 -366 325 -604 154 564 344 1104 -611 -140 -637 -1684 -946 -787 -1159 -378 -435 167 21 560 1080 756 1902 1206 841 614 552 -380 -453 -200 -24 908 841 -1513 -1181 -715 -959 -242 -300 -274 -464 -68 108 364 1043 913 506 -111 -714 -920 56 -82 -122 401 379 981 1626 441 60 135 -17 169 244 -123 -401 55 -43 -514 -258 129 -152 416 -120 -572 73 -517 49 -412 -339 -523 -315 -402 -489 -179 -413 -200 -545 17 -303 -39 -79 68 -17 -170 -151 -290 -181 -586 -199 -297 -42 -123 -13 -173 282 -138 -82 17 -176 48 -217 -42 -449 -17 -360 3 -331 -212 -35 -6 -85 41 269 -80 312 15 181 -100 220 -431 238 106 395 414 429 332 181 644 380 509 700 696 -225 -45 -186 156 -268 61 204 124 434 -288 -77 -402 -1082 -640 -566 -895 -306 -363 139 17 418 814 541 1358 957 706 596 611 -466 -562 -232 -25 855 790 -1564 -1293 -818 -1169 -318 -438 -442 -796 -117 178 562 1517 1324 768 -179 -1221 -1579 93 -129 -187 586 532 1310 2201 673 104 255 -33 354 498 -269 -930 130 -102 -1248 -604 284 -316 894 SS 20200924T044948.0Z 7572.201250 16 1 52.00 2 76.76 83.76 127.79 165.55 0.00 1 0.00 1 0 25 9.568e-02 5.794e-03 4.051e-02 1.163e-03 5.445504e-01 6.057259e-04 5.500795e-03 -6.000000e+00 5.445666e-02 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